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RESEARCH PAPER · Chemistry of Materials · 2026

Cs X Si 15 P 21 ( X = Sn or Pb): Polar Noncentrosymmetric Si–P Frameworks Stabilized by Covalent X –P Bonding

Philip Yox, Victoria Kyveryga, Ernesto Soto, Jessica Warner, Gayatri Viswanathan, Eranga H. Gamage, Kui Wu, Bingbing Zhang, Victor Trinquet, Geoffroy Hautier, Gian‐Marco Rignanese, Kirill A. Kovnir

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Cs X Si 15 P 21 ( X = Sn or Pb): Polar Noncentrosymmetric Si–P Frameworks Stabilized by Covalent X –P BondingOriginalMid‐ to Far‐Infrared Nonlinear Optical Crystals: Design Strategies, Structure–Property Relationships and Engineering Prospects0Topology‐Preserving Ionic‐Unit Substitution Enables Sphalerite‐Like Phosphides Achieving Superior Infrared Optical Nonlinearity0Topology‐Preserving Ionic‐Unit Substitution Enables Sphalerite‐Like Phosphides Achieving Superior Infrared Optical Nonlinearity0

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  1. Mid‐ to Far‐Infrared Nonlinear Optical Crystals: Design Strategies, Structure–Property Relationships and Engineering Prospects

    Advanced Optical Materials · 2026-07-21

    Xiangran Kong, Jingdong Yan, Zi Wang, Hongwei Leng, Shichao Cheng, Sue Hao, Xiaoran Niu, Zuotao Lei, Chunhui Yang

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  2. Topology‐Preserving Ionic‐Unit Substitution Enables Sphalerite‐Like Phosphides Achieving Superior Infrared Optical Nonlinearity

    Angewandte Chemie · 2026-08-26

    Qichao Zhao, Bingxuan Li, Guang Peng, Ning Ye, Jindong Chen

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  3. Topology‐Preserving Ionic‐Unit Substitution Enables Sphalerite‐Like Phosphides Achieving Superior Infrared Optical Nonlinearity

    Angewandte Chemie International Edition · 2026-08-26

    Qichao Zhao, Bingxuan Li, Guang Peng, Ning Ye, Jindong Chen

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