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RESEARCH PAPER · Chemical Society Reviews · 2023

Chiral metal–organic frameworks for photonics

Lyndon A. Hall, Deanna M. D’Alessandro, Girish Lakhwani

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Chiral metal–organic frameworks for photonicsOriginalAn amine decorated MOF for direct capture of CO 2 from ambient air13Enhanced circularly polarized luminescence dissymmetry of [Ru(bpy) 3 ] 2+ complexes in a 3D chiral framework: a study of transparent thin films4Fabrication of a bifunctional fluorescent chiral composite based on magnetic Fe3O4/chiral carbon dots@hierarchical porous metal-organic framework15Hydrogen-bonded metal-organic frameworks with multilevel chirality and strong circular dichroism response for circular polarization luminescence2Conjugation‐Induced Spin Delocalization in Helical Chiral Carbon Radicals via Through‐Bond and Through‐Space Effects12Enhancing nonlinear optical responses via Methoxy Positional Isomerism in Chalcone-Based Materials15Bimetallic Coordination Polymers Based on Acenaphthene-1,2-diimine Ligand0Lanthanide coordination polymers based on an aromatic dicarboxylic acid and 1,10-phenanthroline ligands: synthesis, structure and luminescence properties2Amplified circularly polarized luminescence of chiral metal-organic frameworks via post-synthetic installing pillars12A Highly Stable Eu-Mof As an Excellent Luminescent Probefor Efficient Detection of Trace Cro42- in Water Solutions0Enantioselective assembly of tetrahedral Zr 4 (embonate) 6 cages in zeolitic frameworks for synergetic circularly polarized luminescence1Hierarchical porous amorphous metal–organic frameworks constructed from ZnO/MOF glass composites9Obtaining giant Rashba–Dresselhaus spin splitting in two-dimensional chiral metal–organic frameworks7Removal of organic dyes from aqueous solution using a novel pyrene appended Zn( ii )-based metal–organic framework and its photocatalytic properties6Solvent modulation of the morphology of homochiral gadolinium coordination polymers and its impact on circularly polarized luminescence8Induced Absolute Configuration of Achiral Tetradentate Ligands in Metal–Organic Frameworks for Circularly Polarized Luminescence26Surface-supported metal−organic frameworks with geometric topological diversity via scanning tunneling microscopy14Endowing Metal‐Organic Coordination Materials with Chiroptical Activity by a Chiral Anion Strategy10High Internal Phase Emulsion for Constructing Chiral Helical Polymer-Based Circularly Polarized Luminescent Porous Materials7Synthesis Strategies, Preparation Methods, and Applications of Chiral Metal‐Organic Frameworks23Optical Phenomena in Molecule-Based Magnetic Materials154Brain-specific targeted delivery of therapeutic agents using metal–organic framework-based nanomedicine23Emergent induced circularly polarized luminescence in host–guest crystalline porous assemblies45Highly Stable MOF‐Type Lead Halide Luminescent Ferroelectrics26Highly Stable MOF‐Type Lead Halide Luminescent Ferroelectrics7Enantiomeric ni-cluster organic frameworks containing helixes constructed from alanine derivatives0NLOphoric Anthraquinone Dyes – A Review11Chiral Coordination Assembly-Induced Phosphorescent Frameworks for Circularly Polarized Phosphorescence11Circularly Polarized Luminescence of Tetradentate-Ligand-Based Chiral MOFs: Structural Evidence of Chirality Inversion32Gel transformation fabrication of carbon nanodots incorporated chiral MOF film for circularly polarized afterglow6Solvent-controlled assembly of helical coordination polymers based on lactate synthon from two-dimensional layer to three-dimensional framework5ZIF‐67‐Derived Co@Carbon Polyhedra Anchored on Reduced Graphene Oxide with Multiple Attenuation Abilities for Full X‐ and Ku‐Band Microwave Absorption6Spontaneous resolution and magnetic properties of lanthanide metal organic frameworks based on oxydiacetate1Helical Ni‐Cluster Organic Framework Constructed from Enantiopure Lactate Derivative: Synthesis, Structure and Properties2Enantiopurification by Co-Crystallization within Cyclodextrin Metal–Organic Framework2New Multifunctional Materials for Potential Applications in Molecular Electronics and Spintronics0Metal–organic frameworks for nonlinear optics and lasing17Charting a Path to Tumor Therapy: Mastery of Luminescent Metal–Organic Frameworks for Precise Spatiotemporal Control19Volatile and Non‐Volatile Dual‐Function Electrically Controlled Ultraviolet Magneto‐Optical Effect in TmIG/Pt4Chiral Ca–Mn-frameworks with double helical chains and one-dimensional channels constructed from enantiomorphous lactate synthons4Topochemical Polymerization at Diacetylene Metal–Organic Framework Thin Films for Tuning Nonlinear Optics49Light‐Up Fluorescence and Circularly Polarized Luminescence in Achiral Interlocked Framework via Adaptive Lone Pair‐π Interaction Confinement12Homochiral Zn(Ⅱ) coordination polymers with helixes constructed from semirigid lactate deriatives for circular polarization luminescence and fluorescent prober4Review of Polarized Light‐Spin/Dipole Interactions: Fundamental Physics and Application in Circularly Polarized Detecting25Chiral Metal–Organic Framework Films with Ordered Macropores for Enantioselective Analysis of Proteins21Fluorescent Dye‐Based Chiral Crystalline Organic Salt Networks for Circularly Polarized Luminescence4Enhanced Chirality Transfer in Self‐Assembled Nanocomposites Powered by A Trace Amount of Chiral Dimeric Molecules2Enhanced Chirality Transfer in Self‐Assembled Nanocomposites Powered by A Trace Amount of Chiral Dimeric Molecules6Chirality‐Dependent Anisotropic Nonlinear Optical Effect in Low‐Dimensional Hybrid Metal Halides10Chiral electrolytes for rechargeable metal batteries15Photoluminescent metal-organic frameworks and their composites: Fundamentals, applications, and outlooks48Electrically Modulated Multilevel Optical Chirality in GdFeCo Thin Films3Recent progress in metal-organic frameworks: part I—material preparation59Circularly polarized luminescent framework materials: from synthesis to future applications7Emerging frontiers in chiral metal–organic framework membranes: diverse synthesis techniques and applications8Impact of nuclear number on SHG and THG performances: a comparative study of chiral mono- and dinuclear Tb III complexes with identical organic ligands2Multi-stimuli-responsive and multimode azoquinoline chiroptical switches1Photoswitching chiroptical response in camphorate-based chiral metal–organic frameworks3Structurally isomeric ditopic 2-mercaptobenzoxazole and 2-hydroxybenzothiazole as ligands for design of 2D sodium-based luminescent coordination polymers3Synthesis, structure control and functions of polymers containing conjugated transition metal complex moieties5Topology-guided design of the first 3D penta-COFs with superior ultraviolet optical response2Variable π–d orbital hybridization in 2D transition metal–organic frameworks6Dual-ligand chiral MOFs exhibiting circularly polarized room temperature phosphorescence for anti-counterfeiting20Chiroptical Switching in an Enantiomeric Pair of Binaphthylenes Based on Redox-Active 1,8-Naphthalimide Substituents3Chiral Reticular Chemistry toward Functional Materials Discovery and Beyond18Achiral and chiral metal-organic frameworks (MOFs) as an efficient catalyst for organic synthesis47Zinc(II) 2D Coordination Polymer With Terephthalate and 4,6‐Bis(Imidazol‐1‐yl)‐2,1,3‐Benzoxadiazole Linkers as a Selective Luminescent Probe for Gallium(III) Cations11Giant Enhancement of Optical Nonlinearity by Manipulating Guest Molecular Stacking Modes in Metal–Organic Frameworks35Supersaturation‐Controlled Single‐Crystal Growth of Covalent Organic Frameworks with Binary Solvents10Multi‐Stimuli‐Responsive Circularly Polarized Luminescence with Handedness Inversion and Near‐Infrared Phosphorescence in Chiral Metal‐Organic Framework Platform for White Light Emission and Information Encryption43Red Emissive 1D Copper(I) Thiolates and Green Emissive 2D Copper(I) Halide Thiolates Displaying Second Harmonic Generation and Two‐Photon Absorption Processes2Mechanically Tuneable Circularly Polarized Flexible Spin Light Emitting Diodes10Controlled Assembly of Chiral One-Dimensional Helical Coordination Polymers for Circularly Polarized Luminescence and Polydimethylsiloxane-Assisted Signal Inversion and Amplification5Metallic deep eutectic solvent derived chiral carbon dots functionalized MOF@silica composite: A new and highly efficient column packing material29Synthesis of optically active helical polystyrene and their application in chiral separation0Metal-organic framework composites for green catalysis: Coordination chemistry approaches to sustainable energy and environmental solutions32Enantiomeric Cobalt(II)‐Based Frameworks with Various Helical Structures Formed by Achiral N‐/O‐Mixed Rigid Ligands1Circularly polarized luminescence enhancement in rare-earth MOFs due to framework chirality and host–guest energy transfer18Recent advances in Fe3O4@MOF magnetic framework composites: Preparation methods and catalytic performance17Fully Tunable Circularly Polarized Light from Achiral Soft Plasmonic Multilayers3Ligand-directed assembly of tetranuclear cobalt clusters: structural modulation via a lactate derivative and azacyclic linkers1Circularly Polarized Luminescence in Chiral Materials: Navigating Trade‐Offs between Luminescence Dissymmetry Factor and Photoluminescence Quantum Yield37Absolute Configuration Control in Covalent Organic Frameworks19Controlled surface chiral modification of 2D layered MOFs matrices for full-color circularly polarized luminescence1π‐Conjugation Engineering in New Ladder‐Type Pyrazinoquinoxaline‐Based Chromophores: A Route to High‐Performance NLO Materials With Ultradeep HOMO Levels1Chiral covalent–organic frameworks as a new class of circularly polarized luminescent materials13Amplifying the Circularly Polarized Luminescence of CsPbBr 3 Nanocrystals by Chiral Metal–Organic Frameworks: In‐Situ Growth, Chiral Assemble, and Chirality Transfer12Quantum Chemistry Calculations of Circularly Polarized Luminescence (CPL): From Spectral Modeling to Molecular Design57Synthesis and optical properties of D-π-A-type benzimidazole compounds0Recent Advances in Spin‐LEDs Based on Chiral Nanomaterials: Bridging Fundamental Physics, Materials, and Devices Performance9Chiral metal cluster-mediated chirality transfer in light-harvesting nanoribbons for amplified circularly polarized luminescence12Chiral SURMOFs for Vibrational Circular Dichroism: Multiscale Modeling and Experimental Insights0Chiral induced spin selectivity effect: A review of materials, mechanisms, and application exploration4Helical Chain Engineering in Chiral Metal–Organic Frameworks for Significantly Enhanced Circularly Polarized Luminescence7Coordination bond regulation in metal–organic framework composites: From precise synthesis to advanced catalysis and emerging adsorption/purification applications5Emergence of supramolecular chirality and fluorescence emission shift induced by interfacial self-assembly of symmetric chiral schiff base derivatives0Homochiral Metal–Organic Framework Featuring Transformable Helical and Sheeted Structures4A non-enantiopure H 8 -BINOL metal–organic framework for enantioselective fluorescence sensing0Bis-BINOL chiral dopants with high helical twisting power for photonic modulation of the luminescence dissymmetry factor in liquid crystals0Chiral Eu–K Metal–organic Framework Based on Lactate Derivative and Its Second-Order Nonlinear Optical Properties0Helical Zn-based Chiral Coordination Polymers with Nonlinear Optical Property Constructed from Lactic Acid Derivatives0Metal-Directed Structural Diversity of Lactate-Based Coordination Polymers: From Pillared-layer Framework to Multi-Helical Interpenetrating Networks0Multilevel Helical Cd-based Coordination Polymers with Significant Second NLO Response Constructed from Lactic Acid Derivatives0Research Progress in the Synthesis and Properties of Chiral Metal-Organic Frameworks ★1Structural Modulation of Co(II)-Based Chiral Coordination Polymers Based on Helixes and Lactic Derivatives via N-Donor Co-ligands0Vibrationally-resolved chiroptical spectra and chiral signatures of organic ketones with TD-DFT0Dynamic Modulation of Circularly Polarized Luminescence in Cholesteric Liquid Crystal Systems: Mechanisms, Strategies, and Beyond6Coordination Geometry-Directed Optical Anisotropy and Phase-Matched Nonlinear Optics in Chiral Metal–Organic Frameworks2Achiral Guest-Modulated Circularly Polarized Luminescence of Chiral Macrocycles by Host–Guest Encapsulation20Ligand functionalization boosts circularly polarized luminescence in chiral MOFs1Chiral three-dimensional cadmium(II)-based coordination polymer constructed from a lactic acid derivative: synthesis, structure and properties0Do's and Don'ts When Visiting Circularly Polarized Luminescence9Resonance hybrid state in novel cyclopentadienyl furan-fused systems: a key determinant for nonlinear optical properties optimization0Helical Mn(II)-based enantiomers based on lactic derivatives with ferroelectric and nonlinear optical properties3Cascade-controlled porous composite membranes: pore-supporting synergy enabling high-flux enantioseparation of amino acids and pharmaceuticals1Boosting room-temperature phosphorescence of Lead(II)-based coordination polymers via structural rigidification with auxiliary ligands2Enantiomeric Cd-based coordination polymers with multilevel helical structures and significant second NLO response constructed from lactic acid derivatives2Synthesis and functions of π-conjugated poly(acetylene)s and poly(aryleneethynylene)s with controlled higher-order structures2Structural modulation of Co(II)-based helical coordination polymers with lactic derivatives via N-donor co-ligands1Chirality transfer in helical supramolecular frameworks: Structures and SHG response modulation of Zinc(II) coordination polymers based on lactic derivatives1From central chirality to helical chirality: two chiral coordination polymers based on a lactic acid derivative and their SHG responses2Chiral Zn-based coordination polymers with helical structures and SHG activity assembled from lactic acid derivatives0Metal–organic framework-based second-order nonlinear optical materials: From structural design to functional applications0Research progress on the controllable construction of chiral metal-organic frameworks and their applications in chiral amino acids/drugs separation and detection0Tunable third-order nonlinear optical response of MIL-88B-derived Fe3O4: Solvent and magnetic-field effects0Tuning helical chirality and physical properties in chiral lactate-based coordination polymers by varying metal centres and auxiliary ligands0Chiral-induced spin selectivity in two-dimensional chiral materials: Mechanisms, chirality transfer, and spintronic applications1Hierarchical helical assembly of chiral Pd(II) complexes enabling amplified circularly polarized luminescence and efficient spin filtering0Machine-Learning Discovery of Metal–Organic Framework Crystals for Second-Harmonic Generation0Helical Cd‐Based Frameworks Based on Lactic Acid Derivatives and Their Second‐Order Nonlinear Optical Responses0Structural evolution and optical/magnetic modulation of Mn(II)-based MOFs driven by the configuration of imidazolylbenzene derivatives0Amino Acid-Derived Carbon Dots Exhibiting Chiroptical Properties: Recent Advances and Structure–Property Relationships0

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  5. Conjugation‐Induced Spin Delocalization in Helical Chiral Carbon Radicals via Through‐Bond and Through‐Space Effects

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  35. Enantiopurification by Co-Crystallization within Cyclodextrin Metal–Organic Framework

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  36. New Multifunctional Materials for Potential Applications in Molecular Electronics and Spintronics

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  37. Metal–organic frameworks for nonlinear optics and lasing

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  38. Charting a Path to Tumor Therapy: Mastery of Luminescent Metal–Organic Frameworks for Precise Spatiotemporal Control

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  40. Chiral Ca–Mn-frameworks with double helical chains and one-dimensional channels constructed from enantiomorphous lactate synthons

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  41. Topochemical Polymerization at Diacetylene Metal–Organic Framework Thin Films for Tuning Nonlinear Optics

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  42. Light‐Up Fluorescence and Circularly Polarized Luminescence in Achiral Interlocked Framework via Adaptive Lone Pair‐π Interaction Confinement

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  43. Homochiral Zn(Ⅱ) coordination polymers with helixes constructed from semirigid lactate deriatives for circular polarization luminescence and fluorescent prober

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  44. Review of Polarized Light‐Spin/Dipole Interactions: Fundamental Physics and Application in Circularly Polarized Detecting

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  45. Chiral Metal–Organic Framework Films with Ordered Macropores for Enantioselective Analysis of Proteins

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  46. Fluorescent Dye‐Based Chiral Crystalline Organic Salt Networks for Circularly Polarized Luminescence

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  47. Enhanced Chirality Transfer in Self‐Assembled Nanocomposites Powered by A Trace Amount of Chiral Dimeric Molecules

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  48. Enhanced Chirality Transfer in Self‐Assembled Nanocomposites Powered by A Trace Amount of Chiral Dimeric Molecules

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  49. Chirality‐Dependent Anisotropic Nonlinear Optical Effect in Low‐Dimensional Hybrid Metal Halides

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  50. Chiral electrolytes for rechargeable metal batteries

    Journal of Energy Chemistry · 2024-12-03

    Lan‐Qing Wu, Yu-Jie Ning, Zhenyu Fan, Zhe Li, Kun Li, Jia Li, Shuangxin Ren, Dubin Huang, Yang Yang, Weiwei Xie, Huan Wang, Qing Xiang Zhao

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