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RESEARCH PAPER · Chemistry - A European Journal · 2020

Borosulfates—Synthesis and Structural Chemistry of Silicate Analogue Compounds

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Borosulfates—Synthesis and Structural Chemistry of Silicate Analogue CompoundsOriginalNi[B2(SO4)4] and Co[B2(SO4)4]: Unveiling Systematic Trends in Phyllosilicate Analogue Borosulfates15Synthesis‐Controlled Polymorphism and Optical Properties of Phyllosilicate‐Analogous Borosulfates M[B2(SO4)4] (M=Mg, Co)28Sr6(BO3)3BN2: An Oxido–Nitrido–Borate Phosphor Featuring BN2 Dumbbells10Facile Proton Transport in Ammonium Borosulfate—An Unhumidified Solid Acid Polyelectrolyte for Intermediate Temperatures22From S–O–S to B–O–S to B–O–B Bridges: Ba[B(S2O7)2]2 as a Model System for the Structural Diversity in Borosulfate Chemistry28Die ersten zwei Bismutborosulfate – eines davon enthält Oxonium und ein tektosilicatanaloges Anion8The First Bismuth Borosulfates Comprising Oxonium and a Tectosilicate‐Analogous Anion27Sr[B2(SO4)3(S2O7)]: A Borosulfate with an Unprecedented Chain Structure Comprising Disulfate Groups18Ag[B(S2O7)2]: The First Transition Metal Borosulfate Featuring Disulfate Groups13M3B6O10NO3 (M = K, Rb): Two New Alkali Metal Borate‐Nitrates with Noncentrosymmetric Structures20Starke Lewis‐ und Brønsted‐saure Zentren im Borosulfat Mg3[H2O→B(SO4)3]26Strong Lewis and Brønsted Acidic Sites in the Borosulfate Mg3[H2O→B(SO4)3]218Achieving Short‐Wavelength Phase‐Matching Second Harmonic Generation in Boron‐Rich Borosulfate with Planar [BO3] Units103Achieving Short‐Wavelength Phase‐Matching Second Harmonic Generation in Boron‐Rich Borosulfate with Planar [BO3] Units9From β‐Na2B6O10 to Na3AlB8O15 and Na3Al2B7O15: Structural Tuning of Anionic‐Group Architectures by Substitution of [BO4] by [AlO4] Covalent Tetrahedra10Cd[B 2 (SO 4 ) 4 ] and H 2 [B 2 (SO 4 ) 4 ] – a phyllosilicate-analogous borosulfate and its homeotypic heteropolyacid11Na 2 SrB 16 O 26 : a new borate with independent interpenetrating B–O networks and deep-ultraviolet cutoff edge4New alkaline-earth amidosulfates and their unexpected decomposition to S 4 N 45Polymorphism and optical, magnetic and thermal properties of the either phyllo- or inosilicate-analogous borosulfate Cu[B 2 (SO 4 ) 4 ]8Two lead borate-nitrates with anion-centered [OPb 4 ] tetrahedra and two types of π-conjugated planar units showing large birefringence20A new salt-inclusion compound, |Ag4Br|@[B7O12], with a novel type of the porous double-layered borate anion and strong anharmonicity of the “guest” sublattice11Be[B2(SO4)4] – A Borosulfate Exhibiting Ino‐ and Phyllosilicate Analogue Topology3Polycations Stabilised by Borosulfates: [Au3Cl4][B(S2O7)2] and the One‐Dimensional Metal [Au2Cl4][B(S2O7)2](SO3)8Beyond the Energy Gap Law: The Influence of Selection Rules and Host Compound Effects on Nonradiative Transition Rates in Boltzmann Thermometers21Synthesis and crystal structure of Ge(SO4)23Difluoro(oxalato)borates as Short-Wavelength Optical Crystals with Bifunctional [BF 2 C 2 O 4 ] Units38Targeting Diverse Bridging Motifs within Actinide Borosulfates and Establishing an Unconventional Structural Hierarchy1The Unconventional Cadmium Borosulfates Cd[B2O(SO4)3] and Cd4[B2O(SO4)6]4Exploring Short-Wavelength Phase-Matching Nonlinear Optical Crystals by Employing KBe2BO3F2 as the Template96Borate-Based Compounds as Mixed Polyanion Cathode Materials for Advanced Batteries22Photoluminescence of Mn2+ in the Borosulfate Zn[B2(SO4)4] : Mn2+—A Tool to Detect Weak Coordination Behavior of Ligands18Photolumineszenz von Mn2+ in dem Borosulfat Zn[B2(SO4)4] : Mn2+ – Eine Möglichkeit zum Nachweis schwach koordinierender Liganden0Galloborates as ultraviolet nonlinear optical crystals: advances and perspectives8The Further Development of the Borate Nitrate Family: Synthesis and Structural Characterization of Ag4(B3o6)(No3) with Unique Isolated B9o18 Clusters, 9b:6δ3□:3(<2δ□>–)<3□>0The further development of the borate nitrate family: Synthesis and characterization of Ag12(B9O18)(NO3)3 with unique isolated B9O18 clusters, 9B:6Δ3□:3(<2Δ□>–)<3□>6Na2B6SO13 with unprecedented [B6SO13]∞ double chains and largest birefringence among borosulfates induced by the uniform arrangement of [B3O7] units19Na 2 PbB 6 O 10 SO 4 and Ca 2.58 Pb 0.42 B 6 O 11 SO 4 : first borate–sulfates featuring 3D porous borate anionic frameworks0Die ersten Antimon‐Borosulfate offenbaren das Baukastensystem M III M I [B(SO 4 ) 2 ] 4 (M III =Bi 3+ , Sb 3+ , Lu 3+ ; M I =H 3 O + , NO 2 + , Li + , Na + , K + , Rb + , Cs + )0The First Antimony Borosulfates Unveil a Modular System M III M I [B(SO 4 ) 2 ] 4 (M III =Bi 3+ , Sb 3+ , Lu 3+ ; M I =H 3 O + , NO 2 + , Li + , Na + , K + , Rb + , Cs + )7Pd[B(S 2 O 7 ) 2 ] 2 and Pd[B(SO 4 ) (S 2 O 7 )] 2 : Two Borosulfates with Pd 2+ in Octahedral and One with Pd 2+ in Square Planar Oxygen Coordination2Cs 3 H 2 [BOB(PO 4 ) 3 ] - the Best-Performing 1D Borophosphate Intermediate Temperature Proton Electrolyte1On The Existence of Highly Condensed Sulfatotungstates and Sulfatomolybdates4Variability of a Non‐Centrosymmetric Tecto‐Borosulfate: Introduction of Various Molecular Cations into BiX[B(SO 4 ) 2 ] 4 (X = H 3 O + , NO 2 + , NH 4 + , NO + )5Synthesis and Crystal Structure of Rb[B(SO 4 ) 2 ]: A Borosulfate Obtained from a Reaction with Chlorosulfuric Acid0Between the Sheets: CH 3 SO 3 H Molecules Intercalating B 2 O 3 Layers3Mössbauer Spectroscopy on Antimony Borosulfates Reveals Weak Coordination Behavior1Mößbauer‐Spektroskopie an Antimon‐Borosulfaten belegt deren schwache Koordinationskraft1Metal cation effects on the structural, optical and thermal properties of double tungstates AM(WO 4 ) 2 (A = Li, Na, K; M = Y, La, Ce, Pr, Nd, Sm, Bi)0Stratified sulfatometallates: unlocking a new dimension in sulfatomolybdates0Weakly coordinating borophosphates – Ca 0.5 M(H 2 O) 2 [B(PO 4 ) 2 ]·H 2 O (M = Mg, Mn, Co, Zn, Cd)0Isolation and Structural Elucidation of the Pnictogen Polysulfate Compounds As 2 [S 2 O 7 ] 2 [S 3 O 10 ] and [SeCl 3 ][Pn(S 2 O 7 ) 2 ] (Pn = Sb, Bi)0Borophosphate-based second-order nonlinear optical materials: Advances in structural diversity and optical performance0

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  1. Ni[B2(SO4)4] and Co[B2(SO4)4]: Unveiling Systematic Trends in Phyllosilicate Analogue Borosulfates

    Chemistry - A European Journal · 2020-06-17

    Leonard C. Pasqualini, Oliver Janka, Selina Olthof, Hubert Huppertz, Klaus Roman Liedl, Rainer Pöttgen, Maren Podewitz, Jörn Bruns

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  2. Synthesis‐Controlled Polymorphism and Optical Properties of Phyllosilicate‐Analogous Borosulfates M[B2(SO4)4] (M=Mg, Co)

    Chemistry - A European Journal · 2020-08-03

    Philip Netzsch, Florian Pielnhofer, Robert Glaum, Henning A. Höppe

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  3. Sr6(BO3)3BN2: An Oxido–Nitrido–Borate Phosphor Featuring BN2 Dumbbells

    Chemistry of Materials · 2020-09-01

    Stephan G. Jantz, Rebekka Erdmann, Shruti Hariyani, Jakoah Brgoch, Henning A. Höppe

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  4. Facile Proton Transport in Ammonium Borosulfate—An Unhumidified Solid Acid Polyelectrolyte for Intermediate Temperatures

    Advanced Materials · 2020-09-13

    M.D. Ward, Brian L. Chaloux, M. D. Johannes, Albert Epshteyn

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  5. From S–O–S to B–O–S to B–O–B Bridges: Ba[B(S2O7)2]2 as a Model System for the Structural Diversity in Borosulfate Chemistry

    Inorganic Chemistry · 2020-10-01

    Philip Netzsch, Florian Pielnhofer, Henning A. Höppe

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  6. Die ersten zwei Bismutborosulfate – eines davon enthält Oxonium und ein tektosilicatanaloges Anion

    Angewandte Chemie · 2020-10-07

    Matthias Hämmer, Lkhamsuren Bayarjargal, Henning A. Höppe

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  7. The First Bismuth Borosulfates Comprising Oxonium and a Tectosilicate‐Analogous Anion

    Angewandte Chemie International Edition · 2020-10-07

    Matthias Hämmer, Lkhamsuren Bayarjargal, Henning A. Höppe

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  8. Sr[B2(SO4)3(S2O7)]: A Borosulfate with an Unprecedented Chain Structure Comprising Disulfate Groups

    Inorganic Chemistry · 2020-11-26

    Philip Netzsch, Henning A. Höppe

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  9. Ag[B(S2O7)2]: The First Transition Metal Borosulfate Featuring Disulfate Groups

    European Journal of Inorganic Chemistry · 2020-12-30

    Philip Netzsch, Henning A. Höppe

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  10. M3B6O10NO3 (M = K, Rb): Two New Alkali Metal Borate‐Nitrates with Noncentrosymmetric Structures

    European Journal of Inorganic Chemistry · 2021-02-13

    Qiqi Zhang, Fangfang Zhang, Fuming Li, Shujuan Han, Zhihua Yang, Shilie Pan

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  11. Starke Lewis‐ und Brønsted‐saure Zentren im Borosulfat Mg3[H2O→B(SO4)3]2

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    Philip Netzsch, Regina Stroh, Florian Pielnhofer, Ingo Krossing, Henning A. Höppe

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  12. Strong Lewis and Brønsted Acidic Sites in the Borosulfate Mg3[H2O→B(SO4)3]2

    Angewandte Chemie International Edition · 2021-03-10

    Philip Netzsch, Regina Stroh, Florian Pielnhofer, Ingo Krossing, Henning A. Höppe

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  13. Achieving Short‐Wavelength Phase‐Matching Second Harmonic Generation in Boron‐Rich Borosulfate with Planar [BO3] Units

    Angewandte Chemie International Edition · 2021-10-09

    Zi‐Jian Li, Wenqi Jin, Fangfang Zhang, Zilong Chen, Zhihua Yang, Shilie Pan

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  14. Achieving Short‐Wavelength Phase‐Matching Second Harmonic Generation in Boron‐Rich Borosulfate with Planar [BO3] Units

    Angewandte Chemie · 2021-10-09

    Zi‐Jian Li, Wenqi Jin, Fangfang Zhang, Zilong Chen, Zhihua Yang, Shilie Pan

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  15. From β‐Na2B6O10 to Na3AlB8O15 and Na3Al2B7O15: Structural Tuning of Anionic‐Group Architectures by Substitution of [BO4] by [AlO4] Covalent Tetrahedra

    Chemistry - A European Journal · 2021-11-24

    Jiahao Jiao, Wenqi Jin, Min Zhang, Zhiyong Guo, Zhihua Yang, Shilie Pan

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  16. Cd[B 2 (SO 4 ) 4 ] and H 2 [B 2 (SO 4 ) 4 ] – a phyllosilicate-analogous borosulfate and its homeotypic heteropolyacid

    Dalton Transactions · 2022-01-01

    Matthias Hämmer, Leonard C. Pasqualini, Sean S. Sebastian, Hubert Huppertz, Henning A. Höppe, Jörn Bruns

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  17. Na 2 SrB 16 O 26 : a new borate with independent interpenetrating B–O networks and deep-ultraviolet cutoff edge

    Dalton Transactions · 2022-01-01

    Zhikang Chen, Kewang Zhang, Bei Zhang, Jun Zhang

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  18. New alkaline-earth amidosulfates and their unexpected decomposition to S 4 N 4

    Dalton Transactions · 2022-01-01

    Peter Groß, Yue Zhang, Lkhamsuren Bayarjargal, Björn Winkler, Henning A. Höppe

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  19. Polymorphism and optical, magnetic and thermal properties of the either phyllo- or inosilicate-analogous borosulfate Cu[B 2 (SO 4 ) 4 ]

    Dalton Transactions · 2022-01-01

    Matthias Hämmer, Florian Pielnhofer, Oliver Janka, Hirotaka Takahashi, Peter Groß, Rainer Pöttgen, Henning A. Höppe

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  20. Two lead borate-nitrates with anion-centered [OPb 4 ] tetrahedra and two types of π-conjugated planar units showing large birefringence

    Dalton Transactions · 2022-01-01

    Shuo Bai, Daqing Yang, Bingbing Zhang, Ling Li, Ying Wang

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  21. A new salt-inclusion compound, |Ag4Br|@[B7O12], with a novel type of the porous double-layered borate anion and strong anharmonicity of the “guest” sublattice

    Solid State Sciences · 2022-01-31

    Sergey N. Volkov, Dmitri O. Charkin, Lev S. Manelis, M. Yu. Arsent’ev, Valentina A. Yukhno, Alexey V. Povolotskiy, В. Л. Уголков, Maria Georgievna Krzhizhanovskaya, Vera A. Firsova, Sergey M. Aksenov, Р. С. Бубнова

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  22. Be[B2(SO4)4] – A Borosulfate Exhibiting Ino‐ and Phyllosilicate Analogue Topology

    European Journal of Inorganic Chemistry · 2022-02-09

    Stefan Sutorius, Michael Hanrath, Jörn Bruns

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  23. Polycations Stabilised by Borosulfates: [Au3Cl4][B(S2O7)2] and the One‐Dimensional Metal [Au2Cl4][B(S2O7)2](SO3)

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  24. Beyond the Energy Gap Law: The Influence of Selection Rules and Host Compound Effects on Nonradiative Transition Rates in Boltzmann Thermometers

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  25. Synthesis and crystal structure of Ge(SO4)2

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  26. Difluoro(oxalato)borates as Short-Wavelength Optical Crystals with Bifunctional [BF 2 C 2 O 4 ] Units

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  27. Targeting Diverse Bridging Motifs within Actinide Borosulfates and Establishing an Unconventional Structural Hierarchy

    Inorganic Chemistry · 2022-09-01

    Teagan F. M. Sweet, Daniel E. Felton, Jennifer E. S. Szymanowski, Peter Carman Burns

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  28. The Unconventional Cadmium Borosulfates Cd[B2O(SO4)3] and Cd4[B2O(SO4)6]

    Zeitschrift für anorganische und allgemeine Chemie · 2022-09-02

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  29. Exploring Short-Wavelength Phase-Matching Nonlinear Optical Crystals by Employing KBe2BO3F2 as the Template

    ACS Central Science · 2022-11-11

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  30. Borate-Based Compounds as Mixed Polyanion Cathode Materials for Advanced Batteries

    Molecules · 2022-11-19

    Giancarlo Dominador D. Sanglay, Jayson S. Garcia, Mecaelah S. Palaganas, Maurice Sorolla, Sean Benson A. See, Lawrence A. Limjuco, Joey Duran Ocon

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  31. Photoluminescence of Mn2+ in the Borosulfate Zn[B2(SO4)4] : Mn2+—A Tool to Detect Weak Coordination Behavior of Ligands

    Angewandte Chemie International Edition · 2023-08-07

    Lukas Maximilian Träger, Leonard C. Pasqualini, Hubert Huppertz, Jörn Bruns, Markus Suta

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  32. Photolumineszenz von Mn2+ in dem Borosulfat Zn[B2(SO4)4] : Mn2+ – Eine Möglichkeit zum Nachweis schwach koordinierender Liganden

    Angewandte Chemie · 2023-08-07

    Lukas Maximilian Träger, Leonard C. Pasqualini, Hubert Huppertz, Jörn Bruns, Markus Suta

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  33. Galloborates as ultraviolet nonlinear optical crystals: advances and perspectives

    Dalton Transactions · 2024-01-01

    Jingyi Lu, Yangfeifei Ou, Congcong Jin, Jian‐Wen Cheng

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  34. The Further Development of the Borate Nitrate Family: Synthesis and Structural Characterization of Ag4(B3o6)(No3) with Unique Isolated B9o18 Clusters, 9b:6δ3□:3(<2δ□>–)<3□>

    SSRN Electronic Journal · 2024-01-01

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  35. The further development of the borate nitrate family: Synthesis and characterization of Ag12(B9O18)(NO3)3 with unique isolated B9O18 clusters, 9B:6Δ3□:3(<2Δ□>–)<3□>

    Journal of Crystal Growth · 2024-07-31

    Sergey N. Volkov, Dmitri O. Charkin, Ivan A. Marsiy, Daria A. Banaru, Alexey V. Povolotskiy, Alevtina N. Gosteva, M. Yu. Arsent’ev, Maria Georgievna Krzhizhanovskaya, В. Л. Уголков, Yevgeny E. Savchenko, Vadim E. Kireev, Sergey M. Aksenov, Р. С. Бубнова

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  36. Na2B6SO13 with unprecedented [B6SO13]∞ double chains and largest birefringence among borosulfates induced by the uniform arrangement of [B3O7] units

    Science China Chemistry · 2024-08-19

    Jinbin Fan, Ziting Yan, Zilong Chen, Huimin Li, Zhihua Yang, Fangfang Zhang, Shilie Pan

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  37. Na 2 PbB 6 O 10 SO 4 and Ca 2.58 Pb 0.42 B 6 O 11 SO 4 : first borate–sulfates featuring 3D porous borate anionic frameworks

    Inorganic Chemistry Frontiers · 2025-01-01

    Huan Pei, Zi‐Jian Li, Shaohuan Liu, Xueling Hou, Fangfang Zhang

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  38. Die ersten Antimon‐Borosulfate offenbaren das Baukastensystem M III M I [B(SO 4 ) 2 ] 4 (M III =Bi 3+ , Sb 3+ , Lu 3+ ; M I =H 3 O + , NO 2 + , Li + , Na + , K + , Rb + , Cs + )

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  39. The First Antimony Borosulfates Unveil a Modular System M III M I [B(SO 4 ) 2 ] 4 (M III =Bi 3+ , Sb 3+ , Lu 3+ ; M I =H 3 O + , NO 2 + , Li + , Na + , K + , Rb + , Cs + )

    Angewandte Chemie International Edition · 2025-02-12

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  40. Pd[B(S 2 O 7 ) 2 ] 2 and Pd[B(SO 4 ) (S 2 O 7 )] 2 : Two Borosulfates with Pd 2+ in Octahedral and One with Pd 2+ in Square Planar Oxygen Coordination

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  41. Cs 3 H 2 [BOB(PO 4 ) 3 ] - the Best-Performing 1D Borophosphate Intermediate Temperature Proton Electrolyte

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  42. On The Existence of Highly Condensed Sulfatotungstates and Sulfatomolybdates

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  43. Variability of a Non‐Centrosymmetric Tecto‐Borosulfate: Introduction of Various Molecular Cations into BiX[B(SO 4 ) 2 ] 4 (X = H 3 O + , NO 2 + , NH 4 + , NO + )

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  44. Synthesis and Crystal Structure of Rb[B(SO 4 ) 2 ]: A Borosulfate Obtained from a Reaction with Chlorosulfuric Acid

    Zeitschrift für anorganische und allgemeine Chemie · 2025-10-11

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  45. Between the Sheets: CH 3 SO 3 H Molecules Intercalating B 2 O 3 Layers

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  46. Mössbauer Spectroscopy on Antimony Borosulfates Reveals Weak Coordination Behavior

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  47. Mößbauer‐Spektroskopie an Antimon‐Borosulfaten belegt deren schwache Koordinationskraft

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  48. Metal cation effects on the structural, optical and thermal properties of double tungstates AM(WO 4 ) 2 (A = Li, Na, K; M = Y, La, Ce, Pr, Nd, Sm, Bi)

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    Vivien Wessels, Matthias Hämmer, Florian Becker, Anja Sandner, Narayan Simrit Kaur, Henning A. Höppe

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  49. Stratified sulfatometallates: unlocking a new dimension in sulfatomolybdates

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  50. Weakly coordinating borophosphates – Ca 0.5 M(H 2 O) 2 [B(PO 4 ) 2 ]·H 2 O (M = Mg, Mn, Co, Zn, Cd)

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