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RESEARCH PAPER · Inorganic Chemistry Frontiers · 2024

Cation and anion co-partial substitution induced centrosymmetric to noncentrosymmetric structural transformation to construct nonlinear-optical rare-earth oxythiogermanates

Nan Zhang, Mei Yang, Wen‐Dong Yao, Wei Xu, Wenfeng Zhou, Wenlong Liu, Sheng‐Ping Guo

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Cation and anion co-partial substitution induced centrosymmetric to noncentrosymmetric structural transformation to construct nonlinear-optical rare-earth oxythiogermanatesOriginalHydrogen bond-derived symmetry transformation in hydroxyborates: Converting the nonlinearity from null to active7Rare-Earth/d10 Dual-Metal Oxychalcogenides as Infrared Nonlinear-Optical Materials10La 3 (Ga 3 S 3 O 3 )(Si 2 O 7 ): An Oxychalcogenide Demonstrating Ultrawide Optical Bandgap and Favorable Birefringence Propelled by Divergent Anionic Groups6Two-Step Substitutions of Square Pyramidal VO5 with CdO4Br to Achieve Higher Laser-Induced Damage Threshold from Polar Oxybromides Rb4CdV5O15Br to Rb3CdV4O12Br10From Centrosymmetric Ca3Ge2O3S4 to Noncentrosymmetric Ca3Ge2O4Se3: A Nonlinear Optical Ca-Based Oxyselenide5A Series of Pentanary Rare-Earth Oxysulfides Obtained by Heterovalent Cation and Anion Cosubstitution Exhibiting Nonlinear Optical Activity and Ultrawide Band Gaps1Eu(II) 4 Eu(III) 2 Ge 3 S 11 O 2 : a Single‐Element Mixed‐Valence Engineering Breakthrough for Strongly Enhanced Nonlinearity and Anisotropy in Rare‐Earth Oxysulfides8Doubling Polarizability Anisotropy of The Tetrahedral Motifs to Achieve Phase Matching for Melilite-Type Compound2Structure-property relationships in IR nonlinear optical chalcogenides with stereochemically active lone pairs29Ba-based IR nonlinear optical materials: synthesis, growth, structures, and properties6BiCe(SO 4 ) 3 (H 2 O) 3 : a non-centrosymmetric bismuth cerium( iii ) sulfate with second-order nonlinear optical activity arising from strategic heterovalent cationic substitution0Nonlinear Optical Responses in One-Dimensional Zinc Thiocyanates Functionalized with Natural Amino Acids8Heterometallic Ge–O–Sn-Bridged Oxychalcogenides Sr3GeSnO4Q3 (Q = S, Se) with Wide Band Gaps and Moderate Infrared Nonlinear Optical Responses0

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  1. Hydrogen bond-derived symmetry transformation in hydroxyborates: Converting the nonlinearity from null to active

    Materials Today Chemistry · 2024-08-29

    Ziqi Chen, Changyou Liu, Junjie Li, Zhihua Yang, Shilie Pan, Miriding Mutailipu

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  2. Rare-Earth/d10 Dual-Metal Oxychalcogenides as Infrared Nonlinear-Optical Materials

    Inorganic Chemistry · 2024-11-06

    Fang-Xu Tian, Nan Zhang, Wen‐Dong Yao, Mingyang Li, Haiping Xu, Wenlong Liu, Jing Zhu, Sheng‐Ping Guo

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  3. La 3 (Ga 3 S 3 O 3 )(Si 2 O 7 ): An Oxychalcogenide Demonstrating Ultrawide Optical Bandgap and Favorable Birefringence Propelled by Divergent Anionic Groups

    ACS Materials Letters · 2024-12-19

    Ming‐Shu Zhang, Shao‐Min Pei, Xiao‐Ming Jiang, Bin‐Wen Liu, Guo‐Cong Guo

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  4. Two-Step Substitutions of Square Pyramidal VO5 with CdO4Br to Achieve Higher Laser-Induced Damage Threshold from Polar Oxybromides Rb4CdV5O15Br to Rb3CdV4O12Br

    Inorganic Chemistry · 2025-03-24

    Baozhu Zhu, Lei Geng, Shoubao Zhang, Shuo Han, Chang‐Yu Meng, You‐Zhao Lan, Qi Wu

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  5. From Centrosymmetric Ca3Ge2O3S4 to Noncentrosymmetric Ca3Ge2O4Se3: A Nonlinear Optical Ca-Based Oxyselenide

    Inorganic Chemistry · 2025-07-09

    Rui Xiao, Wen‐Dong Yao, Wenhao Xing, Chunlan Tang, Wenwen Jiang, Sheng‐Ping Guo, Wenlong Yin

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  6. A Series of Pentanary Rare-Earth Oxysulfides Obtained by Heterovalent Cation and Anion Cosubstitution Exhibiting Nonlinear Optical Activity and Ultrawide Band Gaps

    Inorganic Chemistry · 2025-07-10

    Zhi Bing Deng, Qiu-Yang Du, Fang-Xu Tian, Zong-Ze Li, Mingyang Li, Mao‐Yin Ran, Wenlong Liu, Sheng‐Ping Guo

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  7. Eu(II) 4 Eu(III) 2 Ge 3 S 11 O 2 : a Single‐Element Mixed‐Valence Engineering Breakthrough for Strongly Enhanced Nonlinearity and Anisotropy in Rare‐Earth Oxysulfides

    Small · 2025-07-10

    Jingjing Xu, Yan Xiao, Dazhi Lu, Bingbing Zhang, Kui Wu, Haohai Yu, Huaijin Zhang

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  8. Doubling Polarizability Anisotropy of The Tetrahedral Motifs to Achieve Phase Matching for Melilite-Type Compound

    Inorganic Chemistry · 2025-08-18

    Zhi Bing Deng, Rui Xiao, Mao‐Yin Ran, Ao Guo, Xiang Chen, Wenlong Liu, Sheng‐Ping Guo

    Read original paper ↗ ·

  9. Structure-property relationships in IR nonlinear optical chalcogenides with stereochemically active lone pairs

    Coordination Chemistry Reviews · 2025-09-03

    Hong Chen, Xin‐Tao Wu, Hua Lin

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  10. Ba-based IR nonlinear optical materials: synthesis, growth, structures, and properties

    Coordination Chemistry Reviews · 2025-11-19

    Wei Huang, Chi Wang, Guohong Tang, Kexin Huang, Baojun Chen, Z. Y. He, Z. Y. He

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  11. BiCe(SO 4 ) 3 (H 2 O) 3 : a non-centrosymmetric bismuth cerium( iii ) sulfate with second-order nonlinear optical activity arising from strategic heterovalent cationic substitution

    Chemical Communications · 2026-01-01

    Zheng-Yu Yang, C. Z. Chen, Bing-Wei Miao, Yi‐Lei Lv, Wenfeng Zhou, Ming‐Yang Cao, Ru‐Ling Tang

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  12. Nonlinear Optical Responses in One-Dimensional Zinc Thiocyanates Functionalized with Natural Amino Acids

    Inorganic Chemistry · 2026-02-05

    Xuemei Wen, Qinglan Zhong, Guohong Zou, Jing Li, Zhien Lin

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  13. Heterometallic Ge–O–Sn-Bridged Oxychalcogenides Sr3GeSnO4Q3 (Q = S, Se) with Wide Band Gaps and Moderate Infrared Nonlinear Optical Responses

    Inorganic Chemistry · 2026-07-25

    Cihai Hong, Aoge Yao, Chunlan Tang, Zhihui Zhang, Jian Tang, Lei Kang, Jing Ling Zhao, Wenlong Yin, Bin Kang

    Read original paper ↗ ·
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