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RESEARCH PAPER · Inorganic Chemistry · 2022

Organic–Inorganic Hybrid Noncentrosymmetric (Morpholinium) 2 Cd 2 Cl 6 Single Crystals: Synthesis, Nonlinear Optical Properties, and Stability

Defu Sun, Duanliang Wang, Yangyang Dang, Shoubao Zhang, Hanzhang Chen, Ruoxian Hou, Kui Wu, Chuanying Shen

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Organic–Inorganic Hybrid Noncentrosymmetric (Morpholinium) 2 Cd 2 Cl 6 Single Crystals: Synthesis, Nonlinear Optical Properties, and StabilityOriginalA novel 2-(aminomethyl)pyridineH 2 PO 4 crystal with second-order nonlinear optical performance8Organic Cation Modulation Triggered Second Harmonic Response in Manganese Halides with Bright Fluorescence46New Low-Dimensional Lead-Free Perovskite (2-AMP)2BiX7·H2O (X = Cl, Br) Crystals: Synthesis, Stability, and Nonlinear Optical Properties27(C4H10NO)PbX3 (X = Cl, Br): Design of Two Lead Halide Perovskite Crystals with Moderate Nonlinear Optical Properties35Characteristics of structure, thermal stability and optical properties for a novel NLO crystal (C5H12NO)H2PO48Investigating the structure and optical characteristics of two new organic-inorganic hybrid crystals3Facile Synthesis of ZIF-67 for the Adsorption of Methyl Green from Wastewater: Integrating Molecular Models and Experimental Evidence to Comprehend the Removal Mechanism48Sn( ii )-doped one-dimensional hybrid metal halide [C 5 H 14 NO]CdCl 3 single crystals with broadband greenish-yellow light emission17Chiral metal–organic frameworks for photonics132From H 12 C 4 N 2 CdI 4 to H 11 C 4 N 2 CdI 3 : a highly polarizable CdNI 3 tetrahedron induced a sharp enhancement of second harmonic generation response and birefringence50Two pairs of chiral Yb III enantiomers presenting distinct NIR luminescence and circularly polarized luminescence performances with giant differences in second-harmonic generation responses20The synthesis, structure and photoluminescence of new (C8H18N)2CdCl4 crystals9Design, crystal growth and characterizations of novel bis morpholinium zinc bromide single crystals for optoelectronic applications13Exploring the thermo-stability and optical characteristics of (Morpholine)2SbCl5 crystal with a non-centrosymmetric structure6A two-fold interpenetrated mixed-ligands acentric 3D coordination polymer Zn(OBA)(DIB)·0.5H2O: Topological analysis, fluorescent and second-order NLO properties7A review of the relationship between the structure and nonlinear optical properties of organic-inorganic hybrid materials149(C 13 N 3 H 14 ) 2 MBr 4 (M = Zn, Cd): two novel hybrid metal halides with balanced integrated nonlinear optical performance311D Cu( i )-based chiral organic–inorganic hybrid material with second harmonic generation and circular polarized luminescence10Advancing nonlinear optics: discovery and characterization of new non-centrosymmetric phenazine-based halides6Halide-driven polarity tuning and optimized SHG-bandgap balance in (C 4 H 11 N 2 )ZnX 3 (X = Cl, Br, I)34From C4H7N2Ge0.4Sn0.6Br3 to C6H11N2Ge0.4Sn0.6Br3: Effective Modulation of the Second Harmonic Generation Effect and Optical Band Gap by Planar π-Conjugated Organic Cation Size11Structural Elucidation of Electrical and Optical Properties in Lead‐free Organic‐Inorganic Copper Bromide [(CH 3 ) 4 N] 2 CuBr 4 Single Crystals2Chiral Organic Cations and Distorted Inorganic Polyhedra Composing Metal Halide Nonlinear Optical Materials22Tunability of Photovoltaic Functions via Halogen Substitution [(Ade)2 CdX4](X = Cl, Br): A Class of Three-Dimensional Organic–Inorganic Hybrid Materials9Investigations of structure, thermal stability and optical properties of a new NLO crystal (C3H5N2)+(CF3COO)-0Growth, structure, spectral, optical, dielectric, and thermal studies on morpholinium 2,4,6-trinitrophenolate: an organic nonlinear optical crystal12Bismorpholin-4-ium tetrabromo-cadmium metal-organic single crystal delivering Crystal structure, physicochemical properties and Characterizations for Optoelectronic Applications8The synthesis, structures and characterizations of (C5H12NO)4Cd3Cl10·2H2O and (C5H12NO)2BiCl6·H5O2 crystals0Strategically designed anisotropic organic–inorganic metal halides (OIMHs) with superior balance between bandgap and birefringence12An Investigation into the Structure, Microhardness and Opto-Electrical Properties in Lead-Free [C3h7nh3]2bicl5 Single Crystals Using Both Experimental and Theoretical Approaches0Halogen-regulating synthesis of a novel semiconductor hybrid material [(CH 3 ) 3 N(CH 2 ) 3 Br] 2 ZnBr 4 with high-temperature phase transition4Toward the Strongest Nonlinear Optical Response and Largest Birefringence in Solvent‐Free Organic–Inorganic Metal Halides by Hydrogen Bond Engineering39Multifunctional Cd‐based Hybrid with Large Birefringence Achieving Excellent Second Harmonic Generation and Reversible Temperature‐Activated Fluorescence for Anti‐counterfeiting16An investigation into the structure, microhardness, intermolecular interactions, electrical and optical properties in lead-free (CH3CH2CH2NH3)2[BiCl5] single crystals for optoelectronic applications1Designing hybrid zinc-based ultraviolet nonlinear optical crystal with strong NLO response and dual-color luminescence via the integration of two different SHG-active genes6Design, crystallographic, thermal, and optical studies of novel metal-organic and inorganic hybrid single crystal: 1,4-diazabicyclo[2.2.2]octane-1,4-diium hexaaqua-nickel sulfate1Low‐Dimensional Organic–Inorganic Hybrid Metal Halide with Large Optical Anisotropy9Bio-inspired one-dimensional cadmium halide stabilized by cytosinium: Structural, spectroscopic and theoretical investigations1Coordination‐Induced Amplification of Birefringence and Nonlinear Optical Response in a Chiral Metal–Organic Framework6Coordination‐Induced Amplification of Birefringence and Nonlinear Optical Response in a Chiral Metal–Organic Framework11[CdCl 2 (4-Aminopyridine) 2 ] n : Synergistic Enhancement of Second-Harmonic Generation and Birefringence Enabled by a π-Conjugated Ligand for UV Nonlinear Optics5Halogen Engineering and Orbital Origins of Large Second-Harmonic Generation in Organic–Inorganic Hybrid Metal Halides2Entropy‐Driven Precursor Symmetry Breaking for Phase‐Selective Synthesis of Noncentrosymmetric Rb 2 CdCl 2 I 20

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  1. A novel 2-(aminomethyl)pyridineH 2 PO 4 crystal with second-order nonlinear optical performance

    CrystEngComm · 2022-01-01

    Duanliang Wang, Defu Sun, Shoubao Zhang, Jiancai Leng, Ruoxian Hou, Hanzhang Chen, Jie Sun, Yangyang Dang, Chuanying Shen

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  2. Organic Cation Modulation Triggered Second Harmonic Response in Manganese Halides with Bright Fluorescence

    Inorganic Chemistry · 2022-07-20

    Yue Guo, Jiajing Wu, Wenlong Liu, Sheng‐Ping Guo

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  3. New Low-Dimensional Lead-Free Perovskite (2-AMP)2BiX7·H2O (X = Cl, Br) Crystals: Synthesis, Stability, and Nonlinear Optical Properties

    Inorganic Chemistry · 2022-09-12

    Defu Sun, Duanliang Wang, Hanzhang Chen, Ruoxian Hou, Yangyang Dang, Kui Wu, Jiyang Wang, Chuanying Shen

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  4. (C4H10NO)PbX3 (X = Cl, Br): Design of Two Lead Halide Perovskite Crystals with Moderate Nonlinear Optical Properties

    Inorganic Chemistry · 2022-10-07

    Chuanying Shen, Defu Sun, Yangyang Dang, Kui Wu, Tianxiang Xu, Ruoxian Hou, Hanzhang Chen, Jiyang Wang, Duanliang Wang

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  5. Characteristics of structure, thermal stability and optical properties for a novel NLO crystal (C5H12NO)H2PO4

    Optical Materials · 2022-11-27

    Duanliang Wang, Xiangsheng Meng, Nana Zhang, Defu Sun, Ruoxian Hou, Hanzhang Chen, Xiaobing Liu

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  6. Investigating the structure and optical characteristics of two new organic-inorganic hybrid crystals

    Optik · 2022-11-29

    Ruoxian Hou, Hanzhang Chen, Defu Sun, Nana Zhang, Chuanying Shen, Duanliang Wang

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  7. Facile Synthesis of ZIF-67 for the Adsorption of Methyl Green from Wastewater: Integrating Molecular Models and Experimental Evidence to Comprehend the Removal Mechanism

    Molecules · 2022-12-01

    Muniba Ikram, Sadaf Mutahir, Muhammad Humayun, Muhammad Asim Khan, Jehan Y. Al‐Humaidi, Moamen Salah El-Deen Refat, Amr Salah Abouzied

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  8. Sn( ii )-doped one-dimensional hybrid metal halide [C 5 H 14 NO]CdCl 3 single crystals with broadband greenish-yellow light emission

    Dalton Transactions · 2022-12-17

    Haiming Cheng, Chi Cao, Shiyong Teng, Zhinan Zhang, Ying Zhang, Dayang Wang, Wensheng Yang, Renguo Xie

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  9. Chiral metal–organic frameworks for photonics

    Chemical Society Reviews · 2023-01-01

    Lyndon A. Hall, Deanna M. D’Alessandro, Girish Lakhwani

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  10. From H 12 C 4 N 2 CdI 4 to H 11 C 4 N 2 CdI 3 : a highly polarizable CdNI 3 tetrahedron induced a sharp enhancement of second harmonic generation response and birefringence

    Chemical Science · 2023-01-01

    Huai‐Yu Wu, Chun‐Li Hu, Miao‐Bin Xu, Qianqian Chen, Nan Ma, Xiao‐Ying Huang, Ke‐Zhao Du, Jin Chen

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  11. Two pairs of chiral Yb III enantiomers presenting distinct NIR luminescence and circularly polarized luminescence performances with giant differences in second-harmonic generation responses

    Dalton Transactions · 2023-01-01

    Xiaodi Du, Zhiqiang Zhang, Congli Gao, Fengcai Li, Xi-Li Li

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  12. The synthesis, structure and photoluminescence of new (C8H18N)2CdCl4 crystals

    Journal of Molecular Structure · 2023-02-23

    Duan-Liang Wang, Defu Sun, Longyun Xu, Jie Liu, Jiyang Wang, Chuanying Shen

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  13. Design, crystal growth and characterizations of novel bis morpholinium zinc bromide single crystals for optoelectronic applications

    Optical Materials · 2023-03-31

    Thiyagarajan Maadhu, G. Vinitha

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  14. Exploring the thermo-stability and optical characteristics of (Morpholine)2SbCl5 crystal with a non-centrosymmetric structure

    Optical Materials · 2023-04-24

    Duanliang Wang, Ruoxian Hou, Jialin Chen, Defu Sun, Hanzhang Chen, Chuanying Shen

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  15. A two-fold interpenetrated mixed-ligands acentric 3D coordination polymer Zn(OBA)(DIB)·0.5H2O: Topological analysis, fluorescent and second-order NLO properties

    Journal of Molecular Structure · 2023-09-05

    Jian‐Di Lin, Zhenfei Li, Zu‐Jin Lin, Fa‐Kun Zheng

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  16. A review of the relationship between the structure and nonlinear optical properties of organic-inorganic hybrid materials

    Coordination Chemistry Reviews · 2023-10-06

    Yuwei Kang, Qi Wu

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  17. (C 13 N 3 H 14 ) 2 MBr 4 (M = Zn, Cd): two novel hybrid metal halides with balanced integrated nonlinear optical performance

    Inorganic Chemistry Frontiers · 2024-01-01

    Jiajing Wu, Yifan Fu, Wenlong Liu, Sheng‐Ping Guo

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  18. 1D Cu( i )-based chiral organic–inorganic hybrid material with second harmonic generation and circular polarized luminescence

    Dalton Transactions · 2024-01-01

    Zhiyuan Wu, Muxin Yu, Ziqing Zhang, Jiaxin Jiang, Ting Liu, Feilong Jiang, Lian Chen, Maochun Hong

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  19. Advancing nonlinear optics: discovery and characterization of new non-centrosymmetric phenazine-based halides

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    Yibo Cui, Jindong Cao, Jiawei Lin, Chunxiao Li, Jiyong Yao, Kunjie Liu, An Hou, Zhongnan Guo, Jing Wei Zhao, Quanlin Liu

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  20. Halide-driven polarity tuning and optimized SHG-bandgap balance in (C 4 H 11 N 2 )ZnX 3 (X = Cl, Br, I)

    Inorganic Chemistry Frontiers · 2024-01-01

    Jin Chen, Huai-Yu Wu, Miao‐Bin Xu, Mingchang Wang, Qianqian Chen, Bingxuan Li, Chun‐Li Hu, Ke‐Zhao Du

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  21. From C4H7N2Ge0.4Sn0.6Br3 to C6H11N2Ge0.4Sn0.6Br3: Effective Modulation of the Second Harmonic Generation Effect and Optical Band Gap by Planar π-Conjugated Organic Cation Size

    Inorganic Chemistry · 2024-01-22

    Yuwei Kang, Can Yang, Jie Gou, Yaolong Zhu, Qingwen Zhu, Qi Wu

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  22. Structural Elucidation of Electrical and Optical Properties in Lead‐free Organic‐Inorganic Copper Bromide [(CH 3 ) 4 N] 2 CuBr 4 Single Crystals

    ChemistrySelect · 2024-03-07

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  23. Chiral Organic Cations and Distorted Inorganic Polyhedra Composing Metal Halide Nonlinear Optical Materials

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  24. Tunability of Photovoltaic Functions via Halogen Substitution [(Ade)2 CdX4](X = Cl, Br): A Class of Three-Dimensional Organic–Inorganic Hybrid Materials

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    Meixia Lv, Hongzhi Hu, Adila Abuduheni, Yibo Yan, Yang Liu, Zunqi Liu

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  25. Investigations of structure, thermal stability and optical properties of a new NLO crystal (C3H5N2)+(CF3COO)-

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  26. Growth, structure, spectral, optical, dielectric, and thermal studies on morpholinium 2,4,6-trinitrophenolate: an organic nonlinear optical crystal

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  27. Bismorpholin-4-ium tetrabromo-cadmium metal-organic single crystal delivering Crystal structure, physicochemical properties and Characterizations for Optoelectronic Applications

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  28. The synthesis, structures and characterizations of (C5H12NO)4Cd3Cl10·2H2O and (C5H12NO)2BiCl6·H5O2 crystals

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  29. Strategically designed anisotropic organic–inorganic metal halides (OIMHs) with superior balance between bandgap and birefringence

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  30. An Investigation into the Structure, Microhardness and Opto-Electrical Properties in Lead-Free [C3h7nh3]2bicl5 Single Crystals Using Both Experimental and Theoretical Approaches

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  31. Halogen-regulating synthesis of a novel semiconductor hybrid material [(CH 3 ) 3 N(CH 2 ) 3 Br] 2 ZnBr 4 with high-temperature phase transition

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  41. [CdCl 2 (4-Aminopyridine) 2 ] n : Synergistic Enhancement of Second-Harmonic Generation and Birefringence Enabled by a π-Conjugated Ligand for UV Nonlinear Optics

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