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RESEARCH PAPER · Chemical Communications · 2019

Hexagonal perovskite derivatives: a new direction in the design of oxide ion conducting materials

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Hexagonal perovskite derivatives: a new direction in the design of oxide ion conducting materialsOriginalDirect evidence for two-dimensional oxide-ion diffusion in the hexagonal perovskite-related oxide Ba 3 MoNbO 8.5−δ79Discovery of a Rare-Earth-Free Oxide-Ion Conductor Ca3Ga4O9 by Screening through Bond Valence-Based Energy Calculations, Synthesis, and Characterization of Structural and Transport Properties49Hybrid Halide Perovskites: Discussions on Terminology and Materials94Hybrid Halide Perovskites: Discussions on Terminology and Materials19Phonon vibrations and photoluminescence emissions and their correlations with the electrical properties in Er3+ doped Bi3YO6 oxide-ion conductors19Representations and descriptors unifying the study of molecular and bulk systems17The Ba 3 Mo 1−x W x NbO 8.5 ion conductors: insights into local coordination from X-ray and neutron total scattering15The relationship between oxide-ion conductivity and cation vacancy order in the hybrid hexagonal perovskite Ba 3 VWO 8.553Investigating the effect of Cu-doping on the electrochemical properties of perovskite-type Ba0.5Sr0.5Fe1-xCuxO3-δ (0 ≤ x ≤ 0.20) cathodes29High oxide ion and proton conductivity in a disordered hexagonal perovskite246Oxide-ion conduction in the Dion–Jacobson phase CsBi2Ti2NbO10−δ93Enhanced Oxygen Ion Conductivity and Mechanistic Understanding in Ba3Nb1–xVxMoO8.583Hexagonal Stacking Faults Act as Hole-Blocking Layers in Lead Halide Perovskites18Understanding the Correlation between Oxide Ion Mobility and Site Distributions in Ba3NbWO8.517Signature of Oxide-Ion Conduction in Alkaline-Earth-Metal-Doped Y3GaO617A pressure induced reversal to the 9R perovskite in Ba 3 MoNbO 8.56Enhancing the oxide-ionic conductivity of Ba 3 Mo 1+ x Nb 1−2 x Ge x O 8.5 at intermediate temperatures: the effect of site-selective Ge 4+ -substitution9Solid oxide proton conductors beyond perovskites101A Machine Learning Approach for the Prediction of Formability and Thermodynamic Stability of Single and Double Perovskite Oxides148High oxide-ion conductivity through the interstitial oxygen site in Ba7Nb4MoO20-based hexagonal perovskite related oxides181Atomic Structure of the Initial Nucleation Layer in Hexagonal Perovskite BaRuO3 Thin Films3Cation Substitution of Hexagonal Triple Perovskites: A Case in Trimetallic Tellurates A2A′BTe2O910Influence of Re-ions with different ionic radius in Ba12ReNb9O36 on crystal structure and microwave dielectric properties30Hydration and Ionic Conduction Mechanisms of Hexagonal Perovskite Derivatives61Investigation of the Crystal Structure and Ionic Pathways of the Hexagonal Perovskite Derivative Ba3–xVMoO8.5–x10Synthesis and characterization of Ga-doped Ba3MoNbO8.5 electrolytes for intermediate temperature-solid oxide fuel cells18High Oxide‐Ion Conductivity in a Hexagonal Perovskite‐Related Oxide Ba7Ta3.7Mo1.3O20.15 with Cation Site Preference and Interstitial Oxide Ions49Introduction0New Oxide-Ion Conductors of Dion–Jacobson-Type Layered Perovskites CsBi2Ti2NbO10-δ1New Oxide-Ion Conductors of Dion–Jacobson-Type Layered Perovskites CsLn2Ti2NbO10 (Ln = La, Pr, Nd, Sm, Gd, Ho, and Yb) and CsLa2–xMxTi2+yNb1–yO10–x/2–y/2 (M = Ca, Sr, and Ba; x = 0, 0.1; y = 0.1, 0, and –0.1)0Structure–property correlation in oxide-ion and proton conductors for clean energy applications: recent experimental and computational advancements63Variable Temperature Neutron Diffraction Study of the Oxide Ion Conductor Ba3VWO8.517Oxide-Ion Occupational Disorder, Diffusion Path, and Conductivity in Hexagonal Perovskite Derivatives Ba3WNbO8.5 and Ba3MoNbO8.526Improved oxide-ion conductivity by substitution of Sr for Bi in Dion-Jacobson phase CsBi2Ti2NbO109On the Phase Stability of Chalcogenide Perovskites31Luminescence from Self‐Trapped Excitons and Energy Transfers in Vacancy‐Ordered Hexagonal Halide Perovskite Cs2HfF6 Doped with Rare Earths for Radiation Detection18A novel microwave dielectric ceramic La5Sn4O15 with medium-permittivity and low loss15Proton and Oxide Ion Conductivity in Palmierite Oxides45Phase evolution, electrical properties, and conductivity mechanism in LiNbWO61Applications of all-inorganic perovskites for energy storage90Recent developments in oxide ion conductors: focusing on Dion–Jacobson phases42A Variable Temperature Neutron Diffraction Study of Dual Ion Conducting Sr3v2o80Incorporation of protons and hydroxide species in BaZrO 3 and BaCeO 325Enhanced Oxide Ion Conductivity by Ta Doping of Ba3Nb1–xTaxMoO8.53Structure and Magnetic Properties of Pseudo-1D Chromium Thiolate Coordination Polymers10Competing Magnetic Interactions and the Role of Unpaired 4 f Electrons in Oxygen-Deficient Perovskites Ba 3 R Fe 2 O 7.5 ( R = Y, Dy)6Hidden chemical order in disordered Ba7Nb4MoO20 revealed by resonant X-ray diffraction and solid-state NMR32Oxide Ion-Conducting Materials Containing Tetrahedral Moieties: Structures and Conduction Mechanisms94In Situ Formation of Ba3CoNb2O9/Ba5Nb4O15 Heterostructure in Electrolytes for Enhancing Proton Conductivity and SOFC Performance9Protonic transport in the novel complex oxide Ba5Y0.5In1.5Al2ZrO13 with intergrowth structure13LaFeO3-based catalysts for propene total oxidation0Structural diversity and complexity of antiperovskites38Synthesis and Characterizations of Hexagonal Perovskite-Related Oxide for Solid Electrolyte Application0A variable temperature neutron diffraction study of dual ion conducting Sr3V2O88Enhanced Oxygen Ion Conductivity in Ba3w1+Xv1-Xo8.5+X/2 (-0.2 ≤X ≤ 0.2) Hexagonal Perovskite Derivative Compounds0Synthesis and catalytic application of nanostructured metal oxides and phosphates25The role of vanadium substitution in the oxygen sublattice disorder of Ba 7 Nb 4 MoO 20 -based hexagonal perovskite oxide-ion conductors12Strategic Design and Insights into Lanthanum and Strontium Perovskite Oxides for Oxygen Reduction and Oxygen Evolution Reactions88CsCuCl3 perovskite compound under extreme conditions8B-site deficient hexagonal perovskites: Structural stability, ionic order-disorder and electrical properties36Tutorial on Describing, Classifying, and Visualizing Common Crystal Structures in Nanoscale Materials Systems20Advances in chalcogenide perovskites: Fundamentals and applications40Distinct Intercalation and Conduction Behaviors within an Isostructural Series Ba5R2Al2SnO137Advancements and Challenges in Perovskite-Based Photo-Induced Rechargeable Batteries and Supercapacitors: A Comparative Review17Chemistry and Physics of Triple Perovskite Oxides: A Topical Review19The novel Zn-doped hexagonal perovskite Ba7In6Al2O19: electrical conductivity and hydration3The Perfect Imperfections of Perovskite Oxide Catalysts in the Aspect of Defect Equilibria49Ba3Ti0.4W1.6O8.6: An Oxygen- and B-Site-Deficient 9R Hexagonal Perovskite Exhibiting Triple Conduction3Tuning of the ionic conductivity of Ba 7 Nb 4 MoO 20 by pressure: a neutron diffraction and atomistic modelling study4Effect of germanium substitution on the structure and ionic conductivity of the hexagonal perovskite derivative compound Ba 3 WVO 8.52Introduction0Rapid Synthesis and Detailed Characterization of Low-Dimensional Mixed-Valent Sr6Rh5O15 Nanofibers: Theory and Experiments2Enhanced oxygen ion conductivity in Ba3W1+xV1−xO8.5+x/2 (− 0.2 ≤ × ≤ 0.2) hexagonal perovskite derivative compounds4Unlocking the Potential of Palmierite Oxides: High Oxide Ion Conductivity via Induced Interstitial Defects19Strain Engineering in Ba7Nb4MoO20 Hexagonal Perovskites for Enhanced Oxygen-Ion Conductivity2Hybrid Hexagonal Perovskite Ba3Ti0.7Mo1.3O8.3: Integrating High Cationic Disordering with Enhanced Tetrahedral Proportion to Achieve High Oxide Ionic Conductivity0Topological Understanding of the Narrow Emission Band of β-Ca3(PO4)2:Eu2+-Type Phosphors: The Importance of Pinwheel Structural Units1High Oxygen Ion Conductivity in Hexagonal Perovskite Ba7Nb4MoO20 via Epitaxy-Assisted Orienting of Two-Dimensional Diffusion Pathways2Enhanced Oxide Ion Diffusion by Lanthanum Substitution in the Palmierite Sr 3–3 x La 2 x V 2 O 8 via Increased Tetrahedral Distortion and Cation Vacancies5Elucidating oxide-ion and proton transport in ionic conductors using machine learning potentials4Mechanistic approach to enhance oxygen ion conductivity and fuel cell performance in Tb doped Bi3YO6 oxide ion conductor for low temperature solid oxide fuel cells6Fast Oxide Ion Conduction in Ba 3 MoNbO 8.5 Enhanced by Acceptor Substitution and Dehydration3Introduction of Hexagonal-Perovskite Type Ionic Conductors and Order/Disorder in the Crystal0Oxide-Ion Occupational Disorder, Conductivity, and Diffusion Pathways in Ba3MNbO8.5 (M = W, Mo)0Techniques and Terms0Enhanced sinterability of Ba3MoNb0.95Zr0.05O8.475 oxide ion conductor by adding K2CO30Suppress oxygen ordering and deviation for the design of bismuth oxide-based low temperature ionic conductors1Ab initio study of multifaceted properties in cubic NdVO3 perovskite: Structural, electronic, magnetic, and thermodynamic aspects1Photothermal synergistic hydrogen evolution over shifted-type hexagonal perovskite Ba8MnNb6O24: an experimental study and mechanistic insights1Temperature-Stable (1– x )Ba 12 Zn 0.5 Zr 0.5 Nb 9 O 36 - x BaWO 4 Composite Ceramics for Low-Temperature Co-Fired Ceramics and Dielectric Resonator Antenna Applications0Reaction Modeling of the Rapid Two-Step Oxidation Process Assisted by Bayesian Inference with Isothermal Time-Resolved X-ray Diffraction Measurements0Ba7Zn5Ga6O21: Terminal Oxygens Enable High Oxide-Ion and Proton Conductivity in a Condensed Three-Dimensional Tetrahedral Framework0Compressibility, equation of state and thermal expansion of cation deficient hexagonal perovskite type Ba3Te2O90Structural, electronic, and magnetic properties of the hexagonal double perovskite Ba2FeIrO6: A combined computational and experimental investigation0Sm-modified Bi3YO6 electrolyte for low-temperature solid oxide fuel cells: Structure, transport behavior and microscopic mechanisms0Activating Interstitial Oxygen Conduction in Sr3V2O8 Palmierite Oxides Through Minimal Mo-Substitution0

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  1. Direct evidence for two-dimensional oxide-ion diffusion in the hexagonal perovskite-related oxide Ba 3 MoNbO 8.5−δ

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  2. Discovery of a Rare-Earth-Free Oxide-Ion Conductor Ca3Ga4O9 by Screening through Bond Valence-Based Energy Calculations, Synthesis, and Characterization of Structural and Transport Properties

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  3. Hybrid Halide Perovskites: Discussions on Terminology and Materials

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  4. Hybrid Halide Perovskites: Discussions on Terminology and Materials

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  5. Phonon vibrations and photoluminescence emissions and their correlations with the electrical properties in Er3+ doped Bi3YO6 oxide-ion conductors

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  6. Representations and descriptors unifying the study of molecular and bulk systems

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  7. The Ba 3 Mo 1−x W x NbO 8.5 ion conductors: insights into local coordination from X-ray and neutron total scattering

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  8. The relationship between oxide-ion conductivity and cation vacancy order in the hybrid hexagonal perovskite Ba 3 VWO 8.5

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  9. Investigating the effect of Cu-doping on the electrochemical properties of perovskite-type Ba0.5Sr0.5Fe1-xCuxO3-δ (0 ≤ x ≤ 0.20) cathodes

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  10. High oxide ion and proton conductivity in a disordered hexagonal perovskite

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  11. Oxide-ion conduction in the Dion–Jacobson phase CsBi2Ti2NbO10−δ

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  12. Enhanced Oxygen Ion Conductivity and Mechanistic Understanding in Ba3Nb1–xVxMoO8.5

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  13. Hexagonal Stacking Faults Act as Hole-Blocking Layers in Lead Halide Perovskites

    ACS Energy Letters · 2020-06-05

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  14. Understanding the Correlation between Oxide Ion Mobility and Site Distributions in Ba3NbWO8.5

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  15. Signature of Oxide-Ion Conduction in Alkaline-Earth-Metal-Doped Y3GaO6

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  16. A pressure induced reversal to the 9R perovskite in Ba 3 MoNbO 8.5

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  17. Enhancing the oxide-ionic conductivity of Ba 3 Mo 1+ x Nb 1−2 x Ge x O 8.5 at intermediate temperatures: the effect of site-selective Ge 4+ -substitution

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  18. Solid oxide proton conductors beyond perovskites

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  19. A Machine Learning Approach for the Prediction of Formability and Thermodynamic Stability of Single and Double Perovskite Oxides

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  20. High oxide-ion conductivity through the interstitial oxygen site in Ba7Nb4MoO20-based hexagonal perovskite related oxides

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  21. Atomic Structure of the Initial Nucleation Layer in Hexagonal Perovskite BaRuO3 Thin Films

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  22. Cation Substitution of Hexagonal Triple Perovskites: A Case in Trimetallic Tellurates A2A′BTe2O9

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  23. Influence of Re-ions with different ionic radius in Ba12ReNb9O36 on crystal structure and microwave dielectric properties

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  25. Investigation of the Crystal Structure and Ionic Pathways of the Hexagonal Perovskite Derivative Ba3–xVMoO8.5–x

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  26. Synthesis and characterization of Ga-doped Ba3MoNbO8.5 electrolytes for intermediate temperature-solid oxide fuel cells

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  28. Introduction

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  29. New Oxide-Ion Conductors of Dion–Jacobson-Type Layered Perovskites CsBi2Ti2NbO10-δ

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  30. New Oxide-Ion Conductors of Dion–Jacobson-Type Layered Perovskites CsLn2Ti2NbO10 (Ln = La, Pr, Nd, Sm, Gd, Ho, and Yb) and CsLa2–xMxTi2+yNb1–yO10–x/2–y/2 (M = Ca, Sr, and Ba; x = 0, 0.1; y = 0.1, 0, and –0.1)

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  31. Structure–property correlation in oxide-ion and proton conductors for clean energy applications: recent experimental and computational advancements

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  32. Variable Temperature Neutron Diffraction Study of the Oxide Ion Conductor Ba3VWO8.5

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  33. Oxide-Ion Occupational Disorder, Diffusion Path, and Conductivity in Hexagonal Perovskite Derivatives Ba3WNbO8.5 and Ba3MoNbO8.5

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  34. Improved oxide-ion conductivity by substitution of Sr for Bi in Dion-Jacobson phase CsBi2Ti2NbO10

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  35. On the Phase Stability of Chalcogenide Perovskites

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  36. Luminescence from Self‐Trapped Excitons and Energy Transfers in Vacancy‐Ordered Hexagonal Halide Perovskite Cs2HfF6 Doped with Rare Earths for Radiation Detection

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  37. A novel microwave dielectric ceramic La5Sn4O15 with medium-permittivity and low loss

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  39. Phase evolution, electrical properties, and conductivity mechanism in LiNbWO6

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  41. Recent developments in oxide ion conductors: focusing on Dion–Jacobson phases

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  42. A Variable Temperature Neutron Diffraction Study of Dual Ion Conducting Sr3v2o8

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  43. Incorporation of protons and hydroxide species in BaZrO 3 and BaCeO 3

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  44. Enhanced Oxide Ion Conductivity by Ta Doping of Ba3Nb1–xTaxMoO8.5

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  45. Structure and Magnetic Properties of Pseudo-1D Chromium Thiolate Coordination Polymers

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  46. Competing Magnetic Interactions and the Role of Unpaired 4 f Electrons in Oxygen-Deficient Perovskites Ba 3 R Fe 2 O 7.5 ( R = Y, Dy)

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  47. Hidden chemical order in disordered Ba7Nb4MoO20 revealed by resonant X-ray diffraction and solid-state NMR

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  49. In Situ Formation of Ba3CoNb2O9/Ba5Nb4O15 Heterostructure in Electrolytes for Enhancing Proton Conductivity and SOFC Performance

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  50. Protonic transport in the novel complex oxide Ba5Y0.5In1.5Al2ZrO13 with intergrowth structure

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