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RESEARCH PAPER · Chemistry of Materials · 2020

Enhanced Oxygen Ion Conductivity and Mechanistic Understanding in Ba3Nb1–xVxMoO8.5

Sacha Fop, Kirstie S. McCombie, Ronald I. Smith, Abbie Christina Mclaughlin

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Enhanced Oxygen Ion Conductivity and Mechanistic Understanding in Ba3Nb1–xVxMoO8.5OriginalDion–Jacobson-type oxide-ion conductor CsLa 2 Ti 2 NbO 10−δ without phase transitions34The Ba 3 Mo 1−x W x NbO 8.5 ion conductors: insights into local coordination from X-ray and neutron total scattering15The relationship between oxide-ion conductivity and cation vacancy order in the hybrid hexagonal perovskite Ba 3 VWO 8.553Understanding the Correlation between Oxide Ion Mobility and Site Distributions in Ba3NbWO8.517Ferroelectric and photocatalytic behavior of Mn- and Ce-doped BaTiO3 nanoceramics prepared by chemical route47A pressure induced reversal to the 9R perovskite in Ba 3 MoNbO 8.56Enhancing the oxide-ionic conductivity of Ba 3 Mo 1+ x Nb 1−2 x Ge x O 8.5 at intermediate temperatures: the effect of site-selective Ge 4+ -substitution9Phase Evolution, Electrical Properties, and Conduction Mechanism of Ca12Al14–xGaxO33 (0 ≤ x ≤ 14) Ceramics Synthesized by a Glass Crystallization Method16Electrical Properties, Defect Structures, and Ionic Conducting Mechanisms in Alkali Tungstate Li2W2O718Hydration and Ionic Conduction Mechanisms of Hexagonal Perovskite Derivatives61Investigation of the Crystal Structure and Ionic Pathways of the Hexagonal Perovskite Derivative Ba3–xVMoO8.5–x10Expanded Chemistry and Proton Conductivity in Vanadium-Substituted Variants of γ-Ba4Nb2O93Synthesis and characterization of Ga-doped Ba3MoNbO8.5 electrolytes for intermediate temperature-solid oxide fuel cells18New apatite‐type oxide ion conductors Ce9.33+xSi6O26+δ: Structures, phase stabilities, electrical properties, and conducting mechanisms3Preparation and Characterization of Ta and Monovalent Alkali Metals (Li, Na, K) Co-Doping on Sr11mo4o23 Electrolyte for Solid Oxide Fuel Cells7Structure–property correlation in oxide-ion and proton conductors for clean energy applications: recent experimental and computational advancements63Temperature-driven order–disorder structural transition in the oxygen sub-lattice and the complex superstructure of the high-temperature polymorph of CaSrZn 2 Ga 2 O 73Variable Temperature Neutron Diffraction Study of the Oxide Ion Conductor Ba3VWO8.517Insights into Oxygen Migration in LaBaCo2O6−δ Perovskites from In Situ Neutron Powder Diffraction and Bond Valence Site Energy Calculations17Oxide-Ion Occupational Disorder, Diffusion Path, and Conductivity in Hexagonal Perovskite Derivatives Ba3WNbO8.5 and Ba3MoNbO8.526Improved oxide-ion conductivity by substitution of Sr for Bi in Dion-Jacobson phase CsBi2Ti2NbO109Simultaneous Reduction of Proton Conductivity and Enhancement of Oxide-Ion Conductivity by Aliovalent Doping in Ba 7 Nb 4 MoO 2037Different Local Structures of Mo and Nb Polyhedra in the Oxide-Ion-Conducting Hexagonal Perovskite-Related Oxide Ba3MoNbO8.5 Revealed by 95Mo and 93Nb NMR Measurements11Oxide ion conduction and transporting mechanism in the layered perovskite-related material Sr2Nb2O717Influence of Ta doping on the structural stability and conductivity of Sr11Mo4O23 electrolyte10Characteristics of electrolyte-supported SOFC single cells using hexagonal perovskite Ba3MoNbO8.5 and Ba7Nb4MoO20 ceramics8Proton and Oxide Ion Conductivity in Palmierite Oxides45Phase evolution, electrical properties, and conductivity mechanism in LiNbWO61Recent developments in oxide ion conductors: focusing on Dion–Jacobson phases42A Variable Temperature Neutron Diffraction Study of Dual Ion Conducting Sr3v2o80B-site mixed cationic tetrahedral layer confined the concentration and mobility of interstitial oxygen in mellite family9BaLa 5 V 2 O 3 N 7 : a novel anti-perovskite oxynitride for electrode applications1Enhanced Oxide Ion Conductivity by Ta Doping of Ba3Nb1–xTaxMoO8.53Transport Properties of In3+- and Y3+-Doped Hexagonal Perovskite Ba5In2Al2ZrO1314Transport Properties of In3+- and Y3+-Doped Hexagonal Perovskite Ba5In2Al2ZrO130Thermally Induced Oxygen Vacancies and High Oxide Ion Conduction in K2ZnV2O7 with a Melilite-Related Structure15Oxide Ion-Conducting Materials Containing Tetrahedral Moieties: Structures and Conduction Mechanisms94A variable temperature neutron diffraction study of dual ion conducting Sr3V2O88Oxide Ion Conduction in Ca-Doped Yb3Ga5O12 Garnet9Oxide ion dynamics in hexagonal perovskite mixed conductor Ba 7 Nb 4 MoO 20 : a comprehensive ab initio molecular dynamics study10The role of vanadium substitution in the oxygen sublattice disorder of Ba 7 Nb 4 MoO 20 -based hexagonal perovskite oxide-ion conductors12Theoretical study of the oxygen ion conductivity and modeling new hollandite-type structures LnM6O12 (Ln = Pr, Nd; M = Ti, Nb, Mo)1Oxygen Migration Pathways in Layered LnBaCo2O6-δ (Ln = La – Y) Perovskites6B-site deficient hexagonal perovskites: Structural stability, ionic order-disorder and electrical properties36Electron density distribution using maximum entropy method and conductivity studies of BaZr0.85Ho0.10Y0.025Nd0.025O3-δ electrolyte ceramic for intermediate temperature solid oxide fuel cells13Enhanced protonic and oxygen-ionic conductivity in Ga-doped Nd2Ce2O7 electrolytes for intermediate-temperature solid oxide fuel cell9Ba3Ti0.4W1.6O8.6: An Oxygen- and B-Site-Deficient 9R Hexagonal Perovskite Exhibiting Triple Conduction3Conductivity and dielectric studies of spark plasma sintered BaZr0.85Ho0.10Y0.025Nd0.025O3-δ electrolyte ceramic for intermediate temperature solid oxide fuel cells9Tuning of the ionic conductivity of Ba 7 Nb 4 MoO 20 by pressure: a neutron diffraction and atomistic modelling study4Tunable electrocaloric effect in (1-x)Na0.5Bi0.5TiO3-xBa(Ni0.5Nb0.5)O3 ferroelectric ceramics1Effect of germanium substitution on the structure and ionic conductivity of the hexagonal perovskite derivative compound Ba 3 WVO 8.52High temperature dielectric response, AC conductivity and electrical modulus study of Ba3V2O8 ceramic4Hybridizing Fabrications of Gd-CeO2 Thin Films Prepared by EPD and SILAR-A+ for Solid Electrolytes1Structural, electrical, impedance, and modulus correlation in magnetoelectric multiferroic properties of Sm-doped Nb5+ & Co/Fe substitution in Bi5Ti4O15; n = 4 layered Aurivillius5Enhanced oxygen ion conductivity in Ba3W1+xV1−xO8.5+x/2 (− 0.2 ≤ × ≤ 0.2) hexagonal perovskite derivative compounds4High Oxide-Ion Conduction in Rb-Containing Oxides8Designing oxide-ion conductor in superstructural barium tellurate0Unlocking the Potential of Palmierite Oxides: High Oxide Ion Conductivity via Induced Interstitial Defects19Suppressing intrinsic self-compensating of BaSm2Ti4O12- ceramics for high-temperature thermistor application1Development of the ionic conductor-mayenite Ca12Al14O332Strain Engineering in Ba7Nb4MoO20 Hexagonal Perovskites for Enhanced Oxygen-Ion Conductivity2Hybrid Hexagonal Perovskite Ba3Ti0.7Mo1.3O8.3: Integrating High Cationic Disordering with Enhanced Tetrahedral Proportion to Achieve High Oxide Ionic Conductivity0Understanding and design of interstitial oxygen conductors5High Oxygen Ion Conductivity in Hexagonal Perovskite Ba7Nb4MoO20 via Epitaxy-Assisted Orienting of Two-Dimensional Diffusion Pathways2Luminescent ceramic materials based on laser-synthesized europium-stabilized zirconia nanopowders0Ba‐deficient and K‐doped Ba 3 MoNbO 8.5 : Hydration properties, electrical conduction, and stability0Sm-doped Ba3MoNbO8.5-δ hexagonal perovskite membranes with enhanced oxygen permeation and structural stability for solid oxide fuel cells3Fast Oxide Ion Conduction in Ba 3 MoNbO 8.5 Enhanced by Acceptor Substitution and Dehydration3Enhanced oxygen surface exchange in Sm-doped Ba3MoNbO8.5-δ hexagonal perovskites for solid oxide fuel cells0Discovery of a Rubidium-Containing Oxide-Ion Conductor with Hexagonal Perovskite-Related Structure0Non-stoichiometry as a structural lever: tailoring oxygen sublattice occupancy for enhanced oxide-ion transport in BICUVOX0Oxide-Ion Occupational Disorder, Conductivity, and Diffusion Pathways in Ba3MNbO8.5 (M = W, Mo)0Summary and Appendix0Enhanced sinterability of Ba3MoNb0.95Zr0.05O8.475 oxide ion conductor by adding K2CO30Applications of neutron scattering in solid oxide fuel cells1The structure and electrical properties of the palmierite Sr3P2O80Charting the Landscape of Oxygen Ion Conductors: A 60-Year Dataset with Interpretable Regression Models1Investigation of V5+ substitution on the crystal structure and oxide ion conductivity of Ba7Nb4MoO200Neutron Diffraction for Structural Characterisation of Inorganic Materials0Activating Interstitial Oxygen Conduction in Sr3V2O8 Palmierite Oxides Through Minimal Mo-Substitution0

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  1. Dion–Jacobson-type oxide-ion conductor CsLa 2 Ti 2 NbO 10−δ without phase transitions

    Journal of Materials Chemistry A · 2020-01-01

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  2. The Ba 3 Mo 1−x W x NbO 8.5 ion conductors: insights into local coordination from X-ray and neutron total scattering

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  3. The relationship between oxide-ion conductivity and cation vacancy order in the hybrid hexagonal perovskite Ba 3 VWO 8.5

    Journal of Materials Chemistry A · 2020-01-01

    Asma Gilane, Sacha Fop, Falak Sher, Ronald I. Smith, Abbie Christina Mclaughlin

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  4. Understanding the Correlation between Oxide Ion Mobility and Site Distributions in Ba3NbWO8.5

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  5. Ferroelectric and photocatalytic behavior of Mn- and Ce-doped BaTiO3 nanoceramics prepared by chemical route

    Materials Science and Engineering B · 2020-10-18

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  6. A pressure induced reversal to the 9R perovskite in Ba 3 MoNbO 8.5

    Journal of Materials Chemistry A · 2021-01-01

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  7. Enhancing the oxide-ionic conductivity of Ba 3 Mo 1+ x Nb 1−2 x Ge x O 8.5 at intermediate temperatures: the effect of site-selective Ge 4+ -substitution

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  8. Phase Evolution, Electrical Properties, and Conduction Mechanism of Ca12Al14–xGaxO33 (0 ≤ x ≤ 14) Ceramics Synthesized by a Glass Crystallization Method

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    Yun Lv, Yanming Sun, Jungu Xu, Xiangyu Xu, Alberto José Fernández-Carrión, Tianjie Wei, Huaibo Yi, Xiaojun Kuang

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  9. Electrical Properties, Defect Structures, and Ionic Conducting Mechanisms in Alkali Tungstate Li2W2O7

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  10. Hydration and Ionic Conduction Mechanisms of Hexagonal Perovskite Derivatives

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  11. Investigation of the Crystal Structure and Ionic Pathways of the Hexagonal Perovskite Derivative Ba3–xVMoO8.5–x

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    Dylan N. Tawse, Asma Gilane, Sacha Fop, Alfonso Martı́nez-Felipe, Falak Sher, Ronald I. Smith, Abbie Christina Mclaughlin

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  12. Expanded Chemistry and Proton Conductivity in Vanadium-Substituted Variants of γ-Ba4Nb2O9

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  13. Synthesis and characterization of Ga-doped Ba3MoNbO8.5 electrolytes for intermediate temperature-solid oxide fuel cells

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  14. New apatite‐type oxide ion conductors Ce9.33+xSi6O26+δ: Structures, phase stabilities, electrical properties, and conducting mechanisms

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    Tianjie Wei, Jungu Xu, Wenfeng Zhu

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  15. Preparation and Characterization of Ta and Monovalent Alkali Metals (Li, Na, K) Co-Doping on Sr11mo4o23 Electrolyte for Solid Oxide Fuel Cells

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  16. Structure–property correlation in oxide-ion and proton conductors for clean energy applications: recent experimental and computational advancements

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  17. Temperature-driven order–disorder structural transition in the oxygen sub-lattice and the complex superstructure of the high-temperature polymorph of CaSrZn 2 Ga 2 O 7

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  18. Variable Temperature Neutron Diffraction Study of the Oxide Ion Conductor Ba3VWO8.5

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  19. Insights into Oxygen Migration in LaBaCo2O6−δ Perovskites from In Situ Neutron Powder Diffraction and Bond Valence Site Energy Calculations

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  20. Oxide-Ion Occupational Disorder, Diffusion Path, and Conductivity in Hexagonal Perovskite Derivatives Ba3WNbO8.5 and Ba3MoNbO8.5

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  21. Improved oxide-ion conductivity by substitution of Sr for Bi in Dion-Jacobson phase CsBi2Ti2NbO10

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  22. Simultaneous Reduction of Proton Conductivity and Enhancement of Oxide-Ion Conductivity by Aliovalent Doping in Ba 7 Nb 4 MoO 20

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  23. Different Local Structures of Mo and Nb Polyhedra in the Oxide-Ion-Conducting Hexagonal Perovskite-Related Oxide Ba3MoNbO8.5 Revealed by 95Mo and 93Nb NMR Measurements

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  24. Oxide ion conduction and transporting mechanism in the layered perovskite-related material Sr2Nb2O7

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  25. Influence of Ta doping on the structural stability and conductivity of Sr11Mo4O23 electrolyte

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  26. Characteristics of electrolyte-supported SOFC single cells using hexagonal perovskite Ba3MoNbO8.5 and Ba7Nb4MoO20 ceramics

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  27. Proton and Oxide Ion Conductivity in Palmierite Oxides

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  28. Phase evolution, electrical properties, and conductivity mechanism in LiNbWO6

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  29. Recent developments in oxide ion conductors: focusing on Dion–Jacobson phases

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  30. A Variable Temperature Neutron Diffraction Study of Dual Ion Conducting Sr3v2o8

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  31. B-site mixed cationic tetrahedral layer confined the concentration and mobility of interstitial oxygen in mellite family

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  32. BaLa 5 V 2 O 3 N 7 : a novel anti-perovskite oxynitride for electrode applications

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  33. Enhanced Oxide Ion Conductivity by Ta Doping of Ba3Nb1–xTaxMoO8.5

    Inorganic Chemistry · 2023-01-17

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  34. Transport Properties of In3+- and Y3+-Doped Hexagonal Perovskite Ba5In2Al2ZrO13

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  35. Transport Properties of In3+- and Y3+-Doped Hexagonal Perovskite Ba5In2Al2ZrO13

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  36. Thermally Induced Oxygen Vacancies and High Oxide Ion Conduction in K2ZnV2O7 with a Melilite-Related Structure

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  37. Oxide Ion-Conducting Materials Containing Tetrahedral Moieties: Structures and Conduction Mechanisms

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  38. A variable temperature neutron diffraction study of dual ion conducting Sr3V2O8

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  39. Oxide Ion Conduction in Ca-Doped Yb3Ga5O12 Garnet

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  40. Oxide ion dynamics in hexagonal perovskite mixed conductor Ba 7 Nb 4 MoO 20 : a comprehensive ab initio molecular dynamics study

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  41. The role of vanadium substitution in the oxygen sublattice disorder of Ba 7 Nb 4 MoO 20 -based hexagonal perovskite oxide-ion conductors

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  42. Theoretical study of the oxygen ion conductivity and modeling new hollandite-type structures LnM6O12 (Ln = Pr, Nd; M = Ti, Nb, Mo)

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  43. Oxygen Migration Pathways in Layered LnBaCo2O6-δ (Ln = La – Y) Perovskites

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  45. Electron density distribution using maximum entropy method and conductivity studies of BaZr0.85Ho0.10Y0.025Nd0.025O3-δ electrolyte ceramic for intermediate temperature solid oxide fuel cells

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  46. Enhanced protonic and oxygen-ionic conductivity in Ga-doped Nd2Ce2O7 electrolytes for intermediate-temperature solid oxide fuel cell

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  47. Ba3Ti0.4W1.6O8.6: An Oxygen- and B-Site-Deficient 9R Hexagonal Perovskite Exhibiting Triple Conduction

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  48. Conductivity and dielectric studies of spark plasma sintered BaZr0.85Ho0.10Y0.025Nd0.025O3-δ electrolyte ceramic for intermediate temperature solid oxide fuel cells

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  49. Tuning of the ionic conductivity of Ba 7 Nb 4 MoO 20 by pressure: a neutron diffraction and atomistic modelling study

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  50. Tunable electrocaloric effect in (1-x)Na0.5Bi0.5TiO3-xBa(Ni0.5Nb0.5)O3 ferroelectric ceramics

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