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RESEARCH PAPER · Journal of Solid State Chemistry · 2021

Synthesis, crystal structure, linear and nonlinear optical properties of quaternary sulfides Ba6(Cu2X)Ge4S16 (X=Mg, Mn, Cd)

Gary Cicirello, Kui Wu, Jian Wang

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Synthesis, crystal structure, linear and nonlinear optical properties of quaternary sulfides Ba6(Cu2X)Ge4S16 (X=Mg, Mn, Cd)OriginalApplying band gap engineering to tune the linear optical and nonlinear optical properties of noncentrosymmetric chalcogenides La 4 Ge 3 Se x S 12− x ( x = 0, 2, 4, 6, 8, 10)21Transition-metal-based chalcogenides: A rich source of infrared nonlinear optical materials184A 2 P 2 S 6 (A = Ba and Pb): a good platform to study the polymorph effect and lone pair effect to form an acentric structure28Ba6(CuxZy)Sn4S16 (Z = Mg, Mn, Zn, Cd, In, Bi, Sn): High Chemical Flexibility Resulting in Good Nonlinear-Optical Properties12Synthesis, Crystal and Electronic Structures, and Nonlinear Optical Properties of Y4Si3S1212A comprehensive review on metal chalcogenides with three-dimensional frameworks for infrared nonlinear optical applications114An overview of Mg-based IR nonlinear optical materials22Heteroanion-introduction-driven birefringence enhancement in oxychalcogenide Ba 3 M II Ge 3 O 2 S 8 (M II = Mn, Cd)19Revisiting two thiophosphate compounds constituting d 0 transition metal HfP 2 S 6 and d 10 transition metal α-Ag 4 P 2 S 6 as multifunctional materials for combining second harmonic generation response and photocurrent response12Visualizing the alignment of lone pair electrons in La 3 AsS 5 Br 2 and La 5 As 2 S 9 Cl 3 to form an acentric or centrosymmetric structure10Recent progress in the design of IR nonlinear optical materials by partial chemical substitution: Structural evolution and performance optimization133Heteroanionic LaBrVIO4 (VI = Mo, W): Excellence in Both Nonlinear Optical Properties and Photoluminescent Properties11Synthesis, crystal and electronic structures, linear and nonlinear optical properties, and photocurrent response of oxyhalides CeHaVIO 4 (Ha = Cl, Br; VI = Mo, W)10Infrared nonlinear optical materials with multiple strongly ionic cations5Synthesis, Crystal and Electronic Structures, and Magnetic and Electrical Transport Properties of Bismuthides NdZn0.6Bi2 and (La0.5RE0.5)Zn0.6Bi2 (RE = Pr or Nd)7Emergent Mid‐Infrared Nonlinear Optical Candidates With Targeted Balance Performances17Nonbonding Electron Inversion‐Driven Structural Engineering: Synergistic Enhancement of Linear and Nonlinear Optical Properties3Nonbonding Electron Inversion‐Driven Structural Engineering: Synergistic Enhancement of Linear and Nonlinear Optical Properties26A high-performance IR nonlinear optical material Sr 3 MnGe 2 S 8 achieved via partial cation substitution-induced structural transformation2Ba-based IR nonlinear optical materials: synthesis, growth, structures, and properties6Synthesis, Crystal Growth, Linear, and Nonlinear Optical Properties of Water-Grown Giant Optical Anisotropic Thiocyanates ABi(SCN) 4 (A = Rb, Cs)3高性能硫属化物红外非线性光学材料构效关系（特邀）0Achieving Excellent Nonlinear Optics in α ‑Ba 2 Ge 4 S 10 via Flux‑Induced Symmetry Breaking1

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  1. Applying band gap engineering to tune the linear optical and nonlinear optical properties of noncentrosymmetric chalcogenides La 4 Ge 3 Se x S 12− x ( x = 0, 2, 4, 6, 8, 10)

    Inorganic Chemistry Frontiers · 2021-01-01

    Gary Cicirello, Kui Wu, Bingbing Zhang, Jian Wang

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  2. Transition-metal-based chalcogenides: A rich source of infrared nonlinear optical materials

    Coordination Chemistry Reviews · 2021-08-26

    Hong Chen, Wenbo Wei, Hua Lin, Xintao Wu

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  3. A 2 P 2 S 6 (A = Ba and Pb): a good platform to study the polymorph effect and lone pair effect to form an acentric structure

    Dalton Transactions · 2022-01-01

    Bingheng Ji, Arka Sarkar, Kui Wu, Andrew Swindle, Jian Wang

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  4. Ba6(CuxZy)Sn4S16 (Z = Mg, Mn, Zn, Cd, In, Bi, Sn): High Chemical Flexibility Resulting in Good Nonlinear-Optical Properties

    Inorganic Chemistry · 2022-01-26

    Bingheng Ji, Kui Wu, Yunhua Chen, Fei Wang, Aaron J. Rossini, Bingbing Zhang, Jian Wang

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  5. Synthesis, Crystal and Electronic Structures, and Nonlinear Optical Properties of Y4Si3S12

    Zeitschrift für anorganische und allgemeine Chemie · 2022-03-21

    Stefano Bardelli, Zhengyang Ye, Fei Wang, Bingbing Zhang, Jian Wang

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  6. A comprehensive review on metal chalcogenides with three-dimensional frameworks for infrared nonlinear optical applications

    Coordination Chemistry Reviews · 2022-07-19

    Hong Chen, Mao‐Yin Ran, Wenbo Wei, Xintao Wu, Hua Lin, Qi‐Long Zhu

    Read original paper ↗ ·

  7. An overview of Mg-based IR nonlinear optical materials

    Inorganic Chemistry Frontiers · 2023-01-01

    Jiaxiang Zhang, Mao‐Yin Ran, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

    Read original paper ↗ ·

  8. Heteroanion-introduction-driven birefringence enhancement in oxychalcogenide Ba 3 M II Ge 3 O 2 S 8 (M II = Mn, Cd)

    Inorganic Chemistry Frontiers · 2023-01-01

    Shenghua Zhou, Mao‐Yin Ran, Wenbo Wei, A-Yang Wang, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

    Read original paper ↗ ·

  9. Revisiting two thiophosphate compounds constituting d 0 transition metal HfP 2 S 6 and d 10 transition metal α-Ag 4 P 2 S 6 as multifunctional materials for combining second harmonic generation response and photocurrent response

    CrystEngComm · 2023-01-01

    Craig Cropek, Bingheng Ji, Arka Sarkar, Fei Wang, Tajamul Hussain Syed, Wei Wei, Sheng‐Ping Guo, Jian Wang

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  10. Visualizing the alignment of lone pair electrons in La 3 AsS 5 Br 2 and La 5 As 2 S 9 Cl 3 to form an acentric or centrosymmetric structure

    CrystEngComm · 2023-01-01

    Gary Cicirello, Andrew Swindle, Jian Wang

    Read original paper ↗ ·

  11. Recent progress in the design of IR nonlinear optical materials by partial chemical substitution: Structural evolution and performance optimization

    Coordination Chemistry Reviews · 2023-02-08

    Mao‐Yin Ran, A-Yang Wang, Wenbo Wei, Xintao Wu, Hua Lin, Qi‐Long Zhu

    Read original paper ↗ ·

  12. Heteroanionic LaBrVIO4 (VI = Mo, W): Excellence in Both Nonlinear Optical Properties and Photoluminescent Properties

    Chemistry of Materials · 2023-08-14

    Zixian Jiao, Osvaldo Medina Mireles, Kevin Ensz, Fei Wang, Mingli Liang, P. Shiv Halasyamani, Bingbing Zhang, D. Paul Rillema, Jian Wang

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  13. Synthesis, crystal and electronic structures, linear and nonlinear optical properties, and photocurrent response of oxyhalides CeHaVIO 4 (Ha = Cl, Br; VI = Mo, W)

    Dalton Transactions · 2023-12-15

    Zixian Jiao, Jasmine Quah, Tajamul Hussain Syed, Wei Wei, Bingbing Zhang, Fei Wang, Jian Wang

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  14. Infrared nonlinear optical materials with multiple strongly ionic cations

    Progress in Solid State Chemistry · 2024-04-01

    Yang Wang, Yuqiang Fang, Ruiqi Wang, Fuqiang Huang

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  15. Synthesis, Crystal and Electronic Structures, and Magnetic and Electrical Transport Properties of Bismuthides NdZn0.6Bi2 and (La0.5RE0.5)Zn0.6Bi2 (RE = Pr or Nd)

    Inorganic Chemistry · 2024-09-19

    Karishma Prasad, Dinesh Upreti, Md Rafique Un Nabi, Richeal Oppong, Fei Wang, Manish Shinde, Jin Hu, Jian Wang

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  16. Emergent Mid‐Infrared Nonlinear Optical Candidates With Targeted Balance Performances

    Small · 2024-12-23

    Junben Huang, Ailijiang Abudurusuli, Zhihua Yang, Shilie Pan

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  17. Nonbonding Electron Inversion‐Driven Structural Engineering: Synergistic Enhancement of Linear and Nonlinear Optical Properties

    Angewandte Chemie · 2025-04-28

    Jia-Xiang Zhang, Sheng‐Hua Zhou, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  18. Nonbonding Electron Inversion‐Driven Structural Engineering: Synergistic Enhancement of Linear and Nonlinear Optical Properties

    Angewandte Chemie International Edition · 2025-04-28

    Jia-Xiang Zhang, Sheng‐Hua Zhou, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  19. A high-performance IR nonlinear optical material Sr 3 MnGe 2 S 8 achieved via partial cation substitution-induced structural transformation

    Inorganic Chemistry Frontiers · 2025-11-14

    A-Lan Xu, Mao‐Yin Ran, Zuju Ma, Xin-Tao Wu, Hua Lin, Qi‐Long Zhu

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  20. Ba-based IR nonlinear optical materials: synthesis, growth, structures, and properties

    Coordination Chemistry Reviews · 2025-11-19

    Wei Huang, Chi Wang, Guohong Tang, Kexin Huang, Baojun Chen, Z. Y. He, Z. Y. He

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  21. Synthesis, Crystal Growth, Linear, and Nonlinear Optical Properties of Water-Grown Giant Optical Anisotropic Thiocyanates ABi(SCN) 4 (A = Rb, Cs)

    Crystal Growth & Design · 2025-12-30

    Vivian Nguyen, Chu Chu, Monique Sutherlin, Bingbing Zhang, Jian Wang

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  22. 高性能硫属化物红外非线性光学材料构效关系（特邀）

    Chinese Journal of Lasers · 2026-01-01

    张成龙 Zhang Chenglong, 王硕 Wang Shuo, Ailijiang Abudurusuli, 黄君本 Huang Junben

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  23. Achieving Excellent Nonlinear Optics in α ‑Ba 2 Ge 4 S 10 via Flux‑Induced Symmetry Breaking

    Small · 2026-06-24

    Ying Guo, Guo‐Qiang Wang, Yan Guo, Xiao‐Ming Jiang, B C Liu, Guo‐Cong Guo

    Read original paper ↗ ·
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