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RESEARCH PAPER · Inorganic Chemistry Frontiers · 2023

Ce 3 F 4 (SO 4 ) 4 : cationic framework assembly for designing polar nonlinear optical material through fluorination degree modulation

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Ce 3 F 4 (SO 4 ) 4 : cationic framework assembly for designing polar nonlinear optical material through fluorination degree modulationOriginalImproved Birefringence Activated by Tetrahedra Decorated with a Single Linear Unit38Improved Birefringence Activated by Tetrahedra Decorated with a Single Linear Unit1YSO4F·H2O: A Deep-Ultraviolet Birefringent Rare-Earth Sulfate Fluoride with Enhanced Birefringence Induced by Fluorinated Y-Centered Polyhedra19Equivalent cation-tuning to realize a new Ce( iv ) fluoride with excellent comprehensive nonlinear optical performances12Hg4(Te2O5)(SO4): A Giant Birefringent Sulfate Crystal Triggered by a Highly Selective Cation153UV-Transparent SHG Material Explored in an Alkali Metal Sulfate Selenite System16Molecular structure, optical, first-order hyper polarizability, electronic properties, reactivity (ELF and LOL) − computational analysis using DFT and Multiwfn for 2, 3-diaminopyridinium selenate45Old tree blossoms anew: Research progress on the structures and optical properties of ultraviolet selenites56Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units66Unveiling Noncentrosymmetric Pyridine Carboxylates from Centrosymmetric Templates through Motif Configuration Modulation in Zero-Dimensional System7Novel antimony-based mixed halides exhibiting an excellent SHG response and a broad transmission range20CdF(C 6 H 4 NO 2 )(H 2 O): a UV nonlinear optical material with unprecedented SHG and birefringence via π-conjugated rings and a unique “Warren truss structure”11Deep-ultraviolet sulfamate halides with halogen-centered secondary building units for enhanced optical anisotropy4Unveiling the Intrinsic Superior SHG Performance of Ce 4+ Fluoride Masked by Subtle Ce 3+ Impurity and Its Effective Removal13Unveiling the Intrinsic Superior SHG Performance of Ce4+ Fluoride Masked by Subtle Ce3+ Impurity and Its Effective Removal2LiAgCe2F10(H2O)2: Focusing on the Cation Size Effect to Reasonably Design a Nonlinear Optical Hydrated Cerium(IV) Fluoride10Ce-centered polyhedral arrangement pattern and optical performance in Ce-based nonlinear optical materials3Recent achievements of d0 transition-metal-based oxyfluorides: Crystal chemistry and application in second-order NLO materials10Dual-anion synergy drives remarkable birefringence in sulfate–nitrate crystals1RbLa(SO 4 ) 2 : A KBBF-like Deep-UV Transparent Rare Earth Sulfate with Strong SHG Response and High Thermal Stability Enabled by Multicomponent Structural Design2Ternary Anion‐Engineered Rare Earth Crystals for Broadband UV Transparency and Enhanced Second‐Harmonic Generation1A Polar Cerium Iodate Ce 2 (IO 3 ) 6 (H 2 O) with a Strong Second-Harmonic Generation Response in Trivalent Ce-Based Materials1Exploration of the influence of exchange-correlation functionals and hydrostatic pressure on the physical properties of recently synthesized nonlinear optical material Na2CeF60

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  1. Improved Birefringence Activated by Tetrahedra Decorated with a Single Linear Unit

    Angewandte Chemie International Edition · 2023-06-29

    Wenlong Xie, Fuming Li, Jianbang Chen, Zhihuang Yang, Guangmao Li, Shilie Pan

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  2. Improved Birefringence Activated by Tetrahedra Decorated with a Single Linear Unit

    Angewandte Chemie · 2023-06-29

    Wenlong Xie, Fuming Li, Jianbang Chen, Zhihuang Yang, Guangmao Li, Shilie Pan

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  3. YSO4F·H2O: A Deep-Ultraviolet Birefringent Rare-Earth Sulfate Fluoride with Enhanced Birefringence Induced by Fluorinated Y-Centered Polyhedra

    Inorganic Chemistry · 2023-10-12

    Dong‐Xue Jiao, Huili Zhang, Xiao-Fei Li, Chao He, Jinhua Li, Qi Wei, Guo‐Yu Yang

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  4. Equivalent cation-tuning to realize a new Ce( iv ) fluoride with excellent comprehensive nonlinear optical performances

    Inorganic Chemistry Frontiers · 2024-01-01

    Beibei Zhang, Wen‐Ye Gao, Wei Lin Xu, L. Ma, Wenlong Liu, Ru‐Ling Tang, Sheng‐Ping Guo

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  5. Hg4(Te2O5)(SO4): A Giant Birefringent Sulfate Crystal Triggered by a Highly Selective Cation

    Journal of the American Chemical Society · 2024-03-08

    Pengfei Li, Chun‐Li Hu, Yafeng Li, Jiang‐Gao Mao, Fang Kong

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  6. UV-Transparent SHG Material Explored in an Alkali Metal Sulfate Selenite System

    Inorganic Chemistry · 2024-03-15

    Xinwei Zhang, Zhixiang Wang, Chun‐Li Hu, Yafeng Li, Jiang‐Gao Mao, Fang Kong

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  7. Molecular structure, optical, first-order hyper polarizability, electronic properties, reactivity (ELF and LOL) − computational analysis using DFT and Multiwfn for 2, 3-diaminopyridinium selenate

    Inorganic Chemistry Communications · 2024-05-19

    R. Bhavani, Sampandam Elangovan, G. Suresh, S. Sankar, N. Kanagathara, P. Revathi

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  8. Old tree blossoms anew: Research progress on the structures and optical properties of ultraviolet selenites

    Coordination Chemistry Reviews · 2024-06-15

    Pengfei Li, Chun‐Li Hu, Jiang‐Gao Mao, Fang Kong

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  9. Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units

    Coordination Chemistry Reviews · 2024-07-03

    Bo Zhang, Mao‐Yin Ran, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  10. Unveiling Noncentrosymmetric Pyridine Carboxylates from Centrosymmetric Templates through Motif Configuration Modulation in Zero-Dimensional System

    Inorganic Chemistry · 2024-11-12

    Qingwen Zhu, Yong Tao, Can Yang, Jie Gou, Yaolong Zhu, Xuefei Wang, Qi Wu

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  11. Novel antimony-based mixed halides exhibiting an excellent SHG response and a broad transmission range

    Inorganic Chemistry Frontiers · 2024-12-05

    Luli Wang, Han Luo, Siyu Chen, Ling Huang, Liling Cao, Xuehua Dong, Guohong Zou

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  12. CdF(C 6 H 4 NO 2 )(H 2 O): a UV nonlinear optical material with unprecedented SHG and birefringence via π-conjugated rings and a unique “Warren truss structure”

    Inorganic Chemistry Frontiers · 2025-01-01

    Jie Gou, Yaolong Zhu, Xin Su, Can Hui Yang, YunJie Wang, Qingwen Zhu, Yi Xiong, Qi Wu

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  13. Deep-ultraviolet sulfamate halides with halogen-centered secondary building units for enhanced optical anisotropy

    Inorganic Chemistry Frontiers · 2025-01-01

    Xuefei Wang, Qingwen Zhu, Yunseung Kuk, H. W. Chen, Qi Wu, Qun Jing, Kang Min Ok

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  14. Unveiling the Intrinsic Superior SHG Performance of Ce 4+ Fluoride Masked by Subtle Ce 3+ Impurity and Its Effective Removal

    Angewandte Chemie International Edition · 2025-02-18

    Mengyue Li, Xin Liu, Rui Wang, Li‐Ming Wu, Li‐Ming Wu, Ling Chen, Qi Wu, Qi Wu

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  15. Unveiling the Intrinsic Superior SHG Performance of Ce4+ Fluoride Masked by Subtle Ce3+ Impurity and Its Effective Removal

    Angewandte Chemie · 2025-02-18

    Mengyue Li, Xin Liu, Rui Wang, Li‐Ming Wu, Ling Chen, Qi Wu

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  16. LiAgCe2F10(H2O)2: Focusing on the Cation Size Effect to Reasonably Design a Nonlinear Optical Hydrated Cerium(IV) Fluoride

    Inorganic Chemistry · 2025-03-24

    Wen-Ye Gao, Yi‐Lei Lv, Siyu Ma, Cheng Chen, Wenlong Liu, Ru‐Ling Tang

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  17. Ce-centered polyhedral arrangement pattern and optical performance in Ce-based nonlinear optical materials

    Chinese Chemical Letters · 2025-11-01

    Xuan Li, Tianhui Wu, Meiqi Liu, Yang Zhao, Jiahang Liu, Miao Zhang, Weiwei Cao, Jianmin Gu, Desong Wang

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  18. Recent achievements of d0 transition-metal-based oxyfluorides: Crystal chemistry and application in second-order NLO materials

    Coordination Chemistry Reviews · 2025-11-06

    Tianhui Wu, Jiahang Liu, Meiqi Liu, Xuan Li, Miao Zhang, Weiwei Cao, Jianmin Gu, Desong Wang

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  19. Dual-anion synergy drives remarkable birefringence in sulfate–nitrate crystals

    Inorganic Chemistry Frontiers · 2025-11-24

    LeHui Liu, FeiFei Yuan, YiSheng Huang, LiZhen Zhang, ZhouBin Lin

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  20. RbLa(SO 4 ) 2 : A KBBF-like Deep-UV Transparent Rare Earth Sulfate with Strong SHG Response and High Thermal Stability Enabled by Multicomponent Structural Design

    Inorganic Chemistry · 2026-02-02

    Ye Tao, Xiaohui Zhang, Chenglong Xu, Qianshuang Lu, J. N. Tan, Yingjie Li, Junzi Li, Jianke Pan, Feng Su, Tingchao He, Haifeng Dong, Heng Wang, Zhi Chen, Chengmin Ji, Xiujun Yu, Xiaopeng Li

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  21. Ternary Anion‐Engineered Rare Earth Crystals for Broadband UV Transparency and Enhanced Second‐Harmonic Generation

    Chinese Journal of Chemistry · 2026-03-12

    Xiaohui Zhang, Ye Tao, Qianshuang Lu, J. N. Tan, Chenglong Xu, Yingjie Li, Yi Chen, Jianke Pan, F. H. Su, Tingchao He, Haifeng Dong, Heng Wang, Zhi Chen, Xiujun Yu, Xiaopeng Li

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  22. A Polar Cerium Iodate Ce 2 (IO 3 ) 6 (H 2 O) with a Strong Second-Harmonic Generation Response in Trivalent Ce-Based Materials

    Inorganic Chemistry · 2026-03-17

    Jiahang Liu, Miao Zhang, Shizheng Li, Ziyang Wang, Yang Zhao, NianRui Qu, Weiwei Cao, Jianmin Gu, Tianhui Wu

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  23. Exploration of the influence of exchange-correlation functionals and hydrostatic pressure on the physical properties of recently synthesized nonlinear optical material Na2CeF6

    Results in Materials · 2026-05-04

    Jakiul Islam, Nur E-Elahi, Md. Mehedi Hasan, Md. Shahjahan Ali, Md. Kamrul Hassan Bhuiya, Shuvo Sen, Eshrat Zahan Eshita, Aka Talukder, Md. Saiful Alam, Mohasena Ahamed

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