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RESEARCH PAPER · Dalton Transactions · 2022

A 2 P 2 S 6 (A = Ba and Pb): a good platform to study the polymorph effect and lone pair effect to form an acentric structure

Bingheng Ji, Arka Sarkar, Kui Wu, Andrew Swindle, Jian Wang

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A 2 P 2 S 6 (A = Ba and Pb): a good platform to study the polymorph effect and lone pair effect to form an acentric structureOriginalEu 2 P 2 S 6 : The First Rare‐Earth Chalcogenophosphate Exhibiting Large Second‐Harmonic Generation Response and High Laser‐Induced Damage Threshold143Eu2P2S6: The First Rare‐Earth Chalcogenophosphate Exhibiting Large Second‐Harmonic Generation Response and High Laser‐Induced Damage Threshold7Shedding Light on the Structure and Characterization of K2ZnGe2O6: A Phase-Matchable Nonlinear Optical Crystal19Hg2P2S6: A layered mercury hexathiodiphosphate (IV) with large birefringence11Synthesis, Crystal and Electronic Structures, Nonlinear Optical Properties, and Magnetic Properties of Two Thiophosphates: KInP2S7 and KCrP2S79d6versus d10, Which Is Better for Second Harmonic Generation Susceptibility? A Case Study of K2TGe3Ch8 (T = Fe, Cd; Ch = S, Se)18Na 6 Sn 3 P 4 S 16 : Sn( ii )-chelated PS 4 groups inspired an ultra-strong SHG response22Revisiting two thiophosphate compounds constituting d 0 transition metal HfP 2 S 6 and d 10 transition metal α-Ag 4 P 2 S 6 as multifunctional materials for combining second harmonic generation response and photocurrent response12The importance of lone pairs to structure and bonding of the novel germanium nitridophosphate GeP 2 N 47Visualizing the alignment of lone pair electrons in La 3 AsS 5 Br 2 and La 5 As 2 S 9 Cl 3 to form an acentric or centrosymmetric structure10Phase Competition and Strong SHG Responses of the Li2MIIMIVSe4 Family: Atom Response Theory Predictions versus Experimental Results24Pressure-induced superconductivity in the metal thiophosphate Pb2P2S615AEAg7(PS4)3 (AE = Ba, Sr): The homovalent substitution of lead by alkaline earth metals achieves the separation of the two phases and enlarges the band gap1BaCu2SiS4: A New Member of the AIIBI2MIVQ4 Chalcogenide Family with a Chiral Crystal Structure6Noncentrosymmetric Na6Pb3P4S16 and Centrosymmetric K2MIIP2S6 (MII = Mg and Zn) Displaying Multiple Membered-Ring Configurations and Strong Optical Anisotropy10Synthesis, crystal and electronic structures, linear and nonlinear optical properties, and photocurrent response of oxyhalides CeHaVIO 4 (Ha = Cl, Br; VI = Mo, W)10Chemical perspectives on heteroanionic compounds: a potential playground for multiferroics7Pb 3.5 GeS 4 Br 3 : the first phase-matching thiogermanate halide infrared nonlinear optical material12Crystal Structure and Ionic Conductivity of Na2MnP2S61Phosphosulfide semiconductors for optoelectronics and solar energy conversion9Na2MgP2S6: A new solid electrolyte for sodium ion batteries2Influence of dimensionality on superconductivity in pressurized 3D SnPSe 3 single crystal5Synthesis, Crystal and Electronic Structures, and Magnetic and Electrical Transport Properties of Bismuthides NdZn0.6Bi2 and (La0.5RE0.5)Zn0.6Bi2 (RE = Pr or Nd)7Emergent Mid‐Infrared Nonlinear Optical Candidates With Targeted Balance Performances17Introduction of Diverse Divalent Main-Group Metal Cations to Tune the Physical Properties of Rare-Earth Thiophosphates7Structure-property relationships in IR nonlinear optical chalcogenides with stereochemically active lone pairs29Synthesis, Crystal Growth, Linear, and Nonlinear Optical Properties of Water-Grown Giant Optical Anisotropic Thiocyanates ABi(SCN) 4 (A = Rb, Cs)3高性能硫属化物红外非线性光学材料构效关系（特邀）0

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28 direct citing papers saved.

  1. Eu 2 P 2 S 6 : The First Rare‐Earth Chalcogenophosphate Exhibiting Large Second‐Harmonic Generation Response and High Laser‐Induced Damage Threshold

    Angewandte Chemie International Edition · 2022-06-08

    Xiao Fen Huang, Sihan Yang, Xiaohui Li, Wenlong Liu, Sheng‐Ping Guo

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  2. Eu2P2S6: The First Rare‐Earth Chalcogenophosphate Exhibiting Large Second‐Harmonic Generation Response and High Laser‐Induced Damage Threshold

    Angewandte Chemie · 2022-06-08

    Xiao Fen Huang, Sihan Yang, Xiaohui Li, Wenlong Liu, Sheng‐Ping Guo

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  3. Shedding Light on the Structure and Characterization of K2ZnGe2O6: A Phase-Matchable Nonlinear Optical Crystal

    Inorganic Chemistry · 2022-07-13

    Jinmiao Jiao, Fei Liang, Conggang Li, Tao Han, Wenli Zhao, Yuheng She, Ning Ye, Zhanggui Hu, Yicheng Wu

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  4. Hg2P2S6: A layered mercury hexathiodiphosphate (IV) with large birefringence

    Journal of Solid State Chemistry · 2022-07-18

    Li-Jia Yao, Chun‐Li Hu, Zhi Gang Fang, Jiang‐Gao Mao

    Read original paper ↗ ·

  5. Synthesis, Crystal and Electronic Structures, Nonlinear Optical Properties, and Magnetic Properties of Two Thiophosphates: KInP2S7 and KCrP2S7

    Crystals · 2022-10-22

    Craig Cropek, Vivian Nguyen, Santosh Karki Chhetri, Jin Hu, Sheng‐Ping Guo, Jian Wang

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  6. d6versus d10, Which Is Better for Second Harmonic Generation Susceptibility? A Case Study of K2TGe3Ch8 (T = Fe, Cd; Ch = S, Se)

    Inorganic Chemistry · 2022-12-27

    Bingheng Ji, Fei Wang, Kui Wu, Bingbing Zhang, Jian Wang

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  7. Na 6 Sn 3 P 4 S 16 : Sn( ii )-chelated PS 4 groups inspired an ultra-strong SHG response

    Inorganic Chemistry Frontiers · 2023-01-01

    Chenyao Zhao, Bingbing Zhang, Xinyu Tian, Guoqiang Zhou, Jingjing Xu, Kui Wu

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  8. Revisiting two thiophosphate compounds constituting d 0 transition metal HfP 2 S 6 and d 10 transition metal α-Ag 4 P 2 S 6 as multifunctional materials for combining second harmonic generation response and photocurrent response

    CrystEngComm · 2023-01-01

    Craig Cropek, Bingheng Ji, Arka Sarkar, Fei Wang, Tajamul Hussain Syed, Wei Wei, Sheng‐Ping Guo, Jian Wang

    Read original paper ↗ ·

  9. The importance of lone pairs to structure and bonding of the novel germanium nitridophosphate GeP 2 N 4

    Journal of Materials Chemistry A · 2023-01-01

    Tristan de Boer, Cody Somers, Teak D. Boyko, Sebastian J. Ambach, Lucien Eisenburger, Wolfgang Schnick, A. Moewes

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  10. Visualizing the alignment of lone pair electrons in La 3 AsS 5 Br 2 and La 5 As 2 S 9 Cl 3 to form an acentric or centrosymmetric structure

    CrystEngComm · 2023-01-01

    Gary Cicirello, Andrew Swindle, Jian Wang

    Read original paper ↗ ·

  11. Phase Competition and Strong SHG Responses of the Li2MIIMIVSe4 Family: Atom Response Theory Predictions versus Experimental Results

    Chemistry of Materials · 2023-01-24

    Wen‐Dong Yao, Xiyue Cheng, Sheng‐Ping Guo, Myung‐Hwan Whangbo, Bohan Ding, Shuiquan Deng

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  12. Pressure-induced superconductivity in the metal thiophosphate Pb2P2S6

    Physical Review Materials · 2023-05-09

    Xinyi He, Zhitao Zhang, Zhenyu Ding, Shuyang Wang, Chunhua H. Chen, Xuliang Chen, Yonghui Zhou, Yonghui Zhou, Min Zhang, Min Zhang, Ying Zhou, Ying Zhou, Xiaoping Yang, Zhaorong Yang

    Read original paper ↗ ·

  13. AEAg7(PS4)3 (AE = Ba, Sr): The homovalent substitution of lead by alkaline earth metals achieves the separation of the two phases and enlarges the band gap

    Journal of Solid State Chemistry · 2023-08-25

    Jian Tang, Wenhao Xing, Chunlan Tang, Jieyun Wu, Mingjun Xia, Wenlong Yin, Bin Kang, Jianguo Deng

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  14. BaCu2SiS4: A New Member of the AIIBI2MIVQ4 Chalcogenide Family with a Chiral Crystal Structure

    Zeitschrift für anorganische und allgemeine Chemie · 2023-09-08

    Arka Sarkar, Gayatri Viswanathan, Kui Wu, Gordon J. Miller, Kirill A. Kovnir

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  15. Noncentrosymmetric Na6Pb3P4S16 and Centrosymmetric K2MIIP2S6 (MII = Mg and Zn) Displaying Multiple Membered-Ring Configurations and Strong Optical Anisotropy

    Inorganic Chemistry · 2023-12-06

    Chenyao Zhao, Dazhi Lu, Xinyu Tian, Jingjing Xu, Bingbing Zhang, Kui Wu, Haohai Yu, Huaijin Zhang

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  16. Synthesis, crystal and electronic structures, linear and nonlinear optical properties, and photocurrent response of oxyhalides CeHaVIO 4 (Ha = Cl, Br; VI = Mo, W)

    Dalton Transactions · 2023-12-15

    Zixian Jiao, Jasmine Quah, Tajamul Hussain Syed, Wei Wei, Bingbing Zhang, Fei Wang, Jian Wang

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  17. Chemical perspectives on heteroanionic compounds: a potential playground for multiferroics

    Materials Chemistry Frontiers · 2024-01-01

    Karishma Prasad, Vivian Nguyen, Bingheng Ji, Jasmine Quah, Danielle Goodwin, Jian Wang

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  18. Pb 3.5 GeS 4 Br 3 : the first phase-matching thiogermanate halide infrared nonlinear optical material

    Inorganic Chemistry Frontiers · 2024-01-01

    Jiazheng Zhou, Hongshan Wang, Junjie Liu, Xin Su, Yu Chu, Jiale Qu, Xiangzhan Jiang

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  19. Crystal Structure and Ionic Conductivity of Na2MnP2S6

    The Journal of Physical Chemistry C · 2024-02-21

    Hamdi Ben Yahia, Kota Motohashi, Shigeo Mori, Atsushi Sakuda, Akitoshi Hayashi

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  20. Phosphosulfide semiconductors for optoelectronics and solar energy conversion

    Journal of Physics Materials · 2024-04-01

    Lena Angelika Mittmann, Andrea Crovetto

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  21. Na2MgP2S6: A new solid electrolyte for sodium ion batteries

    Journal of Alloys and Compounds · 2024-04-30

    Hamdi Ben Yahia, Kota Motohashi, Shigeo Mori, Atsushi Sakuda, Akitoshi Hayashi

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  22. Influence of dimensionality on superconductivity in pressurized 3D SnPSe 3 single crystal

    Physical Review Materials · 2024-07-16

    Junjie Wang, Xu Liu, L. Zhang, Jiangang Guo, Tianping Ying

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  23. Synthesis, Crystal and Electronic Structures, and Magnetic and Electrical Transport Properties of Bismuthides NdZn0.6Bi2 and (La0.5RE0.5)Zn0.6Bi2 (RE = Pr or Nd)

    Inorganic Chemistry · 2024-09-19

    Karishma Prasad, Dinesh Upreti, Md Rafique Un Nabi, Richeal Oppong, Fei Wang, Manish Shinde, Jin Hu, Jian Wang

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  24. Emergent Mid‐Infrared Nonlinear Optical Candidates With Targeted Balance Performances

    Small · 2024-12-23

    Junben Huang, Ailijiang Abudurusuli, Zhihua Yang, Shilie Pan

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  25. Introduction of Diverse Divalent Main-Group Metal Cations to Tune the Physical Properties of Rare-Earth Thiophosphates

    Inorganic Chemistry · 2025-07-18

    Zi-Nan Chen, Hai-Ping Xu, Wen‐Dong Yao, Mingyang Li, Chen‐Yi Zhao, Wenlong Liu, Sheng‐Ping Guo

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  26. Structure-property relationships in IR nonlinear optical chalcogenides with stereochemically active lone pairs

    Coordination Chemistry Reviews · 2025-09-03

    Hong Chen, Xin‐Tao Wu, Hua Lin

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  27. Synthesis, Crystal Growth, Linear, and Nonlinear Optical Properties of Water-Grown Giant Optical Anisotropic Thiocyanates ABi(SCN) 4 (A = Rb, Cs)

    Crystal Growth & Design · 2025-12-30

    Vivian Nguyen, Chu Chu, Monique Sutherlin, Bingbing Zhang, Jian Wang

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  28. 高性能硫属化物红外非线性光学材料构效关系（特邀）

    Chinese Journal of Lasers · 2026-01-01

    张成龙 Zhang Chenglong, 王硕 Wang Shuo, Ailijiang Abudurusuli, 黄君本 Huang Junben

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