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RESEARCH PAPER · Inorganic Chemistry Frontiers · 2024

Synergistic combination of different types of functional motif in Rb(NO 3 )(SO 3 NH 3 ) for realizing excellent ultraviolet optical nonlinearity

Yunxia Song, Chensheng Lin, Xin Yi Zhao, Tao Yan, Ning Ye, Haotian Tian, Min Luo

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Synergistic combination of different types of functional motif in Rb(NO 3 )(SO 3 NH 3 ) for realizing excellent ultraviolet optical nonlinearityOriginal(C5H12N2S)Hg(NO3)2: A Mercury Nitrate Nonlinear Optical Crystal Motivated by Heteroatom Coordination Strategy9Sulfate Derivatives with Heteroleptic Tetrahedra: New Deep‐Ultraviolet Birefringent Materials in which Weak Interactions Modulate Functional Module Ordering61From [Ba3S][GeS4] to [Ba3CO3][MS4] (M = Ge, Sn): Enhancing optical anisotropy in IR birefringent crystals via functional group implantation11Achieving Phase‐Matching in Nonlinear Optical Materials CsM 2 In 2 S 6 (M = Cd/In, Hg/In) by the Incorporation of Unprecedented Trigonal Planar MS 3 Motifs6Enhanced Birefringence and Excellent Thermal Stability in Two Tellurium(IV) Vanadates: KTeOVO4 and Ca2TeV2O95Reinforced Nonlinear Optical Performances Induced by P‐P Homoatomic Bond in Phosphide SrIn 3 Si 4 P 1131Reinforced Nonlinear Optical Performances Induced by P‐P Homoatomic Bond in Phosphide SrIn 3 Si 4 P 116NH4PO3HCH3 and NH4PO3CH2NH3: Two Phosphate Derivatives with Deep-UV Cutoff Edges and Moderate Birefringence1Achieving an optimal performance balance in UV nonlinear optical crystals via hydrogen-bond regulation1Isoniazid nitrate: synergistic dual π-conjugation triggering prominent second-harmonic generation0Layered perovskite-like nitrates A 2 Ca(NO 3 ) 2 Cl 2 (A = Rb, Cs) as ultraviolet birefringent optical materials3Synthesis and characterization of hydrated alkali metal calcium nitrates ACa(NO 3 ) 3 ·2H 2 O (A = NH 4 , Rb, Cs) as short ultraviolet birefringent materials0The condensation of π-conjugated units: a new paradigm for designing high-performance optical crystals4Hydrogen‐Bond‐Modulated Alignment of Iminodiacetic Acid Cations for Achieving Ultraviolet Second Harmonic Generation6(C 6 H 7 N 2 O)NO 3 : π-Conjugation-Driven Synergistic Enhancement of Second-Harmonic Generation and Birefringence0Synergistic Enhancement of Optical Anisotropy in Nitrate Sulfamate for UV Applications: Role of Functional Group Alignment and Hydrogen Bond Network1NaNO 3 [(NH 2 ) 2 SO 2 ] 2 : A Halogen‐Free KBBF‐Type Nitrate Crystal with Record Birefringence for Ultraviolet Applications0Assembly of dual π-conjugated units toward enhanced birefringence in a 2D organic sulfonate crystal0

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  1. (C5H12N2S)Hg(NO3)2: A Mercury Nitrate Nonlinear Optical Crystal Motivated by Heteroatom Coordination Strategy

    Inorganic Chemistry · 2024-07-31

    Yi‐Lei Lv, Liang Ma, Wenlong Liu, Sheng‐Ping Guo, Ru‐Ling Tang

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  2. Sulfate Derivatives with Heteroleptic Tetrahedra: New Deep‐Ultraviolet Birefringent Materials in which Weak Interactions Modulate Functional Module Ordering

    Angewandte Chemie International Edition · 2024-08-15

    Huan Zhou, Meng Cheng, Dongdong Chu, Xu Liu, Ran An, Shilie Pan, Shilie Pan, Zhihua Yang

    Read original paper ↗ ·

  3. From [Ba3S][GeS4] to [Ba3CO3][MS4] (M = Ge, Sn): Enhancing optical anisotropy in IR birefringent crystals via functional group implantation

    Chinese Journal of Structural Chemistry · 2024-10-24

    Yong‐Fang Shi, Shenghua Zhou, Zuju Ma, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  4. Achieving Phase‐Matching in Nonlinear Optical Materials CsM 2 In 2 S 6 (M = Cd/In, Hg/In) by the Incorporation of Unprecedented Trigonal Planar MS 3 Motifs

    Small · 2024-11-19

    Lin‐Tao Jiang, Yi‐Bing Huang, Shao‐Min Pei, Xiao‐Ming Jiang, Bin‐Wen Liu, Guo‐Cong Guo

    Read original paper ↗ ·

  5. Enhanced Birefringence and Excellent Thermal Stability in Two Tellurium(IV) Vanadates: KTeOVO4 and Ca2TeV2O9

    Inorganic Chemistry · 2025-02-25

    Tingyu Wang, Han Luo, Shunke Zhang, Ling Huang, Liling Cao, Xuehua Dong, Guohong Zou

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  6. Reinforced Nonlinear Optical Performances Induced by P‐P Homoatomic Bond in Phosphide SrIn 3 Si 4 P 11

    Angewandte Chemie International Edition · 2025-02-26

    Shao‐Min Pei, Ming‐Shu Zhang, Xiao‐Ming Jiang, Bin‐Wen Liu, Guo‐Cong Guo

    Read original paper ↗ ·

  7. Reinforced Nonlinear Optical Performances Induced by P‐P Homoatomic Bond in Phosphide SrIn 3 Si 4 P 11

    Angewandte Chemie · 2025-02-26

    Shao‐Min Pei, Ming‐Shu Zhang, Xiao‐Ming Jiang, Bin‐Wen Liu, Guo‐Cong Guo

    Read original paper ↗ ·

  8. NH4PO3HCH3 and NH4PO3CH2NH3: Two Phosphate Derivatives with Deep-UV Cutoff Edges and Moderate Birefringence

    Inorganic Chemistry · 2025-05-01

    Chenhui Hu, Jiale Qu, Jinghui Hu, Junjie Liu, Wenchao Hu, Xiangzhan Jiang

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  9. Achieving an optimal performance balance in UV nonlinear optical crystals via hydrogen-bond regulation

    Inorganic Chemistry Frontiers · 2026-01-01

    S AN, Yaqi Jin, Wenhu Wang, Bailin Chen, Zhihua Yang, Xueling Hou, Shilie Pan

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  10. Isoniazid nitrate: synergistic dual π-conjugation triggering prominent second-harmonic generation

    Chemical Communications · 2026-01-01

    Yang Chi, Ya-Ping Zhao, Sheng‐Ping Guo

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  11. Layered perovskite-like nitrates A 2 Ca(NO 3 ) 2 Cl 2 (A = Rb, Cs) as ultraviolet birefringent optical materials

    Inorganic Chemistry Frontiers · 2026-01-01

    Hussin Elkik, Muhammad Mujahid Iqbal, Aqsa Munawar, Zhihua Yang, Fangfang Zhang, Shilie Pan

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  12. Synthesis and characterization of hydrated alkali metal calcium nitrates ACa(NO 3 ) 3 ·2H 2 O (A = NH 4 , Rb, Cs) as short ultraviolet birefringent materials

    Dalton Transactions · 2026-01-01

    Hussin Elkik, Muhammad Mujahid Iqbal, Aqsa Munawar, Zhihua Yang, Fangfang Zhang, Shilie Pan

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  13. The condensation of π-conjugated units: a new paradigm for designing high-performance optical crystals

    Chemical Society Reviews · 2026-01-01

    Hangwei Jia, Bailin Chen, Fangfang Zhang, Xueling Hou, Shilie Pan

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  14. Hydrogen‐Bond‐Modulated Alignment of Iminodiacetic Acid Cations for Achieving Ultraviolet Second Harmonic Generation

    Advanced Optical Materials · 2026-01-09

    Limin Duan, Xiaomin Zhang, Yan Chun Xiao, Daqing Yang, Ying Wang, Bingbing Zhang

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  15. (C 6 H 7 N 2 O)NO 3 : π-Conjugation-Driven Synergistic Enhancement of Second-Harmonic Generation and Birefringence

    Inorganic Chemistry · 2026-01-26

    Zeqiao Yin, Yue Zhang, Yongpan Lin, Xuehua Dong, Yuqiao Zhou, Daojiang Gao, Ling Huang, Liling Cao

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  16. Synergistic Enhancement of Optical Anisotropy in Nitrate Sulfamate for UV Applications: Role of Functional Group Alignment and Hydrogen Bond Network

    Small · 2026-04-09

    Xiaotian Ma, Hongyuan Sha, Qianzhen Zhang, Ruyi Niu, Xiya Wen, Xifa Long, Shilie Pan, Yun Mo Yang

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  17. NaNO 3 [(NH 2 ) 2 SO 2 ] 2 : A Halogen‐Free KBBF‐Type Nitrate Crystal with Record Birefringence for Ultraviolet Applications

    Advanced Optical Materials · 2026-04-25

    Juhui Cui, Feng Yu, Minqiang Gai

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  18. Assembly of dual π-conjugated units toward enhanced birefringence in a 2D organic sulfonate crystal

    Science China Chemistry · 2026-09-15

    Longyun Xu, Hanjing Huang, Conggang Li, Huijian Zhao, Conghe Liu, Kaidong Xu, Jina Wang, Ning Ye, Zhanggui Hu

    Read original paper ↗ ·
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