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RESEARCH PAPER · Chemical Communications · 2018

Li 4 Na 2 CsB 7 O 14 : a new edge-sharing [BO 4 ] 5− tetrahedra containing borate with high anisotropic thermal expansion

Miriding Mutailipu, Min Zhang, Hao Li, Xiao Fan, Zhihua Yang, Shifeng Jin, Gang Wang, Shilie Pan

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Li 4 Na 2 CsB 7 O 14 : a new edge-sharing [BO 4 ] 5− tetrahedra containing borate with high anisotropic thermal expansionOriginalBa 3 B 10 O 17 F 2 ·0.1KF: the first mixed alkali/alkaline-earth metal fluorooxoborate with unprecedented double-layered B–O/F anionic arrangement17Sr[B(OH) 4 ](IO 3 ) and Li 4 Sr 5 [B 12 O 22 (OH) 4 ](IO 3 ) 2 : two unprecedented metal borate-iodates showing a subtle balance of enlarged band gap and birefringence34Photo-tunable linear and nonlinear optical response of cyclophanediene-dihydropyrene photoswitches9Transformation of the B–O Units from Corner-Sharing to Edge-Sharing Linkages in BaMBO4 (M = Ga, Al)33β‐CsB9O14: A Triple‐Layered Borate with Edge‐Sharing BO4 Tetrahedra Exhibiting a Short Cutoff Edge and a Large Birefringence30Research and Development of Zincoborates: Crystal Growth, Structural Chemistry and Physicochemical Properties20The bismuth orthotantalate with high anisotropic thermal expansion10Sr 5 TeO 2 (BO 3 ) 4 and NaSr 5 (BO 3 )(SiO 4 ) 2 : two inorganic metal borate derivatives with diverse zero dimensional anions21BaLiTe2O5X (X = Cl, Br): mixed alkali/alkaline-earth metal tellurite halides with [Te2O5]∞ chains11Li 3 CaB 2 O 5 F: a unique sandwich-like structure with diverse and wide Li ion diffusion pathways5La3B6O13(OH): The First Acentric High‐Pressure Borate Displaying Edge‐Sharing BO4 Tetrahedra25A Promising Fluorooxoborate Framework with Flexibile Capability for Diverse Cations to Enhance the Second Harmonic Generation14Two New Ferroborates with Three‐Dimensional Framework and Wide Transmittance Window2Flux synthesis and characterization of two barium hydroxyborosilicates with triple and single tetrahedral layers: Ba2[Si3B3O12(OH)] and Ba[Si2BO6(OH)]3Li4Ca2B8O16: A Borate with a Unique Fundamental Building Block and a Short Cutoff Edge14Second-order nonlinear optical-active selenide borate Zn8Se2(BO2)12: Experimental and theoretical analysis9High-pressure synthesis of REB5O8(OH)2 (RE = Ho, Er, Tm)3Borates: A Rich Source for Optical Materials1089Li 5 Cs(SO 4 ) 3 : a potential zero-order wave plate material with short deep-ultraviolet cutoff edge20Pb 2.28 Ba 1.72 B 10 O 19 featuring a three-dimensional B–O anionic network with edge-sharing [BO 4 ] obtained under ambient pressure6Toward the Coordination Fingerprint of the Edge-Sharing BO4 Tetrahedra9Second-order nonlinear optical and photoelectric properties of Zn4B6O12S20Bi2[B2(SeO3)6]: A Metal Boroselenite with a Unique Zero-Dimensional [B2(SeO3)6]6– Anionic Group and Large Birefringence31A New Tubular Borate Built By [B14O24(OH)6]12− Cluster Units12K3BaTeB7O15: A new borotellurite with mixed metal cations5Edge-sharing BO 4 tetrahedra and penta-coordinated silicon in the high-pressure modification of NaBSi 3 O 814γ-BaB2O4: High-Pressure High-Temperature Polymorph of Barium Borate with Edge-Sharing BO4 Tetrahedra15Finding a Deep‐UV Borate BaZnB4O8 with Edge‐sharing [BO4] Tetrahedra and Strong Optical Anisotropy20Ba6Zn6(B3O6)6(B6O12): Barium Zinc Borate Contains π-Conjugated [B3O6]3– Anions and [B6O12]6– Anion with Edge-Sharing BO4 Tetrahedra36Hydroxylherderite (Ca 2 Be 2 P 2 O 8 (OH) 2 ) stability under extreme conditions (up to 750°C/100 GPa)6Topologically prone or cation compression restricted phase transition: An example of feldspar-related SrGe2B2O82Discovery of SrZn 2 B 6 O 12 with an unprecedented quadruple-layered configuration0Hydroxyfluorooxoborate (NH 4 )[C(NH 2 ) 3 ][B 3 O 3 F 4 (OH)] for exploring the effects of cation substitution on structure and optical properties26Recent Progress in Crystalline Borates with Edge-Sharing BO4 Tetrahedra21The Strategy to Improve the Phase Matching Ability in Tetrahedron‐Based Deep‐Ultraviolet Nonlinear Optical Crystals21A novel contribution to the M3B6O10X hexaborate family: The new silver compound Ag3B6O10Br and thermal behavior of Ag3B6O10(NO3) and Na3B6O10I9Synthesis and crystal structure of the new zinc borate Zn6.1B6O19H7.81Cd8(BO3)4SiO4: Metal Cation Inducing the Formation of Isolated [BO3] and [SiO4] Units in Borate Silicate15Asymmetrical LaO9 polyhedron inducing anisotropic positive thermal expansion and moderate lattice thermal conductivity in LaBO3 with isolated planar [BO3] group10“One stone two birds” design of borates featuring edge-sharing [BO 4 ] and different B–O configurations in one structure utilizing covalent tetrahedra8A perspective on deep-ultraviolet nonlinear optical materials13Color-tunability and energy transfer of a highly thermal-stable BaZnB4O8:Tb3+/Eu3+ phosphor for single-component w-LEDs21Thermal Expansion of Alkaline-Earth Borates4LiNa2Ca8B12O24F6Cl and Li1.2Na2.8B6O11: A Case of Cation-Induced Birefringence Enhancement via Dimensional Changes of Highly Polymerized [B12O24] Motifs10Na 2 PbB 6 O 10 SO 4 and Ca 2.58 Pb 0.42 B 6 O 11 SO 4 : first borate–sulfates featuring 3D porous borate anionic frameworks0LiAgCe2F10(H2O)2: Focusing on the Cation Size Effect to Reasonably Design a Nonlinear Optical Hydrated Cerium(IV) Fluoride10A review of the fraction of four-coordinated boron in binary borate glasses and melts34Extending the Chemistry of Scheelite‐type Oxides with Borates7Extending the Chemistry of Scheelite‐type Oxides with Borates2Low Thermal Expansion in Niobate Borate NbBO4 Enabled by Compensated Grüneisen Parameters of NbO8 Polyhedra1Local Bond Engineering in LiMBO 4 (M = Si, Ge): Synergistic Negative Grüneisen Parameter and Bond Stiffening for Reduced Thermal Expansion0Ba 5 Zn 4 (B 3 O 6 ) 2 (B 12 O 24 ): A Borate with Edge-Sharing [BO 4 ] Tetrahedral Connection by Introducing Zn into β-BaB 2 O 42

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  1. Ba 3 B 10 O 17 F 2 ·0.1KF: the first mixed alkali/alkaline-earth metal fluorooxoborate with unprecedented double-layered B–O/F anionic arrangement

    Chemical Communications · 2019-01-01

    Yahui Li, Hongwei Yu, Guopeng Han, Hao Li, Zhihua Yang, Shilie Pan

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  2. Sr[B(OH) 4 ](IO 3 ) and Li 4 Sr 5 [B 12 O 22 (OH) 4 ](IO 3 ) 2 : two unprecedented metal borate-iodates showing a subtle balance of enlarged band gap and birefringence

    Chemical Communications · 2019-01-01

    Guang Peng, Chensheng Lin, Dan Zhao, Liling Cao, Huixin Fan, Kaichuang Chen, Ning Ye

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  3. Photo-tunable linear and nonlinear optical response of cyclophanediene-dihydropyrene photoswitches

    Journal of Molecular Graphics and Modelling · 2019-02-04

    Bibi Saima, Nasir Khan, Yasair Suliman Al-Faiyz, Ralf Ludwig, Wajid Ur Rehman, Mian Habib-ur-Rehman, Nadeem S. Sheikh, Khurshid Ayub

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  4. Transformation of the B–O Units from Corner-Sharing to Edge-Sharing Linkages in BaMBO4 (M = Ga, Al)

    Inorganic Chemistry · 2019-06-04

    Fengjiao Guo, Jian Wei Han, Shichao Cheng, Sujuan Yu, Zhihua Yang, Shilie Pan

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  5. β‐CsB9O14: A Triple‐Layered Borate with Edge‐Sharing BO4 Tetrahedra Exhibiting a Short Cutoff Edge and a Large Birefringence

    Chemistry - A European Journal · 2019-06-18

    Shujuan Han, Chunmei Huang, Abudukadi Tudi, Shuaishuai Hu, Zhihua Yang, Shilie Pan

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  6. Research and Development of Zincoborates: Crystal Growth, Structural Chemistry and Physicochemical Properties

    Molecules · 2019-07-30

    Yanna Chen, Min Zhang, Miriding Mutailipu, Kenneth Reinhard Poeppelmeier, Shilie Pan

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  7. The bismuth orthotantalate with high anisotropic thermal expansion

    Scripta Materialia · 2019-08-01

    Nadezhda A. Zhuk, Maria Georgievna Krzhizhanovskaya, Vladimir Aleksandrovich Belyy, Nikolay A. Sekushin, Alena I. Chichineva

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  8. Sr 5 TeO 2 (BO 3 ) 4 and NaSr 5 (BO 3 )(SiO 4 ) 2 : two inorganic metal borate derivatives with diverse zero dimensional anions

    Dalton Transactions · 2019-10-27

    Ru‐Ling Tang, Chun‐Li Hu, Jianghe Feng, Zhi Gang Fang, Yan Chen, Fang Kong, Jiang‐Gao Mao

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  9. BaLiTe2O5X (X = Cl, Br): mixed alkali/alkaline-earth metal tellurite halides with [Te2O5]∞ chains

    Dalton Transactions · 2020-01-01

    Ting Wang, Yi-Gang Chen, Yao Guo, Fang Wang, Qi Song, Ying‐Jie Jia, Xian‐Ming Zhang

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  10. Li 3 CaB 2 O 5 F: a unique sandwich-like structure with diverse and wide Li ion diffusion pathways

    Dalton Transactions · 2020-01-01

    Mengmeng Ding, Jingjing Xu, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  11. La3B6O13(OH): The First Acentric High‐Pressure Borate Displaying Edge‐Sharing BO4 Tetrahedra

    Chemistry - A European Journal · 2020-01-14

    Birgit Fuchs, Günter Heymann, Xuefei Wang, Abudukadi Tudi, Lkhamsuren Bayarjargal, Renée Siegel, Adrian Schmutzler, Jürgen Senker, Bastian Joachim, Andreas Saxer, Zhihua Yang, Shilie Pan, Hubert Huppertz

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  12. A Promising Fluorooxoborate Framework with Flexibile Capability for Diverse Cations to Enhance the Second Harmonic Generation

    Chemistry - A European Journal · 2020-01-16

    Shichao Cheng, Miriding Mutailipu, Zhihua Yang, Shilie Pan

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  13. Two New Ferroborates with Three‐Dimensional Framework and Wide Transmittance Window

    European Journal of Inorganic Chemistry · 2020-03-19

    Huimin Song, Naizheng Wang, Yunfei Li, Wang Liu, Zheshuai Lin, Jiyong Yao, Guochun Zhang

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  14. Flux synthesis and characterization of two barium hydroxyborosilicates with triple and single tetrahedral layers: Ba2[Si3B3O12(OH)] and Ba[Si2BO6(OH)]

    Journal of Solid State Chemistry · 2020-03-24

    Ling-Wei Chang, Hsin‐Kuan Liu, Kwang‐Hwa Lii

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  15. Li4Ca2B8O16: A Borate with a Unique Fundamental Building Block and a Short Cutoff Edge

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  16. Second-order nonlinear optical-active selenide borate Zn8Se2(BO2)12: Experimental and theoretical analysis

    Journal of Solid State Chemistry · 2020-07-18

    Wenfeng Zhou, Xiaohui Li, Wen‐Dong Yao, Huaiguo Xue, Sheng‐Ping Guo

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  17. High-pressure synthesis of REB5O8(OH)2 (RE = Ho, Er, Tm)

    Zeitschrift für Naturforschung B · 2020-12-04

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  18. Borates: A Rich Source for Optical Materials

    Chemical Reviews · 2020-12-14

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  19. Li 5 Cs(SO 4 ) 3 : a potential zero-order wave plate material with short deep-ultraviolet cutoff edge

    New Journal of Chemistry · 2021-01-01

    Yuchen Yan, Yanna Chen, Bao Jiang, Qun Jing, Jun Zhang

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  20. Pb 2.28 Ba 1.72 B 10 O 19 featuring a three-dimensional B–O anionic network with edge-sharing [BO 4 ] obtained under ambient pressure

    Inorganic Chemistry Frontiers · 2021-01-01

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  21. Toward the Coordination Fingerprint of the Edge-Sharing BO4 Tetrahedra

    Inorganic Chemistry · 2021-01-21

    Éric Quarez, Éric Gautron, Michaël Paris, David Gajan, Jean‐Yves Mevellec

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  22. Second-order nonlinear optical and photoelectric properties of Zn4B6O12S

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  23. Bi2[B2(SeO3)6]: A Metal Boroselenite with a Unique Zero-Dimensional [B2(SeO3)6]6– Anionic Group and Large Birefringence

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    Ru‐Ling Tang, Chun‐Li Hu, Weijie Xie, Q. Huang, Jiang‐Gao Mao

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  24. A New Tubular Borate Built By [B14O24(OH)6]12− Cluster Units

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  25. K3BaTeB7O15: A new borotellurite with mixed metal cations

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  26. Edge-sharing BO 4 tetrahedra and penta-coordinated silicon in the high-pressure modification of NaBSi 3 O 8

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  27. γ-BaB2O4: High-Pressure High-Temperature Polymorph of Barium Borate with Edge-Sharing BO4 Tetrahedra

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  28. Finding a Deep‐UV Borate BaZnB4O8 with Edge‐sharing [BO4] Tetrahedra and Strong Optical Anisotropy

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  29. Ba6Zn6(B3O6)6(B6O12): Barium Zinc Borate Contains π-Conjugated [B3O6]3– Anions and [B6O12]6– Anion with Edge-Sharing BO4 Tetrahedra

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  30. Hydroxylherderite (Ca 2 Be 2 P 2 O 8 (OH) 2 ) stability under extreme conditions (up to 750°C/100 GPa)

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  31. Topologically prone or cation compression restricted phase transition: An example of feldspar-related SrGe2B2O8

    Journal of Alloys and Compounds · 2022-12-28

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  32. Discovery of SrZn 2 B 6 O 12 with an unprecedented quadruple-layered configuration

    New Journal of Chemistry · 2023-01-01

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  33. Hydroxyfluorooxoborate (NH 4 )[C(NH 2 ) 3 ][B 3 O 3 F 4 (OH)] for exploring the effects of cation substitution on structure and optical properties

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  34. Recent Progress in Crystalline Borates with Edge-Sharing BO4 Tetrahedra

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  35. The Strategy to Improve the Phase Matching Ability in Tetrahedron‐Based Deep‐Ultraviolet Nonlinear Optical Crystals

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  36. A novel contribution to the M3B6O10X hexaborate family: The new silver compound Ag3B6O10Br and thermal behavior of Ag3B6O10(NO3) and Na3B6O10I

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  37. Synthesis and crystal structure of the new zinc borate Zn6.1B6O19H7.8

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  38. Cd8(BO3)4SiO4: Metal Cation Inducing the Formation of Isolated [BO3] and [SiO4] Units in Borate Silicate

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  39. Asymmetrical LaO9 polyhedron inducing anisotropic positive thermal expansion and moderate lattice thermal conductivity in LaBO3 with isolated planar [BO3] group

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  40. “One stone two birds” design of borates featuring edge-sharing [BO 4 ] and different B–O configurations in one structure utilizing covalent tetrahedra

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  41. A perspective on deep-ultraviolet nonlinear optical materials

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  42. Color-tunability and energy transfer of a highly thermal-stable BaZnB4O8:Tb3+/Eu3+ phosphor for single-component w-LEDs

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  43. Thermal Expansion of Alkaline-Earth Borates

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  44. LiNa2Ca8B12O24F6Cl and Li1.2Na2.8B6O11: A Case of Cation-Induced Birefringence Enhancement via Dimensional Changes of Highly Polymerized [B12O24] Motifs

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  45. Na 2 PbB 6 O 10 SO 4 and Ca 2.58 Pb 0.42 B 6 O 11 SO 4 : first borate–sulfates featuring 3D porous borate anionic frameworks

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  46. LiAgCe2F10(H2O)2: Focusing on the Cation Size Effect to Reasonably Design a Nonlinear Optical Hydrated Cerium(IV) Fluoride

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  47. A review of the fraction of four-coordinated boron in binary borate glasses and melts

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  48. Extending the Chemistry of Scheelite‐type Oxides with Borates

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  49. Extending the Chemistry of Scheelite‐type Oxides with Borates

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  50. Low Thermal Expansion in Niobate Borate NbBO4 Enabled by Compensated Grüneisen Parameters of NbO8 Polyhedra

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