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RESEARCH PAPER · Chemical Reviews · 2025

Fluorine as a Key Element in Solid-State Chemistry of Mixed Anions 3d Transition Metal-Based Materials for Electronic Properties and Energy

Helies Hyrondelle, Alexandre Terry, Jérôme Lhoste, Sophie Tencé, Kévin Lemoine, Jacob Olchowka, Damien Dambournet, Cédric Tassel, Jacinthe Gamon, Alain Demourgues

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Fluorine as a Key Element in Solid-State Chemistry of Mixed Anions 3d Transition Metal-Based Materials for Electronic Properties and EnergyOriginalBaAlPO 4 F 2 : structure and properties of the first barium fluoroaluminophosphate with the mixed anion group [Al 2 PO 8 F 5 ]1Structure prediction of mixed-anion perovskites: systematic approach integrating octahedral tilting and anion ordering1Resolving the Spectral Signatures of Strong Hydrogen Bonding in Fluoride Hydration11Enhancement of High-Temperature Triboelectric Performance of Polyimide Nanofibers by Introducing Fluorinated Monomers2Engineering synthesis strategies for high-voltage LiMPO4F (M = V,= Zn) cathodes of lithium-ion batteries2Perovskite Anode-Based Gel Polymer Electrolytes for High-Performance Sodium-Ion Batteries: Design, Electrochemical Performance and Stability Analysis: A Review1Efficient synthesis of heteroatom-containing alkylboronates via copper-catalyzed carboboration of alkenes and alkyl halide borylation0Fluorine-mediated regulation: empowering high-performance electrocatalysts for CO 2 electroreduction0Synthesis of F-Doped Carbon Coated TiOF2 and Its Lithiation as Cathode for Advanced Lithium-Metal Batteries0The Key Role of Monovalent Indium and Anionic Vacancies in Oxyfluorides Inducing Fluoride Ion Mobility and Luminescence0Room-temperature synthesis of fluorine-anion engineered cerium oxyfluoride nanozymes via valence-regulation strategy for prompt uric acid biosensing0Size-Mismatched Dual-Cation Alloying for Coexistence H + /Li + Conduction in Lead Bromide Hybrids0Dual regulation of electronic structure and surface property boosts bifunctional catalytic activity of cobalt-based spinel catalysts for zinc-air batteries3Pre-lithiation strategy and performance mechanism of high-entropy perovskite fluoride anodes regulated by conversion–alloying mechanism2Mild Hydrothermal Synthesis of Zirconium-Containing Fluorides: K 2 [ M (H 2 O) 6 ][Zr 2 F 12 ] ( M = Fe, Co), Rb 2 [ M (H 2 O) 6 ][Zr 2 F 12 ] ( M = Fe, Co, Ni, Cu, Zn), Cs 2 [ M (H 2 O) 6 ][Zr 2 F 12 ] ( M = Fe, Co, Ni), and Cs 2 Zr 3 Mn 3 F 200Prediction of doped silicon phases for enhanced lithium-ion battery anodes: Exploring the superior potential of C, N, and F doping0MgO-Promoted [4 + 2] Cyclization Using HFA·3H2O/SOCl2/PPh3: Modular Synthesis of gem -Bis(trifluoromethyl)dihydrothiopyrans0Nickel-Catalyzed Electrophilic Cross-Coupling Reaction of a Pyridylsulfonyl Monofluoro Reagent with Aromatic Bromides0Dual-phase lithium manganese oxide cathode active material via carbon-free active-material synthesis for high-voltage lithium hybrid capacitors0Particle Size and Morphology Effects on the High-Pressure Behavior of NaNiF3 Fluoroperovskite0Crystallographic insights into tetrahedral coordination for advanced electrocatalysis0Evaluation on the migration and equilibrium speciation of impurities in simulated spent nuclear graphite by multi-halogen synergistic roasting0Computer-aided molecular engineering of novel imidazolone–chalcone conjugates as antidiabetic agent: synthesis, molecular docking, DFT study, enzyme kinetics and ADME profiling0

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  1. BaAlPO 4 F 2 : structure and properties of the first barium fluoroaluminophosphate with the mixed anion group [Al 2 PO 8 F 5 ]

    Dalton Transactions · 2025-01-01

    Yanhui Zhang, Jiajia Li, Yaqing Ding, Kaitong Liu, Xiaofeng Gu

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  2. Structure prediction of mixed-anion perovskites: systematic approach integrating octahedral tilting and anion ordering

    Dalton Transactions · 2025-01-01

    Sanni Määttänen, Antti J. Karttunen

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  3. Resolving the Spectral Signatures of Strong Hydrogen Bonding in Fluoride Hydration

    The Journal of Physical Chemistry B · 2025-07-07

    Richa Rashmi, Benjamin Savala, Henry Agnew, Roya Savoj, Francesco Paesani

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  4. Enhancement of High-Temperature Triboelectric Performance of Polyimide Nanofibers by Introducing Fluorinated Monomers

    ACS Applied Materials & Interfaces · 2025-09-04

    Feilong Shi, Xin Wei, Sihan Wang, Huan Zhang, Fan-Yong Yan, Yi Li, Yü Tian, Tong Lin, Xiaoqing Wu

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  5. Engineering synthesis strategies for high-voltage LiMPO4F (M = V,= Zn) cathodes of lithium-ion batteries

    Emergent Materials · 2025-09-12

    Fatima Ezzahra Oujaa, Ismail Assengar, Ismae͏̈l Saadoune, Kamal Samrane

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  6. Perovskite Anode-Based Gel Polymer Electrolytes for High-Performance Sodium-Ion Batteries: Design, Electrochemical Performance and Stability Analysis: A Review

    Asian Journal of Chemistry · 2025-09-30

    Nidhi Yadav, Navneet Kumar

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  7. Efficient synthesis of heteroatom-containing alkylboronates via copper-catalyzed carboboration of alkenes and alkyl halide borylation

    Organic Chemistry Frontiers · 2026-01-01

    Subramaniyan Ramkumar, Suma Basappa, Manoj V. Mane, Andreas Jentys, D. H. Nagaraju, Udo Radius, Todd B. Marder, Mian Zahid Hussain, Shubhankar Kumar Bose

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  8. Fluorine-mediated regulation: empowering high-performance electrocatalysts for CO 2 electroreduction

    Nanoscale · 2026-01-01

    Jiahao Bao, Weibo Hu

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  9. Synthesis of F-Doped Carbon Coated TiOF2 and Its Lithiation as Cathode for Advanced Lithium-Metal Batteries

    SSRN Electronic Journal · 2026-01-01

    Yinting Gu, Lingzhi Zhang

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  10. The Key Role of Monovalent Indium and Anionic Vacancies in Oxyfluorides Inducing Fluoride Ion Mobility and Luminescence

    Inorganic Chemistry · 2026-01-29

    Alizée Deslandes, Fouad Alassani, Stanislav Péchev, Véronique Jubera, Mathieu Duttine, Jacinthe Gamon, Antoine Villesuzanne, Leïlou Loiseau-Foucher, Étienne Durand, Alexandre Fargues, Alain Demourgues

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  11. Room-temperature synthesis of fluorine-anion engineered cerium oxyfluoride nanozymes via valence-regulation strategy for prompt uric acid biosensing

    Colloids and Surfaces B Biointerfaces · 2026-03-13

    Yuheng Wang, Yumin Zhang, Yixiang Huang, Yixiang Huang, Zixuan Xu, Min Li, Gaohong He, Xuehua Ruan, Wenjun Zhang

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  12. Size-Mismatched Dual-Cation Alloying for Coexistence H + /Li + Conduction in Lead Bromide Hybrids

    Chemistry of Materials · 2026-03-16

    Ya-Ru Kong, Jiayi Zhang, Dong-Sheng Shao, Wei Ye, Gang Yang, Qiu Ren, Weihua Ning, Zhengfang Tian, Xiao‐Ming Ren

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  13. Dual regulation of electronic structure and surface property boosts bifunctional catalytic activity of cobalt-based spinel catalysts for zinc-air batteries

    Journal of Colloid and Interface Science · 2026-04-11

    Jiaxing Yan, Shenhua Dai, Yifeng Zheng

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  14. Pre-lithiation strategy and performance mechanism of high-entropy perovskite fluoride anodes regulated by conversion–alloying mechanism

    Journal of Alloys and Compounds · 2026-04-27

    Jintai Li, Minghao Su, Suyang Lu, Song Zhu, Haosen Xiong, Enchao Hu, Junhui Bao, Pengfei Lv, Zhaodong Feng, Haoran Zhan

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  15. Mild Hydrothermal Synthesis of Zirconium-Containing Fluorides: K 2 [ M (H 2 O) 6 ][Zr 2 F 12 ] ( M = Fe, Co), Rb 2 [ M (H 2 O) 6 ][Zr 2 F 12 ] ( M = Fe, Co, Ni, Cu, Zn), Cs 2 [ M (H 2 O) 6 ][Zr 2 F 12 ] ( M = Fe, Co, Ni), and Cs 2 Zr 3 Mn 3 F 20

    Inorganic Chemistry · 2026-06-30

    Timothy E. Whitesell, Hope Eden Catalano, Mark D. Smith, Hans‐Conrad zur Loye

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  16. Prediction of doped silicon phases for enhanced lithium-ion battery anodes: Exploring the superior potential of C, N, and F doping

    Materials Today Communications · 2026-07-01

    Samson Singo, Katlego Phoshoko, Tshidi Mogashoa, Phuti Esrom Ngoepe, Raesibe Sylvia Ledwaba

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  17. MgO-Promoted [4 + 2] Cyclization Using HFA·3H2O/SOCl2/PPh3: Modular Synthesis of gem -Bis(trifluoromethyl)dihydrothiopyrans

    Organic Letters · 2026-07-23

    Zeng Zr, Junyi Rao, Meng Pei, Lu Xiang, Y W Sun, Yongcun Shen, Zhenling Chen, Zhong‐Xing Jiang, Zhigang Yang

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  18. Nickel-Catalyzed Electrophilic Cross-Coupling Reaction of a Pyridylsulfonyl Monofluoro Reagent with Aromatic Bromides

    Organic Letters · 2026-07-27

    Shuang Xia, Xuefeng Gu, Huiming Dai, Junrui Wang, Wenhao Xu, Xin Liu, Zhiyu Cao, Zhibin Huang, Yingsheng Zhao

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  19. Dual-phase lithium manganese oxide cathode active material via carbon-free active-material synthesis for high-voltage lithium hybrid capacitors

    Journal of Energy Storage · 2026-08-06

    Mehmet Feryat Gülcan, Neslihan Yuca

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  20. Particle Size and Morphology Effects on the High-Pressure Behavior of NaNiF3 Fluoroperovskite

    Inorganic Chemistry · 2026-09-15

    Lucas Pelat, Kévin Lemoine, Thomas Erbland, Laure Pison, Nicolas Batisse, Paul Chauvigne, Nicolas Guignot, Geeth M. Manthilake, Laurent J. Jouffret

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  21. Crystallographic insights into tetrahedral coordination for advanced electrocatalysis

    Coordination Chemistry Reviews · 2026-09-16

    Aoxiang Zhu, Mincan Yang, Linai Zhou, Hui Wang, Weilin Xu, Jun Wan

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  22. Evaluation on the migration and equilibrium speciation of impurities in simulated spent nuclear graphite by multi-halogen synergistic roasting

    Journal of Analytical and Applied Pyrolysis · 2026-09-23

    Zhiheng Ma, Meiqian Chen, Ruitao Niu

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  23. Computer-aided molecular engineering of novel imidazolone–chalcone conjugates as antidiabetic agent: synthesis, molecular docking, DFT study, enzyme kinetics and ADME profiling

    Journal of Computer-Aided Molecular Design · 2026-10-08

    Tayyiaba Iqbal, Sampath Chinnam, Iftikhar Hussain, Masi A. Almalki, Sobhi M. Gomha, Magdi E. A. Zaki, Khasan Kayumov, Aftab Ahmad Khan, Rania H. Taha, Faoz H. Al-Atawi, Ahmad Irfan, Shoaib Khan

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