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RESEARCH PAPER · Chemical Communications · 2022

Recent developments in oxide ion conductors: focusing on Dion–Jacobson phases

Wenrui Zhang, Masatomo Yashima

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Recent developments in oxide ion conductors: focusing on Dion–Jacobson phasesOriginalHigh Proton Conductivity in β‐Ba 2 ScAlO 5 Enabled by Octahedral and Intrinsically Oxygen‐Deficient Layers34Multifunctionality of luminescent molecular nanomagnets based on lanthanide complexes67Structural and Electrical Properties of Bi3gasb2o11 at High Temperatures3High Oxide‐Ion Conductivity through the Interstitial Oxygen Site in Sillén Oxychlorides34Hidden chemical order in disordered Ba7Nb4MoO20 revealed by resonant X-ray diffraction and solid-state NMR32Improved Oxide Ion Conductivity of Hexagonal Perovskite-Related Oxides Ba3W1+xV1−xO8.5+x/212Design of Mixed Ionic-Electronic Materials for Permselective Membranes and Solid Oxide Fuel Cells Based on Their Oxygen and Hydrogen Mobility31Machine Learning Combined with Weighted Voting Regression and Proactive Searching Progress to Discover ABO3-δ Perovskites with High Oxide Ionic Conductivity11Tuning of structure and host dynamics via yttrium doping in Bi2O3 to enhance oxygen ion diffusion5Dimer-Mediated Cooperative Mechanism of Ultrafast-Ion Conduction in Hexagonal Perovskite-Related Oxides32High proton conductivity within the ‘Norby gap’ by stabilizing a perovskite with disordered intrinsic oxygen vacancies73Designed functions of oxide/hydroxide nanosheets via elemental replacement/doping46High Conductivity and Diffusion Mechanism of Oxide Ions in Triple Fluorite-Like Layers of Oxyhalides20Phases, stabilities, and oxide ion conductions of multiple lanthanide and tungsten co–doped δ-Bi2O3-based materials: From low to high configuration entropy10Computational Insights into Dion–Jacobson Type Oxide Ion Conductors9Epitaxial quasi-2D/3D hybrid perovskite heterojunctions for photodetector with enhanced detectivity and stability14High Proton Conduction in the Octahedral Layers of Fully Hydrated Hexagonal Perovskite-Related Oxides43Defect Structure, Oxygen Ion Conduction, and Conducting Mechanism in Ruddlesden–Popper Sr3Zr2–xMxO7–0.5x (M = Ga, Y, In)5Ba3Ti0.4W1.6O8.6: An Oxygen- and B-Site-Deficient 9R Hexagonal Perovskite Exhibiting Triple Conduction3Solid-State 95Mo and 93Nb NMR Study of Ba7Nb4MoO20-Based Materials and Ba7Ta3.7Mo1.3O20.154Dimer-Mediated Cooperative Mechanism of Ultrafast-Ion Conduction in Hexagonal Perovskite-Related Oxides1Hydration-driven enhancement of interstitialcy oxide-ion diffusion10Introduction0High Oxide-Ion Conduction in Rb-Containing Oxides8Anionic doping strategy: F− to improve the conductivity and cell performances of SDC1The Effect of Ga and Mo Doping on the Phase and Mobility of Interstitial Oxygen in K2ZnV2O70Oxide ion conduction and conducting mechanisms in novel double perovskite La1-Sr1+Zr1-Ga1+O6- (0 ≤ x ≤ 0.1)0Novel Low‐Temperature Operating Catalytic Combustion‐Type Methane Gas Sensor Based on Gadolinium Silicate‐Supported Palladium Oxide2Crossover from insulating into solid electrolyte behavior in bulk CaSO4⋅0.5H2O material due to ion exchange processes induced by high-temperature treatment with orthophosphoric acid2Synthesis of δ-bismuth oxide stable at room temperature for use in industrial applications3Enhanced oxygen surface exchange in Sm-doped Ba3MoNbO8.5-δ hexagonal perovskites for solid oxide fuel cells0Discovery of a Rubidium-Containing Oxide-Ion Conductor with Hexagonal Perovskite-Related Structure0Hidden Occupational Order in Disordered Ba7Nb4MoO20 Revealed by a Combined Technique of Resonant X-ray Diffraction and Solid-State NMR0Highly stable apatite-type Ni/La 10 Si 6 O 27 : achieving near-zero coking and sintering in auto-thermal reforming of acetic acid0Advanced electrochemical impedance spectroscopy for high-performance solid oxide fuel cells: A critical review15Applications of neutron scattering in solid oxide fuel cells1High Conductivity and Diffusion Mechanism of Oxide‐Ion in Sillén‐Aurivillius Phase Oxobromide0Ferroelectricity‐Enhanced Photocatalysis: Mechanisms, Materials, and Engineering Strategies0Suppress oxygen ordering and deviation for the design of bismuth oxide-based low temperature ionic conductors1Charting the Landscape of Oxygen Ion Conductors: A 60-Year Dataset with Interpretable Regression Models1Evolution of electrolyte materials for solid oxide electrolysis cells: From traditional oxides to high-performance ionic conductors3Layer Alignment via Short Strong Hydrogen Bonding in the Dion–Jacobson Perovskite Solid Acid HLaNb2O70

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  1. High Proton Conductivity in β‐Ba 2 ScAlO 5 Enabled by Octahedral and Intrinsically Oxygen‐Deficient Layers

    Advanced Functional Materials · 2022-12-19

    Taito Murakami, Maxim Avdeev, Riho Morikawa, James Hester, Masatomo Yashima

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  2. Multifunctionality of luminescent molecular nanomagnets based on lanthanide complexes

    Chemical Communications · 2023-01-01

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  3. Structural and Electrical Properties of Bi3gasb2o11 at High Temperatures

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    Kohei Matsuzaki, Wenrui Zhang, K. Saito, Kotaro Fujii, Masatomo Yashima

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  4. High Oxide‐Ion Conductivity through the Interstitial Oxygen Site in Sillén Oxychlorides

    Advanced Functional Materials · 2023-04-20

    Hiroshi Yaguchi, Daisuke Morikawa, Takashi Saito, Kenji Tsuda, Masatomo Yashima

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  5. Hidden chemical order in disordered Ba7Nb4MoO20 revealed by resonant X-ray diffraction and solid-state NMR

    Nature Communications · 2023-04-24

    Yuta Yasui, Masataka Tansho, Kotaro Fujii, Yuichi Sakuda, Atsushi Goto, Shinobu Ohki, Yuuki Mogami, Takahiro Iijima, Shintaro Kobayashi, Shogo Kawaguchi, Keiichi Osaka, Kazutaka Ikeda, Toshiya Otomo, Masatomo Yashima

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  6. Improved Oxide Ion Conductivity of Hexagonal Perovskite-Related Oxides Ba3W1+xV1−xO8.5+x/2

    Inorganics · 2023-05-29

    Yugo Kikuchi, Yuta Yasui, James Hester, Masatomo Yashima

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  7. Design of Mixed Ionic-Electronic Materials for Permselective Membranes and Solid Oxide Fuel Cells Based on Their Oxygen and Hydrogen Mobility

    Membranes · 2023-07-27

    Vladіslav Sadykov, Elena Yu. Pikalova, Ekaterina M. Sadovskaya, A. V. Shlyakhtina, Elena A. Filonova, Nikita Eremeev

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  8. Machine Learning Combined with Weighted Voting Regression and Proactive Searching Progress to Discover ABO3-δ Perovskites with High Oxide Ionic Conductivity

    The Journal of Physical Chemistry C · 2023-08-18

    Pengcheng Xu, Tian Lu, Xiaobo Ji, Minjie Li, Wencong Lu

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  9. Tuning of structure and host dynamics via yttrium doping in Bi2O3 to enhance oxygen ion diffusion

    Physical Review Materials · 2023-09-25

    Prabhatasree Goel, Mayanak K. Gupta, Sajan Kumar, R. Mittal, Aditya Prasad Roy, Dipanshu Bansal, Manh Duc Le, Rakesh Shukla, Srungarpu Nagabhusan Achary, Sanghamitra Mukhopadhyay, A. K. Tyagi, Samrath Lal Chaplot

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  10. Dimer-Mediated Cooperative Mechanism of Ultrafast-Ion Conduction in Hexagonal Perovskite-Related Oxides

    Chemistry of Materials · 2023-11-14

    Yuichi Sakuda, Taito Murakami, Maxim Avdeev, Kotaro Fujii, Yuta Yasui, James Hester, Masato Hagihala, Yoichi Ikeda, Yusuke Nambu, Masatomo Yashima

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  11. High proton conductivity within the ‘Norby gap’ by stabilizing a perovskite with disordered intrinsic oxygen vacancies

    Nature Communications · 2023-11-17

    K. Saito, Masatomo Yashima

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  12. Designed functions of oxide/hydroxide nanosheets via elemental replacement/doping

    Chemical Society Reviews · 2024-01-01

    Kanji Saito, Masashi Morita, Tomohiko Okada, Rattanawadee Ploy Wijitwongwan, Makoto Ogawa

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  13. High Conductivity and Diffusion Mechanism of Oxide Ions in Triple Fluorite-Like Layers of Oxyhalides

    Journal of the American Chemical Society · 2024-04-09

    Nachi Ueno, Hiroshi Yaguchi, Kotaro Fujii, Masatomo Yashima

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  14. Phases, stabilities, and oxide ion conductions of multiple lanthanide and tungsten co–doped δ-Bi2O3-based materials: From low to high configuration entropy

    Ceramics International · 2024-04-26

    Man Tian, Hujun Cao, Laijun Liu, Jungu Xu

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  15. Computational Insights into Dion–Jacobson Type Oxide Ion Conductors

    The Journal of Physical Chemistry C · 2024-05-24

    Bettina Schwaighofer, Miguel Angel Gonzalez, Ivana Radosavljević Evans

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  16. Epitaxial quasi-2D/3D hybrid perovskite heterojunctions for photodetector with enhanced detectivity and stability

    Nano Research · 2024-05-25

    Yifu Chen, Lin Zhang, Xinxin Peng, Weiran Qin, Shiqing Li, Yingwei Wang, Zhihui Chen, Si Xiao, Bin Yang, Biao Liu, Junliang Yang, Han Huang, Yun Lin, Jun He, Liming Ding, Yongbo Yuan

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  17. High Proton Conduction in the Octahedral Layers of Fully Hydrated Hexagonal Perovskite-Related Oxides

    Journal of the American Chemical Society · 2024-06-25

    Kohei Matsuzaki, K. Saito, Yoichi Ikeda, Yusuke Nambu, Masatomo Yashima

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  18. Defect Structure, Oxygen Ion Conduction, and Conducting Mechanism in Ruddlesden–Popper Sr3Zr2–xMxO7–0.5x (M = Ga, Y, In)

    Inorganic Chemistry · 2024-09-12

    Keke Hou, Chenjie Lou, Mingxue Tang, Hujun Cao, Laijun Liu, Jungu Xu

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  19. Ba3Ti0.4W1.6O8.6: An Oxygen- and B-Site-Deficient 9R Hexagonal Perovskite Exhibiting Triple Conduction

    Inorganic Chemistry · 2024-11-04

    Zien Cheng, Yuling An, Rong Wang, Jöerg C. Neuefeind, Xiaoyan Yang, Rihong Cong, Tao Yang, Pengfei Jiang

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  20. Solid-State 95Mo and 93Nb NMR Study of Ba7Nb4MoO20-Based Materials and Ba7Ta3.7Mo1.3O20.15

    The Journal of Physical Chemistry C · 2024-11-08

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  21. Dimer-Mediated Cooperative Mechanism of Ultrafast-Ion Conduction in Hexagonal Perovskite-Related Oxides

    Springer theses · 2025-01-01

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  22. Hydration-driven enhancement of interstitialcy oxide-ion diffusion

    Journal of Materials Chemistry A · 2025-01-01

    Yuichi Sakuda, Mudasir A. Yatoo, Bhuvaneshwari Manivannan, Vediyappan Veeramani, Junko Habasaki, Stephen J. Skinner, Hiroshige Matsumoto, Masatomo Yashima

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  23. Introduction

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  24. High Oxide-Ion Conduction in Rb-Containing Oxides

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  25. Anionic doping strategy: F− to improve the conductivity and cell performances of SDC

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  26. The Effect of Ga and Mo Doping on the Phase and Mobility of Interstitial Oxygen in K2ZnV2O7

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  27. Oxide ion conduction and conducting mechanisms in novel double perovskite La1-Sr1+Zr1-Ga1+O6- (0 ≤ x ≤ 0.1)

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  28. Novel Low‐Temperature Operating Catalytic Combustion‐Type Methane Gas Sensor Based on Gadolinium Silicate‐Supported Palladium Oxide

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  29. Crossover from insulating into solid electrolyte behavior in bulk CaSO4⋅0.5H2O material due to ion exchange processes induced by high-temperature treatment with orthophosphoric acid

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  30. Synthesis of δ-bismuth oxide stable at room temperature for use in industrial applications

    Scientific Reports · 2025-12-21

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  31. Enhanced oxygen surface exchange in Sm-doped Ba3MoNbO8.5-δ hexagonal perovskites for solid oxide fuel cells

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  32. Discovery of a Rubidium-Containing Oxide-Ion Conductor with Hexagonal Perovskite-Related Structure

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  33. Hidden Occupational Order in Disordered Ba7Nb4MoO20 Revealed by a Combined Technique of Resonant X-ray Diffraction and Solid-State NMR

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  34. Highly stable apatite-type Ni/La 10 Si 6 O 27 : achieving near-zero coking and sintering in auto-thermal reforming of acetic acid

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  35. Advanced electrochemical impedance spectroscopy for high-performance solid oxide fuel cells: A critical review

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  36. Applications of neutron scattering in solid oxide fuel cells

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  37. High Conductivity and Diffusion Mechanism of Oxide‐Ion in Sillén‐Aurivillius Phase Oxobromide

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  39. Suppress oxygen ordering and deviation for the design of bismuth oxide-based low temperature ionic conductors

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  40. Charting the Landscape of Oxygen Ion Conductors: A 60-Year Dataset with Interpretable Regression Models

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  42. Layer Alignment via Short Strong Hydrogen Bonding in the Dion–Jacobson Perovskite Solid Acid HLaNb2O7

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