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RESEARCH PAPER · Journal of Materials Chemistry A · 2021

Solid oxide proton conductors beyond perovskites

Sacha Fop

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Solid oxide proton conductors beyond perovskitesOriginalElectrochemistry and energy conversion features of protonic ceramic cells with mixed ionic-electronic electrolytes203Structure–property correlation in oxide-ion and proton conductors for clean energy applications: recent experimental and computational advancements63Nickel-Containing Perovskites, PrNi0.4Fe0.6O3–δ and PrNi0.4Co0.6O3–δ, as Potential Electrodes for Protonic Ceramic Electrochemical Cells7Proton and Oxygen-Ion Conductivities of Hexagonal Perovskite Ba5In2Al2ZrO1329First-Principles Computational Design and Discovery of Solid-Oxide Proton Conductors31Improved oxide-ion and lower proton conduction of hexagonal perovskite-related oxides based on Ba7Nb4MoO20 by Cr6+ doping28Sodium diffusion in scheelite-type Na2Zr(MoO4)3 and Na4Zr(MoO4)46Proton and Oxide Ion Conductivity in Palmierite Oxides45Materials Research Directions Toward a Green Hydrogen Economy: A Review114Alkaline earth–doped La2Zr2O7 oxides with a pyrochlore structure: phase equilibria and electrical properties13Performance of BaCe0.8Y0.2O3-δ Proton Electrolyte Materials for Solid Oxide Fuel Cells by Compositing the Transition Metal Oxide NiO10High Proton Conductivity in β‐Ba 2 ScAlO 5 Enabled by Octahedral and Intrinsically Oxygen‐Deficient Layers34A Variable Temperature Neutron Diffraction Study of Dual Ion Conducting Sr3v2o80Electrochemical membrane reactors4Investigation of the physicochemical properties of Bi,Ca-doped BaZrO 3 perovskites4Anhydrous Superprotonic Conductivity in the Zirconium Acid Triphosphate ZrH 5 (PO 4 ) 3 **26Anhydrous Superprotonic Conductivity in the Zirconium Acid Triphosphate ZrH5(PO4)3**2Transport Properties of In3+- and Y3+-Doped Hexagonal Perovskite Ba5In2Al2ZrO1314Transport Properties of In3+- and Y3+-Doped Hexagonal Perovskite Ba5In2Al2ZrO130La2Ce2O7 based materials for next generation proton conducting solid oxide cells: Progress, opportunity and future prospects43Hidden chemical order in disordered Ba7Nb4MoO20 revealed by resonant X-ray diffraction and solid-state NMR32On the role of copper as a sintering aid in proton conducting Gd-doped barium cerate (BCGO)13Solids with Two Mobile Ions: Proton H+ Self-Diffusion in Li–H Exchanged Garnet-Type Li6La3ZrTaO7 as Seen by Solid-State 1H NMR Relaxation18High proton conduction in Ba2LuAlO5 with highly oxygen-deficient layers33Proton Diffusion Mechanism in Hydrated Barium Indate Oxides15Oxide Ion-Conducting Materials Containing Tetrahedral Moieties: Structures and Conduction Mechanisms94Discovery of Unconventional Proton‐Conducting Inorganic Solids via Defect‐Chemistry‐Trained, Interpretable Machine Learning31Mechanism of sodium diffusion in Na5-xM1-xZrx(MoO4)4 (M = Y, La, Bi; 0 ≤ x ≤ 0.1) revealed from 23Na NMR, impedance spectroscopy and ab initio calculations3Proton-conducting oxides based on LaScO 3 : structure, properties and electrochemical applications. A focus review27Anisotropic Proton Migration in Hexagonal Perovskite-Related Ba 5 Er 2 Al 2 ZrO 13 Oxide22Proton Conduction over the Zeolite with Surface Water Cluster for the Water Electrolysis at Neutral Condition0A variable temperature neutron diffraction study of dual ion conducting Sr3V2O88Green hydrogen production by intermediate‐temperature protonic solid oxide electrolysis cells: Advances, challenges, and perspectives62Mixed oxide ion–proton conductivity and the ionic migration mechanism in isolated tetrahedral LaVO 4 by acceptor doping7Revisiting the ionic conductivity of solid oxide electrolytes: a technical review81Proton-polaron and thermionic identity of BaCeO3 polymorph for intermediate temperature fuel cell technology: A first principles and molecular dynamics approach13Current and further trajectories in designing functional materials for solid oxide electrochemical cells: A review of other reviews116Hydrogen in energy and information sciences15Ion Migration Study on YAlO3-perovskite through Atomistic Simulations4Tunnel-Structured Phosphate Exhibiting High Proton Conductivity and Thermal Stability over a Wide Intermediate Temperature Range7Transport properties of highly dense proton-conducting BaSn1−xInxO3−δ ceramics18Features of electrical transport and H/D isotope effects in the proton-conducting electrolyte BaCe0.7Zr0.1Y0.1Yb0.1O3-δ14Withdrawn: Alternative Oxide-Based Materials for Electrochemical and Catalytic Applications: A Review2Technological achievements in the fabrication of tubular-designed protonic ceramic electrochemical cells6The novel Zn-doped hexagonal perovskite Ba7In6Al2O19: electrical conductivity and hydration3Developing advanced oxygen electrodes for reversible protonic ceramic electrochemical cells via controlled bismuth doping on diverse perovskite lattice positions17Emerging computational and machine learning methodologies for proton-conducting oxides: materials discovery and fundamental understanding17Advances in alternative metal oxide materials of various structures for electrochemical and catalytic applications9Clean and hydrated low-index Rb 2 Ti 2 O 5 surfaces0Hydration-driven enhancement of interstitialcy oxide-ion diffusion10Improved Oxide-Ion and Lower Proton Conduction of Hexagonal Perovskite-Related Oxides Based on Ba7Nb4MoO20 by Cr6+ Doping0Introduction0Overcoming Synthesis Challenges on Proton Conducting Perovskites: An Overview on the Role of Sintering Additives0Photoluminescent, dielectric, and magnetic responsivity to the humidity variation in SHG-active pyroelectric manganese( ii )-based molecular material9Rb 2 Ti 2 O 5 : A layered ionic conductor at the sub-micrometer scale1Coking resistant Ru supported on Sm-substituted CaZrO3 catalyst for dry reforming of methane: The effect of Ru loading on catalytic activity9Internal biogas reforming in solid oxide and proton conducting fuel cells: progress, challenges and perspectives6How AI guided the development of green hydrogen production: in the case of solid oxide electrolysis cell?9Ion-conducting materials based on Y-doped SrSnO3: Features of ceramics preparation and transport properties4Proton Conduction Mechanisms in Spinel Compounds: A First-Principles Study of Structural and Elemental Effects0Acidifying the Madrid-2019 force field: A rigid model for H3O+ with scaled charges6Machine learning-assisted advances and perspectives for electrolytes of protonic solid oxide fuel cells14The effect of doping of transition metals (V, Cr, Mn, and Co) to CaTiO3 for improving proton conductivity in solid-state electrolyzers0Novel materials based on Ruddlesden–Popper phases for solid oxide fuel cells and oxygen separation membranes: Fundamentals of oxygen transport10Study on structural, thermal stability, optical, and electrical properties of (Nd₀.₂₅Sm₀.₂₅ho₀.₂₅Yb₀.₂₅)₂Zr₂O₇ medium-entropy ceramic for optoelectronic applications4Doping design strategies of proton-conducting perovskite oxides: A brief compositional map23Hydrogen production by dry reforming of methane in a catalytic reactor with La niobate-based hydrogen separation membrane0Novel super-protonic conductor with coherent intergrown structure for fuel cell applications at low to intermediate temperatures4Tolerance factor for melilite structure and high-throughput screening accelerated discovery of a novel family of triple (Na+/O2−/H+) conducting melilite-type oxides1Electrical conductivity changes through low and high O2 pressures on Y1-MAlO3-/2 perovskite (M = Ca, Sr, and Ba) with x = 0.00 and 0.02 and its correlation with point defect concentration1Enhanced proton conductivity assisted by isovalent Ga3 + - doping of Ba7In6Al2O19 proton conductor with hexagonal perovskite structure6Materials for Protonic Ceramic Fuel Cells (PCFCs)0Preparation and transport properties of Ba3Nb2O8 hexagonal perovskite-derivative oxide1Enhanced Oxide Ion Diffusion by Lanthanum Substitution in the Palmierite Sr 3–3 x La 2 x V 2 O 8 via Increased Tetrahedral Distortion and Cation Vacancies5Remarkably high hydration capability of BaSn1–In O3– perovskite materials: What do we need to know about protons in complex oxides?2Preparation and ionic transport features of BaTi1–xInxO3–δ perovskite materials3Electrical properties of Sc-doped CaZrO3 solid electrolytes1Multi-phase interfaces and low-temperature ultra-high ionic conductivity transport in xBaCe0.9Y0.1O3-yLi2CO3 composite electrolytes0High Proton Conductivity over a Wide Intermediate-Temperature Range in Benitoite-Type KMg 1– x Li x H x (PO 3 ) 3 · y H 2 O with a Three-Dimensional Water Network within a Rigid Open Framework2Dual ionic conductivity in Ba 3 InGa 2 O 7.5 : correlating structure and electrochemical properties0Eu( iii ) dilution of Er( iii ) and Yb( iii ) molecular nanomagnets as a route to improving their magnetic features and creating a link with optical thermometry0Hidden Occupational Order in Disordered Ba7Nb4MoO20 Revealed by a Combined Technique of Resonant X-ray Diffraction and Solid-State NMR0High Proton Conductivity and Thermal Stability in Benitoite-Type KCa1- x H2 x (PO3)3·yH2O with a Crystal-Water Diffusion Network0Unraveling the defect-induced conduction mechanism in BNT-based ceramics for solid oxide fuel cells9Atomic Two-Dimensional Materials as Solid Proton Conductors: Achieving the Shortest Proton Transfer Distance with High Selectivity for Energy Applications2Perovskite-based electrocatalysts: A new frontier in water splitting for sustainable hydrogen production12First-Principles Evaluation of Proton Hopping in Tetrahedral Oxide Motifs0Formation of protonic defects in complex oxides: Fundamentals and methodological considerations of hydration3High proton conductivity and thermal stability in Benitoite-type KCa1-H2(PO3)3·yH2O with a crystal-water diffusion network02026 Roadmap on compositionally complex and high entropy materials for energy applications5Emerging horizons for ABO3 perovskite proton conductors: Innovations, bottlenecks and pathways toward next-generation solid oxide cells2Heavily doped proton-conducting perovskites: Relationships between defect structure and functional properties3Hydrogen storage materials and performance-conditioning technologies bridging gravimetric capacity, usable performance, and deployment readiness: A review8Structural insights and proton transport features in a hexagonal Ba5Ho2Al2SnO13 perovskite2Proton-conducting electrolytes for high-performance ceramic electrolysis cells: Materials, mechanisms, modification, and process8Critical role of B-site cation in ABO2.5-type Brownmillerite proton conductor: A first-principles study1Recent progress in hydrogenated perovskite nickelate: Mechanism, modulation, and applications0Three-phase-coexisting anode enabling high-performance water splitting in protonic solid oxide electrolysis cells0Operando Characterization of Protonic Ceramic Electrochemical Cells: Revealing Proton Defect Chemistry, Electrode Reconstruction and Interface Evolution0Recent Advances and Future Perspectives of Proton-Conducting Electrolytes for Reversible Solid Oxide Cells1Boosting proton conduction in Ruddlesden-Popper perovskite La3Mn2O7 electrolyte via layered structure and grain boundaries0

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  2. Structure–property correlation in oxide-ion and proton conductors for clean energy applications: recent experimental and computational advancements

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  3. Nickel-Containing Perovskites, PrNi0.4Fe0.6O3–δ and PrNi0.4Co0.6O3–δ, as Potential Electrodes for Protonic Ceramic Electrochemical Cells

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  4. Proton and Oxygen-Ion Conductivities of Hexagonal Perovskite Ba5In2Al2ZrO13

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  5. First-Principles Computational Design and Discovery of Solid-Oxide Proton Conductors

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  6. Improved oxide-ion and lower proton conduction of hexagonal perovskite-related oxides based on Ba7Nb4MoO20 by Cr6+ doping

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  7. Sodium diffusion in scheelite-type Na2Zr(MoO4)3 and Na4Zr(MoO4)4

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  12. High Proton Conductivity in β‐Ba 2 ScAlO 5 Enabled by Octahedral and Intrinsically Oxygen‐Deficient Layers

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  13. A Variable Temperature Neutron Diffraction Study of Dual Ion Conducting Sr3v2o8

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  15. Investigation of the physicochemical properties of Bi,Ca-doped BaZrO 3 perovskites

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  16. Anhydrous Superprotonic Conductivity in the Zirconium Acid Triphosphate ZrH 5 (PO 4 ) 3 **

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  17. Anhydrous Superprotonic Conductivity in the Zirconium Acid Triphosphate ZrH5(PO4)3**

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  18. Transport Properties of In3+- and Y3+-Doped Hexagonal Perovskite Ba5In2Al2ZrO13

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  19. Transport Properties of In3+- and Y3+-Doped Hexagonal Perovskite Ba5In2Al2ZrO13

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  21. Hidden chemical order in disordered Ba7Nb4MoO20 revealed by resonant X-ray diffraction and solid-state NMR

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  41. Transport properties of highly dense proton-conducting BaSn1−xInxO3−δ ceramics

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  49. Clean and hydrated low-index Rb 2 Ti 2 O 5 surfaces

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  50. Hydration-driven enhancement of interstitialcy oxide-ion diffusion

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