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RESEARCH PAPER · Crystal Growth & Design · 2019

One-Dimensional Quaternary and Penternary Alkali Rare Earth Thiophosphates Obtained via Alkali Halide Flux Crystal Growth

Mohammad Usman, Mark D. Smith, Vladislav V. Klepov, Hans‐Conrad zur Loye

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One-Dimensional Quaternary and Penternary Alkali Rare Earth Thiophosphates Obtained via Alkali Halide Flux Crystal GrowthOriginalNearly Identical but Not Isotypic: Influence of Lanthanide Contraction on Cs2NaLn(PS4)2 (Ln = La–Nd, Sm, and Gd–Ho)23A series of Rb 4 Ln 2 (P 2 S 6 )(PS 4 ) 2 (Ln = La, Ce, Pr, Nd, Sm, Gd) rare earth thiophosphates with two distinct thiophosphate units [P V S 4 ] 3− and [P IV 2 S 6 ] 4−16Trends in rare earth thiophosphate syntheses: Rb 3 Ln(PS 4 ) 2 (Ln = La, Ce, Pr), Rb 3−x Na x Ln(PS 4 ) 2 (Ln = Ce, Pr; x = 0.50, 0.55), and RbEuPS 4 obtained by molten flux crystal growth5New Compounds and Phase Selection of Nickel Sulfides via Oxidation State Control in Molten Hydroxides20Lanthanide thioborates, an emerging class of nonlinear optical materials, efficiently synthesized using the boron–chalcogen mixture method23A review of structures and physical properties of rare earth chalcophosphates78Synthesis, Crystal and Electronic Structures, Nonlinear Optical Properties, and Magnetic Properties of Two Thiophosphates: KInP2S7 and KCrP2S79NaREP 2 Se 6 (RE = Y, Sm, Gd–Dy): Quaternary Rare-Earth Selenophosphates with Unique 3D {[REP 2 Se 6 ] − } ∞ Framework Built by RESe 8 and P 2 Se 6 Motifs and Multiple Properties4Alkali halide flux synthesis, crystal structure, and photoelectric response of quaternary thiosilicates K 3 Ga 3 Si 7 S 20 and K 2 ZnSi 3 S 81Centrosymmetric to noncentrosymmetric structure transition of the RbREP 2 Se 6 (RE = La–Nd, Sm, Ho–Yb) series: crystal growth, magnetic and optical properties4A Surprising Continuation of the Nonisotypic Rb 3 Ln [AsS 4 ] 2 Series: The Diverse Crystal Structures of the End‐Members with Ln = Gd–Ho0

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  1. Nearly Identical but Not Isotypic: Influence of Lanthanide Contraction on Cs2NaLn(PS4)2 (Ln = La–Nd, Sm, and Gd–Ho)

    Inorganic Chemistry · 2020-01-22

    Vladislav V. Klepov, Kristen A. Pace, Logan S. Breton, Vancho Kocevski, Theodore M. Besmann, Hans‐Conrad zur Loye

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  2. A series of Rb 4 Ln 2 (P 2 S 6 )(PS 4 ) 2 (Ln = La, Ce, Pr, Nd, Sm, Gd) rare earth thiophosphates with two distinct thiophosphate units [P V S 4 ] 3− and [P IV 2 S 6 ] 4−

    Dalton Transactions · 2021-01-01

    Ceren Kütahyalı Aslani, Logan S. Breton, Vladislav V. Klepov, Hans‐Conrad zur Loye

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  3. Trends in rare earth thiophosphate syntheses: Rb 3 Ln(PS 4 ) 2 (Ln = La, Ce, Pr), Rb 3−x Na x Ln(PS 4 ) 2 (Ln = Ce, Pr; x = 0.50, 0.55), and RbEuPS 4 obtained by molten flux crystal growth

    CrystEngComm · 2021-01-01

    Logan S. Breton, Mark D. Smith, Hans‐Conrad zur Loye

    Read original paper ↗ ·

  4. New Compounds and Phase Selection of Nickel Sulfides via Oxidation State Control in Molten Hydroxides

    Journal of the American Chemical Society · 2021-08-19

    Xiuquan Zhou, David J. Mandia, Hyowon Park, Mahalingam Balasubramanian, Lei Yu, Jianguo Wen, Andrey Andreevich Yakovenko, Duck Young Chung, Mercouri G. Kanatzidis

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  5. Lanthanide thioborates, an emerging class of nonlinear optical materials, efficiently synthesized using the boron–chalcogen mixture method

    Chemical Communications · 2022-01-01

    Logan S. Breton, Gregory W. Morrison, Matthew R. Lacroix, P. Shiv Halasyamani, Hans‐Conrad zur Loye

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  6. A review of structures and physical properties of rare earth chalcophosphates

    Coordination Chemistry Reviews · 2022-10-11

    Zi‐Xia Chen, Wenlong Liu, Sheng‐Ping Guo

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  7. Synthesis, Crystal and Electronic Structures, Nonlinear Optical Properties, and Magnetic Properties of Two Thiophosphates: KInP2S7 and KCrP2S7

    Crystals · 2022-10-22

    Craig Cropek, Vivian Nguyen, Santosh Karki Chhetri, Jin Hu, Sheng‐Ping Guo, Jian Wang

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  8. NaREP 2 Se 6 (RE = Y, Sm, Gd–Dy): Quaternary Rare-Earth Selenophosphates with Unique 3D {[REP 2 Se 6 ] − } ∞ Framework Built by RESe 8 and P 2 Se 6 Motifs and Multiple Properties

    Inorganic Chemistry · 2023-11-30

    Chen‐Yi Zhao, Zi‐Xia Chen, Wen‐Dong Yao, Wenfeng Zhou, Wenlong Liu, Sheng‐Ping Guo

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  9. Alkali halide flux synthesis, crystal structure, and photoelectric response of quaternary thiosilicates K 3 Ga 3 Si 7 S 20 and K 2 ZnSi 3 S 8

    CrystEngComm · 2024-01-01

    Jia-Ting Liu, Abdusalam Ablez, Qianqian Hu, Jun-Hao Tang, Chuan Lv, Lu Yang, Mei‐Ling Feng, Xiao‐Ying Huang

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  10. Centrosymmetric to noncentrosymmetric structure transition of the RbREP 2 Se 6 (RE = La–Nd, Sm, Ho–Yb) series: crystal growth, magnetic and optical properties

    Dalton Transactions · 2026-01-01

    Habiba Binte Kashem, Abdullah Al Muhit, Hope Eden Smith, Eric A. Gabilondo, P. Shiv Halasyamani, Hans‐Conrad zur Loye

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  11. A Surprising Continuation of the Nonisotypic Rb 3 Ln [AsS 4 ] 2 Series: The Diverse Crystal Structures of the End‐Members with Ln = Gd–Ho

    Zeitschrift für anorganische und allgemeine Chemie · 2026-07-15

    Katja Engel, Thomas Schleid

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