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RESEARCH PAPER · Journal of the American Chemical Society · 2021

Catalytic Amination of Polylactic Acid to Alanine

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Catalytic Amination of Polylactic Acid to AlanineOriginalNanocatalyzed Upcycling of the Plastic Wastes for a Circular Economy123A chemical approach for the future of PLA upcycling: from plastic wastes to new 3D printing materials79A recyclable process between a monomer and polyester with a natural catalyst13Efficient conversion of lactic acid to alanine over noble metal supported on Ni@C catalysts22Expanding plastics recycling technologies: chemical aspects, technology status and challenges610From trash to treasure: Chemical recycling and upcycling of commodity plastic waste to fuels, high-valued chemicals and advanced materials269The role of feed-grade amino acids in the bioeconomy: Contribution from production activities and use in animal feed19Selective Hydrogenation of Naphthalene to Decalin Over Surface‐Engineered α‐MoC Based on Synergy between Pd Doping and Mo Vacancy Generation50Progress in upcycling polylactic acid waste as an alternative carbon source: A review206Electrocatalytic Valorization of Poly(ethylene terephthalate) Plastic and CO 2 for Simultaneous Production of Formic Acid344RETRACTED: Highly Bio‐Based Unsaturated Polyester Resins with Improved Performance by Incorporating Isosorbide into the Polyester Prepolymer12Plastic Waste Valorization by Leveraging Multidisciplinary Catalytic Technologies169Sustainably Recycling and Upcycling of Single-Use Plastic Wastes through Heterogeneous Catalysis32Building a bridge from solid wastes to solar fuels and chemicals via artificial photosynthesis45Catalytic oxidation of polystyrene to aromatic oxygenates over a graphitic carbon nitride catalyst260Catalytic strategies for upvaluing plastic wastes209Trash to Treasure: Photoreforming of Plastic Waste into Commodity Chemicals and Hydrogen over MoS 2 -Tipped CdS Nanorods271Enhanced Production of Liquid Alkanes from Waste Polyethylene via the Electronic Effect‐Favored Csecondary−Csecondary Bond Cleavage42A Síntese Homoquiral da Alanina: Avaliação do Caminho Reacional Através de Métodos de Estrutura Eletrônica0Leveraging Chemolysis to Confront the Raise of Emerging Polyester Waste: A Sustainable Strategy Alongside Biological Degradation0Plastic-derived sandwich-like porous carbon nanosheet-supported hexagonal carbon micro-flakes for K-ion storage4Recent advances in plastic recycling and upgrading under mild conditions147Selective oxidative upgrade of waste polystyrene plastics by nitric acid to produce benzoic acid43State of the art in the photochemical degradation of (micro)plastics: from fundamental principles to catalysts and applications112Converting Plastic Wastes to Naphtha for Closing the Plastic Loop187One-Pot Tandem Alcoholysis-Hydrogenation of Polylactic Acid to 1,2-Propanediol5Lactate anion catalyzes aminolysis of polyesters with anilines51Recent Advancements and Perspectives of Biodegradable Polymers for Supercapacitors80Catalytic conversion of biomass-derived compoUnds to various amino acids: status and perspectives21Valorization of waste biodegradable polyester for methyl methacrylate production111Artificial photosynthesis bringing new vigor into plastic wastes63Catalytic Cracking of Polylactic Acid to Acrylic Acid19Sustainable catalytic strategies for the transformation of plastic wastes into valued products53Solvent‐Free Heterogeneous Catalytic Hydrogenation of Polyesters to Diols48Solvent‐Free Heterogeneous Catalytic Hydrogenation of Polyesters to Diols6Highly Selective Catalytic Oxi‐upcycling of Polyethylene to Aliphatic Dicarboxylic Acid under a Mild Hydrogen‐Free Process7Highly Selective Catalytic Oxi‐upcycling of Polyethylene to Aliphatic Dicarboxylic Acid under a Mild Hydrogen‐Free Process73Catalytic recycling of polyesters via a binuclear catalyst6Recent Advances in the Photoreforming of Plastic Waste: Principles, Challenges, and Perspectives40High-entropy (FeCoNiCuZn)WO4 photocatalysts-based fibrous membrane for efficient capturing and upcycling of plastic42Photocatalytic Upcycling of Plastic Waste: Mechanism, Integrating Modus, and Selectivity77Upcycling of Polylactic acid to 2-Bromopropionates and Lactates0A Generic Platform for Upcycling Polystyrene to Aryl Ketones and Organosulfur Compounds37A Generic Platform for Upcycling Polystyrene to Aryl Ketones and Organosulfur Compounds4Solution plasma synthesis of Pt-decorated Bi12O17Cl2 photocatalysts for efficient upcycling of plastics17Surface‐Controlled CdS/Ti3C2 MXene Schottky Junction for Highly Selective and Active Photocatalytic Dehydrogenation‐Reductive Amination55Surface‐Controlled CdS/Ti3C2 MXene Schottky Junction for Highly Selective and Active Photocatalytic Dehydrogenation‐Reductive Amination16Impacts of poly(lactic acid) microplastics on organic compound leaching and heavy metal distribution during hydrothermal treatment of sludge11Heterogeneous catalytic dehydrogenative coupling of ethylene glycol and primary alcohols into α-hydroxycarboxylic acids17Conversion of nitrogenous small molecules into value-added chemicals by building N–C bonds14Multi‐Functional Organofluoride Catalysts for Polyesters Production and Upcycling Degradation12Upgrading Waste Polylactide via Catalyst‐Controlled Tandem Hydrolysis‐Oxidation21Co-upcycling of polyvinyl chloride and polyesters199Quantum chemistry and metadynamics study of kinetic routes to alanine formation by CO or CO2 insertions in E- or Z-ethanimine isomers0Boosting the selective catalytic pyrolysis of plastic waste polylactic acid to monomer16Catalytic depolymerization of polyester plastics toward closed-loop recycling and upcycling127Degradation behavior and mechanism of P(AM/AA/AMPS)@PLA core-shell self-degrading temporary plugging agent27Boosting the Electrical Performance of PLA‐Based Triboelectric Nanogenerators for Sustainable Power Sources and Self‐Powered Sensing38Excavating the Potential of Photo‐ and Electroupcycling Platforms Toward a Sustainable Future for Waste Plastics11Bio-based hyperbranched epoxy resins: synthesis and recycling220Polyurethane with β‐Selenocarbonyl Structure Enabling the Combination of Plastic Degradation and Waste Upcycling5Polyurethane with β‐Selenocarbonyl Structure Enabling the Combination of Plastic Degradation and Waste Upcycling31Advancements in the Bio-degradation of Plastic Waste into Value-added Chemicals: A Recent Perspective4Advances in solar-driven, electro/photoelectrochemical, and microwave-assisted upcycling of waste polyesters15Amination of polylactic acid to alanine using a Ru–Co bimetallic catalyst7Beyond biodegradation: upcycling of polylactic acid plastic waste into amino acids via cascade catalysis under mild conditions60CO 2 catalyzed recycling of polyester and polycarbonate plastics16Direct amination of poly( p -phenylene oxide) to substituted anilines over bimetallic Pd–Ru catalysts13Hydroxyl carboxylate anion catalyzed depolymerization of biopolyesters and transformation to chemicals8Nanosized “Rice Ball” Like Hierarchical Beta Zeolites with Inter-Crystalline Mesopores for Efficient Catalytic Synthesis of Lactide0Selective Recovery of Para-Xylene from Polyethylene Terephthalate Plastic26Sustainable Recycling Strategy for Biodegradable Polyester Poly(Butylene Succinate) Through Efficient and Selective Catalytic Hydrolysis and Repolymerization Process0Upcycling of waste polyesters for the development of a circular economy36Valorization of polycaprolactone for the production of nylon-6 monomers13Polyethylene Upgrading to Liquid Fuels Boosted by Atomic Ce Promoters74Polyethylene Upgrading to Liquid Fuels Boosted by Atomic Ce Promoters21Solvent-Promoted Catalyst-Free Recycling of Waste Polyester and Polycarbonate Materials39One-Pot Conversion of Polyester and Carbonate into Formate without External H240Highly Efficient Ru-Based Catalysts for Lactic Acid Conversion to Alanine10Direct Photoreforming of Real-World Polylactic Acid Plastics into Highly Selective Value-Added Pyruvic Acid under Visible Light191Photocatalytic Upgrading of Polylactic Acid Waste into Alanine under Mild Conditions15Photocatalytic Upgrading of Polylactic Acid Waste into Alanine under Mild Conditions83Recycled polymer: Green roads for polyester plastics65One-pot solvent-free green strategy to fabricate ultra-efficient polyphosphoester flame retardant for Poly(Lactic acid)38Chemical recycling of waste plastics: Current challenges and perspectives37Polymeric Carbon Nitride Nanosheets as a Metal‐Free Heterogeneous Catalyst for Highly Efficient Methanolysis of Polycarbonates14Recent Progresses and Challenges in Upcycling of Plastics through Selective Catalytic Oxidation15Valorization of polylactic acid to 2-bromopropionates and lactates1Upcycling of waste poly(lactic acid) into crumped carbon nanosheet towards high-performance interfacial solar-driven evaporation15Depolymerization and Re/Upcycling of Biodegradable PLA Plastics106Exploring the hidden environmental pollution of microplastics derived from bioplastics: A review34One-pot photothermal upcycling of polylactic acid to hydrogen and pyruvic acid32Assessing the structural stability and drug encapsulation efficiency of poly(ethylene glycol)-poly(L-lactic acid) nanoparticles loaded with atorvastatin calcium: Based on dissipative particle dynamics4Atomic Ruthenium‐Promoted Cadmium Sulfide for Photocatalytic Production of Amino Acids from Biomass Derivatives3Atomic Ruthenium‐Promoted Cadmium Sulfide for Photocatalytic Production of Amino Acids from Biomass Derivatives63Ce-promoted Ni-NiO small ensemble constrained in an MgO catalyst for efficient hydrogen production through NH3 decomposition15Amino Acid Self-Regenerating Cell-Free Protein Synthesis System that Feeds on PLA Plastics, CO 2 , Ammonium, and α-Ketoglutarate18Alkaline Modified Mesoporous Silica Supported Ruthenium Catalyst for Improved α‐Amino Acid Synthesis2Chemical Upcycling of Polyolefin Plastics Using Structurally Well-defined Catalysts35Efficient and selective upcycling of waste polylactic acid into acetate using nickel selenide34Enhancement of mechanical and flame‐retardant properties of PLA composites through the combined action of flexible chain segments and hydrogen bonding interactions6Sustainable recycling of the biodegradable polyester poly(butylene succinate) via selective catalytic hydrolysis and repolymerization16Amines From Renewables0Ultrafast and highly‐selective upcycling of plastic polylactic acid waste driven by ZnInFe ‐mixed metal oxide17Highly efficient recycling of polyester wastes to diols using Ru and Mo dual-atom catalyst53Nanosized “rice ball” like hierarchical beta zeolites with inter-crystalline mesopores for efficient catalytic synthesis of lactide5Chemical Upcycling of Polylactic Acid Plastic Waste into Alanine over Ru/CeO 2 with Decoration of Indium20Chemical recycling of post-consumer polyester wastes using a tertiary amine organocatalyst9Electrocatalytic upcycling of plastic waste: Progress, challenges, and future53Chemolysis for Efficient and Sustainable Upcycling of Biodegradable Polyester Waste to Value-Added Products5Key Terms in Plastic Waste Transformation Reactions3Alanine Production by Chemical Upcycling of Polylactic Acid Waste Over Fe‐Doped Ru/CeO210Closed-loop recycling of biodegradable poly(butylene adipate-co-terephthalate) based on hydrolysis and repolymerization strategy17Upcycling of monomers derived from waste polyester plastics via electrocatalysis38Reinforcing the Efficiency of Plastic Upgrading through Full‐Spectrum Photothermal Effect Integration of Heat Isolator15Enzyme-Friendly Solvent for One-Pot Chemobiocatalytic Valorization of Fructose into Valuable Furanics via 5-Hydroxymethylfurfural12Room-temperature co-upcycling of polyvinyl chloride and polypropylene50Photoreforming of Plastic Waste to Sustainable Fuels and Chemicals: Waste to Energy59Research progress and challenges in the upcycling of polyolefin plastics through chemical oxidation4One-pot synthesis of alanine from glycerol without additional H2 over a rutile-supported Ru catalyst10A non-derivatized high-performance liquid chromatography method for simultaneous quantification of hydroxyl acids and amino acids in ammonolysis reactions2Efficient upgrading of polystyrene plastics to nitriles through a catalytic oxidative amination process9Prospects of high-value recycling methods for polyurethane based on the selective cleavage of C–O/C–N bonds22Recent advances in catalytic hydrogenolysis of polyester1Reductive amidation of polylactic acid with nitro compounds using nickel based nanocatalysts5Solvent-promoted catalyst-free aminolytic degradation for chemical recycling of single and mixed plastic wastes18Synergistic promoting effect of nickel in bimetallic catalyst for highly efficient ammonolysis of polylactic acid plastic waste into alanine0Synergistic Promoting Effect of Nickel in Bimetallic Catalyst for Highly Efficient Ammonolysis of Polylactic Acid Plastic Waste into Alanine0Upcycling of poly(ethylene terephthalate) waste plastics to terephthalonitrile6Ultraresponsive Donor–Acceptor System for Transforming Poly(lactic) Acid into Amino Acids with Visible Light7Co-upcycling of polyethylene terephthalate and polyoxymethylene into valuable chemicals13Crucial role of pre-treatment in plastic photoreforming for precision upcycling11Photocatalytic upcycling of polylactic acid to alanine by sulfur vacancy-rich cadmium sulfide103Recent advancements in upcycling of polyolefins by hydrocracking: Effect of various heterogeneous catalysts and reaction parameters8Triazole Drives Hole Localization and Superoxide Radical Formation for Enhancive Photocatalytic Cascade Isomerization/C─C Bond Scission of Biomass to Lactic Acid7High‐Performance Electrocatalysts of Potassium Lactate Oxidation for Hydrogen and Solid Potassium Acetate Production32Glycine electrosynthesis by the co-reduction of oxalic and nitric acids on rutile TiO212Selective photo-conversion of benzaldehyde with ammonia tuned by metal nanoparticles3Toward a Circular Economy of Heteroatom Containing Plastics: A Focus on Heterogeneous Catalysis in Recycling21Valorization of Waste Polyester for 1,4-Cyclohexanedimethanol Production22Insights into Chemical Recycling and Upgrading Strategies for Polyolefin-Based Plastics15Recycling Polyester and Polycarbonate Plastics with Carbocation Lewis Acidic Organocatalysts15Novel superhydrophilic nanofiber membranes with high flux and durability enable multifunctional oil-water separation18Photoreforming polylactic acid plastics into pyruvate over CdS/Bi4Ti3O12 S-scheme heterojunction: Successive removal of hydrogen from α-C11Reductive Upcycling of Polyolefins, Polyesters and Mixed Plastic Wastes to Valuable Chemicals: Bridging Chemical Catalysis With Plastic Waste Management35Fully recyclable flame-retardant PLA composites with balanced performance based on a phosphorus/nitrogen-containing zwitterion45Photothermal recycling of polylactic acid into H2 and gaseous C1 products via cooperative depolymerization and reforming11Oxygen vacancy mediated oxidative reforming of polylactic acid to hydrocarbon11Co-recycling of plastics and other waste materials70NaOH-Catalyzed Alcoholysis of Polylactide7

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