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RESEARCH PAPER · Angewandte Chemie International Edition · 2019

Sr 6 Cd 2 Sb 6 O 7 S 10 : Strong SHG Response Activated by Highly Polarizable Sb/O/S Groups

Ruiqi Wang, Fei Liang, Fakun Wang, Yangwu Guo, Xian Zhang, Yi Xiao, Kejun Bu, Zheshuai Lin, Jiyong Yao, Tianyou Zhai, Fuqiang Huang

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Sr 6 Cd 2 Sb 6 O 7 S 10 : Strong SHG Response Activated by Highly Polarizable Sb/O/S GroupsOriginal“Two in one”: an unprecedented mixed anion, Ba 2 (C 3 N 3 O 3 )(CNO), with the coexistence of isolated sp and sp 2 π-conjugated groups15Ba 4 (BS 3 S) 2 S 4 : a new thioborate with unprecedented [BS 3 -S] and [S 4 ] fundamental building blocks19Cs 2 CdV 2 O 6 Cl 2 and Cs 3 CdV 4 O 12 Br: two new non-centrosymmetric oxyhalides containing d 0 and d 10 cations and exhibiting second harmonic generation activity19LiO 4 tetrahedra lock the alignment of π-conjugated layers to maximize optical anisotropy in metal hydroisocyanurates44Synthesis, crystal structures and optical properties of noncentrosymmetric oxysulfides AeGeS 2 O (Ae = Sr, Ba)45LiMII(IO3)3 (MII=Zn and Cd): Two Promising Nonlinear Optical Crystals Derived from a Tunable Structure Model of α‐LiIO398LiMII(IO3)3 (MII=Zn and Cd): Two Promising Nonlinear Optical Crystals Derived from a Tunable Structure Model of α‐LiIO337“Old dog, new tricks”: the lone pair effect inducing divergent optical responses in lead cyanurates containing π-bonds18Sr 4 Pb 1.5 Sb 5 O 5 Se 8 : a new mid-infrared nonlinear optical material with a moderate SHG response22Synthesis, crystal structure, and magnetic properties of layered SmCrS 2−x Se x O solid solutions3Insight into the Expanded Mislinked Porphyrins with High Second Order Nonlinear Optical Response34Volume Modulation of Nonlinear Optical Properties by Cation Substitution8HgCuPS4: An Exceptional Infrared Nonlinear Optical Material with Defect Diamond-like Structure145Identifying the Crystalline Orientation of Mechanically Exfoliated Anisotropic Layered Materials through Their Morphologies9Second-Order Nonlinear-Optical-Active Selenide Borate YSeBO2: Featuring a [YSeBO2]n Planar Belt39Partial Isovalent Anion Substitution to Access Remarkable Second-Harmonic Generation Response: A Generic and Effective Strategy for Design of Infrared Nonlinear Optical Materials1142D Inorganic Bimolecular Crystals with Strong In‐Plane Anisotropy for Second‐Order Nonlinear Optics57Sr5Ga8O3S14: A Nonlinear Optical Oxysulfide with Melilite-Derived Structure and Wide Band Gap48Anionic Aliovalent Substitution from Structure Models of ZnS: Novel Defect Diamond‐like Halopnictide Infrared Nonlinear Optical Materials with Wide Band Gaps and Large SHG Effects78Anionic Aliovalent Substitution from Structure Models of ZnS: Novel Defect Diamond‐like Halopnictide Infrared Nonlinear Optical Materials with Wide Band Gaps and Large SHG Effects19Two Mixed-Anion Units of [GeOSe3] and [GeO3S] Originating from Partial Isovalent Anion Substitution and Inducing Moderate Second Harmonic Generation Response and Large Birefringence55Growth of 2D MoP single crystals on liquid metals by chemical vapor deposition20From AgGaS 2 to AgHgPS 4 : vacancy defects and highly distorted HgS 4 tetrahedra double-induced remarkable second-harmonic generation response67Recent Achievements in Lone-Pair Cation-Based Infrared Second-Order Nonlinear Optical Materials95Sb6O7(SO4)2: A Promising Ultraviolet Nonlinear Optical Material with an Enhanced Second‐Harmonic‐Generation Response Activated by SbIII Lone‐Pair Stereoactivity62[GaF(H 2 O)][IO 3 F]: a promising NLO material obtained by anisotropic polycation substitution42A series of oxysulfides RE 2 M 2 S 3 O 4 (RE = Y, Tm; M = Zr, Hf) featuring a unique MS 3 O 4 motif and {[M 2 S 3 O 4 ] 8− } ∞ wrinkle layer13Aliovalent-cation-substitution-induced structure transformation: a new path toward high-performance IR nonlinear optical materials47Application of Second Harmonic Generation in Characterization of 2D Materials16Ba 2 Ge 2 Te 5 : a ternary NLO-active telluride with unusual one-dimensional helical chains and giant second harmonic-generation tensors31La 6 Cd 0.75 Ga 2 Q 11.5 Cl 2.5 (Q = S and Se): two new nonlinear optical chalcohalides with a large laser-induced damage threshold15Recent progress in oxychalcogenides as IR nonlinear optical materials79Tuning the first hyperpolarizability of hexaphyrins with different connections of mislinked pyrrole units: a theoretical study17Synthesis, Crystal Structures, and Thermal Analyses of Two New Antimony Tellurite Sulfates: [Sb2(TeO4)](SO4) and [Sb2(TeO3)2](SO4)10AXHg3P2S8 (A = Rb, Cs; X = Cl, Br): New Excellent Infrared Nonlinear Optical Materials with Mixed‐Anion Chalcohalide Groups of Trigonal Planar [HgS2X]3− and Tetrahedral [HgS3X]5−58Structural Transformation and Second-Harmonic-Generation Activity in Rare-Earth and d0 Transition-Metal Oxysulfides RE3NbS3O4 (RE = Ce, Sm, Gd, Dy)38Hg 3 P 2 S 8 : A New Promising Infrared Nonlinear Optical Material with a Large Second-Harmonic Generation and a High Laser-Induced Damage Threshold111Transition-metal-based chalcogenides: A rich source of infrared nonlinear optical materials184Symmetry and the Role of the Anion Sublattice in Aurivillius Oxyfluoride Bi2TiO4F218La 3 Ga 3 Ge 2 S 3 O 10 : An Ultraviolet Nonlinear Optical Oxysulfide Designed by Anion‐Directed Band Gap Engineering63La3Ga3Ge2S3O10: An Ultraviolet Nonlinear Optical Oxysulfide Designed by Anion‐Directed Band Gap Engineering18Highly polarized [GeOTe 3 ] motif-driven structural order promotion and an enhanced second harmonic generation response in the new nonlinear optical oxytelluride Ba 3 Ge 2 O 4 Te 334Ca-cluster-constructed deep-ultraviolet nonlinear-optical crystal Na2Ca17Al2(PO4)14 with strong NLO response11Cd7SiAs6, a Nonchalcopyrite Arsenide with a Strong Nonlinear-Optical Response9Complex coordinated functional groups: A great genes for nonlinear optical materials64Rational Crystal Structure Design and Nonlinear-Optical Properties of Noncentrosymmetric RbCu2NbS47Structural modification from centrosymmetric Rb 4 Hg 2 Ge 2 S 8 to noncentrosymmetric (Na 3 Rb)Hg 2 Ge 2 S 8 : mixed alkali metals strategy for infrared nonlinear optical material design28[ASr 4 Cl][Ge 3 S 10 ] (A = Na, K) and [KBa 4 Cl][Ge 3 S 10 ]: new salt-inclusion infrared nonlinear optical crystals with zero-dimensional [Ge 3 S 9 ] clusters32Antiferromagnetic quaternary chalco-halide Ba 3 (FeS 4 )I with long Fe⋯Fe distances3From oxides to oxysulfides: the mixed-anion GeS 3 O unit induces huge improvement in the nonlinear optical effect and optical anisotropy for potential nonlinear optical materials19Infrared nonlinear optical sulfide CsCd 4 In 5 S 12 exhibiting large second harmonic generation response16Metal oxyhalides: an emerging family of nonlinear optical materials124Rational design of a promising oxychalcogenide infrared nonlinear optical crystal60Structural dimension modulation in a new oxysulfide system of Ae 2 Sb 2 O 2 S 3 (Ae = Ca and Ba)4Sr3[SnOSe3][CO3]: A Heteroanionic Nonlinear Optical Material Containing Planar π‐conjugated [CO3] and Heteroleptic [SnOSe3] Anionic Groups78Sr3[SnOSe3][CO3]: A Heteroanionic Nonlinear Optical Material Containing Planar π‐conjugated [CO3] and Heteroleptic [SnOSe3] Anionic Groups7One-Side Capping in Two-Dimensional WO 3 -Type Materials Leading to Strong Second-Harmonic Response29Enhanced Second-Harmonic-Generation Efficiency and Birefringence in Melillite Oxychalcogenides Sr2MGe2OS6 (M = Mn, Zn, and Cd)97Negative Second Harmonic Response of Sn4+in the Fresnoite Oxysulfide Ba2SnSSi2O720Improved Polarization in the Sr6Cd2Sb6O7Se10 Oxyselenide through Design of Lateral Sublattices for Efficient Photoelectric Conversion4Improved Polarization in the Sr6Cd2Sb6O7Se10 Oxyselenide through Design of Lateral Sublattices for Efficient Photoelectric Conversion16Zero-Dimensional Molecular Ferroelectrics with Significant Nonlinear Effect and Giant Entropy33First Investigation of Nonlinear Optical Oxychalcogenide with Three‐Dimensional Anionic Framework and Special Windmill‐Like Functional Motifs †28Mixed-Anion-Oriented Design of LnMGa3S6O (Ln = La, Pr, and Nd; M = Ca and Sr) Nonlinear Optical Oxysulfides with Targeted Property Balance56Interfacial Engineering towards Enhanced Photovoltaic Performance of Sb2Se3 Solar Cell79Chemical Vapor Deposition Growth of Homogeneous Stacked Polycrystalline WSe2 with Branched Patterns for Modulating Light–Matter Interactions1Oxychalcogenides as Promising Ultraviolet Nonlinear Optical Candidates: Experimental and Theoretical Studies of AEGeOS2(AE = Sr and Ba)24Characterizations and Nonlinear-Optical Properties of Pentanary Transition-Metal Oxysulfide Sr2CoGe2OS626Ag[SC(NH2)2]2F: A Laser Damage-Tolerant Infrared Nonlinear Optical Material9Photocatalytic and Photocurrent Responses to Visible Light of the Lone-Pair-Based Oxysulfide Sr6Cd2Sb6S10O728The Antiperovskite‐Type Oxychalcogenides Ae3Q[GeOQ3] (Ae = Ba, Sr; Q = S, Se) with Large Second Harmonic Generation Responses and Wide Band Gaps68Large-Area Orientation-Controlled Growth of Hexagonal Boron Nitride on Liquid Copper9KREP2Se6 (RE = Sm, Gd, Tb): The First Rare‐Earth Selenophosphates with Remarkable Nonlinear Optical Activities Realized by Synergistic Effect of RE‐ and P‐Based Motifs39Ba5Ga2SiO4S6: a Phase-Matching Nonlinear Optical Oxychalcogenide Design via Structural Regulation Originated from Heteroanion Introduction25Oxychalcogenides: A Promising Class of Materials for Nonlinear Optical Crystals with Mixed‐Anion Groups35Effect of strain on the band structure and optical properties of Na2Bi2(SeO3)3F21A unique [Sb 6 O 2 S 13 ] 12− finite chain in oxychalcogenide Ba 6 Sb 6 O 2 S 13 leading to ultra-low thermal conductivity and giant birefringence12Ba4cd2ge2te9: A Promising Infrared Functional Crystal with Large Birefringent And Photoluminescent Properties0Heteroanion-introduction-driven birefringence enhancement in oxychalcogenide Ba 3 M II Ge 3 O 2 S 8 (M II = Mn, Cd)19Hg 3 O 2 (NO 3 )F: a mercury nitrate oxyfluoride with an unprecedented [(Hg 3 O 2 F) + ] ∞ cationic framework and excellent optical anisotropy21Rational Design of a Rare‐Earth Oxychalcogenide Nd3[Ga3O3S3][Ge2O7] with Superior Infrared Nonlinear Optical Performance64[K2PbX][Ga7S12] (X = Cl, Br, I): The First Lead‐Containing Cationic Moieties with Ultrahigh Second‐Harmonic Generation and Band Gaps Exceeding the Criterion of 2.33 eV46Chain‐like [S x ] ( x =2–6) Units Realizing Giant Birefringence with Transparency in the Near‐Infrared for Optoelectronic Materials53Chain‐like [S x ] ( x =2–6) Units Realizing Giant Birefringence with Transparency in the Near‐Infrared for Optoelectronic Materials5Comprehensive review on multiple mixed-anion ligands, physicochemical performances and application prospects in metal oxysulfides32Non‐Centrosymmetric 2D Nb3SeI7 with High In‐Plane Anisotropy and Optical Nonlinearity24Transition Metal Dichalcogenides Heterostructures Nanoribbons9Hg3(SeO3)2(SO4): A UV Nonlinear Optical Mercury Selenite Sulfate Constructed by Neat [Hg6O8(SeO3)4]∞ Layers and SO4 Tetrahedra27[Ba4(S2)][ZnGa4S10]: Design of an Unprecedented Infrared Nonlinear Salt‐Inclusion Chalcogenide with Disulfide‐Bonds36Synthesis of Non-centrosymmetric, Metastable Rare-Earth Oxysulfides by Anionic Redox Topochemistry8Towards the design of oxychalcogenide materials as candidates for solar water- splitting photocatalysis0Low Carrier Effective Masses in Photoactive Sr2Sb2O2Q3 (Q = S, Se): The Role of the Lone Pair17AGe2O4Q (A = Ba, Sr; Q = S, Se): A series of heteroanionic oxychalcogenides with large birefringence9Solvent Annealing Enabling Reconstruction of Cadmium Sulfide Film for Improved Heterojunction Quality and Photovoltaic Performance of Antimony Selenosulfide Solar Cells28Ba4Cd2Ge2Te9: A promising infrared functional crystal with large birefringent and photoluminescence properties2Partial substitution with a significant effect: coexistence of a wide band gap and large birefringence in the oxychalcogenide AEGe 2 O 4 Se (AE = Sr and Ba)17Rare-earth-based chalcogenides and their derivatives: an encouraging IR nonlinear optical material candidate70Screening Large Birefringent Materials via Halogen Regulation in Ternary d0-Transition Metal Oxyhalides8Ba10In2Mn11Si3O12S18: First Hexanary Oxychalcogenide Containing an Infrequent Three-Dimensional Noncentrosysmmetric Framework8Evaluation and prospect of Mid-Infrared nonlinear optical materials in f0 rare earth (RE = Sc, Y, La) chalcogenides44Infrared nonlinear optical materials with multiple strongly ionic cations5La2O2MQ2 phases: Stability and synthetic challenges0Carbonatoperoxovanadates with Strong Second‐Harmonic Generation: Insights from First‐Principles Calculations on Anisotropic Structures and Optical Parameters0Balanced IR Nonlinear Optical Performance Achieved by Cation–Anion Module Cosubstitution in V-Based Salt-Inclusion Oxychalcogenides22Birefringence Disparity Induced by Synergistic Effects of Stereochemically Active Lone Pairs19La 3 (Ga 3 S 3 O 3 )(Si 2 O 7 ): An Oxychalcogenide Demonstrating Ultrawide Optical Bandgap and Favorable Birefringence Propelled by Divergent Anionic Groups6Advances in oxychalcogenide materials for hydrogen evolution photocatalysis in aqueous media9La 2 ZnGa 2 S 6 O: a melilite-type transition metal oxysulfide achieving a well-balanced nonlinear optical behavior5Structural diversity and photocurrent responses of multi-component chalcogenidometalates8Hetero‐Anionic Oxychalcogenides with Structures and Properties Tuned by the O:S Ratio14Layered Anion‐Mixed Oxycompounds: Synthesis, Properties, and Applications29Zero-Dimensional Oxyselenide Ba12[(Ga2OSe5)3(Si2O7)]: Enhanced Optical Anisotropy through Heteroanionic Engineering4Recent progress in structural design strategies of high-birefringence optical crystals54Recent Research Progress of Antimony‐Based Two‐Dimensional Materials for Electronics and Optoelectronics20Structure-property relationships in IR nonlinear optical chalcogenides with stereochemically active lone pairs29Metal Chloride‐Iodate Nonlinear Optical Materials via Direct Chlorination of Centrosymmetric Metal Iodate Crystals0A Homoatomic Heteroleptic Coordination Strategy for Exceptional Infrared Linear and Nonlinear Optical Properties in ANb 2 PS 4 (S 2 ) 3 (A = K,Rb,Cs)3Syntheses, structures and optical properties of two new cadmium antimonites: Cs 4 Cd(SbF 5 ) 3 (H 2 O) 2 and Cd[Sb 7 O 10 (OH)](SO 4 )0First‐Principles Investigation of the Structural, Electronic, Optical, Elastic, and Thermal Properties of Defect Diamond‐Like Hg 3 P 2 S 80CaM 3 Si 4 P 11 (M = Al, Ga): [P 2 ] Motifs‐Modified Quasi‐T 3 Supertetrahedra Drive Superior Infrared Nonlinear Optical Performances1Heterometallic Ge–O–Sn-Bridged Oxychalcogenides Sr3GeSnO4Q3 (Q = S, Se) with Wide Band Gaps and Moderate Infrared Nonlinear Optical Responses0Non-π-conjugated tetrahedra-based optical crystals: The improvement of the linear and nonlinear optical properties by the combination of trigonal pyramidal [XO3] (X = I, Se, Te) units1Sulfur-doping-engineered compressive strain promotes interlayer charge transport for efficient CO2 photoreduction in bismuth oxyhalides0Coordination chemistry of Sb(III)-based optical crystals: from lone-pair-induced distortion to birefringence and second-harmonic generation0

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  1. “Two in one”: an unprecedented mixed anion, Ba 2 (C 3 N 3 O 3 )(CNO), with the coexistence of isolated sp and sp 2 π-conjugated groups

    Dalton Transactions · 2019-01-01

    Jian Tang, Fei Liang, Xianghe Meng, Kaijin Kang, Tixian Zeng, Wenlong Yin, Mingjun Xia, Zheshuai Lin, Bin Kang

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  2. Ba 4 (BS 3 S) 2 S 4 : a new thioborate with unprecedented [BS 3 -S] and [S 4 ] fundamental building blocks

    Chemical Communications · 2019-01-01

    Guangmao Li, Junjie Li, Kui Wu, Zhihua Yang, Shilie Pan

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  3. Cs 2 CdV 2 O 6 Cl 2 and Cs 3 CdV 4 O 12 Br: two new non-centrosymmetric oxyhalides containing d 0 and d 10 cations and exhibiting second harmonic generation activity

    Dalton Transactions · 2019-01-01

    Yanjun Li, Dan Zhang, Lili Liu, Weiguo Zhang, Jiang Zhang, Ye Cong, Xuanke Li, P. Shiv Halasyamani

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  4. LiO 4 tetrahedra lock the alignment of π-conjugated layers to maximize optical anisotropy in metal hydroisocyanurates

    Inorganic Chemistry Frontiers · 2019-01-01

    Xianghe Meng, Fei Liang, Jian Tang, Kaijin Kang, Wenlong Yin, Tixian Zeng, Bin Kang, Zheshuai Lin, Mingjun Xia

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  5. Synthesis, crystal structures and optical properties of noncentrosymmetric oxysulfides AeGeS 2 O (Ae = Sr, Ba)

    Dalton Transactions · 2019-01-01

    Xian Zhang, Yi Xiao, Ruiqi Wang, Peng‐Xiang Fu, Chong Zheng, Fuqiang Huang

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  6. LiMII(IO3)3 (MII=Zn and Cd): Two Promising Nonlinear Optical Crystals Derived from a Tunable Structure Model of α‐LiIO3

    Angewandte Chemie International Edition · 2019-09-20

    Ying‐Jie Jia, Yi-Gang Chen, Yao Guo, Xiao‐Fang Guan, Chengbo Li, Bingxuan Li, Minmin Liu, Xian‐Ming Zhang

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  7. LiMII(IO3)3 (MII=Zn and Cd): Two Promising Nonlinear Optical Crystals Derived from a Tunable Structure Model of α‐LiIO3

    Angewandte Chemie · 2019-09-20

    Ying‐Jie Jia, Yi-Gang Chen, Yao Guo, Xiao‐Fang Guan, Chengbo Li, Bingxuan Li, Min‐Min Liu, Xian‐Ming Zhang

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  8. “Old dog, new tricks”: the lone pair effect inducing divergent optical responses in lead cyanurates containing π-bonds

    Dalton Transactions · 2019-12-11

    Xianghe Meng, Kaijin Kang, Fei Liang, Jian Tang, Zheshuai Lin, Wenlong Yin, Mingjun Xia

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  9. Sr 4 Pb 1.5 Sb 5 O 5 Se 8 : a new mid-infrared nonlinear optical material with a moderate SHG response

    CrystEngComm · 2020-01-01

    Yang Wang, Mengjia Luo, Pei Zhao, Xiangli Che, Yunzhen Cao, Fuqiang Huang

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  10. Synthesis, crystal structure, and magnetic properties of layered SmCrS 2−x Se x O solid solutions

    Inorganic Chemistry Frontiers · 2020-01-01

    Yi Xiao, Xian Zhang, Ruiqi Wang, Chong Zheng, Fuqiang Huang

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  11. Insight into the Expanded Mislinked Porphyrins with High Second Order Nonlinear Optical Response

    The Journal of Physical Chemistry A · 2020-01-23

    Bo Li, Palanivel Sathishkumar, Feng Long Gu, Chaoyuan Zhu

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  12. Volume Modulation of Nonlinear Optical Properties by Cation Substitution

    The Journal of Physical Chemistry C · 2020-04-15

    Jingmei Min, Hao Li, Jun Zhang

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  13. HgCuPS4: An Exceptional Infrared Nonlinear Optical Material with Defect Diamond-like Structure

    Chemistry of Materials · 2020-04-24

    Mengyue Li, Zuju Ma, Bingxuan Li, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  14. Identifying the Crystalline Orientation of Mechanically Exfoliated Anisotropic Layered Materials through Their Morphologies

    Advanced Materials Interfaces · 2020-05-29

    Xia Wang, Xiaofang Jiang, Zongbao Li, Yubin Xue, Jieyu Wu, Yongsong Wang, Xianhu Liu, Xiaobo Xing, Zhilie Tang, Ding‐Jiang Xue

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  15. Second-Order Nonlinear-Optical-Active Selenide Borate YSeBO2: Featuring a [YSeBO2]n Planar Belt

    Inorganic Chemistry · 2020-05-29

    Zhen‐Tao Lu, Wenjing Fan, Zhiqian Wang, Ning Gu, Zeng-Hao Yue, Huaiguo Xue, Sheng‐Ping Guo

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  16. Partial Isovalent Anion Substitution to Access Remarkable Second-Harmonic Generation Response: A Generic and Effective Strategy for Design of Infrared Nonlinear Optical Materials

    Chemistry of Materials · 2020-06-04

    Mao‐Yin Ran, Zuju Ma, Hong Chen, Bingxuan Li, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  17. 2D Inorganic Bimolecular Crystals with Strong In‐Plane Anisotropy for Second‐Order Nonlinear Optics

    Advanced Materials · 2020-06-26

    Xinliang Feng, Zongdong Sun, Ke Pei, Wei Han, Fakun Wang, Peng Luo, Jianwei Su, Nian Zuo, Guiheng Liu, Huiqiao Li, Tianyou Zhai

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  18. Sr5Ga8O3S14: A Nonlinear Optical Oxysulfide with Melilite-Derived Structure and Wide Band Gap

    Inorganic Chemistry · 2020-07-02

    Ruiqi Wang, Yangwu Guo, Xian Zhang, Yi Xiao, Jiyong Yao, Fuqiang Huang

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  19. Anionic Aliovalent Substitution from Structure Models of ZnS: Novel Defect Diamond‐like Halopnictide Infrared Nonlinear Optical Materials with Wide Band Gaps and Large SHG Effects

    Angewandte Chemie International Edition · 2020-09-04

    Jindong Chen, Chensheng Lin, Dan Zhao, Min Luo, Guang Peng, Bingxuan Li, Shunda Yang, Yingshuang Sun, Ning Ye

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  20. Anionic Aliovalent Substitution from Structure Models of ZnS: Novel Defect Diamond‐like Halopnictide Infrared Nonlinear Optical Materials with Wide Band Gaps and Large SHG Effects

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  21. Two Mixed-Anion Units of [GeOSe3] and [GeO3S] Originating from Partial Isovalent Anion Substitution and Inducing Moderate Second Harmonic Generation Response and Large Birefringence

    Inorganic Chemistry · 2020-10-26

    Wenhao Xing, Pan Fang, Naizheng Wang, Zhuang Li, Zheshuai Lin, Jiyong Yao, Wenlong Yin, Bin Kang

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  22. Growth of 2D MoP single crystals on liquid metals by chemical vapor deposition

    Science China Materials · 2020-11-13

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  23. From AgGaS 2 to AgHgPS 4 : vacancy defects and highly distorted HgS 4 tetrahedra double-induced remarkable second-harmonic generation response

    Journal of Materials Chemistry C · 2020-12-12

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  24. Recent Achievements in Lone-Pair Cation-Based Infrared Second-Order Nonlinear Optical Materials

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  25. Sb6O7(SO4)2: A Promising Ultraviolet Nonlinear Optical Material with an Enhanced Second‐Harmonic‐Generation Response Activated by SbIII Lone‐Pair Stereoactivity

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  26. [GaF(H 2 O)][IO 3 F]: a promising NLO material obtained by anisotropic polycation substitution

    Chemical Science · 2021-01-01

    Q. Huang, Chun‐Li Hu, Bing‐Ping Yang, Zhi Gang Fang, Yuan Hua Lin, Jin Chen, Bingxuan Li, Jiang‐Gao Mao

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  27. A series of oxysulfides RE 2 M 2 S 3 O 4 (RE = Y, Tm; M = Zr, Hf) featuring a unique MS 3 O 4 motif and {[M 2 S 3 O 4 ] 8− } ∞ wrinkle layer

    Chemical Communications · 2021-01-01

    Zhen‐Tao Lu, Sihan Yang, Wenlong Liu, Sheng‐Ping Guo

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  28. Aliovalent-cation-substitution-induced structure transformation: a new path toward high-performance IR nonlinear optical materials

    Journal of Materials Chemistry C · 2021-01-01

    Chang Liu, Shenghua Zhou, Yu Xiao, Chao Zhang, Hua Lin, Yi Liu

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  29. Application of Second Harmonic Generation in Characterization of 2D Materials

    Journal of Inorganic Materials · 2021-01-01

    Fangfang XIA, Fakun Wang, Hailong Hu, Xiang XU, Yang Li, Tianyou Zhai

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  30. Ba 2 Ge 2 Te 5 : a ternary NLO-active telluride with unusual one-dimensional helical chains and giant second harmonic-generation tensors

    Inorganic Chemistry Frontiers · 2021-01-01

    Mao‐Yin Ran, Zuju Ma, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  31. La 6 Cd 0.75 Ga 2 Q 11.5 Cl 2.5 (Q = S and Se): two new nonlinear optical chalcohalides with a large laser-induced damage threshold

    CrystEngComm · 2021-01-01

    Feng Lin, Mengjia Luo, Ruiqi Wang, Xiangli Che, Fuqiang Huang

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  32. Recent progress in oxychalcogenides as IR nonlinear optical materials

    Dalton Transactions · 2021-01-01

    Yang-Fang Shi, Wenbo Wei, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  33. Tuning the first hyperpolarizability of hexaphyrins with different connections of mislinked pyrrole units: a theoretical study

    Physical Chemistry Chemical Physics · 2021-01-01

    Bo Li, Palanivel Sathishkumar, Feng Long Gu

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  34. Synthesis, Crystal Structures, and Thermal Analyses of Two New Antimony Tellurite Sulfates: [Sb2(TeO4)](SO4) and [Sb2(TeO3)2](SO4)

    Zeitschrift für anorganische und allgemeine Chemie · 2021-05-06

    Jiayuan Zhang, Xiao Zhao, Yuandong Wu, Dajiang Mei, Shaoguo Wen, Thomas Doert

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  35. AXHg3P2S8 (A = Rb, Cs; X = Cl, Br): New Excellent Infrared Nonlinear Optical Materials with Mixed‐Anion Chalcohalide Groups of Trigonal Planar [HgS2X]3− and Tetrahedral [HgS3X]5−

    Advanced Optical Materials · 2021-05-20

    Wenhao Xing, Chunlan Tang, Naizheng Wang, Chunxiao Li, Ece Uykur, Jieyun Wu, Zheshuai Lin, Jiyong Yao, Wenlong Yin, Bin Kang

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  36. Structural Transformation and Second-Harmonic-Generation Activity in Rare-Earth and d0 Transition-Metal Oxysulfides RE3NbS3O4 (RE = Ce, Sm, Gd, Dy)

    Inorganic Chemistry · 2021-07-09

    Xin Lian, Zhen‐Tao Lu, Wen‐Dong Yao, Sihan Yang, Wenlong Liu, Ru‐Ling Tang, Sheng‐Ping Guo

    Read original paper ↗ ·

  37. Hg 3 P 2 S 8 : A New Promising Infrared Nonlinear Optical Material with a Large Second-Harmonic Generation and a High Laser-Induced Damage Threshold

    Chemistry of Materials · 2021-08-05

    Yu Chu, Peng Wang, Hao Zeng, Shichao Cheng, Xin Su, Zhihua Yang, Junjie Li, Shilie Pan

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  38. Transition-metal-based chalcogenides: A rich source of infrared nonlinear optical materials

    Coordination Chemistry Reviews · 2021-08-26

    Hong Chen, Wenbo Wei, Hua Lin, Xintao Wu

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  39. Symmetry and the Role of the Anion Sublattice in Aurivillius Oxyfluoride Bi2TiO4F2

    Inorganic Chemistry · 2021-09-01

    A. T. Giddings, Euan A. S. Scott, Martin Christopher. Stennett, David C. Apperley, Colin Greaves, Neil Christian Hyatt, Emma E. McCabe

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  40. La 3 Ga 3 Ge 2 S 3 O 10 : An Ultraviolet Nonlinear Optical Oxysulfide Designed by Anion‐Directed Band Gap Engineering

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  47. Structural modification from centrosymmetric Rb 4 Hg 2 Ge 2 S 8 to noncentrosymmetric (Na 3 Rb)Hg 2 Ge 2 S 8 : mixed alkali metals strategy for infrared nonlinear optical material design

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