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RESEARCH PAPER · Laser & Photonics Review · 2022

Ultra‐Broadband Green‐Emitting Phosphors without Cyan Gap Based on Double‐Heterovalent Substitution Strategy for Full‐Spectrum WLED Lighting

Shuai Huang, Mengmeng Shang, Yan Yu, Yining Wang, Peipei Dang, Jun Lin

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Ultra‐Broadband Green‐Emitting Phosphors without Cyan Gap Based on Double‐Heterovalent Substitution Strategy for Full‐Spectrum WLED LightingOriginalReducing the cyan-cavity: Lu 2 MAl 4 SiO 12 :Ce 3+ (M = Mg, Ca, Sr and Ba) phosphor-in-glass film towards full-spectrum laser-driven lighting24Zero-thermal-quenching of LiAl5O8: Eu2+, Mn2+ phosphors by energy transfer and defects engineering26Comparison of luminescence between Eu2+-activated Na2CaPO4F and NaCaPO4 green-emitting phosphors for pc-wLEDs17A novel bright cyan emitting phosphor of Eu 2+ activated Ba 6 BO 3 Cl 9 with robust thermal stability for full-spectrum WLED applications65Achieving efficient violet-light-excited blue phosphors by nitridation for violet-chip-based full-spectrum lighting47Achieving excellent thermostable red emission in singly Mn 2+ -doped near-zero thermal expansion (NZTE) material Li 2 Zn 3 (P 2 O 7 ) 26Cyan-rich sunlight-like spectra from Mn 2+ -doped CsCd(Cl 1− y Br y ) 3 perovskites with dual tunable emissions and high stability2High performance of broad excitation and narrow emission green phosphor NaAl 11 O 17 :Eu 2+ , Mn 2+ for backlight displays20Monolithically Integrating III‐Nitride Quantum Structure for Full‐Spectrum White LED via Bandgap Engineering Heteroepitaxial Growth129Ultrahighly Efficient Narrowband Red Luminescence of Uniquely Distorted Mn 4+ Octahedron in the Feldspar‐Type LED Phosphor47Recent Advances in Multi-Site Luminescent Materials: Design, Identification and Regulation20Investigation of gamma-ray sensitivity of YAG:Ce based scintillation structures2Designing multicolor luminescence in Tb3+/Eu3+-codoped KGd2F7 nanoparticles through energy transfer engineering for warm white light-emitting diode5Recent Progress in Long‐Wavelength InGaN Light‐Emitting Diodes from the Perspective of Epitaxial Structure49Enhancing External Quantum Efficiency of Blue-Emitting Phosphor Ba(K)-β-Al2O3:Eu2+ by Lattice Site Engineering for Full-Spectrum Lighting40Cyan-green-emitting Ca 3 Sc 2 Si 3 O 12 :Ce 3+ transparent ceramics: A promising color converter for high-brightness laser lighting43The ultra-wideband near-infrared luminescence properties and applications of K2SrGe8O18:Cr3+ phosphor26Enhanced red luminescence of Ca 3 Si 2− x M x O 7 :Eu 3+ (M = Al, P) phosphors via partial substitution of Si 4+ for applications in white light‐emitting diodes49Improved thermal stability and quantum efficiency of novel cyan phosphors toward full-visible-spectrum lighting15K2CaPO4F:Eu2+,RE3+ for pc-WLEDs: Cationic substitution inducing tunable emission and anti-thermal quenching8Design the green emitting phosphor Ca9La(PO4)7:Eu2+ by the structural modulation and its application to white LEDs5Multi-luminescent center integrated metal–organic frameworks for high-performance white light-emitting diodes12Dendrimer-Encapsulated Halide Perovskite Nanocrystals for Self-Powered White Light-Emitting Glass18Ce:(Lu,Sr) 3 (Al,Si) 5 O 12 transparent ceramics for high-power white LEDs/LDs with ultra-high luminance saturation threshold12Highly efficient and thermally stable broadband green-emitting BaY 2 Sc 2 Al 2 SiO 12 :Ce 3+ phosphors enabling warm-white LEDs with high luminous efficacy and high color rendering index44BaLiZn 3 (PO 4 ) 3 :Eu 2+ : Ultranarrow-Band Violet Emission in a Highly Symmetric Crystal Structure24Multicolor regulation of trivalent lanthanide ions-codoped boggildite-type phosphor toward superb warm white luminescence for white light-emitting diodes13Deep‐Red (Sr,Ba)Lu2O4: Eu2+ Phosphor for Full‐Spectrum Lighting7Ce 3+ -Activated SrLu 2 Al 3 ScSiO 12 Cyan-Green-Emitting Garnet-Structured Inorganic Phosphor Materials toward Application in Blue-Chip-Based Phosphor-Converted Solid-State White Lighting68Super thermally stable Rb-β-Al2O3:Eu blue phosphor for full-spectra lighting4LaMg6Ga6S16: a chemical stable divalent lanthanide chalcogenide70High recorded color rendering performance of single-structured Ce,Mn:Y 3 (Al,Sc) 2 Al 3 O 12 phosphor ceramics for high-power white LEDs/LDs35Manipulating cationic ordering toward highly efficient and zero-thermal-quenching cyan photoluminescence34Suppressing Self‐Oxidation of Eu 2+ in Li 2 CaSiO 4 for Full‐Spectrum Lighting and Accurate Temperature Sensing65Simultaneous NIR Emission and Thermal Stability Enhancement in Garnet‐Type NIR Phosphors through the Synergistic Effect of Lattice Distortion and Enhanced Rigidity60Multi-sites induced ultra-broadband luminescence based on Eu2+ doped whitlockite-type phosphor for full-spectrum WLEDs9A novel green phosphor Ba2Sc2((BO3)2B2O5):Ce3+ for high color rendering index full-spectrum lighting and low-temperature sensors21One stone, two birds: Luminescence properties of Ca8ZnY(PO4)7:Eu2+, Mn2+ and multifunctional applications in WLEDs & optical anti-counterfeiting26Europium Ions Self‐Reduction Benefiting from AlO4/Si(Al)O4 Network Structure for Multimode Optical Thermometry Manometry27Theoretical investigation and optimisation of strain relief layers for highly efficient and spectrally pure Green-LED3Atom Probe Tomography Investigation of the Impact of Stacking Faults on InGaN/GaN Quantum Well LED Systems0Engineering interstitial Eu2+ in α-quartz creates broadband cyan emission toward full-visible-spectrum white LED lighting2Efficient solid-state photoluminescence based on sodium citrate and CsPbI3 quantum dots3Crystal Field Engineering Inducing Transformation from Narrow Band of Eu3+ to Broadband of Eu2+2An efficient violet-excited and cyan-green/near-infrared dual emitting phosphor for full-spectrum lighting14Ca9–yMgyNaGd0.667(PO4)7:Eu2+: A Single Eu2+-Doped Full-Spectrum White Light Emission Phosphor with High Color Rendering Index20Super‐Sensitive Multi‐Modal Optical Manometer Based on Huge Pressure‐Induced Spectral Red‐Shift and Broadening of Mn2+ Emission Band in Green‐Emitting Zn2GeO4 Phosphors20Customized Cyan Phosphors for Efficient Full‐Spectrum Illumination and Fingerprint Detection22Double-Matrix Encapsulation of Cyan Perovskite Nanomaterials for High-Efficiency Full-Spectrum White Light-Emitting Diodes5Sr 8 MgSc(PO 4 ) 7 :Eu 2+ phosphor: d–f transition driven applications for solid-state lighting and extreme environment multimode sensing investigations18Dual-mode fluorescence intensity ratio temperature measurement based on Dy3+ doped boroaluminosilicate glass6Violet light excitable Sm/Eu activated zirconium silicate towards white light-emitting diodes7Narrow-Band Deep-Blue Emitting Basr2(Po4)2: Eu2+ Phosphor with High Thermal Stability for Advanced Anti-Counterfeiting and Wleds0Well-designed sunlight-like Bi 3+ -activated white-light phosphor for general lighting6A thermally stable Ce3+ activated green phosphor for illuminating and temperature sensing application10CaLu 2 Sc 2 Al 2 SiO 12 :Ce 3+ Green Phosphors for High-Quality White LEDs31Tailoring of Blue‐Cyan Luminescence in Rb 3 Y[(P 1‐ x Si x )O 4 ] 2 :Eu 2+ Phosphor via Si 4+ ‐P 5+ Heterovalent Substitution for Full‐Spectrum Healthy Lighting25Efficient and stable cyan phosphor Ca 2 LuZr 2 Al 3 O 12 :Ce 3+ for full-spectrum LEDs8Beyond transmission electron microscopy imaging: Atom probe tomography reveals chemical inhomogeneity at stacking fault interfaces in InGaN/GaN light-emitting diodes3Efficient broadband green-emitting Ca2LuScGaAlSi2O12:Ce3+ garnet phosphor towards high-color-rendering full-spectrum WLED lighting17Rice Husk-derived Biomass Silicon for Single-phase White-light Inorganic Phosphor and WLEDs4β-Ca3(PO4)2-type Eu2+-doped Phosphor: Applications in optical thermometry and full-spectrum lighting5Unlocking novel halogen germanate phosphors for full-spectrum lighting and ultra-sensitive temperature sensing7Density functional theory facilitates heterovalent substitution: The multi-functional application of near-infrared emitting phosphors with excellent thermal stability0High-pressure dual-mode optical manometry for visual pressure sensing using Ce3+-activated NaMgBO3 phosphors5Thermal‐Robust and Glass‐Compatible K 1.3 Al 9 Ga 2 O 17.15 :Eu for Laser‐Driven Lighting and Underwater Optical Communication3A novel deep-blue emitting BaSr2(PO4)2: Eu2+ phosphor with excellent thermostability for advanced anti-counterfeiting and white light-emitting diodes1Simultaneous emission and thermal stability enhancement of long-wavelength NIR luminescence of Cr 3+ ions in spinel phosphors via pivot-polyhedron linkage engineering4Blue-light-excited SrLu2Al2GaScSiO12:Ce3 + cyan-emitting garnet phosphor for high color rendering index full-spectrum WLEDs8Red-emitting luminescence properties and Judd-Ofelt analysis of Ca19Mg2(PO4)14: Eu3+ powders synthesized by the solid-state reaction method1Enhanced luminescence performance and environment-dependent multicolor emissions of Bi3+-activated KBaYSi2O7 achieved by an efficient doping strategy1Sr2Sb2O7: A multifunctional oxide platform for cyan-compensated healthy lighting and near-infrared applications3Efficient green emission via energy transfer in CaLuAlO4:Ce3+,Tb3+ phosphors for high-quality warm white lighting4High-performance multifunctional NIR phosphor K2NaAlF6:Mn4+,Cr3+ for pc-LED and X-ray imaging via efficient energy transfer3Preparation and multifunctional applications of SrGa4O7: Sm3+ orange-red long-persistent phosphor0Blue‐Light‐Excited Cyan‐Emitting Carbon‐Dot‐Ormosil Gel for Blue‐Overshoot Mitigation and Cyan‐Gap Bridging in WLEDs4High-temperature-stable Sr3GaAlO6: Eu2+ broadband red phosphor: Dual applications from LED lighting to fingerprint development0Ce3+-activated BaAlSi5N7O2: A novel cyan-emitting phosphor with superior thermal stability for full-visible-spectrum LED lighting2Sunlike Full‐Spectrum White Light‐Emitting Diodes Based on Efficient and Eco‐Friendly Hybrid Copper Halide Ionic Crystals1Customized high-efficiency full-spectrum near-white vanadate phosphors enabling bifunctional integrated visualization applications1Single-component white-light phosphor Ca8ZnAl(PO4)7: Eu2 +, Dy3+ with high thermal stability and IQE for high-CRI WLEDs3Cyan-emitting Eu(II)-based hybrid bromides luminescence materials for full-spectrum lighting0A tunable monophasic white light phosphor Ca8ZnIn(PO4)7: Eu2+, Dy3+ exhibits high stability and high-efficiency luminescence0Enhanced photoluminescence and color controllable LaPO4:RB6 (R = Ce3+, Sm3+, Eu3+) phosphors0Thermally robust garnet yellow-green phosphors with near-unity quantum yield for white light-emitting diodes0Heavy-element substitution simultaneously boosts comprehensive photoluminescence performance of Ce3+-activated garnets toward multifunctional optical applications0Temperature-sensitive color modulation in Ca7-mSrmMg2(PO4)6: Eu2 + for advanced anti-counterfeiting and WLED applications0Highly efficient blue-emitting Eu2+-doped borate glasses with optical thermometric capability for plant-lighting applications0Optical dual-mode temperature sensing and information encryption applications using a novel color-tunable NaSrLa(PO4)2: Eu2+, Tb3+0

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  1. Reducing the cyan-cavity: Lu 2 MAl 4 SiO 12 :Ce 3+ (M = Mg, Ca, Sr and Ba) phosphor-in-glass film towards full-spectrum laser-driven lighting

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  2. Zero-thermal-quenching of LiAl5O8: Eu2+, Mn2+ phosphors by energy transfer and defects engineering

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  3. Comparison of luminescence between Eu2+-activated Na2CaPO4F and NaCaPO4 green-emitting phosphors for pc-wLEDs

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  4. A novel bright cyan emitting phosphor of Eu 2+ activated Ba 6 BO 3 Cl 9 with robust thermal stability for full-spectrum WLED applications

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  5. Achieving efficient violet-light-excited blue phosphors by nitridation for violet-chip-based full-spectrum lighting

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  16. Cyan-green-emitting Ca 3 Sc 2 Si 3 O 12 :Ce 3+ transparent ceramics: A promising color converter for high-brightness laser lighting

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  42. Engineering interstitial Eu2+ in α-quartz creates broadband cyan emission toward full-visible-spectrum white LED lighting

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  43. Efficient solid-state photoluminescence based on sodium citrate and CsPbI3 quantum dots

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  44. Crystal Field Engineering Inducing Transformation from Narrow Band of Eu3+ to Broadband of Eu2+

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  45. An efficient violet-excited and cyan-green/near-infrared dual emitting phosphor for full-spectrum lighting

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  46. Ca9–yMgyNaGd0.667(PO4)7:Eu2+: A Single Eu2+-Doped Full-Spectrum White Light Emission Phosphor with High Color Rendering Index

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  47. Super‐Sensitive Multi‐Modal Optical Manometer Based on Huge Pressure‐Induced Spectral Red‐Shift and Broadening of Mn2+ Emission Band in Green‐Emitting Zn2GeO4 Phosphors

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  48. Customized Cyan Phosphors for Efficient Full‐Spectrum Illumination and Fingerprint Detection

    Small · 2024-10-31

    Zheng Lu, Guan Peng, Dashuai Sun, Zeyu Lyu, Xiaowei Zhang, Pengcheng Luo, Luhui Zhou, Chunchun Chen, Qingxian Xu, Fu‐Xiang Cheng, Hongpeng You

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  49. Double-Matrix Encapsulation of Cyan Perovskite Nanomaterials for High-Efficiency Full-Spectrum White Light-Emitting Diodes

    ACS Applied Nano Materials · 2024-11-15

    Zhengtong Wang, Cong Chen, Kai Lian, Zhihui Deng, Yiwei Zhao, Jiachen Han, Yelin Ding, Chun Hua Sun

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  50. Sr 8 MgSc(PO 4 ) 7 :Eu 2+ phosphor: d–f transition driven applications for solid-state lighting and extreme environment multimode sensing investigations

    Inorganic Chemistry Frontiers · 2024-12-09

    Baofeng Zheng, Jiahao Yan, Jingyao Li, Yixuan Wang, Xinyi Yang, Wenze Li

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