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RESEARCH PAPER · Journal of Materials Chemistry C · 2017

A bright and moisture-resistant red-emitting Lu 3 Al 5 O 12 :Mn 4+ ,Mg 2+ garnet phosphor for high-quality phosphor-converted white LEDs

Yibo Chen, Kuanglun Wu, Jin He, Zhengbin Tang, Jianxin Shi, Yiqin Xu, Zhao‐Qing Liu

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A bright and moisture-resistant red-emitting Lu 3 Al 5 O 12 :Mn 4+ ,Mg 2+ garnet phosphor for high-quality phosphor-converted white LEDsOriginalDesigned synthesis, morphology evolution and enhanced photoluminescence of a highly efficient red dodec-fluoride phosphor, Li 3 Na 3 Ga 2 F 12 :Mn 4+ , for warm WLEDs127A far-red emission (Ca,Sr)14Zn6Ga10O35:Mn4+ phosphor for potential application in plant-growth LEDs57Bond energy, site preferential occupancy and Eu 2+/3+ co-doping system induced by Eu 3+ self-reduction in Ca 10 M(PO 4 ) 7 (M = Li, Na, K) crystals36Efficient rare-earth free red-emitting Ca 2 YSbO 6 :Mn 4+ ,M(M = Li + , Na + , K + , Mg 2+ ) phosphors for white light-emitting diodes117Hybrid organic–inorganic lead bromide perovskite supercrystals self-assembled with l -cysteine and their good luminescence properties47Luminescent properties of Eu 3+ -activated Gd 2 ZnTiO 6 double perovskite red-emitting phosphors for white light-emitting diodes and field emission displays40Mn 2+ and Mn 4+ red phosphors: synthesis, luminescence and applications in WLEDs. A review706Novel far-red-emitting SrGdAlO 4 :Mn 4+ phosphors with excellent responsiveness to phytochrome P FR for plant growth lighting39Synthesis and photoluminescence properties of novel far-red-emitting BaLaMgNbO 6 :Mn 4+ phosphors for plant growth LEDs106Ln3Al5O12:Mn4+ (Ln = Y and Lu): non-rare-earth doped red phosphor for improving light properties of white light emitting diodes6A novel dazzling Eu 3+ ‐doped whitlockite‐type phosphate red‐emitting phosphor for white light‐emitting diodes60Luminescence properties of YVO4: Ln (Ln = Dy3+, Eu3+, Tm3+) for white LED by hydrothermal method22Photoluminescent properties and Judd-Ofelt analysis of Eu3+-doped NaMg(PO3)3 red phosphor28Structure, site-occpancy and luminescent properties of a novel blue phosphor Na 3 ZrMgP 3 O 12 : Eu 2+17Synthesis, photoluminescence, energy transfer and thermal stability of SmPO4@SiO2:Eu3+ core-shell structured red phosphors for WLEDs19Tunable Optical Properties and Enhanced Thermal Quenching of Non-Rare-Earth Double-Perovskite (Ba1–xSrx)2YSbO6:Mn4+ Red Phosphors Based on Composition Modulation135Synthesis and photoluminescent properties of high-efficient color-tunable Ba3Y2B6O15: Ce3+, Tb3+ phosphors20A novel rare-earth free red-emitting Li3Mg2SbO6:Mn4+ phosphor-in-glass for warm w-LEDs: Synthesis, structure, and luminescence properties101A high-performance non-rare-earth deep-red-emitting Ca14-xSrxZn6Al10O35:Mn4+ phosphor for high-power plant growth LEDs71A highly luminescent Mn 4+ activated LaAlO 3 far-red-emitting phosphor for plant growth LEDs: charge compensation induced Mn 4+ incorporation31Enhanced deep-red emission from Mn 4+ /Mg 2+ co-doped CaGdAlO 4 phosphors for plant cultivation63Mn 4+ -activated BaLaMgSbO 6 double-perovskite phosphor: a novel high-efficiency far-red-emitting luminescent material for indoor plant growth lighting42Local Structure Modulation Induced Highly Efficient Far-Red Luminescence of La 1– x Lu x AlO 3 :Mn 4+ for Plant Cultivation89Luminescence of Tb3Al5O12 phosphors co-doped with Ce3+/Gd3+ for white light-emitting diodes26Studies on luminescence properties of double perovskite deep red phosphor La2ZnTiO6:Mn4+ for indoor plant growth LED applications91Synthesis and photoluminescence properties of a novel Ca2LaNbO6:Mn4+ double perovskite phosphor for plant growth LEDs20Synthesis and photoluminescence properties of novel red-emitting phosphor SrAl3BO7:Mn4+ with enhanced emission by Mg2+/Zn2+/Ca2+ incorporation for plant growth LED lighting48Influence of dopants oxidation states control on the photoluminescence properties of inorganic phospors0Tunable lanthanide/transition metal ion‐doped novel phosphors for possible application in w‐LEDs: a review77Synthesis and luminescence properties of CaLaMgNbO6:Mn4+ red phosphor for UV-based w-LEDs3Hydrolysis kinetic study of CaAlSiN3:Eu2+ red phosphor with both water immersion test and first-principles calculation23A New Co-Substitution Strategy as a Model to Study a Rare-Earth-Free Spinel-Type Phosphor with Red Emissions and Its Application in Light-Emitting Diodes33A novel efficient single-phase dual-emission phosphor with high resemblance to the photosynthetic spectrum of chlorophyll A and B61Enhanced red luminescence in CaAl 12 O 19 :Mn 4+ via doping Ga 3+ for plant growth lighting220Novel red-emitting Lu3Te2Li3O12: Eu3+ phosphor with high color purity for n-UV WLEDs2Super stable (Ba,Sr)LuAl 2 Si 2 O 2 N 5 :Ce 3+ ,Eu 2+ phosphors30Dual-Mode Optical Thermometry Design in Lu3Al5O12:Ce3+/Mn4+ Phosphor189Zero-thermal-quenching of Mn4+ far-red-emitting in LaAlO3 perovskite phosphor via energy compensation of electrons’ traps193Influences of thermal post-treatment on the Mn valence states and luminescence properties of red-emitting Lu3Al5O12: Mn4+ transparent ceramic phosphors22Novel color tunable garnet phosphor of Tb3+ and Eu3+ co-doped Ca2YZr2Al3O12 with high thermal stability via energy transfer73Structure identification and strongly enhanced luminescence of Sr9Y2(WO6)4: Mn4+ phosphors by co-doping Mg2+ ions for plant growth LEDs21Intense blue emission of perovskite-type fluoride phosphor Cs4Mg3CaF12: Eu2+ as a promising pc-WLEDs material30Red shift properties, crystal field theory and nephelauxetic effect on Mn4+-doped SrMgAl10-yGayO17 red phosphor for plant growth LED light222Luminescence properties of nitrogen-rich Ca-SiAlON:Eu2+ phosphors prepared by freeze-drying assisted combustion synthesis3Charge compensation assisted enhanced photoluminescence derived from Al3+-codoped NaLaMgWO6:Mn4+ phosphors for plant growth lighting applications22Achieving full-visible-spectrum LED lighting via employing an efficient Ce3+-activated cyan phosphor115Tuning the Oxidation States of Dopants: A Strategy for the Modulation of Material Photoluminescence Properties11A novel efficient Mn4+-activated Ba2YTaO6 far-red emitting phosphor for plant cultivation LEDs: Preparation and photoluminescence properties26Localized Charge Accumulation Driven by Li+ Incorporation for Efficient LED Phosphors with Tunable Photoluminescence77Improved Moisture-Resistant and Luminescence Properties of a Red Phosphor Based on Dodec-fluoride K3RbGe2F12:Mn4+ through Surface Modification34Rational Design of a Nd3+‐Mn4+ Co‐doped Luminescent Thermometer: Towards High‐Sensitivity Temperature Sensing4Flux-assisted low-temperature synthesis of Mn4+-doped unusual broadband deep-red phosphors toward warm w-LEDs39Preparation of far-red emitting Ba2YTaO6:Mn4+ phosphors for plant growth LEDs applications31Synthesis and photoluminescence of high color purity red-emitting BaLaLiTeO6:Eu3+ phosphors24Narrow-band far red-emitting double-perovskite SrGd2Al2O7:Mn4+ phosphors25Distortion and energy transfer assisted tunability in garnet phosphors62Enhanced luminescence of Mn4+-activated CaAl12O19 red phosphors by synergetic manipulation of the flux effect and charge compensation for warm WLEDs application9Mn4+-doped La(CaZr)0.5O3 phosphors for plant grow LEDs: Ab initio site occupy and photoluminescence properties9Blue-light-excitable broadband yellow-emitting CaGd2HfSc(AlO4)3:Ce3+ garnet phosphors for white light-emitting diode devices with improved color rendering index68Fundamental luminescence properties of Mn 4+ activated Ca 14 Al 10 Zn 6 O 35 phosphor24Thermometric and Luminescence Studies of Eu3+ Activated Casr2(Po4)2 Phosphor for Temperature Sensing and Solid-State Lighting Applications2A new series of long wavelength red phosphors BaLaLiTe1-xO6:xMn4+ for plant cultivation LED13A garnet-structured (Y, Ca)3(Al, Mg)2(Al, Si)3O12:Ce3+ phosphor-in-glass engineering for use in high color rendering white LEDs2Modulation strategy of manganese valence state in yttrium gallium garnet8Thermometric and luminescence studies of Eu3+ activated CaSr2(PO4)2 phosphor for non-contact optical thermometry and solid state lighting applications33Wide-band blue-emitting in Ce3+ doped Ca2YZr2Al3O12 garnet-type phosphor designed via local structural lattice distortion and synthesized in nonreducing atmosphere27Equivalent chemical substitution in double–double perovskite-type ALaLiTeO 6 :Mn 4+ (A = Ba 2+ , Sr 2+ , Ca 2+ ) phosphors enabling wide range crystal field strength regulation and efficient far-red emission17Highly emissive Sb 3+ -doped Rb 2 InCl 5 ·H 2 O perovskites: cost-effective synthesis, luminescence, and its application11Rare-Earth Doped Inorganic Materials for Light-Emitting Applications4Synthesis, luminescence properties and potential applications for plant growth: A novel Mn4+-activated SrLa2Al2O7 phosphor with far-red emission39Bi3+ ions doped double perovskite Ca2MgWO6 phosphor for yellow light emission33Ultrahighly Efficient Narrowband Red Luminescence of Uniquely Distorted Mn 4+ Octahedron in the Feldspar‐Type LED Phosphor47Highly bright broadband cyan-emitting CaLu2HfGaAl3O12:Ce3+ garnet phosphors for high-color-quality white light-emitting diodes15Synthesis of garnet-type Mn4+-activated Y3(Al,Ga)5O12 and (Y,Gd)3Al5O12 phosphors with controlled emission by cation substitution2A highly efficient deep red-emitting Mn 4+ -powered oxyfluoride nanophosphor developed for plant growth and optical thermometric applications13Synthesis and Photoluminescence Properties of Novel Far-Red Emitting Garnet Phosphor Y3ga3mgsi(1-Y)Geyo12:Mn4+1Synthesis and Photoluminescence Properties of Novel Far-Red Emitting Garnet Phosphor Y3ga3mgsi(1-Y)Geyo12:Mn4+2Double perovskite La2LiNb(1-)O6: xMn4+ red phosphors with excellent humidity stability and high thermal stability for plant growth LEDs11Effects of Na+, Ga3+ introduction on the luminescence properties of LiAl4O6F: Mn4+ red fluorescent materials6The nephelauxetic function he: A tool to locate the emission of Mn4+ in oxides and fluorides3A green-light-driven Mn4+ doped aluminate for agricultural cultivation with high resemblance to the phytochrome spectrum9Adjusting luminescence properties of ZnAl2O4:Mn2+(Mn4+), Li+ phosphors through cation substitution1DFT based computational investigations of the physical properties of manganese doped Ba2YTaO6 phosphors for optoelectronic and mechanical applications8Synthesis and photoluminescence properties of novel far-red emitting garnet phosphor Y3Ga3MgSi(1-y)GeyO12:Mn4+17Tunable broadband luminescence of the novel Sn2+ doped oxyfluoride glass and glass-ceramics for W-LEDs8(Sr 3 Ca 4 )(Ca 2 Ga 6 )O 18 :Mn 4+ : crystallographic spatial isolation enables high doping levels, exceptional anti-thermal quenching, and promising temperature sensing applications0Fluorescence and water stability enhancement of K2NaScF6:Mn4+ red phosphor by crystal field optimization of Mg2+/Zn2+ for warm WLEDs30Dual-emitting Mn4+-doped Tb3Al5O12 garnet phosphor for high-sensitive, self-referenced optical thermometry0Preparation and Luminescence Properties of Mn4+ Ions Doped CaAl12O19 Red Phosphors1Boosting luminescence of Ca2GdTaO6: Mn4+ red phosphors via Li+ charge compensation for plant growth LEDs1Investigating the Spectroscopic Performance of Y3Al5O12:Mn4+ Phosphors Co-Doped with Divalent Metal Ions and the Use of Phosphor Film for “Green” Plant Cultivation2Narrowband Far-Red Emitting Sr2ZnAl22O36:Mn4+ Spinel Phosphor for Integrated Horticultural LED, Optical Thermometry, and Forensic Fingerprint Imaging0Advancing health-oriented LED illumination using an excellent broadband cyan-emitting Ba2MgGe2O7:Bi3 + phosphor0

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  2. A far-red emission (Ca,Sr)14Zn6Ga10O35:Mn4+ phosphor for potential application in plant-growth LEDs

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  3. Bond energy, site preferential occupancy and Eu 2+/3+ co-doping system induced by Eu 3+ self-reduction in Ca 10 M(PO 4 ) 7 (M = Li, Na, K) crystals

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  4. Efficient rare-earth free red-emitting Ca 2 YSbO 6 :Mn 4+ ,M(M = Li + , Na + , K + , Mg 2+ ) phosphors for white light-emitting diodes

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  5. Hybrid organic–inorganic lead bromide perovskite supercrystals self-assembled with l -cysteine and their good luminescence properties

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  6. Luminescent properties of Eu 3+ -activated Gd 2 ZnTiO 6 double perovskite red-emitting phosphors for white light-emitting diodes and field emission displays

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  7. Mn 2+ and Mn 4+ red phosphors: synthesis, luminescence and applications in WLEDs. A review

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  8. Novel far-red-emitting SrGdAlO 4 :Mn 4+ phosphors with excellent responsiveness to phytochrome P FR for plant growth lighting

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  9. Synthesis and photoluminescence properties of novel far-red-emitting BaLaMgNbO 6 :Mn 4+ phosphors for plant growth LEDs

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  10. Ln3Al5O12:Mn4+ (Ln = Y and Lu): non-rare-earth doped red phosphor for improving light properties of white light emitting diodes

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  11. A novel dazzling Eu 3+ ‐doped whitlockite‐type phosphate red‐emitting phosphor for white light‐emitting diodes

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  12. Luminescence properties of YVO4: Ln (Ln = Dy3+, Eu3+, Tm3+) for white LED by hydrothermal method

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  13. Photoluminescent properties and Judd-Ofelt analysis of Eu3+-doped NaMg(PO3)3 red phosphor

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  14. Structure, site-occpancy and luminescent properties of a novel blue phosphor Na 3 ZrMgP 3 O 12 : Eu 2+

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  15. Synthesis, photoluminescence, energy transfer and thermal stability of SmPO4@SiO2:Eu3+ core-shell structured red phosphors for WLEDs

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  16. Tunable Optical Properties and Enhanced Thermal Quenching of Non-Rare-Earth Double-Perovskite (Ba1–xSrx)2YSbO6:Mn4+ Red Phosphors Based on Composition Modulation

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  17. Synthesis and photoluminescent properties of high-efficient color-tunable Ba3Y2B6O15: Ce3+, Tb3+ phosphors

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  18. A novel rare-earth free red-emitting Li3Mg2SbO6:Mn4+ phosphor-in-glass for warm w-LEDs: Synthesis, structure, and luminescence properties

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  19. A high-performance non-rare-earth deep-red-emitting Ca14-xSrxZn6Al10O35:Mn4+ phosphor for high-power plant growth LEDs

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  20. A highly luminescent Mn 4+ activated LaAlO 3 far-red-emitting phosphor for plant growth LEDs: charge compensation induced Mn 4+ incorporation

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  21. Enhanced deep-red emission from Mn 4+ /Mg 2+ co-doped CaGdAlO 4 phosphors for plant cultivation

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  22. Mn 4+ -activated BaLaMgSbO 6 double-perovskite phosphor: a novel high-efficiency far-red-emitting luminescent material for indoor plant growth lighting

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  23. Local Structure Modulation Induced Highly Efficient Far-Red Luminescence of La 1– x Lu x AlO 3 :Mn 4+ for Plant Cultivation

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  24. Luminescence of Tb3Al5O12 phosphors co-doped with Ce3+/Gd3+ for white light-emitting diodes

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  27. Synthesis and photoluminescence properties of novel red-emitting phosphor SrAl3BO7:Mn4+ with enhanced emission by Mg2+/Zn2+/Ca2+ incorporation for plant growth LED lighting

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  30. Synthesis and luminescence properties of CaLaMgNbO6:Mn4+ red phosphor for UV-based w-LEDs

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  31. Hydrolysis kinetic study of CaAlSiN3:Eu2+ red phosphor with both water immersion test and first-principles calculation

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  32. A New Co-Substitution Strategy as a Model to Study a Rare-Earth-Free Spinel-Type Phosphor with Red Emissions and Its Application in Light-Emitting Diodes

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  33. A novel efficient single-phase dual-emission phosphor with high resemblance to the photosynthetic spectrum of chlorophyll A and B

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  34. Enhanced red luminescence in CaAl 12 O 19 :Mn 4+ via doping Ga 3+ for plant growth lighting

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  35. Novel red-emitting Lu3Te2Li3O12: Eu3+ phosphor with high color purity for n-UV WLEDs

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  36. Super stable (Ba,Sr)LuAl 2 Si 2 O 2 N 5 :Ce 3+ ,Eu 2+ phosphors

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  37. Dual-Mode Optical Thermometry Design in Lu3Al5O12:Ce3+/Mn4+ Phosphor

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  38. Zero-thermal-quenching of Mn4+ far-red-emitting in LaAlO3 perovskite phosphor via energy compensation of electrons’ traps

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  39. Influences of thermal post-treatment on the Mn valence states and luminescence properties of red-emitting Lu3Al5O12: Mn4+ transparent ceramic phosphors

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  40. Novel color tunable garnet phosphor of Tb3+ and Eu3+ co-doped Ca2YZr2Al3O12 with high thermal stability via energy transfer

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  41. Structure identification and strongly enhanced luminescence of Sr9Y2(WO6)4: Mn4+ phosphors by co-doping Mg2+ ions for plant growth LEDs

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  42. Intense blue emission of perovskite-type fluoride phosphor Cs4Mg3CaF12: Eu2+ as a promising pc-WLEDs material

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  43. Red shift properties, crystal field theory and nephelauxetic effect on Mn4+-doped SrMgAl10-yGayO17 red phosphor for plant growth LED light

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  44. Luminescence properties of nitrogen-rich Ca-SiAlON:Eu2+ phosphors prepared by freeze-drying assisted combustion synthesis

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  45. Charge compensation assisted enhanced photoluminescence derived from Al3+-codoped NaLaMgWO6:Mn4+ phosphors for plant growth lighting applications

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  46. Achieving full-visible-spectrum LED lighting via employing an efficient Ce3+-activated cyan phosphor

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  47. Tuning the Oxidation States of Dopants: A Strategy for the Modulation of Material Photoluminescence Properties

    Chemistry - A European Journal · 2020-07-28

    Estelle Glais, Florian Massuyeau, Romain Gautier

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  48. A novel efficient Mn4+-activated Ba2YTaO6 far-red emitting phosphor for plant cultivation LEDs: Preparation and photoluminescence properties

    Journal of Luminescence · 2020-09-06

    Wei Hua Li, Nan Ma, Qi Sun, Shaoying Wang, Zongjie Zhang, Balaji Devakumar, Xiaoyong Huang

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  49. Localized Charge Accumulation Driven by Li+ Incorporation for Efficient LED Phosphors with Tunable Photoluminescence

    Chemistry of Materials · 2020-09-24

    Yibo Chen, Jinquan Chen, Jinhui Liang, Jin He, Zhao‐Qing Liu, Yadong Yin

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  50. Improved Moisture-Resistant and Luminescence Properties of a Red Phosphor Based on Dodec-fluoride K3RbGe2F12:Mn4+ through Surface Modification

    Inorganic Chemistry · 2020-11-11

    Yajun Jia, Yuexiao Pan, Yiqian Li, Lijie Zhang, Hongzhou Lian, Jun Lin

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