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RESEARCH PAPER · Dalton Transactions · 2019

Enhanced deep-red emission from Mn 4+ /Mg 2+ co-doped CaGdAlO 4 phosphors for plant cultivation

Jianxu Hu, Ting‐Hong Huang, Yuanpeng Zhang, Bin Lü, Huanqing Ye, Baojiu Chen, Haiping Xia, Changyan Ji

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Enhanced deep-red emission from Mn 4+ /Mg 2+ co-doped CaGdAlO 4 phosphors for plant cultivationOriginalA single-phase white light emitting phosphor Ba 3 Y(PO 4 ) 3 :Ce 3+ /Tb 3+ /Mn 2+ : luminescence, energy transfer and thermal stability26Novel red-emitting Sr6Al18Si2O37:Mn4+ phosphor for white LEDs14High-efficient and thermal-stable Ca19Zn2(PO4)14: Eu2+, Mn2+ blue-red dual-emitting phosphor for plant cultivation LEDs57Effects of Al3+-substitution on photoluminescence properties of Sr2YNbO6:Mn4+ far-red phosphor for plant cultivation28Engineering cation vacancies to improve the luminescence properties of Ca 14 Al 10 Zn 6 O 35 : Mn 4+ phosphors for LED plant lamp42Comparative investigation on luminescence properties of Mn4+ doped Ba6Y2W3O18 and Ba6Gd2W3O18 phosphors24Eu3+-doped SrGe4O9 red emitting phosphors: structural, luminescence properties, theoretical calculation and applications2Effects of Ti4+- and W6+-substitution on photoluminescence properties of Sr2GdSbO6:Mn4+ phosphor for plant cultivation41Red shift properties, crystal field theory and nephelauxetic effect on Mn4+-doped SrMgAl10-yGayO17 red phosphor for plant growth LED light222Structure analysis, tuning photoluminescence and enhancing thermal stability on Mn4+-doped La2-xYxMgTiO6 red phosphor for agricultural lighting78Achieving Efficient Red-Emitting Sr2Ca1−δLnδWO6:Mn4+ (Ln = La, Gd, Y, Lu, δ = 0.10) Phosphors with Extraordinary Luminescence Thermal Stability for Potential UV-LEDs Application via Facile Ion Substitution in Luminescence-Ignorable Sr2CaWO6:Mn4+52Sm3+/Pr3+ biactivated Ca3Y2Ge3O12:0.04Sm3+:Pr3+ red phosphor with high thermal stability for low correlated temperature WLED23Short review on recent progress in Mn 4+ ‐activated oxide phosphors for indoor plant light‐emitting diodes42A review on the structural dependent optical properties and energy transfer of Mn 4+ and multiple ion-codoped complex oxide phosphors36Achieving high thermal sensitivity from ratiometric CaGdAlO 4 :Mn 4+ ,Tb 3+ thermometers26Enhancing and tuning broadband near-infrared (NIR) photoluminescence properties in Cr 3+ -doped Ca 2 YHf 2 Al 3 O 12 garnet phosphors via Ce 3+ /Yb 3+ -codoping for LED applications101Band gap tailoring, structural and optical features of MgS nanoparticles: Influence of Ag+ ions24Deep-red-emitting Mg2InSbO6:Mn4+ phosphors with a double-perovskite structure for plant-cultivation LEDs: Synthesis and photoluminescence properties81Combustion synthesis of Ba3Y1-xSm3+x(BO3)3asred-light emitting phosphors for indoor plant cultivation applications5Enhanced luminescence performance and efficiency of La2NaSbO6: Mn4+ by co-doping Ca2+ for plant growth lighting11Review on deep red-emitting rare-earth free germanates and their efficiency as well as adaptability for various applications27Finding an efficient far-red-emitting CaMg2La2W2O12:Mn4+ phosphor toward indoor plant cultivation LED lighting91Synthesis of red photoluminescent nickel doped self-assembled copper nanoclusters and their application in biothiol sensing16Luminescence of a novel double-perovskite Sr2InSbO6:Eu3+ orange-red-emitting phosphor for white LEDs and visualization of latent fingerprints72Optimization of the luminescence efficiency and moisture stability of a red phosphor KRb3Ge2F12:Mn4+ for indoor plant growth LED applications22Preparation and luminescent properties of double perovskite-type La2-x-yYxMgTiO6:yEu3+ red fluorescent materials4Suppression of charge imbalance via Li+-Mn4+ co-incorporated Sr2YSbO6 red phosphors for warm w-LEDs43Light keys open locks of plant photoresponses: A review of phosphors for plant cultivation LEDs75Nanostructured III-nitride light emitting diodes0Structural, spectroscopic, luminescence and magnetic properties of a novel far-red emitting phosphor Er, Mn doped ZrTe3O81Luminescence studies of a Li 2 Ca 1−x SiO 4 :xSm 3+ phosphor for the generation of white light under NUV‐excited phosphor converting LEDs1Highly efficient and thermally stable red emitting CaGdMgNbO6:Mn4+ double perovskites for indoor plant growth LEDs13Synthesis and luminescence properties of yellow-emitting LiGd6(BO3)3O5:Dy3+ borate phosphors with good thermal stability for white LEDs5Greatly enhanced deep-red luminescence performance of Ca2InSbO6:Mn4+ phosphor via multiple optimization strategies34Novel far-red emitting phosphor Mn4+-activated BaLaLiWO6 with excellent performance for indoor plant cultivation of light-emitting diodes37Bi3+/Mn4+ co-activated phosphors for indoor plant growth and temperature sensing21Red Light Emitting Transition Metal Ion Doped Calcium Antimony Oxide for Plant Growth Lighting Applications7Defect-induced deep red luminescence of CaGdAlO 4 -type layered perovskites: multi-cationic sites partial/full substitution and application in pc-LED and plant lighting14Flux induced highly efficient and stable phosphor Sr 2 ScSbO 6 :Mn 4+ for plant growth lighting41Influence of Doping Concentration on Defects, Nanopores and Photoluminesence Property of Γ-Al2o3:Mn4+,Mg2+ Nanowire-Phosphor Studied by Positron Annihilation Spectroscopy0Structural confinement-induced highly efficient deep-red emission and negative thermal quenching performance in Mn 4+ -activated Ca 7 Mg 2 Ga 6− y Al y O 18 :Mn 4+ phosphors38Highly Stable White Light Emission from III-Nitride Nanowire LEDs Utilizing Nanostructured Alumina-Doped Mn4+ and Mg2+10Al3+ ions co-doped Ba2YSbO6: Mn4+ phosphors with high thermal stability and strong far-red emission for plant growth LEDs18Enriching the Deep-Red Emission in (Mg, Ba)3M2GeO8: Mn4+ (M = Al, Ga) Compositions for Light-Emitting Diodes44Ultrahighly Efficient Narrowband Red Luminescence of Uniquely Distorted Mn 4+ Octahedron in the Feldspar‐Type LED Phosphor47Luminescence characteristics of white light emitting BaGa2O4:Dy3+ phosphors for LEDs and stress sensing applications5Structurally stable Mn4+-doped oxide phosphor with improved thermal stability for agricultural lighting22Effect of the local environment on the luminescence of Er3+/Yb3+-doped aluminate upconversion phosphors4Optical grade (Gd 0.95- x Lu x Eu 0.05 ) 3 Al 5 O 12 ceramics with near-zero optical loss: Effects of Lu 3+ doping on structural feature, microstructure evolution, and far-red luminescence33Novel broadband near-infrared emission in Cr3+-activated Sr3ZnGe5O14 phosphor for an electroluminescent stable pc-LED12Unravelling the white light emission in a single-phase new stoichiometric vanadate phosphor synthesized by rapid low-temperature one-pot synthesis and its W-LED prototype with high CRI and luminous efficacy13Synthesis, structural, photoluminescence, and EPR analysis of far red emitting Ca3La2W2O12:Mn4+ inorganic phosphor for applications in plant-growth LEDs63Optimized Mn4+ doped Sr9Y2W4O24 perovskite for enhanced far-red-emitting luminescent material30Analysis of structural defects and their influence on red‐emitting γ‐Al 2 O 3 :Mn 4+ ,Mg 2+ nanowires using positron annihilation spectroscopy4Self‐Trapped Exciton Emission Based on Halogen‐Substituted Metal Halides3A far-red phosphor based on garnet-related Li6CaLa2Ta2O12:Mn4+ and its responsiveness to phytochrome PFR3Garnet-type Mn4+-activated Li5La3Sb2O12 far-red phosphor for indoor plant growth LEDs11Mn–Yb co-doped CaGdAlO4 nanoparticles as efficient blue-to-NIR converters for photovoltaic enhancement0The incorporation of Ge 4+ enhances the performance of La 2 MgSnO 6 :Mn 4+ double perovskite phosphors1A novel Sr2LaAlO5:Eu3+ phosphor with targeted deep-red emission for High-CRI WLEDs and plant growth lighting4A highly efficient near-infrared emitting garnet phosphor for plant growth lighting1Correlating photoluminescence and thermoluminescence in Dy³⁺-doped BaSi2O5 phosphors: A dual-functional approach1

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  3. High-efficient and thermal-stable Ca19Zn2(PO4)14: Eu2+, Mn2+ blue-red dual-emitting phosphor for plant cultivation LEDs

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  4. Effects of Al3+-substitution on photoluminescence properties of Sr2YNbO6:Mn4+ far-red phosphor for plant cultivation

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  5. Engineering cation vacancies to improve the luminescence properties of Ca 14 Al 10 Zn 6 O 35 : Mn 4+ phosphors for LED plant lamp

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  6. Comparative investigation on luminescence properties of Mn4+ doped Ba6Y2W3O18 and Ba6Gd2W3O18 phosphors

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  9. Red shift properties, crystal field theory and nephelauxetic effect on Mn4+-doped SrMgAl10-yGayO17 red phosphor for plant growth LED light

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  15. Achieving high thermal sensitivity from ratiometric CaGdAlO 4 :Mn 4+ ,Tb 3+ thermometers

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  48. Effect of the local environment on the luminescence of Er3+/Yb3+-doped aluminate upconversion phosphors

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  50. Novel broadband near-infrared emission in Cr3+-activated Sr3ZnGe5O14 phosphor for an electroluminescent stable pc-LED

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