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RESEARCH PAPER · Inorganic Chemistry · 2024

LiNa2Ca8B12O24F6Cl and Li1.2Na2.8B6O11: A Case of Cation-Induced Birefringence Enhancement via Dimensional Changes of Highly Polymerized [B12O24] Motifs

Ziting Yan, Jinbin Fan, Dongdong Chu, Zhihua Yang, Juanjuan Lu, Shilie Pan, Min Zhang

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LiNa2Ca8B12O24F6Cl and Li1.2Na2.8B6O11: A Case of Cation-Induced Birefringence Enhancement via Dimensional Changes of Highly Polymerized [B12O24] MotifsOriginalCa 3 Al 2 B 8 O 18 : borate with a graphene-like layer featuring two types of topological six-membered rings induced by [AlO 4 ] units7K0.9Rb2.1B8PO16: Design and Synthesis of a Deep-Ultraviolet Nonlinear Optical Crystal with Balanced Performance Derived from π-Conjugated and Non-π-Conjugated Groups11CO2-Promoted Assembly of Nonplanar B12O24-Ring as a Fundamental Building Block in Lithium–Sodium Alkali Borates during Carbon Capture0NH4B5O7(OH)2 and CsRbB10O14(OH)4·H2O: Two Hydroxyborates Feature Significant Optical Anisotropy and Contain 1∞[B5O7(OH)2] Chains1Cation-modulated aligned arrangement of [B3O7] units in an unprecedented 2∞[B3O5] layer with remarkable birefringence10Studies on Three 3D Bimetallic Tellurates: Including a Second-Order NLO Material with d10-Zn2+ and SOJT-Effect Te4+/Mo6+ Cations2Tuning birefringence in alkaline-earth metal oxyhalides through diverse mixed-cation coordination architectures1A New Short-Wavelength UV NLO Material based on Dual Alkaline-Earth Metal Borophosphate with 1D Helical Anionic Chains0Achieving record-high birefringence in a 3D fluorozincoborate via coplanar alignment of π-conjugated [BO 3 ] units0[Sr(H 2 O)]{Sr[B(OH) 3 ]}[B 5 O 8 (OH)] 2 : A Deep-Ultraviolet Second-Order Nonlinear Optical Strontium Borate Constructed by Mixing π-Conjugated and Non-π-Conjugated Units1

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  1. Ca 3 Al 2 B 8 O 18 : borate with a graphene-like layer featuring two types of topological six-membered rings induced by [AlO 4 ] units

    Chemical Communications · 2024-01-01

    Ziting Yan, Dongdong Chu, Zhihua Yang, Shilie Pan, Min Zhang

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  2. K0.9Rb2.1B8PO16: Design and Synthesis of a Deep-Ultraviolet Nonlinear Optical Crystal with Balanced Performance Derived from π-Conjugated and Non-π-Conjugated Groups

    Inorganic Chemistry · 2024-09-22

    Wenyu He, Xianchao Zhu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  3. CO2-Promoted Assembly of Nonplanar B12O24-Ring as a Fundamental Building Block in Lithium–Sodium Alkali Borates during Carbon Capture

    Inorganic Chemistry · 2025-04-18

    David Unnervik, Takuya Harada

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  4. NH4B5O7(OH)2 and CsRbB10O14(OH)4·H2O: Two Hydroxyborates Feature Significant Optical Anisotropy and Contain 1∞[B5O7(OH)2] Chains

    Inorganic Chemistry · 2025-07-17

    Xueli Du, Haoran Wang, Haoran Liu, Qingyu Liu, Wenhu Wang, Jiahao Jiao, Yuchen Yan, Xueyan Wu, Min Zhang

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  5. Cation-modulated aligned arrangement of [B3O7] units in an unprecedented 2∞[B3O5] layer with remarkable birefringence

    Science China Materials · 2025-07-28

    Ziting Yan, Dongdong Chu, Zhihua Yang, Shilie Pan, Min Zhang

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  6. Studies on Three 3D Bimetallic Tellurates: Including a Second-Order NLO Material with d10-Zn2+ and SOJT-Effect Te4+/Mo6+ Cations

    Inorganic Chemistry · 2025-08-14

    Yuquan Feng, Zhiguo Zhong, Shuyang Chen, Sujuan Jin, Zhaohui Meng, Hongwei Wang

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  7. Tuning birefringence in alkaline-earth metal oxyhalides through diverse mixed-cation coordination architectures

    Dalton Transactions · 2025-12-04

    Shenghong Zeng, Mayinuer Maimaiti, Jinche Wu, Tingwen Han, Hui Chai, Fangfang Zhang, Min Zhang

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  8. A New Short-Wavelength UV NLO Material based on Dual Alkaline-Earth Metal Borophosphate with 1D Helical Anionic Chains

    SSRN Electronic Journal · 2026-01-01

    Zhiguo Zhong, Yu-Quan Feng, Jing Li

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  9. Achieving record-high birefringence in a 3D fluorozincoborate via coplanar alignment of π-conjugated [BO 3 ] units

    Inorganic Chemistry Frontiers · 2026-01-01

    Yucheng Hao, Qiuhui Zhang, Haoran Yu, Xikai Miu, Simin Cai, Xinnan Li, Fengshan Yu, Yuan Lin, Mingyang Cao

    Read original paper ↗ ·

  10. [Sr(H 2 O)]{Sr[B(OH) 3 ]}[B 5 O 8 (OH)] 2 : A Deep-Ultraviolet Second-Order Nonlinear Optical Strontium Borate Constructed by Mixing π-Conjugated and Non-π-Conjugated Units

    Inorganic Chemistry · 2026-01-07

    Yuquan Feng, Dongqin Bi, K. C. Liu, Shuyang Chen, Limin Gao, Zhaohui Meng

    Read original paper ↗ ·
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