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RESEARCH PAPER · ACS Catalysis · 2022

Processive Depolymerization Catalysts: A Population Balance Model for Chemistry’s “While” Loop

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Processive Depolymerization Catalysts: A Population Balance Model for Chemistry’s “While” LoopOriginalPopulation balance models for polymer upcycling: signatures of the mechanism in the molecular weight evolution22Competing Time Scales in Surface-Driven Solution Depolymerization2Mass transfer in catalytic depolymerization: External effectiveness factors and serendipitous processivity in stagnant and stirred melts31Molecular-Weight-Dependent Infiltration and Adsorption of Polymers into Nanochannels10Mechanistic Insights into Processive Polyethylene Hydrogenolysis throughIn SituNMR25Two Mesoporous Domains Are Better Than One for Catalytic Deconstruction of Polyolefins62Chemical Recycling of Polybutadiene Rubber with Tailored Depolymerization Enabled by Microencapsulated Metathesis Catalysts16Influence of Pore Length on Hydrogenolysis of Polyethylene within a Mesoporous Support Architecture17Catalytic Hydrogenolysis of Polyethylene Under Reactive Separation46Population Balance Equations for Reactive Separation in Polymer Upcycling20The Overlooked Potential of Sulfated Zirconia: Reexamining Solid Superacidity Toward the Controlled Depolymerization of Polyolefins11Layered self-pillared zeolites convert polyethylene to gasoline6Chemical Upcycling of Polyolefin Plastics Using Structurally Well-defined Catalysts35How Depolymerization‐Based Plasticization Affects the Process of Cold Crystallization in Poly(P‐Dioxanone)2Kinetic Models for Polymer Upcycling by Tag-and-Cut Strategies6Pushing forward kinetic modeling tools for polymer circularity design and recycling15Polymer Molecular Weight Distributions: A Tutorial on Transformations between Number Density, Mass Density, and Linear/Logarithmic Axes4Population Balance Models for Catalytic Depolymerization: From Elementary Steps to Multiphase Reactors8Enlightening the Depolymerization Kinetic Mechanism in Reversed Atom Transfer Radical Polymerization via In Silico Modeling3

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  1. Population balance models for polymer upcycling: signatures of the mechanism in the molecular weight evolution

    Journal of Materials Chemistry A · 2022-01-01

    Ryan D. Yappert, Baron Peters

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  2. Competing Time Scales in Surface-Driven Solution Depolymerization

    Macromolecules · 2022-10-14

    Whitney C. Blocher McTigue, Charles E. Sing

    Read original paper ↗ ·
  3. Mass transfer in catalytic depolymerization: External effectiveness factors and serendipitous processivity in stagnant and stirred melts

    Chemical Engineering Journal · 2023-05-03

    Jiankai Ge, Baron Peters

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  4. Molecular-Weight-Dependent Infiltration and Adsorption of Polymers into Nanochannels

    ACS Applied Materials & Interfaces · 2023-05-23

    Xingyi Lyu, Max Meirow, Xun Wei Wu, Xinwei Zhou, Yuzi Liu, Wenyu Huang, Tao Li, Byeongdu Lee

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  5. Mechanistic Insights into Processive Polyethylene Hydrogenolysis throughIn SituNMR

    Macromolecules · 2023-05-30

    Yunpu Zhao, Max Meirow, Akalanka Tennakoon, Xun Wei Wu, Alexander L. Paterson, Long Hao Qi, Anne M. LaPointe, Jessica V. Lamb, Takeshi Kobayashi, Massimiliano Delferro, Aaron David Sadow, Wenyu Huang, Erik Luijten, Frédéric A. Perras

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  6. Two Mesoporous Domains Are Better Than One for Catalytic Deconstruction of Polyolefins

    Journal of the American Chemical Society · 2023-08-04

    Akalanka Tennakoon, Xun Wei Wu, Max Meirow, Daniel Howell, Jarod Willmon, Jiaqi Yu, Jessica V. Lamb, Massimiliano Delferro, Erik Luijten, Wenyu Huang, Aaron David Sadow

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  7. Chemical Recycling of Polybutadiene Rubber with Tailored Depolymerization Enabled by Microencapsulated Metathesis Catalysts

    ACS Sustainable Chemistry & Engineering · 2023-09-25

    Matthew J. Warner, James P. Lassa, Hannah L. Narcross, Alex J. Commisso, Koushik Ghosh, Mikayla Romero, Jared M. Schwartz, Anthony Christian Engler, Paul A. Kohl, Samuel C. Leguizamon, Brad H. Jones

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  8. Influence of Pore Length on Hydrogenolysis of Polyethylene within a Mesoporous Support Architecture

    The Journal of Physical Chemistry C · 2023-12-01

    Max Meirow, Akalanka Tennakoon, Xun Wei Wu, Jarod Willmon, Daniel Howell, Wenyu Huang, Aaron David Sadow, Erik Luijten

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  9. Catalytic Hydrogenolysis of Polyethylene Under Reactive Separation

    ACS Catalysis · 2024-01-24

    Yi‐Yu Wang, Akalanka Tennakoon, Xun Wei Wu, Chinmay Sahasrabudhe, Long Hao Qi, Baron Peters, Aaron David Sadow, Wenyu Huang

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  10. Population Balance Equations for Reactive Separation in Polymer Upcycling

    Langmuir · 2024-02-13

    Changhae Andrew Kim, Chinmay Sahasrabudhe, Yiyu Wang, Ryan D. Yappert, Andreas Heyden, Wenyu Huang, Aaron David Sadow, Baron Peters

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  11. The Overlooked Potential of Sulfated Zirconia: Reexamining Solid Superacidity Toward the Controlled Depolymerization of Polyolefins

    Langmuir · 2024-03-21

    Scott R. Cleary, Anne K. Starace, Caleb C. Curran-Velasco, Daniel A. Ruddy, C. Michael McGuirk

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  12. Layered self-pillared zeolites convert polyethylene to gasoline

    Nature Chemistry · 2024-05-28

    Chris Torres, Julie E. Rorrer

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  13. Chemical Upcycling of Polyolefin Plastics Using Structurally Well-defined Catalysts

    JACS Au · 2024-06-04

    Simin Sun, Wenyu Huang

    Read original paper ↗ ·
  14. How Depolymerization‐Based Plasticization Affects the Process of Cold Crystallization in Poly(P‐Dioxanone)

    Macromolecular Rapid Communications · 2024-06-25

    Roman Svoboda, Jana Machotová

    Read original paper ↗ ·
  15. Kinetic Models for Polymer Upcycling by Tag-and-Cut Strategies

    Industrial & Engineering Chemistry Research · 2024-12-06

    Emmanuel Ejiogu, Baron Peters

    Read original paper ↗ ·
  16. Pushing forward kinetic modeling tools for polymer circularity design and recycling

    Fundamental Research · 2025-01-30

    Jiang Wang, Tiantian Wang, Robert Conka, Dagmar D’hooge, Zheng‐Hong Luo, Yin‐Ning Zhou

    Read original paper ↗ ·
  17. Polymer Molecular Weight Distributions: A Tutorial on Transformations between Number Density, Mass Density, and Linear/Logarithmic Axes

    Industrial & Engineering Chemistry Research · 2025-02-06

    Ziqiu Chen, Changhae Andrew Kim, Yiyu Wang, Aaron David Sadow, Anne M. LaPointe, Baron Peters

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  18. Population Balance Models for Catalytic Depolymerization: From Elementary Steps to Multiphase Reactors

    Accounts of Chemical Research · 2025-05-16

    Lela K. Manis, Jiankai Ge, Changhae Andrew Kim, Emmanuel Ejiogu, Ziqiu Chen, Ryan D. Yappert, Baron Peters

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  19. Enlightening the Depolymerization Kinetic Mechanism in Reversed Atom Transfer Radical Polymerization via In Silico Modeling

    Macromolecules · 2025-08-29

    Jiang Wang, Tiantian Wang, Chao Bian, Zheng‐Hong Luo, Yin‐Ning Zhou

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