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RESEARCH PAPER · Inorganic Chemistry · 2018

Why Some Noncentrosymmetric Borates Do Not Make Good Nonlinear Optical Materials: A Case Study with K3B5O8(OH)2

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Why Some Noncentrosymmetric Borates Do Not Make Good Nonlinear Optical Materials: A Case Study with K3B5O8(OH)2OriginalMg(H 2 O) 6 B 4 O 5 (OH) 4 (H 2 O) 3 : a new hydrated borate with a short DUV cutoff edge9Bi2Te2O6(NO3)2(OH)2(H2O): A layered bismuth tellurium nitrate hydroxide with multiple noncentrosymmetric chromophores14Li2CsB7O10(OH)4: A Deep-Ultraviolet Nonlinear-Optical Mixed-Alkaline Borate Constructed by Unusual Heptaborate Anions98Layered Bismuth Oxyfluoride Nitrates Revealing Large Second-Harmonic Generation and Photocatalytic Properties37NaCa5BO3(SiO4)2 with Interesting Isolated [BO3] and [SiO4] Units in Alkali- and Alkaline-Earth-Metal Borosilicates14Two Deep Ultraviolet Hydrated Borate Crystals: Centrosymmetric LiRbB5O8(OH)·H2O and Non-Centrosymmetric K2B5O8(OH)·2H2O8The first silver bismuth borate, AgBi2B5O115Nitrate nonlinear optical crystals: A survey on structure-performance relationships146Al8(BO3)4(B2O5)F8: A F-Containing Aluminum Borate Featuring Two Types of Isolated B–O Groups12Ba 6 BO 3 Cl 9 and Pb 6 BO 4 Cl 7 : structural insights into ortho -borates with uncondensed BO 4 tetrahedra10Second-Order Nonlinear-Optical-Active Selenide Borate YSeBO2: Featuring a [YSeBO2]n Planar Belt39Enhanced birefringence and suppressed second harmonic generation response mechanism in nonlinear optical materials via structural fine-tuning9Li3La2(BO3)3 and Li1.75Na1.25La2(BO3)3: A Great Enhancement in Birefringence Induced by Optimal Arrangement of π-Conjugated [BO3] Units28Pb 2 Al 2 B 3 O 8 F 3 : structure and properties of a new fluoroaluminoborate with non-traditional chain-like B 3 O 8 groups4Ba2B10O16(OH)2·(H3BO3)(H2O): A Possible Deep-Ultraviolet Nonlinear-Optical Barium Borate36Beyond π–π Stacking: Understanding Inversion Symmetry Breaking in Crystalline Racemates27Rare-Earth Scandium Borate Fluoride with a Deep-Ultraviolet Cutoff Edge12Cd8(BO3)4SiO4: Metal Cation Inducing the Formation of Isolated [BO3] and [SiO4] Units in Borate Silicate15Structural Regulations of Layered Borates: From Centric Layers to Chiral Porous Layers3K6NaCaRe2(B5O10)3 (Re = Y, Lu): Two NLO Compounds Exhibiting a Short Absorption Edge in the A7–xA’xAeRe2(B5O10)3 (x = 0, 1) Family4Two Alkaline Metal Borates: from Layer to Layer-Pillared Framework8NH4B5O7(OH)2 and CsRbB10O14(OH)4·H2O: Two Hydroxyborates Feature Significant Optical Anisotropy and Contain 1∞[B5O7(OH)2] Chains1

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  1. Mg(H 2 O) 6 B 4 O 5 (OH) 4 (H 2 O) 3 : a new hydrated borate with a short DUV cutoff edge

    Dalton Transactions · 2019-01-01

    Ya Wang, Jian Wei Han, Fengjiao Guo, Shichao Cheng, Zhihua Yang, Shilie Pan

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  2. Bi2Te2O6(NO3)2(OH)2(H2O): A layered bismuth tellurium nitrate hydroxide with multiple noncentrosymmetric chromophores

    Journal of Solid State Chemistry · 2019-01-11

    Soyon Lee, Hongil Jo, Kang Min Ok

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  3. Li2CsB7O10(OH)4: A Deep-Ultraviolet Nonlinear-Optical Mixed-Alkaline Borate Constructed by Unusual Heptaborate Anions

    Inorganic Chemistry · 2019-01-14

    Jianhao Huang, Congcong Jin, Pei-Li Xu, Pifu Gong, Zheshuai Lin, Jian‐Wen Cheng, Guo‐Yu Yang

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  4. Layered Bismuth Oxyfluoride Nitrates Revealing Large Second-Harmonic Generation and Photocatalytic Properties

    Inorganic Chemistry · 2019-01-16

    Eun Jeong Cho, Seung‐Jin Oh, Hongil Jo, Junsu Lee, Tae‐Soo You, Kang Min Ok

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  5. NaCa5BO3(SiO4)2 with Interesting Isolated [BO3] and [SiO4] Units in Alkali- and Alkaline-Earth-Metal Borosilicates

    Inorganic Chemistry · 2019-03-04

    Zhaohong Miao, Yun Mo Yang, Zhonglei Wei, Zhihua Yang, Sujuan Yu, Shilie Pan

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  6. Two Deep Ultraviolet Hydrated Borate Crystals: Centrosymmetric LiRbB5O8(OH)·H2O and Non-Centrosymmetric K2B5O8(OH)·2H2O

    Crystal Growth & Design · 2019-04-03

    Yutong Shi, Min Luo, Chensheng Lin, Guang Peng, Ning Ye

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  7. The first silver bismuth borate, AgBi2B5O11

    Acta Crystallographica Section C Structural Chemistry · 2019-06-14

    Sergey Volkov, Dmitri O. Charkin, Р. С. Бубнова, Alexey V. Povolotskiy, M. Yu. Arsent’ev, M. Krzhizhanovskay, Sergey Yu. Stefanovich, В. Л. Уголков, Л. Н. Куриленко

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  8. Nitrate nonlinear optical crystals: A survey on structure-performance relationships

    Coordination Chemistry Reviews · 2019-09-10

    Xiaomeng Liu, Pifu Gong, Yi Jin Yang, Gaomin Song, Zheshuai Lin

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  9. Al8(BO3)4(B2O5)F8: A F-Containing Aluminum Borate Featuring Two Types of Isolated B–O Groups

    Inorganic Chemistry · 2019-12-26

    Ya Wang, Jian Wei Han, Junben Huang, Zhihua Yang, Shilie Pan

    Read original paper ↗ ·
  10. Ba 6 BO 3 Cl 9 and Pb 6 BO 4 Cl 7 : structural insights into ortho -borates with uncondensed BO 4 tetrahedra

    Chemical Communications · 2020-01-01

    Wei Li, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  11. Second-Order Nonlinear-Optical-Active Selenide Borate YSeBO2: Featuring a [YSeBO2]n Planar Belt

    Inorganic Chemistry · 2020-05-29

    Zhen‐Tao Lu, Wenjing Fan, Zhiqian Wang, Ning Gu, Zeng-Hao Yue, Huaiguo Xue, Sheng‐Ping Guo

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  12. Enhanced birefringence and suppressed second harmonic generation response mechanism in nonlinear optical materials via structural fine-tuning

    Materials Chemistry Frontiers · 2021-01-01

    Fuming Li, Shilie Pan, Zhihua Yang

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  13. Li3La2(BO3)3 and Li1.75Na1.25La2(BO3)3: A Great Enhancement in Birefringence Induced by Optimal Arrangement of π-Conjugated [BO3] Units

    Inorganic Chemistry · 2021-07-30

    Xuping Shi, Wenbin Zhang, Wenbing Cai, Shujuan Han, Zhihua Yang, Shilie Pan

    Read original paper ↗ ·
  14. Pb 2 Al 2 B 3 O 8 F 3 : structure and properties of a new fluoroaluminoborate with non-traditional chain-like B 3 O 8 groups

    Dalton Transactions · 2022-01-01

    Bao Jiang, Shan Shu, Zhihua Yang, Fangfang Zhang, Min Zhang, Shilie Pan

    Read original paper ↗ ·
  15. Ba2B10O16(OH)2·(H3BO3)(H2O): A Possible Deep-Ultraviolet Nonlinear-Optical Barium Borate

    Inorganic Chemistry · 2022-03-01

    Wen-Zhuo Zhao, Yinan Zhang, You‐Zhao Lan, Jian‐Wen Cheng, Guo‐Yu Yang

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  16. Beyond π–π Stacking: Understanding Inversion Symmetry Breaking in Crystalline Racemates

    Journal of the American Chemical Society · 2023-07-24

    Yiran Wang, Matthew Lander Nisbet, Kendall R. Kamp, Emily Hiralal, Romain Gautier, P. Shiv Halasyamani, Kenneth Reinhard Poeppelmeier

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  17. Rare-Earth Scandium Borate Fluoride with a Deep-Ultraviolet Cutoff Edge

    Inorganic Chemistry · 2023-09-04

    Qianzhen Zhang, Ran An, Abudukadi Tudi, Zhihua Yang, Xifa Long, Yun Mo Yang

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  18. Cd8(BO3)4SiO4: Metal Cation Inducing the Formation of Isolated [BO3] and [SiO4] Units in Borate Silicate

    Inorganic Chemistry · 2023-12-19

    Guangsheng Xu, Huimin Li, Jian Wei Han, Xueling Hou, Zhihua Yang, Shilie Pan

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  19. Structural Regulations of Layered Borates: From Centric Layers to Chiral Porous Layers

    Precision Chemistry · 2024-05-19

    Chong‐An Chen, Guo‐Yu Yang

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  20. K6NaCaRe2(B5O10)3 (Re = Y, Lu): Two NLO Compounds Exhibiting a Short Absorption Edge in the A7–xA’xAeRe2(B5O10)3 (x = 0, 1) Family

    Inorganic Chemistry · 2024-12-19

    Wencong Li, Zhaowei Hu, Yanyan Ding, Yueting Zhu, Qun Jing, Lili Liu

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  21. Two Alkaline Metal Borates: from Layer to Layer-Pillared Framework

    Inorganic Chemistry · 2024-12-31

    Juan Chen, Dan Qin, Guo‐Yu Yang

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  22. NH4B5O7(OH)2 and CsRbB10O14(OH)4·H2O: Two Hydroxyborates Feature Significant Optical Anisotropy and Contain 1∞[B5O7(OH)2] Chains

    Inorganic Chemistry · 2025-07-17

    Xueli Du, Haoran Wang, Haoran Liu, Qingyu Liu, Wenhu Wang, Jiahao Jiao, Yuchen Yan, Xueyan Wu, Min Zhang

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