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RESEARCH PAPER · Dalton Transactions · 2019

Two rare-earth-based quaternary chalcogenides EuCdGeQ 4 (Q = S, Se) with strong second-harmonic generation

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Two rare-earth-based quaternary chalcogenides EuCdGeQ 4 (Q = S, Se) with strong second-harmonic generationOriginalA highly distorted HgS 4 tetrahedron-induced moderate second-harmonic generation response of EuHgGeS 462Mixed-metal thiophosphate CuCd 3 PS 6 : an infrared nonlinear optical material activated by its three-in-one tetrahedra-stacking architecture33New quaternary chalcogenide Ba 4 HgAs 2 S 10 originating from the combination of linear [HgS 2 ] 2− and tetrahedral [AsS 4 ] 3− modules8(Na0.60Ba0.70)Ga2Se4: An Infrared Nonlinear Optical Crystal Designed using AgGaSe2 as the Template38Crystal chemistry, second-order nonlinear optical, and magnetic properties of Eu8Sn4Se2014Second-order nonlinear optical-active selenide borate Zn8Se2(BO2)12: Experimental and theoretical analysis9Two Mixed-Anion Units of [GeOSe3] and [GeO3S] Originating from Partial Isovalent Anion Substitution and Inducing Moderate Second Harmonic Generation Response and Large Birefringence55EuHgGeSe 4 and EuHgSnS 4 : Two Quaternary Eu-Based Infrared Nonlinear Optical Materials with Strong Second-Harmonic-Generation Responses55Aliovalent-cation-substitution-induced structure transformation: a new path toward high-performance IR nonlinear optical materials47Applying band gap engineering to tune the linear optical and nonlinear optical properties of noncentrosymmetric chalcogenides La 4 Ge 3 Se x S 12− x ( x = 0, 2, 4, 6, 8, 10)21Breaking through the “3.0 eV wall” of energy band gap in mid-infrared nonlinear optical rare earth chalcogenides by charge-transfer engineering145Facile syntheses of silver thioantimonates exhibiting second-harmonic generation responses and large birefringence18Ternary rare-earth sulfides RE3GaS6 (RE = Ho, Er): Crystal chemistry, second-order nonlinear optical properties and theoretical investigation18Magnetotransport Effects and Electronic Phase Separation in Manganese Sulfides with Electron–Hole Doping7Recent advances in nonlinear optical rare earth structures63Stepwise Li Substitution Induced Structure Evolution and Improved Nonlinear Optical Performance for Diamond-like Sulfides28Transition-metal-based chalcogenides: A rich source of infrared nonlinear optical materials184Noncentrosymmetric chalcohalide K2Ba3Ge3S9Cl2: A new nonlinear optical material with remarkable laser-induced damage threshold17Structural modification from centrosymmetric Rb 4 Hg 2 Ge 2 S 8 to noncentrosymmetric (Na 3 Rb)Hg 2 Ge 2 S 8 : mixed alkali metals strategy for infrared nonlinear optical material design28AAg 2 PS 4 (A = K, Na/K): the first-type of noncentrosymmetric alkali metal Ag-based thiophosphates exhibiting excellent second-order nonlinear optical performances21Alkali metal partial substitution-induced improved second-harmonic generation and enhanced laser-induced damage threshold for Ag-based sulfides21Characterization of soft chemically deposited yttrium sulfide (Y2S3) thin films4Rational design via dual-site aliovalent substitution leads to an outstanding IR nonlinear optical material with well-balanced comprehensive properties69Quaternary Noncentrosymmetric Rare-Earth Sulfides Ba4RE2Cd3S10 (RE = Sm, Gd, or Tb): A Joint Experimental and Theoretical Investigation17Magnetoresistance and magnetoimpedance in holmium manganese sulfides13SrZnSnSe4: A quaternary selenide with large second harmonic generation and birefringence40SrAgAsS4: A Noncentrosymmetric Sulfide with Good Infrared Nonlinear Optical Performance Induced by Aliovalent Substitution from Centrosymmetric SrGa2S412Eu 2 P 2 S 6 : The First Rare‐Earth Chalcogenophosphate Exhibiting Large Second‐Harmonic Generation Response and High Laser‐Induced Damage Threshold144Eu2P2S6: The First Rare‐Earth Chalcogenophosphate Exhibiting Large Second‐Harmonic Generation Response and High Laser‐Induced Damage Threshold7(Na0.74Ag1.26)BaSnS4: A New AgGaS2‐Type Nonlinear Optical Sulfide with a Wide Band Gap and High Laser Induced Damage Threshold14Structural, optical, electrical, and photovoltaic investigations of p-type Cu2MnSnSe4 thin films as a novel absorber layer for thin film solar cells13LaAeAl 3 S 7 (Ae = Ca, Sr): Cairo pentagonal layered thioaluminates achieving a good balance between a strong second harmonic generation response and a wide bandgap23Quaternary alkaline-earth metal thiophosphate SrAgPS 4 : syntheses, structures, and optical properties9Rational Design of a Rare‐Earth Oxychalcogenide Nd3[Ga3O3S3][Ge2O7] with Superior Infrared Nonlinear Optical Performance64Tailoring the structural, optical, and optoelectrical parameters of the thermally evaporated Ag2FeGeSe4 thin films18Recent advances in IR nonlinear optical chalcogenides with well-balanced comprehensive performance57AgMAsS3 (M = Cd, Hg): Double d10 Cation-Containing Thioarsenites(III) Exhibiting High Photocurrent Response and Moderate Second Harmonic Generation11Chemical modulation of A I RE III C IV QVI4 family compounds for band gap and optical anisotropy enhancement16Rare-earth oxychalcogenide Eu 2 ZnGe 2 OS 6 : a phase-matching infrared nonlinear optical material with [GeOS 3 ] units7Rare-earth-based chalcogenides and their derivatives: an encouraging IR nonlinear optical material candidate70Mixed Anionic M(S/X)6 Polyhedra as Symmetry-Breaking Motifs to Enhance the Infrared Nonlinear Optical Response in Y–M–S–X (M = Ga, Ge; X = Cl, Br)5A Rare Earth Chalcogenide Nonlinear Optical Crystal KLaGeS4: Achieving Good Balance among Band Gap, Second Harmonic Generation Effect, and Birefringence13K2HgGe3Se8: A Quaternary Hg-Based Selenide with Nonlinear Optical Properties6Phase-Matching Second-Harmonic Generation and Enhanced Laser-Induced Damage Threshold Induced by Cs Substitution: Cu 3 PSe 4 vs Cs 2 CuP 3 S 94LiLnGeS 4 (Ln=La−Nd): Designing High Performance Infrared Nonlinear Optical Sulfides through “Band Reformation of AGS”37LiLnGeS 4 (Ln=La−Nd): Designing High Performance Infrared Nonlinear Optical Sulfides through “Band Reformation of AGS”5Realizing Excellent Infrared Nonlinear Optical Performance in Eu-Based Chalcogenides via Rational Cross Substitution Strategy26Synthesis, Optical, and Magnetic Properties of the Mixed Chalcogenide Semiconductor Series Eu(II)2SiSexS4-x, Prepared via the Flux-Assisted Boron Chalcogen Mixture Method4Isovalent cation substitution drives structural transformation and infrared nonlinear optical activity in Eu-based chalcogenides11Synthesis of a series of rare-earth-based multi-anion chalcogenide iodides RE 3 Si 2 Se x S 8− x I (RE = La, Ce, Pr, and Nd) using the flux-assisted boron–chalcogen mixture method14Nonbonding Electron Inversion‐Driven Structural Engineering: Synergistic Enhancement of Linear and Nonlinear Optical Properties3Nonbonding Electron Inversion‐Driven Structural Engineering: Synergistic Enhancement of Linear and Nonlinear Optical Properties26Cation Equivalent Multisubstitution Realizing Structure Transformation and Balanced Nonlinear Optical Performance of Quaternary Eu-Based Chalcogenides8KYSiSe 4 : A Rare-Earth Selenide Infrared Nonlinear Optical Crystal with Wide Infrared Transparency and Well-Balanced E g and SHG Response9From Centrosymmetric Eu 2 Ga 2 S 5 to Noncentrosymmetric EuMg 6 Ga 6 S 16 via Introduction of Distorted MgS 6 Octahedron: Featuring Wide Bandgap and Nonlinear Optical Activity3Structure-property relationships in IR nonlinear optical chalcogenides with stereochemically active lone pairs29Exploring Al- and Ga-based quaternary materials: Toward next-gen UV protection and solar efficiency4ABCQ4型硫属化物红外非线性光学材料的构效关系(特邀)0SrMnGeS 4 : A Two-Dimensional Layered Chalcogenide with Magnetic Triangular Lattice0Synergistic Distortion Engineering: Activating Nonlinear Optical Response in Quaternary Chalcogenides via Lattice‐Induced [MnS 4 ] Asymmetry2From KBa 4 Ge 3 S 10 Cl to ABa 3 EuGe 3 S 11 (A = Na, K) Synthesized by Reactive Flux Assisted Metal Oxide-Boron-Chalcogen (MOBQ) Method: Effect of Cation/Anion Cosubstitution on Crystal Structure and Nonlinear Optical Properties0Flux-Assisted Growth and Characterization of Noncentrosymmetric Quaternary Rare-Earth Selenides CsRESiSe 4 (RE = La, Pr, Nd, Sm, Gd, Tb): Crystal Structure, Magnetism, and Theoretical Studies0AgEuPS4: Unlocking the Centrosymmetric Shackle of Rare-Earth Thiophosphates via Microscopic Distortion Cascading for Enhanced Second-Harmonic Generation Response1EuMn6Ga6S16: A Wide Bandgap Europium-Based Nonlinear Optical Sulfide0NaGa2PS6: A Noncentrosymmetric Thiophosphate with Wide Band Gap and High Laser-Induced Damage Threshold0Where Are Eu? Structural Diversity from Coloring Variants in Tellurides Eu(Al1– x Ga x )2Te40

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  1. A highly distorted HgS 4 tetrahedron-induced moderate second-harmonic generation response of EuHgGeS 4

    Inorganic Chemistry Frontiers · 2020-01-01

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  2. Mixed-metal thiophosphate CuCd 3 PS 6 : an infrared nonlinear optical material activated by its three-in-one tetrahedra-stacking architecture

    Journal of Materials Chemistry C · 2020-01-01

    Zhuang Li, Shengzi Zhang, Wenhao Xing, Yangwu Guo, Chunxiao Li, Zheshuai Lin, Jiyong Yao, Yicheng Wu

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  3. New quaternary chalcogenide Ba 4 HgAs 2 S 10 originating from the combination of linear [HgS 2 ] 2− and tetrahedral [AsS 4 ] 3− modules

    Dalton Transactions · 2020-01-01

    Wenhao Xing, Naizheng Wang, Zhuang Li, Wenhao Liu, Jian Tang, Wenlong Yin, Zheshuai Lin, Bin Kang, Jiyong Yao

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  4. (Na0.60Ba0.70)Ga2Se4: An Infrared Nonlinear Optical Crystal Designed using AgGaSe2 as the Template

    Inorganic Chemistry · 2020-03-03

    Yanan Li, Huaiguo Xue, Sheng‐Ping Guo

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  5. Crystal chemistry, second-order nonlinear optical, and magnetic properties of Eu8Sn4Se20

    Journal of Solid State Chemistry · 2020-05-08

    Sihan Yang, Xiaohui Li, Wen‐Dong Yao, Qian-Ting Xu, Sheng‐Ping Guo

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  6. Second-order nonlinear optical-active selenide borate Zn8Se2(BO2)12: Experimental and theoretical analysis

    Journal of Solid State Chemistry · 2020-07-18

    Wenfeng Zhou, Xiaohui Li, Wen‐Dong Yao, Huaiguo Xue, Sheng‐Ping Guo

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  7. Two Mixed-Anion Units of [GeOSe3] and [GeO3S] Originating from Partial Isovalent Anion Substitution and Inducing Moderate Second Harmonic Generation Response and Large Birefringence

    Inorganic Chemistry · 2020-10-26

    Wenhao Xing, Pan Fang, Naizheng Wang, Zhuang Li, Zheshuai Lin, Jiyong Yao, Wenlong Yin, Bin Kang

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  8. EuHgGeSe 4 and EuHgSnS 4 : Two Quaternary Eu-Based Infrared Nonlinear Optical Materials with Strong Second-Harmonic-Generation Responses

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  9. Aliovalent-cation-substitution-induced structure transformation: a new path toward high-performance IR nonlinear optical materials

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    Chang Liu, Shenghua Zhou, Yu Xiao, Chao Zhang, Hua Lin, Yi Liu

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  10. Applying band gap engineering to tune the linear optical and nonlinear optical properties of noncentrosymmetric chalcogenides La 4 Ge 3 Se x S 12− x ( x = 0, 2, 4, 6, 8, 10)

    Inorganic Chemistry Frontiers · 2021-01-01

    Gary Cicirello, Kui Wu, Bingbing Zhang, Jian Wang

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  11. Breaking through the “3.0 eV wall” of energy band gap in mid-infrared nonlinear optical rare earth chalcogenides by charge-transfer engineering

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    Dajiang Mei, Wangzhu Cao, Naizheng Wang, Xingxing Jiang, Jun Zhao, Weikang Wang, Junhui Dang, Shiyan Zhang, Yuandong Wu, Pinhua Rao, Zheshuai Lin

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  12. Facile syntheses of silver thioantimonates exhibiting second-harmonic generation responses and large birefringence

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    Gang Yang, Xingxing Jiang, Chao Wu, Zheshuai Lin, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

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  13. Ternary rare-earth sulfides RE3GaS6 (RE = Ho, Er): Crystal chemistry, second-order nonlinear optical properties and theoretical investigation

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    Hao-Yu Chen, Yingying Zhang, Yifan Yang, Sheng‐Ping Guo

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  14. Magnetotransport Effects and Electronic Phase Separation in Manganese Sulfides with Electron–Hole Doping

    Journal of Experimental and Theoretical Physics · 2021-05-01

    О. Б. Романова, Аплеснин Сергей Степанович, М. Н. Ситников, Lubov V. Udod

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  15. Recent advances in nonlinear optical rare earth structures

    Journal of Rare Earths · 2021-07-15

    Jun Zhao, Dajiang Mei, Weikang Wang, Yuandong Wu, Dongfeng Xue

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  16. Stepwise Li Substitution Induced Structure Evolution and Improved Nonlinear Optical Performance for Diamond-like Sulfides

    Inorganic Chemistry · 2021-07-27

    Wenfeng Zhou, Qingming Zhang, Wen‐Dong Yao, Huaiguo Xue, Sheng‐Ping Guo

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  17. Transition-metal-based chalcogenides: A rich source of infrared nonlinear optical materials

    Coordination Chemistry Reviews · 2021-08-26

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  18. Noncentrosymmetric chalcohalide K2Ba3Ge3S9Cl2: A new nonlinear optical material with remarkable laser-induced damage threshold

    Journal of Alloys and Compounds · 2021-11-13

    Wenfeng Zhou, Zhi‐Hui Shi, Wenlong Liu, Sheng‐Ping Guo

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  19. Structural modification from centrosymmetric Rb 4 Hg 2 Ge 2 S 8 to noncentrosymmetric (Na 3 Rb)Hg 2 Ge 2 S 8 : mixed alkali metals strategy for infrared nonlinear optical material design

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  20. AAg 2 PS 4 (A = K, Na/K): the first-type of noncentrosymmetric alkali metal Ag-based thiophosphates exhibiting excellent second-order nonlinear optical performances

    Inorganic Chemistry Frontiers · 2022-01-01

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  21. Alkali metal partial substitution-induced improved second-harmonic generation and enhanced laser-induced damage threshold for Ag-based sulfides

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  22. Characterization of soft chemically deposited yttrium sulfide (Y2S3) thin films

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  23. Rational design via dual-site aliovalent substitution leads to an outstanding IR nonlinear optical material with well-balanced comprehensive properties

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  24. Quaternary Noncentrosymmetric Rare-Earth Sulfides Ba4RE2Cd3S10 (RE = Sm, Gd, or Tb): A Joint Experimental and Theoretical Investigation

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  25. Magnetoresistance and magnetoimpedance in holmium manganese sulfides

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  26. SrZnSnSe4: A quaternary selenide with large second harmonic generation and birefringence

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  27. SrAgAsS4: A Noncentrosymmetric Sulfide with Good Infrared Nonlinear Optical Performance Induced by Aliovalent Substitution from Centrosymmetric SrGa2S4

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  28. Eu 2 P 2 S 6 : The First Rare‐Earth Chalcogenophosphate Exhibiting Large Second‐Harmonic Generation Response and High Laser‐Induced Damage Threshold

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  29. Eu2P2S6: The First Rare‐Earth Chalcogenophosphate Exhibiting Large Second‐Harmonic Generation Response and High Laser‐Induced Damage Threshold

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  30. (Na0.74Ag1.26)BaSnS4: A New AgGaS2‐Type Nonlinear Optical Sulfide with a Wide Band Gap and High Laser Induced Damage Threshold

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  31. Structural, optical, electrical, and photovoltaic investigations of p-type Cu2MnSnSe4 thin films as a novel absorber layer for thin film solar cells

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  32. LaAeAl 3 S 7 (Ae = Ca, Sr): Cairo pentagonal layered thioaluminates achieving a good balance between a strong second harmonic generation response and a wide bandgap

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    Jingjing Xu, Kui Wu, Bingbing Zhang, Haohai Yu, Huaijin Zhang

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  33. Quaternary alkaline-earth metal thiophosphate SrAgPS 4 : syntheses, structures, and optical properties

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  34. Rational Design of a Rare‐Earth Oxychalcogenide Nd3[Ga3O3S3][Ge2O7] with Superior Infrared Nonlinear Optical Performance

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  35. Tailoring the structural, optical, and optoelectrical parameters of the thermally evaporated Ag2FeGeSe4 thin films

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  36. Recent advances in IR nonlinear optical chalcogenides with well-balanced comprehensive performance

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  37. AgMAsS3 (M = Cd, Hg): Double d10 Cation-Containing Thioarsenites(III) Exhibiting High Photocurrent Response and Moderate Second Harmonic Generation

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  38. Chemical modulation of A I RE III C IV QVI4 family compounds for band gap and optical anisotropy enhancement

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  39. Rare-earth oxychalcogenide Eu 2 ZnGe 2 OS 6 : a phase-matching infrared nonlinear optical material with [GeOS 3 ] units

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  40. Rare-earth-based chalcogenides and their derivatives: an encouraging IR nonlinear optical material candidate

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  41. Mixed Anionic M(S/X)6 Polyhedra as Symmetry-Breaking Motifs to Enhance the Infrared Nonlinear Optical Response in Y–M–S–X (M = Ga, Ge; X = Cl, Br)

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  42. A Rare Earth Chalcogenide Nonlinear Optical Crystal KLaGeS4: Achieving Good Balance among Band Gap, Second Harmonic Generation Effect, and Birefringence

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  43. K2HgGe3Se8: A Quaternary Hg-Based Selenide with Nonlinear Optical Properties

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  44. Phase-Matching Second-Harmonic Generation and Enhanced Laser-Induced Damage Threshold Induced by Cs Substitution: Cu 3 PSe 4 vs Cs 2 CuP 3 S 9

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  45. LiLnGeS 4 (Ln=La−Nd): Designing High Performance Infrared Nonlinear Optical Sulfides through “Band Reformation of AGS”

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  46. LiLnGeS 4 (Ln=La−Nd): Designing High Performance Infrared Nonlinear Optical Sulfides through “Band Reformation of AGS”

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  47. Realizing Excellent Infrared Nonlinear Optical Performance in Eu-Based Chalcogenides via Rational Cross Substitution Strategy

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  48. Synthesis, Optical, and Magnetic Properties of the Mixed Chalcogenide Semiconductor Series Eu(II)2SiSexS4-x, Prepared via the Flux-Assisted Boron Chalcogen Mixture Method

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  49. Isovalent cation substitution drives structural transformation and infrared nonlinear optical activity in Eu-based chalcogenides

    Inorganic Chemistry Frontiers · 2025-01-01

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  50. Synthesis of a series of rare-earth-based multi-anion chalcogenide iodides RE 3 Si 2 Se x S 8− x I (RE = La, Ce, Pr, and Nd) using the flux-assisted boron–chalcogen mixture method

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