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RESEARCH PAPER · Inorganic Chemistry · 2025

SnHPO4: A Layered Tin(II) Phosphate with Enhanced Birefringence

Xinyue Shi, Xueqing Liu, Chunxiao Nie, Yangkai Zhang, Degao Zhong, Bing Teng, Zhoubin Lin, Yisheng Huang, Shijia Sun

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SnHPO4: A Layered Tin(II) Phosphate with Enhanced BirefringenceOriginalHg 2 (HTe 2 O 5 )(PO 4 ): a novel phosphate crystal with enhanced birefringence enabled by the synergistic modification of multiple functional groups12Identification of interstitial oxygen color centers in CaGdAlO 4 single crystals and their elimination strategy1Two alkali metal borates built by {Li@B 14 } and {B 15 } cluster units1Sb2(TeO4)(SO4): An Anhydrous Tellurite Sulfate with Large Birefringence and Enhanced Thermal Stability8Giant Birefringence Enabled by the Highly Anisotropic Linear IX 2 − (X = Cl, Br) Building Blocks6Giant Birefringence Enabled by the Highly Anisotropic Linear IX 2 − (X = Cl, Br) Building Blocks33Cd-Based Coordination Frameworks with Multiple Optical Properties: Tunable RTP, Photochromism, and SHG Efficiency12Two Halobismuthates Decorated by Cesium and N-Methylated Isonicotinato: Crystal Architectures, Optical/Photoelectrical Performances, and Theoretical Insights5All-Optical Broadband Terahertz Modulator Based on CsPbX3(X = Cl, Br) Perovskite Quantum Dots Heterostructure6Superionic Transition in Mixed Conducting Graphite Intercalation Compounds CsC 8 and RbC 84Remarkable Birefringence Enhancement Enabled by π-Conjugated Cyanoguanidine Group Based on Anisotropic Molecule Coordination Approach8Sc3+-doped host modulation enhances the spectroscopy and laser properties of Yb3+:ScYPO4 crystal0Ag(Te 2 O 3 )(PO 4 ): Linear and Nonlinear Optical Properties of a Noncentrosymmetric Phosphotellurite with P–O–Te Connection1K 6 Mo 8 PO 29 OH·H 2 O and K 6 Mo 5 P 2 O 23 ·7H 2 O: strongly distorted [MoO 6 ] octahedral groups effectively enhance birefringence0Room temperature phosphorescence and photochromism in a series of pyridine-based hybrid compounds2Chiral-Unit-Driven Short-Wave Ultraviolet Nonlinear Optical Acetates with Balanced Overall Optical Properties3Synergistic engineering of hollow flower-like Co9S8/MoS2 heterostructures with N/S co-doped and carbon coating layer for enhanced sodium storage4A multi-scale birefringence modulation strategy in DUV/UV crystals induced by organic cations1A polyoxovanadate-based metal–organic framework unlocks the potential for advanced calcium-ion storage0Achieving giant optical anisotropy in the mid-far infrared region via ideal alignment of dual functional motifs0Application of nanogenerators in oral and respiratory systems: a review0Flexible and high-color-rendering electroluminescent device via self-adsorptive carbon quantum dots13Interfacial stabilization of quantum dot/liquid crystal co-assemblies for efficient circularly polarized luminescence0Rational design of large birefringence infrared oxychalcogenides via heteroanionic octahedron engineering0Microwave-terahertz response of H3BO3-added CaAlB2O5.5 ceramics sintered at low temperature for patch antenna application1Selenium-Based Molecular Cage Crystal β-P 4 Se 3 Br 2 : A Promising Candidate for Infrared Nonlinear Optical Applications1(C 6 H 7 N 2 O)NO 3 : π-Conjugation-Driven Synergistic Enhancement of Second-Harmonic Generation and Birefringence0Unveiling the Superior Birefringence Property of a Record‐Birefringent Crystal with Unique Building Block13Unveiling the Superior Birefringence Property of a Record‐Birefringent Crystal with Unique Building Block4Enhancing the performance of PMN-PT transparent piezoelectric ceramics by multi-rare earth doping based on the high-entropy strategy6Excitation-Controlled Singlet–Triplet Channel Redistribution in a Stable 0D Sn(II) Hybrid Halide0Li 6 Lu(BO 3 ) 3 : A Rare-Earth Borate Crystal Exhibiting Large Birefringence and Broad UV Transparency1Environmental-adaptable near perfect chirality with ultra-high Q-factor based on BIC metasurface2Fluxes optimization of Yb3+/Er3+:GdMgB5O10 crystal and 1.5–1.6 μm CW laser properties0Hydrogen‐Bond‐Directed Assembly of Urea Derivatives: Exceptional Birefringence Achieved by π ‐Conjugated Unit Alignment3Gd3+ synergistic sensitization in Tb3+-doped LBSO glasses: influence of cluster dispersion and energy transfer on luminescence and X-ray detection0K 2 ZrSi 2 O 7 with a Wide Transmission Range and Enhanced Birefringence Induced by the d 0 -TM Zr-Based Units2Synergistic Interfacial Charge Storage and Transfer Mechanisms for Extra Capacity in Mn‐Based Oxide Anodes0The novel Zn-based ultraviolet birefringent crystals combined both large birefringence and wide bandgap2Highly sensitive optical thermometer based on dual-site luminescence of Sr3SiO4F2: Eu2 + for CPU temperature visualization0Optical Modulation of Near‐Infrared‐Emitting KNN‐ x Nd Transparent Photochromic Ceramics0Simultaneous Improvement of Bendability and Passive Daytime Radiative Cooling Performance in Multilayer Alumina Fiber Membranes0Boron-Doped Graphite Intercalation Compounds as Mixed Ionic–Electronic Conductors0A super-long near-infrared persistent luminescent material BaMgAl6Ga4O17:Cr3+0Deep-sea self-powered system based on pressure-adaptive balloon triboelectric nanogenerator0Symmetry Breaking Induced by Hydration-Number Tuning Enables Second-Order Nonlinear Optical Responses in Lanthanum Sulfate Hydrates0Deep‐Learning‐Assisted Design of Dynamically Tunable Near‐Infrared Dual‐Band Lithium Niobate Metamaterial Absorber for Optical Communication0Synthesis of morphologically different SnHPO 4 using a refluxing method0Reversible Symmetry Switching, Giant Birefringence, and UV Second‐Harmonic Generation in Hybrid Niobium Oxyfluorides0Reversible Symmetry Switching, Giant Birefringence, and UV Second‐Harmonic Generation in Hybrid Niobium Oxyfluorides0Potential Deep Ultraviolet Phosphate With Y‐Based: 1 [(PO 3 ) 4 ] ∞ Chains AYP 4 O 12 (A = K, NH 4 ) and the First [P 3 O 10 ] Anionic Framework KLiYP 3 O 100

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  1. Hg 2 (HTe 2 O 5 )(PO 4 ): a novel phosphate crystal with enhanced birefringence enabled by the synergistic modification of multiple functional groups

    Inorganic Chemistry Frontiers · 2025-01-01

    Pengfei Li, Chun‐Li Hu, Bo Zhang, Jiang‐Gao Mao, Fang Kong

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  2. Identification of interstitial oxygen color centers in CaGdAlO 4 single crystals and their elimination strategy

    CrystEngComm · 2025-01-01

    Fazheng Huang, Xiao Hui Lin, Qingyi Liu, Yu Jing Yan, Dongfeng Xue, Lingyun Li

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  3. Two alkali metal borates built by {Li@B 14 } and {B 15 } cluster units

    Dalton Transactions · 2025-01-01

    Mian Li, Dan Qin, Juan Chen, Qi Wei, Guo‐Yu Yang

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  4. Sb2(TeO4)(SO4): An Anhydrous Tellurite Sulfate with Large Birefringence and Enhanced Thermal Stability

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    Xi-Ming Dong, Kai Huang, Hui‐Yan Zhao, Chao He, Xing‐Tao An, Qi Wei, Guo‐Yu Yang

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  5. Giant Birefringence Enabled by the Highly Anisotropic Linear IX 2 − (X = Cl, Br) Building Blocks

    Angewandte Chemie · 2025-04-16

    Chong‐An Chen, Yang Li, Hongbo Huang, Congcong Jin, Bingbing Zhang, Kang Min Ok

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  6. Giant Birefringence Enabled by the Highly Anisotropic Linear IX 2 − (X = Cl, Br) Building Blocks

    Angewandte Chemie International Edition · 2025-04-16

    Chong‐An Chen, Yang Li, Hongbo Huang, Congcong Jin, Bingbing Zhang, Kang Min Ok

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  7. Cd-Based Coordination Frameworks with Multiple Optical Properties: Tunable RTP, Photochromism, and SHG Efficiency

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  8. Two Halobismuthates Decorated by Cesium and N-Methylated Isonicotinato: Crystal Architectures, Optical/Photoelectrical Performances, and Theoretical Insights

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  9. All-Optical Broadband Terahertz Modulator Based on CsPbX3(X = Cl, Br) Perovskite Quantum Dots Heterostructure

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  10. Superionic Transition in Mixed Conducting Graphite Intercalation Compounds CsC 8 and RbC 8

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  11. Remarkable Birefringence Enhancement Enabled by π-Conjugated Cyanoguanidine Group Based on Anisotropic Molecule Coordination Approach

    The Journal of Physical Chemistry Letters · 2025-10-24

    Xinyue Shi, Xueqing Liu, Ying Su, Yangkai Zhang, Yong Wu, Run Li, Degao Zhong, Bing Teng, Yisheng Huang, Zhoubin Lin, Shijia Sun

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  12. Sc3+-doped host modulation enhances the spectroscopy and laser properties of Yb3+:ScYPO4 crystal

    Infrared Physics & Technology · 2025-11-22

    Ziliang Zhu, Hua Zheng, Chunxiao Nie, Bingtao Zhang, Junjun Zhao, Degao Zhong, Honghao Xu, Shijia Sun

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  13. Ag(Te 2 O 3 )(PO 4 ): Linear and Nonlinear Optical Properties of a Noncentrosymmetric Phosphotellurite with P–O–Te Connection

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    Wei Chen, Zi-Xuan Zhao, Chao He, Mengjiao Xu, Hui‐Yan Zhao, Qi Wei, Guo‐Ming Wang

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  14. K 6 Mo 8 PO 29 OH·H 2 O and K 6 Mo 5 P 2 O 23 ·7H 2 O: strongly distorted [MoO 6 ] octahedral groups effectively enhance birefringence

    Materials Chemistry Frontiers · 2025-12-09

    Jianlong Huang, Wenhu Wang, Juanjuan Lu, Feng Yu, Jian Wei Han

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  15. Room temperature phosphorescence and photochromism in a series of pyridine-based hybrid compounds

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  16. Chiral-Unit-Driven Short-Wave Ultraviolet Nonlinear Optical Acetates with Balanced Overall Optical Properties

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  17. Synergistic engineering of hollow flower-like Co9S8/MoS2 heterostructures with N/S co-doped and carbon coating layer for enhanced sodium storage

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  18. A multi-scale birefringence modulation strategy in DUV/UV crystals induced by organic cations

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  19. A polyoxovanadate-based metal–organic framework unlocks the potential for advanced calcium-ion storage

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  48. Synthesis of morphologically different SnHPO 4 using a refluxing method

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  50. Reversible Symmetry Switching, Giant Birefringence, and UV Second‐Harmonic Generation in Hybrid Niobium Oxyfluorides

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