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RESEARCH PAPER · Chemical Communications · 2022

Lanthanide thioborates, an emerging class of nonlinear optical materials, efficiently synthesized using the boron–chalcogen mixture method

Logan S. Breton, Gregory W. Morrison, Matthew R. Lacroix, P. Shiv Halasyamani, Hans‐Conrad zur Loye

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Lanthanide thioborates, an emerging class of nonlinear optical materials, efficiently synthesized using the boron–chalcogen mixture methodOriginalLaBS 3 revisited: a promising mid-infrared nonlinear optical material34An overview of Mg-based IR nonlinear optical materials23MB 3 P 2 S 10 (M = Rb, Cs): two new alkali metal thioboratephosphates with [B 6 P 4 S 20 ] T3-supertetrahedra2Crystal Structures and Property Measurements of Rare Earth Magnesium Thiosilicates Synthesized via Flux Crystal Growth Utilizing the Boron Chalcogen Mixture (BCM) Method15Theoretical Prediction‐Assisted Synthesis and Characterization of Infrared Nonlinear Optical Material NaSrBS324Recent advances in IR nonlinear optical chalcogenides with well-balanced comprehensive performance57Advances in Chalcogenide Crystal Growth: Flux and Solution Syntheses, and Approaches for Postsynthetic Modifications13Boron Chalcogen Mixture Method-Assisted Alkali Halide Flux Crystal Growth of an Extensive Family of Quaternary Rare Earth Transition-Metal Thiosilicates: Investigation of Their Structures and Magnetic Properties9[RbSr 3 X][(BS 3 ) 2 ] (X = Cl, Br): two salt-inclusion thioborates with large birefringence and structure transformation from centrosymmetric to asymmetric8A I B 3 II C 2 III Q 6 VI X VII : A Thioborate Halide Family for Developing Wide Bandgap Infrared Nonlinear Materials by Coupling Planar [BS 3 ] and Polycations25NaREP 2 Se 6 (RE = Y, Sm, Gd–Dy): Quaternary Rare-Earth Selenophosphates with Unique 3D {[REP 2 Se 6 ] − } ∞ Framework Built by RESe 8 and P 2 Se 6 Motifs and Multiple Properties4Secondary‐Bond‐Driven Construction of a Polar Material Exhibiting Strong Broad‐Spectrum Second‐Harmonic Generation and Large Birefringence9Secondary‐Bond‐Driven Construction of a Polar Material Exhibiting Strong Broad‐Spectrum Second‐Harmonic Generation and Large Birefringence41Rare-earth-based chalcogenides and their derivatives: an encouraging IR nonlinear optical material candidate70Evaluation and prospect of Mid-Infrared nonlinear optical materials in f0 rare earth (RE = Sc, Y, La) chalcogenides45Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units66Rare Bird: U+5 in Uranium Chalcogenides6Synthesis, Optical, and Magnetic Properties of the Mixed Chalcogenide Semiconductor Series Eu(II)2SiSexS4-x, Prepared via the Flux-Assisted Boron Chalcogen Mixture Method4Na 2 B 12 Si 6 Se 18 : a novel B 12 -cluster-containing quaternary selenoborate framework material2Selenoborates: a latent structure resource for infrared functional crystal materials1Synergistic Machine Learning Guided Discovery of ABa 3 (BSe 3 ) 2 X (A = Rb, Cs; X = Cl, Br, I): A Promising Family as Property‐Balanced IR Functional Materials10Directing Cluster Nuclearity in Semiconducting Lead Thioborates Built from Adamantane and Superadamantane Boron–Sulfur Clusters0(Nd3SiS7)2(Nd3SiS4BS3): A mixed metal thioborate-thiosilicate0

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23 direct citing papers saved.

  1. LaBS 3 revisited: a promising mid-infrared nonlinear optical material

    Journal of Materials Chemistry C · 2022-01-01

    Ya‐Xiang Han, Chun‐Li Hu, Zhi Gang Fang, Qianqian Chen, Bingxuan Li, Yuan Hua Lin, Jiang‐Gao Mao

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  2. An overview of Mg-based IR nonlinear optical materials

    Inorganic Chemistry Frontiers · 2023-01-01

    Jiaxiang Zhang, Mao‐Yin Ran, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

    Read original paper ↗ ·

  3. MB 3 P 2 S 10 (M = Rb, Cs): two new alkali metal thioboratephosphates with [B 6 P 4 S 20 ] T3-supertetrahedra

    Dalton Transactions · 2023-01-01

    Jiazheng Zhou, Xin Su, Ling Luo, Junjie Li, Feng Yu

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  4. Crystal Structures and Property Measurements of Rare Earth Magnesium Thiosilicates Synthesized via Flux Crystal Growth Utilizing the Boron Chalcogen Mixture (BCM) Method

    Inorganic Chemistry · 2023-05-03

    Adam A. King, Logan S. Breton, Gregory W. Morrison, Mark D. Smith, Mingli Liang, P. Shiv Halasyamani, Hans‐Conrad zur Loye

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  5. Theoretical Prediction‐Assisted Synthesis and Characterization of Infrared Nonlinear Optical Material NaSrBS3

    Advanced Optical Materials · 2023-05-05

    Yihan Yun, Mengfan Wu, Congwei Xie, Zhihua Yang, Guangmao Li, Shilie Pan

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  6. Recent advances in IR nonlinear optical chalcogenides with well-balanced comprehensive performance

    Materials Today Physics · 2023-05-26

    Hedi Yang, Mao‐Yin Ran, Wenbo Wei, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

    Read original paper ↗ ·

  7. Advances in Chalcogenide Crystal Growth: Flux and Solution Syntheses, and Approaches for Postsynthetic Modifications

    Crystal Growth & Design · 2023-07-10

    Anna A. Berseneva, Hans‐Conrad zur Loye

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  8. Boron Chalcogen Mixture Method-Assisted Alkali Halide Flux Crystal Growth of an Extensive Family of Quaternary Rare Earth Transition-Metal Thiosilicates: Investigation of Their Structures and Magnetic Properties

    Inorganic Chemistry · 2023-10-23

    Adam A. King, Logan S. Breton, Gregory W. Morrison, Mark D. Smith, Hans‐Conrad zur Loye

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  9. [RbSr 3 X][(BS 3 ) 2 ] (X = Cl, Br): two salt-inclusion thioborates with large birefringence and structure transformation from centrosymmetric to asymmetric

    Chemical Communications · 2023-11-17

    Yihan Yun, Xueling Hou, Zhihua Yang, Guangmao Li, Shilie Pan

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  10. A I B 3 II C 2 III Q 6 VI X VII : A Thioborate Halide Family for Developing Wide Bandgap Infrared Nonlinear Materials by Coupling Planar [BS 3 ] and Polycations

    Small · 2023-11-27

    Jiazheng Zhou, Ketian Hou, Yu Chu, Zhihua Yang, Junjie Li, Shilie Pan

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  11. NaREP 2 Se 6 (RE = Y, Sm, Gd–Dy): Quaternary Rare-Earth Selenophosphates with Unique 3D {[REP 2 Se 6 ] − } ∞ Framework Built by RESe 8 and P 2 Se 6 Motifs and Multiple Properties

    Inorganic Chemistry · 2023-11-30

    Chen‐Yi Zhao, Zi‐Xia Chen, Wen‐Dong Yao, Wenfeng Zhou, Wenlong Liu, Sheng‐Ping Guo

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  12. Secondary‐Bond‐Driven Construction of a Polar Material Exhibiting Strong Broad‐Spectrum Second‐Harmonic Generation and Large Birefringence

    Angewandte Chemie · 2023-12-20

    Tianhui Wu, Xingxing Jiang, Kaining Duanmu, Chao Wu, Zheshuai Lin, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

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  13. Secondary‐Bond‐Driven Construction of a Polar Material Exhibiting Strong Broad‐Spectrum Second‐Harmonic Generation and Large Birefringence

    Angewandte Chemie International Edition · 2023-12-20

    Tianhui Wu, Xingxing Jiang, Kaining Duanmu, Chao Wu, Zheshuai Lin, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

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  14. Rare-earth-based chalcogenides and their derivatives: an encouraging IR nonlinear optical material candidate

    Chemical Science · 2024-01-01

    Ping Feng, Jiaxiang Zhang, Mao‐Yin Ran, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  15. Evaluation and prospect of Mid-Infrared nonlinear optical materials in f0 rare earth (RE = Sc, Y, La) chalcogenides

    Coordination Chemistry Reviews · 2024-03-22

    Linfeng Dong, Shengzi Zhang, Pifu Gong, Lei Kang, Zheshuai Lin

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  16. Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units

    Coordination Chemistry Reviews · 2024-07-03

    Bo Zhang, Mao‐Yin Ran, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  17. Rare Bird: U+5 in Uranium Chalcogenides

    Chemistry of Materials · 2024-08-12

    Anna A. Berseneva, Vladislav V. Klepov, Habiba Binte Kashem, Alevtina A. Maksimova, Gregory W. Morrison, Joshua Wright, Joseph C. Schaeperkoetter, Scott T. Misture, Hans‐Conrad zur Loye

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  18. Synthesis, Optical, and Magnetic Properties of the Mixed Chalcogenide Semiconductor Series Eu(II)2SiSexS4-x, Prepared via the Flux-Assisted Boron Chalcogen Mixture Method

    Inorganic Chemistry · 2024-12-04

    Gopabandhu Panigrahi, Gregory W. Morrison, Mark D. Smith, Hans‐Conrad zur Loye

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  19. Na 2 B 12 Si 6 Se 18 : a novel B 12 -cluster-containing quaternary selenoborate framework material

    Dalton Transactions · 2024-12-09

    Gopabandhu Panigrahi, Hunter B. Tisdale, Gregory W. Morrison, Hans‐Conrad zur Loye

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  20. Selenoborates: a latent structure resource for infrared functional crystal materials

    Inorganic Chemistry Frontiers · 2025-01-01

    Yihan Yun, Abudukadi Tudi, Zhihua Yang, Guangmao Li, Shilie Pan

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  21. Synergistic Machine Learning Guided Discovery of ABa 3 (BSe 3 ) 2 X (A = Rb, Cs; X = Cl, Br, I): A Promising Family as Property‐Balanced IR Functional Materials

    Advanced Science · 2025-04-26

    Yihan Yun, Mengfan Wu, Zhihua Yang, Guangmao Li, Shilie Pan

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  22. Directing Cluster Nuclearity in Semiconducting Lead Thioborates Built from Adamantane and Superadamantane Boron–Sulfur Clusters

    Chemistry of Materials · 2026-09-04

    Nicholas Britt, Michael J. Waters, Khasim Saheb Bayikadi, Safdar Imam, James M. Rondinelli, Mercouri G. Kanatzidis

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  23. (Nd3SiS7)2(Nd3SiS4BS3): A mixed metal thioborate-thiosilicate

    Solid State Sciences · 2026-09-08

    Habiba Binte Kashem, Rachita Panigrahi, Hope Eden Catalano, Abdullah Al Muhit, Mark D. Smith, Hans‐Conrad zur Loye

    Read original paper ↗ ·
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