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RESEARCH PAPER · Journal of Materials Chemistry A · 2020

The relationship between oxide-ion conductivity and cation vacancy order in the hybrid hexagonal perovskite Ba 3 VWO 8.5

Asma Gilane, Sacha Fop, Falak Sher, Ronald I. Smith, Abbie Christina Mclaughlin

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The relationship between oxide-ion conductivity and cation vacancy order in the hybrid hexagonal perovskite Ba 3 VWO 8.5OriginalThe Ba 3 Mo 1−x W x NbO 8.5 ion conductors: insights into local coordination from X-ray and neutron total scattering15A pressure induced reversal to the 9R perovskite in Ba 3 MoNbO 8.56Enhancing the oxide-ionic conductivity of Ba 3 Mo 1+ x Nb 1−2 x Ge x O 8.5 at intermediate temperatures: the effect of site-selective Ge 4+ -substitution9Solid oxide proton conductors beyond perovskites101Atomic Structure of the Initial Nucleation Layer in Hexagonal Perovskite BaRuO3 Thin Films3New Solids in As-O-Mo, As(P)-O-Mo(W) and As(P)-O-Nb(W) Systems That Exhibit Nonlinear Optical Properties0Hydration and Ionic Conduction Mechanisms of Hexagonal Perovskite Derivatives61Investigation of the Crystal Structure and Ionic Pathways of the Hexagonal Perovskite Derivative Ba3–xVMoO8.5–x10Synthesis and characterization of Ga-doped Ba3MoNbO8.5 electrolytes for intermediate temperature-solid oxide fuel cells18High Oxide‐Ion Conductivity in a Hexagonal Perovskite‐Related Oxide Ba7Ta3.7Mo1.3O20.15 with Cation Site Preference and Interstitial Oxide Ions49Structure–property correlation in oxide-ion and proton conductors for clean energy applications: recent experimental and computational advancements63Variable Temperature Neutron Diffraction Study of the Oxide Ion Conductor Ba3VWO8.517Oxide-Ion Occupational Disorder, Diffusion Path, and Conductivity in Hexagonal Perovskite Derivatives Ba3WNbO8.5 and Ba3MoNbO8.526Simultaneous Reduction of Proton Conductivity and Enhancement of Oxide-Ion Conductivity by Aliovalent Doping in Ba 7 Nb 4 MoO 2037Characteristics of electrolyte-supported SOFC single cells using hexagonal perovskite Ba3MoNbO8.5 and Ba7Nb4MoO20 ceramics8Proton and Oxide Ion Conductivity in Palmierite Oxides45Recent developments in oxide ion conductors: focusing on Dion–Jacobson phases42A novel yttrium stabilized zirconia and ceria composite electrolyte lowering solid oxide fuel cells working temperature to 400 °C5A Variable Temperature Neutron Diffraction Study of Dual Ion Conducting Sr3v2o80Prospective oxygen-ion conductors Ln X O : Geometry and energy calculations14Enhanced Oxide Ion Conductivity by Ta Doping of Ba3Nb1–xTaxMoO8.53Improved Oxide Ion Conductivity of Hexagonal Perovskite-Related Oxides Ba3W1+xV1−xO8.5+x/212Dimer-Mediated Cooperative Mechanism of Ultrafast-Ion Conduction in Hexagonal Perovskite-Related Oxides32A variable temperature neutron diffraction study of dual ion conducting Sr3V2O88Enhanced Oxygen Ion Conductivity in Ba3w1+Xv1-Xo8.5+X/2 (-0.2 ≤X ≤ 0.2) Hexagonal Perovskite Derivative Compounds0The role of vanadium substitution in the oxygen sublattice disorder of Ba 7 Nb 4 MoO 20 -based hexagonal perovskite oxide-ion conductors12B-site deficient hexagonal perovskites: Structural stability, ionic order-disorder and electrical properties36Enhanced ionic conductivity through B-site Zr doping in NaNbO3 solid electrolytes14Ba3Ti0.4W1.6O8.6: An Oxygen- and B-Site-Deficient 9R Hexagonal Perovskite Exhibiting Triple Conduction3Tuning of the ionic conductivity of Ba 7 Nb 4 MoO 20 by pressure: a neutron diffraction and atomistic modelling study4Dimer-Mediated Cooperative Mechanism of Ultrafast-Ion Conduction in Hexagonal Perovskite-Related Oxides1Effect of germanium substitution on the structure and ionic conductivity of the hexagonal perovskite derivative compound Ba 3 WVO 8.52Introduction0Enhanced oxygen ion conductivity in Ba3W1+xV1−xO8.5+x/2 (− 0.2 ≤ × ≤ 0.2) hexagonal perovskite derivative compounds4High Oxide-Ion Conduction in Rb-Containing Oxides8Unlocking the Potential of Palmierite Oxides: High Oxide Ion Conductivity via Induced Interstitial Defects19Hybrid Hexagonal Perovskite Ba3Ti0.7Mo1.3O8.3: Integrating High Cationic Disordering with Enhanced Tetrahedral Proportion to Achieve High Oxide Ionic Conductivity0Ba7Nb4MoO20: A Proton or Oxide Ion Conductor?13Topochemical Reaction Involving Double-to-Single Layer Conversion: Mo 3 Ta 2 O 10 N with a Kagomé Lattice3Hydration and conduction behavior of Sc and Zr-substituted Ba7Nb4MoO203Enhanced oxygen surface exchange in Sm-doped Ba3MoNbO8.5-δ hexagonal perovskites for solid oxide fuel cells0Discovery of a Rubidium-Containing Oxide-Ion Conductor with Hexagonal Perovskite-Related Structure0Introduction of Hexagonal-Perovskite Type Ionic Conductors and Order/Disorder in the Crystal0Lattice oxygen redistribution in Ba 7 Nb 4 MoO 20 by La-doping enables high oxide ion conductivity0Oxide-Ion Occupational Disorder, Conductivity, and Diffusion Pathways in Ba3MNbO8.5 (M = W, Mo)0Summary and Appendix0Applications of neutron scattering in solid oxide fuel cells1Charting the Landscape of Oxygen Ion Conductors: A 60-Year Dataset with Interpretable Regression Models1All-solid-state proton batteries with a wide operation-temperature range of 160 °C0Impact of Spark Plasma Sintering on the Ionic Conductivity of La‐Doped NaNbO 31Neutron Diffraction for Structural Characterisation of Inorganic Materials0

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  1. The Ba 3 Mo 1−x W x NbO 8.5 ion conductors: insights into local coordination from X-ray and neutron total scattering

    Journal of Materials Chemistry A · 2020-01-01

    Mauro Coduri, Andrea Bernasconi, Henry E. Fischer, Lorenzo Malavasi

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  2. A pressure induced reversal to the 9R perovskite in Ba 3 MoNbO 8.5

    Journal of Materials Chemistry A · 2021-01-01

    B. Sherwood, Christopher J. Ridley, Craig L. Bull, Sacha Fop, J.M.S. Skakle, Abbie Christina Mclaughlin, Eve J. Wildman

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  3. Enhancing the oxide-ionic conductivity of Ba 3 Mo 1+ x Nb 1−2 x Ge x O 8.5 at intermediate temperatures: the effect of site-selective Ge 4+ -substitution

    Dalton Transactions · 2021-01-01

    Zien Cheng, Jia Yang, Pengfei Jiang, He Huang, Iván da Silva, Wenliang Gao, Rihong Cong, Tao Yang

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  4. Solid oxide proton conductors beyond perovskites

    Journal of Materials Chemistry A · 2021-01-01

    Sacha Fop

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  5. Atomic Structure of the Initial Nucleation Layer in Hexagonal Perovskite BaRuO3 Thin Films

    Advanced Materials Interfaces · 2021-02-28

    Sangmoon Yoon, Jong Mok Ok, Sang A Lee, Jegon Lee, Amanda Huon, Andrew R. Lupini, Woo Seok Choi, Ho Nyung Lee

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  6. New Solids in As-O-Mo, As(P)-O-Mo(W) and As(P)-O-Nb(W) Systems That Exhibit Nonlinear Optical Properties

    Molecules · 2021-03-09

    Nikolay Gerasimchuk, Lauri Kivijärvi, Bruce C. Noll, Meriem Goudjil, S. Khanra, Ping Yu, Miles Pearson, Frank Röminger

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  7. Hydration and Ionic Conduction Mechanisms of Hexagonal Perovskite Derivatives

    Chemistry of Materials · 2021-06-06

    Sacha Fop, James Alexander Dawson, Andrew Dominic Fortes, C. Ritter, Abbie Christina Mclaughlin

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  8. Investigation of the Crystal Structure and Ionic Pathways of the Hexagonal Perovskite Derivative Ba3–xVMoO8.5–x

    Inorganic Chemistry · 2021-08-18

    Dylan N. Tawse, Asma Gilane, Sacha Fop, Alfonso Martı́nez-Felipe, Falak Sher, Ronald I. Smith, Abbie Christina Mclaughlin

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  9. Synthesis and characterization of Ga-doped Ba3MoNbO8.5 electrolytes for intermediate temperature-solid oxide fuel cells

    Ceramics International · 2021-11-01

    Dongliang Liao, Gurong Lin, Feng Chen, Xian Pan, Kaiping Peng

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  10. High Oxide‐Ion Conductivity in a Hexagonal Perovskite‐Related Oxide Ba7Ta3.7Mo1.3O20.15 with Cation Site Preference and Interstitial Oxide Ions

    Small · 2021-12-19

    Taito Murakami, Toshiya Shibata, Yuta Yasui, Kotaro Fujii, James Hester, Masatomo Yashima

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  11. Structure–property correlation in oxide-ion and proton conductors for clean energy applications: recent experimental and computational advancements

    Journal of Materials Chemistry A · 2022-01-01

    Mauro Coduri, Maths Karlsson, Lorenzo Malavasi

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  12. Variable Temperature Neutron Diffraction Study of the Oxide Ion Conductor Ba3VWO8.5

    Inorganic Chemistry · 2022-01-11

    Asma Gilane, Sacha Fop, Dylan N. Tawse, C. Ritter, Abbie Christina Mclaughlin

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  13. Oxide-Ion Occupational Disorder, Diffusion Path, and Conductivity in Hexagonal Perovskite Derivatives Ba3WNbO8.5 and Ba3MoNbO8.5

    The Journal of Physical Chemistry C · 2022-01-27

    Yuta Yasui, Takafumi Tsujiguchi, Yuichi Sakuda, James Hester, Masatomo Yashima

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  14. Simultaneous Reduction of Proton Conductivity and Enhancement of Oxide-Ion Conductivity by Aliovalent Doping in Ba 7 Nb 4 MoO 20

    Inorganic Chemistry · 2022-05-03

    Yuki Suzuki, Taito Murakami, Kotaro Fujii, James Hester, Yuta Yasui, Masatomo Yashima

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  15. Characteristics of electrolyte-supported SOFC single cells using hexagonal perovskite Ba3MoNbO8.5 and Ba7Nb4MoO20 ceramics

    Results in Materials · 2022-09-02

    S. Nakayama

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  16. Proton and Oxide Ion Conductivity in Palmierite Oxides

    Chemistry of Materials · 2022-09-06

    Sacha Fop, James Alexander Dawson, Dylan N. Tawse, Matthew G. Skellern, J.M.S. Skakle, Abbie Christina Mclaughlin

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  17. Recent developments in oxide ion conductors: focusing on Dion–Jacobson phases

    Chemical Communications · 2022-11-15

    Wenrui Zhang, Masatomo Yashima

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  18. A novel yttrium stabilized zirconia and ceria composite electrolyte lowering solid oxide fuel cells working temperature to 400 °C

    RSC Advances · 2023-01-01

    Yu Liu, Liwen Zuo, Yulian Ye, Cong Jiang, Dan Zheng, Chunlei Liu, Baoyuan Wang, Xunying Wang

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  19. A Variable Temperature Neutron Diffraction Study of Dual Ion Conducting Sr3v2o8

    SSRN Electronic Journal · 2023-01-01

    Abbie Christina Mclaughlin, Dylan N. Tawse, Sacha Fop, C. Ritter, Alfonso Martı́nez-Felipe

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  20. Prospective oxygen-ion conductors Ln X O : Geometry and energy calculations

    Solid State Ionics · 2023-01-13

    Natalia A. Kabanova, Yelizaveta A. Morkhova, Alexander V. Antonyuk, Eugeny. I. Frolov

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  21. Enhanced Oxide Ion Conductivity by Ta Doping of Ba3Nb1–xTaxMoO8.5

    Inorganic Chemistry · 2023-01-17

    Brent Sherwood, Eve J. Wildman, Ronald I. Smith, Abbie Christina Mclaughlin

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  22. Improved Oxide Ion Conductivity of Hexagonal Perovskite-Related Oxides Ba3W1+xV1−xO8.5+x/2

    Inorganics · 2023-05-29

    Yugo Kikuchi, Yuta Yasui, James Hester, Masatomo Yashima

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  23. Dimer-Mediated Cooperative Mechanism of Ultrafast-Ion Conduction in Hexagonal Perovskite-Related Oxides

    Chemistry of Materials · 2023-11-14

    Yuichi Sakuda, Taito Murakami, Maxim Avdeev, Kotaro Fujii, Yuta Yasui, James Hester, Masato Hagihala, Yoichi Ikeda, Yusuke Nambu, Masatomo Yashima

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  24. A variable temperature neutron diffraction study of dual ion conducting Sr3V2O8

    Journal of Solid State Chemistry · 2023-12-19

    Dylan N. Tawse, Sacha Fop, C. Ritter, Alfonso Martı́nez-Felipe, Abbie Christina Mclaughlin

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  25. Enhanced Oxygen Ion Conductivity in Ba3w1+Xv1-Xo8.5+X/2 (-0.2 ≤X ≤ 0.2) Hexagonal Perovskite Derivative Compounds

    SSRN Electronic Journal · 2024-01-01

    Nitin Kumar, K. Sandeep Rao, Uday Prabhakarrao Deshpande, Vasant Sathe, A. K. Sahu, Srungarpu Nagabhusan Achary, S. Deshpande

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  26. The role of vanadium substitution in the oxygen sublattice disorder of Ba 7 Nb 4 MoO 20 -based hexagonal perovskite oxide-ion conductors

    Journal of Materials Chemistry A · 2024-01-01

    BIFFO Abdulkadir Olatunbosun, Theodosios Famprikis, Pedro B. Groszewicz

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  27. B-site deficient hexagonal perovskites: Structural stability, ionic order-disorder and electrical properties

    Progress in Solid State Chemistry · 2024-04-30

    Xiaoyan Yang, Alberto José Fernández-Carrión, Xinyue Geng, Xiaojun Kuang

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  28. Enhanced ionic conductivity through B-site Zr doping in NaNbO3 solid electrolytes

    Journal of Power Sources · 2024-06-24

    Deepanshu Kaneria, Deepak Yadav, Deepak Yadav, Udeshwari Jamwal, Shivam Kumar Mittal, K. L. Yadav

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  29. Ba3Ti0.4W1.6O8.6: An Oxygen- and B-Site-Deficient 9R Hexagonal Perovskite Exhibiting Triple Conduction

    Inorganic Chemistry · 2024-11-04

    Zien Cheng, Yuling An, Rong Wang, Jöerg C. Neuefeind, Xiaoyan Yang, Rihong Cong, Tao Yang, Pengfei Jiang

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  30. Tuning of the ionic conductivity of Ba 7 Nb 4 MoO 20 by pressure: a neutron diffraction and atomistic modelling study

    Journal of Materials Chemistry A · 2024-12-20

    Victoria Watson, Ying Zhou, Dylan N. Tawse, Oscar J. B. Ballantyne, Christopher J. Ridley, James Alexander Dawson, Abbie Christina Mclaughlin

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  31. Dimer-Mediated Cooperative Mechanism of Ultrafast-Ion Conduction in Hexagonal Perovskite-Related Oxides

    Springer theses · 2025-01-01

    Yuichi Sakuda

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  32. Effect of germanium substitution on the structure and ionic conductivity of the hexagonal perovskite derivative compound Ba 3 WVO 8.5

    Journal of Materials Chemistry C · 2025-01-01

    Nitin Kumar, K. Sandeep Rao, Anu, A. K. Sahu, Srungarpu Nagabhusan Achary, Sudhanshu K. Deshpande

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  33. Introduction

    Springer theses · 2025-01-01

    Yuichi Sakuda

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  34. Enhanced oxygen ion conductivity in Ba3W1+xV1−xO8.5+x/2 (− 0.2 ≤ × ≤ 0.2) hexagonal perovskite derivative compounds

    Ionics · 2025-02-01

    Nitin Kumar, K. Sandeep Rao, Uday Prabhakarrao Deshpande, Vasant Sathe, A. K. Sahu, Srungarpu Nagabhusan Achary, Sudhanshu K. Deshpande

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  35. High Oxide-Ion Conduction in Rb-Containing Oxides

    Chemistry of Materials · 2025-02-03

    Yuta Yasui, Kazuaki Jojima, Kotaro Fujii, Kazuhiro John Mori, Masatomo Yashima

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  36. Unlocking the Potential of Palmierite Oxides: High Oxide Ion Conductivity via Induced Interstitial Defects

    Journal of the American Chemical Society · 2025-03-07

    Dylan N. Tawse, Sacha Fop, John W. Still, Oscar J. B. Ballantyne, C. Ritter, Ying Zhou, James Alexander Dawson, Abbie Christina Mclaughlin

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  37. Hybrid Hexagonal Perovskite Ba3Ti0.7Mo1.3O8.3: Integrating High Cationic Disordering with Enhanced Tetrahedral Proportion to Achieve High Oxide Ionic Conductivity

    Chemistry of Materials · 2025-06-22

    Zien Cheng, Liyang Zhang, Yuling An, Iván da Silva, Jöerg C. Neuefeind, Zhengyang Zhou, Congling Yin, Rihong Cong, Tao Yang, Pengfei Jiang

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  38. Ba7Nb4MoO20: A Proton or Oxide Ion Conductor?

    Journal of the American Chemical Society · 2025-07-01

    Sara Adeeba Ismail, Kazuaki Toyoura, Lulu Jiang, Amir Masoud Dayaghi, Hui Min Guo, Maxim Avdeev, Huaican Chen, Wen Yin, Wang Hay Kan, Truls Norby, Donglin Han

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  39. Topochemical Reaction Involving Double-to-Single Layer Conversion: Mo 3 Ta 2 O 10 N with a Kagomé Lattice

    Journal of the American Chemical Society · 2025-07-24

    Ryoya Higuchi, K. Ishida, Cédric Tassel, Baptiste Vignolle, Daichi Kato, Kantaro Murayama, Hsin‐Hui Huang, Akihide Kuwabara, Shunsuke Kobayashi, Yusuke Nambu, Hiroyasu Matsudaira, Shunsaku Kitagawa, Kenji Ishida, Congling Yin, Hiroshi Takatsu, Hiroshi Kageyama

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  40. Hydration and conduction behavior of Sc and Zr-substituted Ba7Nb4MoO20

    Solid State Ionics · 2025-09-16

    Sara Adeeba Ismail, Lulu Jiang, Hui Min Guo, Wenhao Li, Donglin Han

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  41. Enhanced oxygen surface exchange in Sm-doped Ba3MoNbO8.5-δ hexagonal perovskites for solid oxide fuel cells

    Ceramics International · 2025-12-30

    Saim Saher, Affaq Qamar, Chou Yong Tan, S. Ramesh

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  42. Discovery of a Rubidium-Containing Oxide-Ion Conductor with Hexagonal Perovskite-Related Structure

    Springer theses · 2026-01-01

    Yuta Yasui

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  43. Introduction of Hexagonal-Perovskite Type Ionic Conductors and Order/Disorder in the Crystal

    Springer theses · 2026-01-01

    Yuta Yasui

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  44. Lattice oxygen redistribution in Ba 7 Nb 4 MoO 20 by La-doping enables high oxide ion conductivity

    Journal of Materials Chemistry A · 2026-01-01

    Sara Adeeba Ismail, Wang Hay Kan, Lulu Jiang, Amir Masoud Dayaghi, Hui Guo, Wenqi Lei, Sumei Lin, Wenhao Li, Huaican Chen, Wen Yin, Zhaohao Qin, Xiaofeng Ye, Maxim Avdeev, Donglin Han

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  45. Oxide-Ion Occupational Disorder, Conductivity, and Diffusion Pathways in Ba3MNbO8.5 (M = W, Mo)

    Springer theses · 2026-01-01

    Yuta Yasui

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  46. Summary and Appendix

    Springer theses · 2026-01-01

    Yuta Yasui

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  47. Applications of neutron scattering in solid oxide fuel cells

    Materials Futures · 2026-02-24

    De Ning, Shaoshuai Chen, Dongxia Wang, Xuemei Li, Jia Song, Wenyuan Li, Xingbo Liu, Qingsong Wang, Qingyuan Li

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  48. Charting the Landscape of Oxygen Ion Conductors: A 60-Year Dataset with Interpretable Regression Models

    Scientific Data · 2026-04-01

    Seong‐Hoon Jang, Shin Kiyohara, Hitoshi Takamura, Yu Kumagai

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  49. All-solid-state proton batteries with a wide operation-temperature range of 160 °C

    Energy Materials · 2026-06-30

    Lifen Long, Yike Huang, Yun Zheng, Yan Guo, Yinan Liu, Yingying Shen, Pingshan Jia, Zikang Xu, Shengyang Dong, Huaiyu Shao

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  50. Impact of Spark Plasma Sintering on the Ionic Conductivity of La‐Doped NaNbO 3

    Advanced Sustainable Systems · 2026-08-01

    Deepanshu Kaneria, K. L. Yadav

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