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RESEARCH PAPER · Chemistry of Materials · 2023

Controlling the Luminescence of Rare-Earth Chalcogenide Iodides RE3(Ge1–xSix)2S8I (RE = La, Ce, and Pr) and Ce3Si2(S1–ySey)8I

Dundappa Mumbaraddi, Vidyanshu Mishra, Mohammed Jomaa, Xiaoyuan Liu, Abhoy Karmakar, Sambhavi Thirupurasanthiran, Vladimir K. Michaelis, Andrew P. Grosvenor, A. Meldrum, Arthur Mar

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Controlling the Luminescence of Rare-Earth Chalcogenide Iodides RE3(Ge1–xSix)2S8I (RE = La, Ce, and Pr) and Ce3Si2(S1–ySey)8IOriginalAre Selenides the Same as Sulfides? Structure, Spectroscopy, and Properties of Narrow-Gap Rare-Earth Semiconductors RE2Sn(S1–xSex)5 (RE = La, Ce; x = 0–0.8)7Crystal Growth of Quaternary AkRE 2 Si 2 S 8 (Ak = Ca and Sr; RE = La–Tb) Thiosilicates Using Flux-Assisted Boron Chalcogen Mixture Method: Exploring X-ray Scintillation, Luminescence, and Magnetic Properties11Enhancement of Crystal Growth in Molten Salts by a Cocrystallization Agent: Synthesis and Luminescent Properties of Ce3+- and Eu2+-Doped La3(SiS4)2I4Synthesis of a series of rare-earth-based multi-anion chalcogenide iodides RE 3 Si 2 Se x S 8− x I (RE = La, Ce, Pr, and Nd) using the flux-assisted boron–chalcogen mixture method14Rare-Earth Substitution of La 3 Si 2 S 8 I for Efficient and Color-Tunable Phosphor Converted White Light Emitting Diodes14Flux-Assisted Boron Chalcogen Mixture (BCM) Method for Synthesizing Mixed Chalcogenide Semiconductors (AkRE 2 Si 2 Se x S 8– x and CaRE 2 Si 2 Se 8 ) ( Ak = Ca and Sr; RE = La, Ce, Pr, Nd, and Sm): Investigation of Their Magnetic and Optical Properties0Indirect-to-direct bandgap transition in CsRESiS 4 (RE = Sc, Y, and Lanthanides) through intrinsic charge-transfer transition (CTT) behaviour1Discovery of Noncentrosymmetric Sr 3 As 2 S 7 and Sr 3 As 2 Se 2.5 S 4.5 Featuring As 3+ /As 5+ Coordination and Their Strong Nonlinear Optical Response2

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  1. Are Selenides the Same as Sulfides? Structure, Spectroscopy, and Properties of Narrow-Gap Rare-Earth Semiconductors RE2Sn(S1–xSex)5 (RE = La, Ce; x = 0–0.8)

    Inorganic Chemistry · 2024-05-24

    Trinanjan Dey, Dundappa Mumbaraddi, Fuwei Wen, Vidyanshu Mishra, Vladimir K. Michaelis, A. Mar

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  2. Crystal Growth of Quaternary AkRE 2 Si 2 S 8 (Ak = Ca and Sr; RE = La–Tb) Thiosilicates Using Flux-Assisted Boron Chalcogen Mixture Method: Exploring X-ray Scintillation, Luminescence, and Magnetic Properties

    Inorganic Chemistry · 2024-06-29

    Gopabandhu Panigrahi, Anna A. Berseneva, Gregory W. Morrison, Adam A. King, Robin L. Conner, Luiz Gustavo Jacobsohn, Hans‐Conrad zur Loye

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  3. Enhancement of Crystal Growth in Molten Salts by a Cocrystallization Agent: Synthesis and Luminescent Properties of Ce3+- and Eu2+-Doped La3(SiS4)2I

    Inorganic Chemistry · 2024-12-05

    Rahidul Hasan, Hafiz Zohaib Aslam, Nethmi W. Hewage, Ernesto Soto, Roger A. Lalancette, Georgiy Akopov

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  4. Synthesis of a series of rare-earth-based multi-anion chalcogenide iodides RE 3 Si 2 Se x S 8− x I (RE = La, Ce, Pr, and Nd) using the flux-assisted boron–chalcogen mixture method

    Dalton Transactions · 2025-01-01

    Gopabandhu Panigrahi, Habiba Binte Kashem, Gregory W. Morrison, Hans‐Conrad zur Loye

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  5. Rare-Earth Substitution of La 3 Si 2 S 8 I for Efficient and Color-Tunable Phosphor Converted White Light Emitting Diodes

    Journal of the American Chemical Society · 2025-08-07

    Trinanjan Dey, Dundappa Mumbaraddi, Razieh Firouzi-Haji, Dmitry Vrublevskiy, Zhongqi Lin, A. Meldrum, Arthur Mar

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  6. Flux-Assisted Boron Chalcogen Mixture (BCM) Method for Synthesizing Mixed Chalcogenide Semiconductors (AkRE 2 Si 2 Se x S 8– x and CaRE 2 Si 2 Se 8 ) ( Ak = Ca and Sr; RE = La, Ce, Pr, Nd, and Sm): Investigation of Their Magnetic and Optical Properties

    Inorganic Chemistry · 2025-11-05

    Gopabandhu Panigrahi, Manish Kumar, Gregory W. Morrison, Christopher A. Sutton, Hans‐Conrad zur Loye

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  7. Indirect-to-direct bandgap transition in CsRESiS 4 (RE = Sc, Y, and Lanthanides) through intrinsic charge-transfer transition (CTT) behaviour

    Journal of Materials Chemistry C · 2026-01-01

    Sheng Zhang, Pengxiang Qiu, Shuxian Hu

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  8. Discovery of Noncentrosymmetric Sr 3 As 2 S 7 and Sr 3 As 2 Se 2.5 S 4.5 Featuring As 3+ /As 5+ Coordination and Their Strong Nonlinear Optical Response

    Chemistry of Materials · 2026-01-27

    Vidyanshu Mishra, Jinseong Kim, Joshua Lim, Manya Rishi, Joon Ik Jang, Abishek K. Iyer

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