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RESEARCH PAPER · Dalton Transactions · 2019

Li 2 ZnGeS 4 : a promising diamond-like infrared nonlinear optical material with high laser damage threshold and outstanding second-harmonic generation response

Yi Huang, Kui Wu, Jianian Cheng, Yu Chu, Zhihua Yang, Shilie Pan

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Li 2 ZnGeS 4 : a promising diamond-like infrared nonlinear optical material with high laser damage threshold and outstanding second-harmonic generation responseOriginalLi4HgSn2Se7: The First Second-Order Nonlinear Optical-Active Selenide in the I4–II–IV2–VI7 Diamond-like Family32Rational design of infrared nonlinear optical chalcogenides by chemical substitution287A review of the AI2B II C IV DVI4 family as infrared nonlinear optical materials: the effect of each site on the structure and optical properties59Coordinated regulation on critical physiochemical performances activated from mixed tetrahedral anionic ligands in new series of Sr 6 A 4 M 4 S 16 (A = Ag, Cu; M = Ge, Sn) nonlinear optical materials28Experimental and theoretical studies of the ternary thiophosphate PbPS 3 featuring ethane-like [P 2 S 6 ] 4− units15Non-centrosymmetric sulfides A 2 Ba 6 MnSn 4 S 16 (A = Li, Ag): syntheses, structures and properties21Simulation Study on Laser Damage of Iron Plate0Synthesis and structure of the new semiconductor compounds Tl2BIIDIVX4 (BII–Cd, Hg; DIV– Si, Ge; X–Se, Te) and isothermal sections of the Tl2Se–CdSe-Ge(Sn)Se2 systems at 570 K14A review on phase transition and structure-performance relationship of second-order nonlinear optical polymorphs107Ab initio prediction of the elastic, electronic and optical properties of a new family of diamond-like semiconductors, Li2HgMS4 (M = Si, Ge and Sn)34Inherent laws between tetrahedral arrangement pattern and optical performance in tetrahedron-based mid-infrared nonlinear optical materials130α‑Li2ZnGeS4: A Wide-Bandgap Diamond-like Semiconductor with Excellent Balance between Laser-Induced Damage Threshold and Second Harmonic Generation Response157The effect of volume inclusions of the ZnGeP2 single-crystal on the dispersion of the refraction index and the absorption coefficient in mid-IR and terahertz ranges of wavelengths4Phase Matching, Strong Frequency Doubling, and Outstanding Laser-Induced Damage Threshold in the Biaxial, Quaternary Diamond-like Semiconductor Li 4 CdSn 2 S 779A series of M 3 PS 4 (M = Ag, Cu and Ag/Cu) thiophosphates with diamond-like structures exhibiting large second harmonic generation responses and moderate ion conductivities28Cu 4 MnGe 2 S 7 and Cu 2 MnGeS 4 : two polar thiogermanates exhibiting second harmonic generation in the infrared and structures derived from hexagonal diamond22Stepwise Li Substitution Induced Structure Evolution and Improved Nonlinear Optical Performance for Diamond-like Sulfides28Synthesis, structure, linear and nonlinear optical properties of noncentrosymmetric quaternary diamond-like semiconductors, Cu2ZnGeSe4 (CZGSe) and the novel Cu4ZnGe2Se720Transition-metal-based chalcogenides: A rich source of infrared nonlinear optical materials184Rational Crystal Structure Design and Nonlinear-Optical Properties of Noncentrosymmetric RbCu2NbS47Rational combination of multiple structural groups on regulating nonlinear optical property in hexagonal Ln3MGeS7 polar crystals10The exploration of new infrared nonlinear optical crystals based on the polymorphism of BaGa 4 S 731Structural, elastic, electronic and optical properties of the newly synthesized selenides Tl2CdXSe4 (X = Ge, Sn)11New quaternary sulfide LiGaSiS4: Synthesis, structure and optical properties0Crystal structure, electronic structure, and optical properties of the novel Li 4 CdGe 2 S 7 , a wide-bandgap quaternary sulfide with a polar structure derived from lonsdaleite6Ag4SnGe2S7: A Noncentrosymmetric Chalcogenide in I4–II–IV2–VI7 System with Non-Diamond-Like Structure Featuring 1D ∞[SnGe2S8]6– Infinite Chain2A non-centrosymmetric chalcohalide synthesized through the combination of chemical tailoring with aliovalent substitution12Nitrides: a promising class of nonlinear optical material candidates9Phase Competition and Strong SHG Responses of the Li2MIIMIVSe4 Family: Atom Response Theory Predictions versus Experimental Results24Accurate X-ray diffraction data required for proper evaluation of bond valence sums and global instability indexes: redetermination of the crystal structures of diamond-like Cu 2 CdSiS 4 and Cu 2 HgSnS 4 as a case study1LiGa(IO3)4: An Excellent NLO Material with Unprecedented 2D [Ga(IO3)4]∞− Layer Synthesized by Aliovalent Substitution20Crystal structure, electronic structure, and optical properties of Cu4ZnGe2S7 and Cu4CdGe2S7: Polar diamond-like semiconductors exhibiting second harmonic generation10Recent advances in rational structure design for nonlinear optical crystals: leveraging advantageous templates153Correction to “Phase Matching, Strong Frequency Doubling, and Outstanding Laser-Induced Damage Threshold in the Biaxial, Quaternary Diamond-like Semiconductor Li4CdSn2S7”0Correction to “α-Li2ZnGeS4: A Wide-Bandgap Diamond-like Semiconductor with Excellent Balance between Laser-Induced Damage Threshold and Second Harmonic Generation Response”2Emergent Mid‐Infrared Nonlinear Optical Candidates With Targeted Balance Performances17Exploring the functional properties of the diamond-like quaternary compound Li 2 ZnGeS 4 for potential energy applications: a theoretical approach2Isothermal Sections Tl2se–Cdse–Si(Ge)Se2, Quasi-Binary Systems Tl2si(Ge)Se3–Cdse, Tl2cdgese4–Gese2 and the Crystal Structure, Electronic and Optical Properties of Novel Quaternary Selenides Tl2cdsi(Ge)3se81La 2 ZnGa 2 S 6 O: a melilite-type transition metal oxysulfide achieving a well-balanced nonlinear optical behavior5BaAl2MS6 (M = Si and Ge): the rational construction of diamond-like structures with ultrawide band gap by group-optimization approach6Effect of the cation-to-silicon ratio on structural transformation and optical performance in [NaSr 3 Cl 3 ][SiS 4 ] and [NaSr 4 SCl][Si 3 S 9 ]0Harnessing tetrahedral diversity: The path to superior diamond-like IR NLO crystals13First‐Principles Investigation of the Structural, Electronic, Optical, Elastic, and Thermal Properties of Defect Diamond‐Like Hg 3 P 2 S 80

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  1. Li4HgSn2Se7: The First Second-Order Nonlinear Optical-Active Selenide in the I4–II–IV2–VI7 Diamond-like Family

    Crystal Growth & Design · 2019-09-09

    Yangwu Guo, Fei Liang, Zhuang Li, Wenhao Xing, Zheshuai Lin, Jiyong Yao, Yicheng Wu

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  2. Rational design of infrared nonlinear optical chalcogenides by chemical substitution

    Coordination Chemistry Reviews · 2019-12-21

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  3. A review of the AI2B II C IV DVI4 family as infrared nonlinear optical materials: the effect of each site on the structure and optical properties

    Chemical Communications · 2020-01-01

    Guangmao Li, Zhihua Yang, Junjie Li, Shilie Pan

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  4. Coordinated regulation on critical physiochemical performances activated from mixed tetrahedral anionic ligands in new series of Sr 6 A 4 M 4 S 16 (A = Ag, Cu; M = Ge, Sn) nonlinear optical materials

    Dalton Transactions · 2020-01-01

    Ya Feng Yang, Miao Song, Jie Zhang, Lihua Gao, Xiaowen Wu, Kui Wu

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  5. Experimental and theoretical studies of the ternary thiophosphate PbPS 3 featuring ethane-like [P 2 S 6 ] 4− units

    Dalton Transactions · 2020-01-01

    Peng Wang, Maierhaba Abudoureheman, Zhaohui Chen

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  6. Non-centrosymmetric sulfides A 2 Ba 6 MnSn 4 S 16 (A = Li, Ag): syntheses, structures and properties

    Dalton Transactions · 2020-01-01

    Ruihuan Duan, Hua Lin, Yue Wang, Yuqiao Zhou, Li‐Ming Wu

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  7. Simulation Study on Laser Damage of Iron Plate

    IOP Conference Series Materials Science and Engineering · 2020-01-01

    Tianyu Wang, Jintian Bian, Qing Ye, Xin Li, Xiaoquan Sun

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  8. Synthesis and structure of the new semiconductor compounds Tl2BIIDIVX4 (BII–Cd, Hg; DIV– Si, Ge; X–Se, Te) and isothermal sections of the Tl2Se–CdSe-Ge(Sn)Se2 systems at 570 K

    Journal of Solid State Chemistry · 2020-05-06

    Andrii Selezen, Ivan D. Olekseyuk, G.L. Myronchuk, O.V. Smitiukh, Л.В. Піскач

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  9. A review on phase transition and structure-performance relationship of second-order nonlinear optical polymorphs

    Coordination Chemistry Reviews · 2020-05-25

    Kui Wu, Ya Feng Yang, Lihua Gao

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  10. Ab initio prediction of the elastic, electronic and optical properties of a new family of diamond-like semiconductors, Li2HgMS4 (M = Si, Ge and Sn)

    Journal of Alloys and Compounds · 2020-06-10

    S. Alnujaim, Abdelmadjid Bouhemadou, Abdelhak Bedjaoui, Saad Bin-Omran, Yarub Al-Douri, R. Khenata, Said Maabed

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  11. Inherent laws between tetrahedral arrangement pattern and optical performance in tetrahedron-based mid-infrared nonlinear optical materials

    Coordination Chemistry Reviews · 2020-06-29

    Weikang Wang, Dajiang Mei, Fei Liang, Jun Zhao, Yuandong Wu, Zheshuai Lin

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  12. α‑Li2ZnGeS4: A Wide-Bandgap Diamond-like Semiconductor with Excellent Balance between Laser-Induced Damage Threshold and Second Harmonic Generation Response

    Chemistry of Materials · 2020-09-01

    Jian‐Han Zhang, Daniel J. Clark, Jacilynn A. Brant, Kimberly A. Rosmus, P. Grima, Jonathan W. Lekse, Joon Ik Jang, Jennifer A. Aitken

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  13. The effect of volume inclusions of the ZnGeP2 single-crystal on the dispersion of the refraction index and the absorption coefficient in mid-IR and terahertz ranges of wavelengths

    Optical Materials · 2020-11-22

    Mikhail Zinovev, Nikolay Yudin, Alexander Gribenyukov, Sergey N. Podzyvalov, Victor Dyomin, Igor G. Polovtsev, Valentin I. Suslyaev, Yelena V. Zhuravlyova

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  14. Phase Matching, Strong Frequency Doubling, and Outstanding Laser-Induced Damage Threshold in the Biaxial, Quaternary Diamond-like Semiconductor Li 4 CdSn 2 S 7

    Chemistry of Materials · 2020-11-25

    Jian‐Han Zhang, Stanislav S. Stoyko, Andrew J. Craig, P. Grima, Joshua W. Kotchey, Joon Ik Jang, Jennifer A. Aitken

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  15. A series of M 3 PS 4 (M = Ag, Cu and Ag/Cu) thiophosphates with diamond-like structures exhibiting large second harmonic generation responses and moderate ion conductivities

    Dalton Transactions · 2021-01-01

    Ya Feng Yang, Bingbing Zhang, Xiaowen Wu, Kui Wu

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  16. Cu 4 MnGe 2 S 7 and Cu 2 MnGeS 4 : two polar thiogermanates exhibiting second harmonic generation in the infrared and structures derived from hexagonal diamond

    Dalton Transactions · 2021-01-01

    Jennifer R. Glenn, Jeong Bin Cho, Yiqun Wang, Andrew J. Craig, Jian‐Han Zhang, Marvene Cribbs, Stanislav S. Stoyko, Kate E. Rosello, Christopher Barton, Allyson Bonnoni, P. Grima, Joseph H. MacNeil, James M. Rondinelli, Joon Ik Jang, Jennifer A. Aitken

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  17. Stepwise Li Substitution Induced Structure Evolution and Improved Nonlinear Optical Performance for Diamond-like Sulfides

    Inorganic Chemistry · 2021-07-27

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  18. Synthesis, structure, linear and nonlinear optical properties of noncentrosymmetric quaternary diamond-like semiconductors, Cu2ZnGeSe4 (CZGSe) and the novel Cu4ZnGe2Se7

    Journal of Alloys and Compounds · 2021-08-09

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  19. Transition-metal-based chalcogenides: A rich source of infrared nonlinear optical materials

    Coordination Chemistry Reviews · 2021-08-26

    Hong Chen, Wenbo Wei, Hua Lin, Xintao Wu

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  20. Rational Crystal Structure Design and Nonlinear-Optical Properties of Noncentrosymmetric RbCu2NbS4

    Inorganic Chemistry · 2021-12-14

    Mengjia Luo, Chongxiang Huang, Feng Lin, Xiangli Che, Xian Zhang, Fuqiang Huang

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  21. Rational combination of multiple structural groups on regulating nonlinear optical property in hexagonal Ln3MGeS7 polar crystals

    Journal of Alloys and Compounds · 2021-12-31

    Lihua Gao, Xiaowen Wu, Jingjing Xu, Xinyu Tian, Bingbing Zhang, Kui Wu

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  22. The exploration of new infrared nonlinear optical crystals based on the polymorphism of BaGa 4 S 7

    Inorganic Chemistry Frontiers · 2022-01-01

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  23. Structural, elastic, electronic and optical properties of the newly synthesized selenides Tl2CdXSe4 (X = Ge, Sn)

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  24. New quaternary sulfide LiGaSiS4: Synthesis, structure and optical properties

    Journal of Solid State Chemistry · 2022-05-10

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  25. Crystal structure, electronic structure, and optical properties of the novel Li 4 CdGe 2 S 7 , a wide-bandgap quaternary sulfide with a polar structure derived from lonsdaleite

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  26. Ag4SnGe2S7: A Noncentrosymmetric Chalcogenide in I4–II–IV2–VI7 System with Non-Diamond-Like Structure Featuring 1D ∞[SnGe2S8]6– Infinite Chain

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  27. A non-centrosymmetric chalcohalide synthesized through the combination of chemical tailoring with aliovalent substitution

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  28. Nitrides: a promising class of nonlinear optical material candidates

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  29. Phase Competition and Strong SHG Responses of the Li2MIIMIVSe4 Family: Atom Response Theory Predictions versus Experimental Results

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  30. Accurate X-ray diffraction data required for proper evaluation of bond valence sums and global instability indexes: redetermination of the crystal structures of diamond-like Cu 2 CdSiS 4 and Cu 2 HgSnS 4 as a case study

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  31. LiGa(IO3)4: An Excellent NLO Material with Unprecedented 2D [Ga(IO3)4]∞− Layer Synthesized by Aliovalent Substitution

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  32. Crystal structure, electronic structure, and optical properties of Cu4ZnGe2S7 and Cu4CdGe2S7: Polar diamond-like semiconductors exhibiting second harmonic generation

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  33. Recent advances in rational structure design for nonlinear optical crystals: leveraging advantageous templates

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  34. Correction to “Phase Matching, Strong Frequency Doubling, and Outstanding Laser-Induced Damage Threshold in the Biaxial, Quaternary Diamond-like Semiconductor Li4CdSn2S7”

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  35. Correction to “α-Li2ZnGeS4: A Wide-Bandgap Diamond-like Semiconductor with Excellent Balance between Laser-Induced Damage Threshold and Second Harmonic Generation Response”

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  36. Emergent Mid‐Infrared Nonlinear Optical Candidates With Targeted Balance Performances

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  37. Exploring the functional properties of the diamond-like quaternary compound Li 2 ZnGeS 4 for potential energy applications: a theoretical approach

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  38. Isothermal Sections Tl2se–Cdse–Si(Ge)Se2, Quasi-Binary Systems Tl2si(Ge)Se3–Cdse, Tl2cdgese4–Gese2 and the Crystal Structure, Electronic and Optical Properties of Novel Quaternary Selenides Tl2cdsi(Ge)3se8

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  39. La 2 ZnGa 2 S 6 O: a melilite-type transition metal oxysulfide achieving a well-balanced nonlinear optical behavior

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  40. BaAl2MS6 (M = Si and Ge): the rational construction of diamond-like structures with ultrawide band gap by group-optimization approach

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  42. Harnessing tetrahedral diversity: The path to superior diamond-like IR NLO crystals

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