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RESEARCH PAPER · ACS Applied Materials & Interfaces · 2020

Dual-Mode Light-Emitting Lanthanide Metal–Organic Frameworks with High Water and Thermal Stability and Their Application in White LEDs

Linna Xu, Yini Li, Qing‐Jiang Pan, Dan Wang, Sijia Li, Guofeng Wang, Yajie Chen, Peifen Zhu, Weiping Qin

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Dual-Mode Light-Emitting Lanthanide Metal–Organic Frameworks with High Water and Thermal Stability and Their Application in White LEDsOriginalA luminescent Eu coordination polymer with near-visible excitation for sensing and its homologues constructed from 1,4-benzenedicarboxylate and 1 H -imidazo[4,5- f ][1,10]-phenanthroline19State of the art methods and challenges of luminescent metal–organic frameworks for antibiotic detection124Robust Anionic Ln III –Organic Frameworks: Chemical Fixation of CO 2 , Tunable Light Emission, and Fluorescence Recognition of Fe 3+38Energy Transfer in Metal–Organic Frameworks and Its Applications57Rare earth metal–organic frameworks (RE-MOFs): Synthesis, properties, and biomedical applications257NIR-II luminescence and X-ray induced UV luminescence from Ce3+, Nd3+ co-doped NaLuF4 phosphors10Luminescence tuning and sensing properties of stable 2D lanthanide metal–organic frameworks built with symmetrical flexible tricarboxylic acid ligands containing ether oxygen bonds16Applications of reticular diversity in metal–organic frameworks: An ever-evolving state of the art998-Hydroxyquinoline and Eu3+ Incorporated Metal–Organic Framework Nanosystems with Tunable Emissions for White Light and Anticounterfeiting Applications16Lanthanide Isophthalate Metal‐Organic Frameworks: Crystal Structure, Thermal Behavior, and White Luminescence7Eu3+/Tb3+ supramolecular assembly hybrids for ultrasensitive and ratiometric detection of anthrax spore biomarker in water solution and actual spore samples35Efficient luminescence sensing in two lanthanide metal–organic frameworks with rich uncoordinated Lewis basic sites7Luminescence-colour-changing sensing toward neurological drug carbamazepine in water and biofluids based on white light-emitting CD/Ln-MOF/PVA test papers35Recent advances in luminescent metal–organic frameworks and their photonic applications57Tuning dimensionality between 2D and 1D MOFs by lanthanide contraction and ligand-to-metal ratio14Near-Infrared-Light emitting diode driven white light Emission: Upconversion nanoparticles decorated Metal-Organic Frame-works thin film31Single-component white-light-emitting Eu3+-metallopolymer for near-ultraviolet white light-emitting diode (n-UV-WLED)2Metal–organic frameworks of lanthanide iminodiacetates and tartrates: Synthesis, structural characterization and luminescence properties — Commemorating the 100th anniversary of the birth of Academician Guangxian Xu7Tunable Dual-Mode MOF-Based Composite Fluorescent Materials: Stimuli-Responsive and Anti-counterfeiting Application37Phosphor-Free Electrically Driven White Light Emission from Nanometer-Thick Barium–Organic Framework Films11Substitution of Pb with Mn2+/Nd3+ to improve the luminescence and thermal stability of Cs4PbBr628Gram‐Scale Synthesis of Highly Efficient Rare‐Earth‐Element‐Free Red/Green/Blue Solid‐State Bandgap Fluorescent Carbon Quantum Rings for White Light‐Emitting Diodes114Gram‐Scale Synthesis of Highly Efficient Rare‐Earth‐Element‐Free Red/Green/Blue Solid‐State Bandgap Fluorescent Carbon Quantum Rings for White Light‐Emitting Diodes19Photonic Metal‐Organic Frameworks31A Tb-MOF anion, porous coordination framework constructed with oxalate ligand: Crystal structure, adsorption properties, and luminescence sensing33Dual-Function Lanthanide–Organic Frameworks Based on a Zwitterionic Ligand as a Ratiometric Thermometer and a Selective Sensor for Nitroaromatic Explosives20Luminescent lanthanide single atom composite materials: Tunable full-color single phosphor and applications in white LEDs33Rare-earth single atom based luminescent composite nanomaterials: Tunable full-color single phosphor and applications in WLEDs51Simultaneous Synthesis, Modification, and DFT Calculation of Three‐Color Lead Halide Perovskite Phosphors for Improving Stability and Luminous Efficiency of WLEDs23Molecular dysprosium complexes for white-light and near-infrared emission controlled by the coordination environment19Luminescent magnets: hybrid supraparticles of a lanthanide-based MOF and ferromagnetic iron oxide by assembly in a droplet via spray-drying20A series of carbonate-brisdged Ln (Ln = Eu, Tb, Gd) frameworks: Colour tunability for barcode applications and selective luminescence sensing towards nitroimidazole antibiotics7Dye contaminated wastewater treatment through metal–organic framework (MOF) based materials67Color tunable of Ln-MOFs (Ln = Tb, Eu) and excellent stability for white light-emitting diode37Design and facile synthesis of a photothermally active metal–organic framework bearing persistent radicals via post-synthetic thermal annealing17Lanthanide-based metal–organic framework materials as bifunctional fluorescence sensors toward acetylacetone and aspartic acid21Luminescent samarium(III) heteroleptic complex of naphthol functionalized Imidazo[4,5-f][1,10]phenanthroline and dibenzoylmethane1Tunable fluorescence emission based on multi-layered MOF-on-MOF17Bi3+ sensitized Gd2O3:Eu3+: A potential red phosphor for UV LED pumped white light emission22pH response luminescence reversible lanthanide-2,6-pyridinedicarboxylic acid complex with tunable multi-color and white light emission for fluorescent anti-counterfeiting labels and LED50Poly(β-hydroxyl amine)s: Valuable Building Blocks for Supramolecular Elastomers with Tunable Mechanical Performance and Superior Healing Capacity7Mixed-Metal and Mixed-Ligand Lanthanide Metal–Organic Frameworks Based on 2,6-Naphthalenedicarboxylate: Thermally Activated Sensitization and White-Light Emission25Total Luminescence Spectroscopy for Quantification of Temperature Effects on Photophysical Properties of Photoluminescent Materials12Application of photo-responsive metal-organic framework in cancer therapy and bioimaging37A new mode of luminescence in lanthanide oxalates metal–organic frameworks31Synthesis, modification, and adsorption properties of Yb‐MOF: Kinetic and thermodynamic studies11Upconversion Luminescence through Cooperative and Energy‐Transfer Mechanisms in Yb 3+ ‐Metal‐Organic Frameworks67Upconversion Luminescence through Cooperative and Energy‐Transfer Mechanisms in Yb3+‐Metal‐Organic Frameworks11Phosphate-Modulated Luminol-Tb Fluorescent Probe for the Ratiometric Detection of Anthrax Biomarker0PMMA or PVDF films blended with β-diketonate tetrakis Eu III or Tb III complexes used as downshifting coatings of near-UV LEDs15Single-phase white light material and antibiotic detection of lanthanide metal–organic frameworks27Energy transfer, anticounterfeiting, white light emission and sensing in fine-regulating series of lanthanide metal-organic frameworks86Recent progress in mixed rare earth metal-organic frameworks: From synthesis to application80Tetra-Nuclear Cluster-Based Lanthanide Metal–Organic Frameworks as White Phosphor, Information Encryption, Self-Calibrating Thermometers, and Fe2+ Sensors57Tunable multicolor luminescence in vanadates from yttrium to indium with enhanced luminous efficiency and stability for its application in WLEDs and indoor photovoltaics12Design and preparation of white light emission from up-conversion transitions in Er3+/Tm3+/Yb3+ co-doped cubic zirconia single crystals12Silicon-based nanoparticles grafted lanthanide coordination polymer phosphor: Facile synthesis, formation process and white light-emitting diodes3Eu-MOF based fluorescence probe for ratiometric and visualization detection of Cu2+43Hydrophilic-hydrophobic polymer strip with intrinsic signal and chemical-electromagnetic synergistic enhancement for non-metallic SERS-based identification of SARS-CoV-2 antigen16Er3+-Sensitized Upconversion/Down-Shifting Luminescence in Metal–Organic Frameworks10Lanthanide-Doped Materials for Optical Applications3A LA-BTC MOF as a sensor element of an electronic nose for selective adsorption of biomarkers of diseases: Molecular dynamics simulations of adsorption3Modulating the Photoluminescence of Europium through Crystalline Assembly Formation with Gold Nanoclusters and Then Phosphate Ions6Advances and Applications of Metal‐Organic Frameworks (MOFs) in Emerging Technologies: A Comprehensive Review426Optimizing white light emission in Dy( iii ) complexes: impact of energy transfer from mono and bidentate ligands on luminescence19Rare-earth upconversion luminescence and its applications: from molecular to nano and micro scales4Advancements of Lanthanide-doped Phosphors in Solid-state Lighting Applications27Enhancement of Luminescence from Lanthanide Metal–Organic Frameworks by Ytterbium and Calcium Doping: Application to Photonic Barcodes and Fingerprint Detection71Construction of composite SERS substrate based on black phosphorus/mesoporous ZIF-67 and its selective monitoring of food additives21Triazine Core Anchored Lanthanide Driven Soft Gels: Photo Switching Emission, Robust Anticounterfeiting, and Smart Sensor Probe for Nitroexplosive/Nitrofuran Antibiotics12Zn, Cd and Cu Coordination Polymers for Metronidazole Sensing and for Ullmann and Chan‐Lam Coupling Reactions3Dual excitation channel ratiometric fluorescent probes for visual and fluorescent detection of anthrax spore biomarker and tetracycline hydrochloride4Temperature dependent self-assembly of lanthanide coordination polymers based on a benzimidazolium dicarboxylate linker: synthesis, structure and luminescence properties0Dual-emission rare-earth fluorescent nanomaterials for ratiometric and visual detection of N-acetylneuraminic acid and applications in information encryption and anti-counterfeiting12Metal–organic framework-based hybrids with photon upconversion52Enhancing white light-emitting diode performance with an ultra-wide spectrum ZnS:Mn-CDs@SiO 2 dual core@shell composite3Photoluminescent metal-organic frameworks and their composites: Fundamentals, applications, and outlooks47Design and Synthesis of a Series of Rare-Earth Coordination Polymer-Based Phosphors: Exploration of the White Light Emission Property4Lead-free lanthanide-based Cs 3 LnCl 6 metal halides6Cu- and Zn-based 1D MOFs as hosts to encapsulate Eu( iii ) for tuning white light emission2Enhanced Photoelectrocatalytic Degradation of Salicylic Acid Using an n-n Heterojunction NH2-La-MOFs@B-GQDs@NTFs/Ti Photoelectrode0Lanthanide‐Based Metal–Organic Frameworks Offering Hydrogen Bonding Cavities: Luminescent Characteristics and Sensing Applications3Electrically induced quenching effect in photoluminescence devices composed of Eu3+-complex-doped polyethylene oxide6Multi-Emitting Ratiometric Temperature Sensing and Tunable White Light Emitting Based on Effective Energy Transfer in a Lanthanide-Brønsted Acidic Ionic Liquid Coordination Polymer7Tunable Multicolor in Heterojunction Ln(BTB) Fast Prepared by Liquid Plasma with In Situ Spectral Monitoring for Anticounterfeiting Application7A strategy to obtain highly luminescent MOF-76 based on hydrothermal annealing treatment8Ultrathin Lanthanide‐Based Metal‐Organic Nanosheets with Thickness‐ and Temperature‐Driven Light Emission5Reversible Thermo/hydrochromic Luminescence in a Ln-MOF Film for Anticounterfeiting Application6Investigation on the highly fluorescent IRMOF-3/thiol-ene polymer and its ligand-based composite with 76 % quantum yield0Upconversion Lanthanide‐Based 2D Metal‐Organic Frameworks for Multimode Information Encryption23Upconversion Lanthanide‐Based 2D Metal‐Organic Frameworks for Multimode Information Encryption4Multi-emission metal–organic framework (MOF)-based composites: A comprehensive review of synthesis strategies and luminescence applications15Dual-lanthanide functionalized hydrogen-bonded organic frameworks for fluorescent detection of quinolone antibiotics in multi-media18Sensitive detection and visual recognition of 3,3′-diaminobenzidine based on a fluorescent Eu-MOF sensor0A dual-emission ln-MOF as ratiometric fluorescence sensor for detecting NF and OTC with high sensitivity and selectivity8Spectroscopic characterization of europium fumarate MOF for LED applications- photoluminescence studies and evaluation of radiative parameters1Perovskite-embedded crystalline porous materials: From synthesis to applications1A highly water stable Dual-Ligand Eu-MOF with enhanced fluorescence for sensitive detection of three fluoroquinolone Antibiotics0Confinement-guided performance enhancement of perovskites within metal–organic frameworks0Lanthanide upconverting luminescence in molecular complexes and metal–organic frameworks9Preparation and characterization of holmium doped ZIF-8 nanocrystals for white light emitting phosphors4Mixed-Lanthanide Metal–Organic Frameworks for Near-Infrared-I Bioimaging and Near-Infrared-III Four-Photon Upconversion21Dual-mode immunosensor combining quantitative surface-enhanced Raman scattering and visual upconversion luminescence for prostate-specific antigen detection0Interfacial coupling of boron-doped graphene quantum dots and amino-functionalized La-MOFs on TiO2 nanoflowers for enhanced photoelectrochemical oxidation0

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  8. Applications of reticular diversity in metal–organic frameworks: An ever-evolving state of the art

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  9. 8-Hydroxyquinoline and Eu3+ Incorporated Metal–Organic Framework Nanosystems with Tunable Emissions for White Light and Anticounterfeiting Applications

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  10. Lanthanide Isophthalate Metal‐Organic Frameworks: Crystal Structure, Thermal Behavior, and White Luminescence

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  11. Eu3+/Tb3+ supramolecular assembly hybrids for ultrasensitive and ratiometric detection of anthrax spore biomarker in water solution and actual spore samples

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  19. Tunable Dual-Mode MOF-Based Composite Fluorescent Materials: Stimuli-Responsive and Anti-counterfeiting Application

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  45. A new mode of luminescence in lanthanide oxalates metal–organic frameworks

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  46. Synthesis, modification, and adsorption properties of Yb‐MOF: Kinetic and thermodynamic studies

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  47. Upconversion Luminescence through Cooperative and Energy‐Transfer Mechanisms in Yb 3+ ‐Metal‐Organic Frameworks

    Angewandte Chemie International Edition · 2022-11-27

    Yao Xie, Guotao Sun, Gabrielle Arona Mandl, Steven L. Maurizio, Jiabo Chen, John A. Capobianco, Lining Sun

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  48. Upconversion Luminescence through Cooperative and Energy‐Transfer Mechanisms in Yb3+‐Metal‐Organic Frameworks

    Angewandte Chemie · 2022-11-28

    Yao Xie, Guotao Sun, Gabrielle Arona Mandl, Steven L. Maurizio, Jiabo Chen, John A. Capobianco, Lining Sun

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  49. Phosphate-Modulated Luminol-Tb Fluorescent Probe for the Ratiometric Detection of Anthrax Biomarker

    Advances in Analytical Chemistry · 2023-01-01

    浩哲 孙

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  50. PMMA or PVDF films blended with β-diketonate tetrakis Eu III or Tb III complexes used as downshifting coatings of near-UV LEDs

    Soft Matter · 2023-01-01

    Ariane C. F. Beltrame, Airton Germano Bispo Junior, Felipe S. M. Canisares, Ricardo Vignoto Fernandes, Édson Laureto, Sergio A. M. Lima, Ana Maria Pires

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