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RESEARCH PAPER · Journal of Materials Chemistry C · 2017

Optical properties of Mn 2+ doped cesium lead halide perovskite nanocrystals via a cation–anion co-substitution exchange reaction

Fei Li, Zhiguo Xia, Yue Hong Gong, Lin Gu, Quanlin Liu

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Optical properties of Mn 2+ doped cesium lead halide perovskite nanocrystals via a cation–anion co-substitution exchange reactionOriginalChemical Cosubstitution-Oriented Design of Rare-Earth Borates as Potential Ultraviolet Nonlinear Optical Materials267Ba 2 ZnSc(BO 3 ) 3 and Ba 4 Zn 5 Sc 2 (BO 3 ) 8 : first examples of borates in the Zn–Sc–B–O system featuring special structure configurations15BaLiZn 3 (BO 3 ) 3 : a new member of the KBe 2 BO 3 F 2 family possessing dense BO 3 triangles and the smallest interlayer distance16Building bridges between halide perovskite nanocrystals and thin-film solar cells47CsPbX 3 /Cs 4 PbX 6 core/shell perovskite nanocrystals141Enhanced luminescence and energy transfer in Mn 2+ doped CsPbCl 3−x Br x perovskite nanocrystals77Hybrid organic–inorganic lead bromide perovskite supercrystals self-assembled with l -cysteine and their good luminescence properties47Ultrathin CsPbX 3 (X = Cl, Br, I) nanoplatelets: solvothermal synthesis and optical spectroscopic properties38High Br – Content CsPb(Cl y Br 1– y ) 3 Perovskite Nanocrystals with Strong Mn 2+ Emission through Diverse Cation/Anion Exchange Engineering104Highly Luminescent Lead Halide Perovskite Quantum Dots in Hierarchical CaF2 Matrices with Enhanced Stability as Phosphors for White Light‐Emitting Diodes132Highly Efficient Carbon Dots with Reversibly Switchable Green–Red Emissions for Trichromatic White Light-Emitting Diodes186Efficient recycling of trapped energies for dual-emission in Mn-doped perovskite nanocrystals65Confining Mn2+-Doped Lead Halide Perovskite in Zeolite-Y as Ultrastable Orange-Red Phosphor Composites for White Light-Emitting Diodes118Colour- and structure-stable CsPbBr3-CsPb2Br5 compounded quantum dots with tuneable blue and green light emission45Tuning Exciton–Mn2+ Energy Transfer in Mixed Halide Perovskite Nanocrystals147Metal-Doped Lead Halide Perovskites: Synthesis, Properties, and Optoelectronic Applications650Doping of metal ions in CsPbX3 all inorganic lead trihalide perovskite nanocrystals1An overview on enhancing the stability of lead halide perovskite quantum dots and their applications in phosphor-converted LEDs1206All-inorganic cesium lead halide perovskite nanocrystals: synthesis, surface engineering and applications245B-Site doped lead halide perovskites: synthesis, band engineering, photophysics, and light emission applications179Barium as doping element tuning both toxicity and optoelectric properties of lead-based halide perovskites14Photons and charges from colloidal doped semiconductor quantum dots23The luminescence properties of CsPb x M 1−x Br 3 perovskite nanocrystals transformed from Cs 4 PbBr 6 mediated by various divalent bromide MBr 2 salts19Synthesis and Luminescence Properties of CsPbX 3 @Uio-67 Composites toward Stable Photoluminescence Convertors99Metal Halide Perovskite Nanocrystals: Synthesis, Post-Synthesis Modifications, and Their Optical Properties1812Tuning the electronic structures of all-inorganic lead halide perovskite CsPbI3 via heterovalent doping: A first-principles investigation35Insights of Doping and the Photoluminescence Properties of Mn-Doped Perovskite Nanocrystals136A comprehensive review of doping in perovskite nanocrystals/quantum dots: evolution of structure, electronics, optics, and light-emitting diodes232Anchored Ligands Facilitate Efficient B-Site Doping in Metal Halide Perovskites68Compositional, Processing, and Interfacial Engineering of Nanocrystal- and Quantum-Dot-Based Perovskite Solar Cells90Sodium Doping-Enhanced Emission Efficiency and Stability of CsPbBr 3 Nanocrystals for White Light-Emitting Devices192Efficient Trap-Mediated Mn2+ Dopant Emission in Two Dimensional Single-Layered Perovskite (CH3CH2NH3)2PbBr481Ultrasonic synthesis of Mn-doped CsPbCl3 quantum dots (QDs) with enhanced photoluminescence20Synthesis of high-efficient Mn2+ doped CsPbCl3 perovskite nanocrystals in toluene and surprised lattice ejection of dopants at mild temperature8Spinodal Decomposition During Anion Exchange in Colloidal Mn2+-Doped CsPbX3 (X = Cl, Br) Perovskite Nanocrystals52Synthesis and optical properties of novel mixed‐metal cation CsPb 1− x Ti x Br 3 ‐based perovskite glasses for W‐LED14Assessment for Anion-Exchange Reaction in CsPbX3 (X = Cl, Br, I) Nanocrystals from Bond Strength of Inorganic Salt37Energetic hot electrons from exciton-to-hot electron upconversion in Mn-doped semiconductor nanocrystals25Band structure engineering in metal halide perovskite nanostructures for optoelectronic applications200Pink all-inorganic halide perovskite nanocrystals with adjustable characteristics: Fully reversible cation exchange, improving the stability of dopant emission and light-emitting diode application23Mechanochemical synthesis and characterization of Mn-doped CsPbCl3 perovskite nanocrystals14Cation-doping matters in caesium lead halide perovskite nanocrystals: from physicochemical fundamentals to optoelectronic applications57Doping and ion substitution in colloidal metal halide perovskite nanocrystals482First Synthesis of Mn-Doped Cesium Lead Bromide Perovskite Magic Sized Clusters at Room Temperature61Ligand Engineering for Mn2+ Doping Control in CsPbCl3 Perovskite Nanocrystals via a Quasi-Solid–Solid Cation Exchange Reaction71Fabrication and optimization of nanocube mixed halide perovskite films for solar cell application6Water triggered interfacial synthesis of highly luminescent CsPbX3:Mn2+ quantum dots from nonluminescent quantum dots54Ultrastable Lead-Free Double Perovskite Warm-White Light-Emitting Devices with a Lifetime above 1000 Hours89Enhanced Luminescence and Mechanistic Studies on Layered Double-Perovskite Phosphors: Cs 4 Cd 1– x Mn x Bi 2 Cl 1257Perovskite materials as superior and powerful platforms for energy conversion and storage applications202AB 11 O 16 (OH) 2 (A = K and Cs): interpenetrating 2D layers with large birefringence7Structural, paramagnetic centres and luminescence investigations of the UV radiation-emitting BaZrO3:Gd3+ perovskite ceramic prepared via sol-gel route13Metamorphoses of Cesium Lead Halide Nanocrystals57The mechanism of alkali doping in CsPbBr3: A first-principles perspective20Ion exchange for halide perovskite: From nanocrystal to bulk materials67Recent Advances in Ligand Design and Engineering in Lead Halide Perovskite Nanocrystals215State of the Art and Prospects for Halide Perovskite Nanocrystals1474Near-unity blue-orange dual-emitting Mn-doped perovskite nanocrystals with metal alloying for efficient white light-emitting diodes34Stability improvement of photoluminescent QLEDs based on Mn-doped all-inorganic metal halide perovskite quantum dots with silica shell26Structure‐Property Relationships and Idiosyncrasies of Bulk, 2D Hybrid Lead Bromide Perovskites25Defects and doping engineering towards high performance lead-free or lead-less perovskite solar cells62Aluminum chloride assisted synthesis of near-unity emitting Mn 2+ -doped CsPbCl 3 perovskite nanocrystals for bright white light-emitting diodes18Metal Halide Perovskite-Based Phosphors and Their Applications in LEDs3CsPbX3 (X = Cl, Br, I) perovskite quantum dots embedded in glasses: Recent advances and perspectives90Uncovering the Influence of Ni2+ Doping in Lead-Halide Perovskite Nanocrystals Using Optically Detected Magnetic Resonance Spectroscopy20Improvement of Photophysical Properties of CsPbBr3 and Mn2+:CsPb(Br,Cl)3 Perovskite Nanocrystals by Sr2+ Doping for White Light-Emitting Diodes29Systematic Microwave-Assisted Postsynthesis of Mn-Doped Cesium Lead Halide Perovskites with Improved Color-Tunable Luminescence and Stability15Ion-exchange controlled precipitation of CsPbX3 nanocrystals in glasses11Exciton Recombination versus Energy Transfer: Mapping Competing Excited-State Dynamics in Various Mn-Doped CsPb(Cl1–yBry)3 Perovskite Nanocrystals for Achieving White Light Emission23Recent Advances on Mn2+‐Doping in Diverse Metal Halide Perovskites66Structural and Optical Properties of SmFe0.8Mn0.2O3 Nanocrystallites1The role of oxygen defects in the electronic, optical and phonon dispersion of the LAGO perovskite: a density functional theory investigation8Designing stable lead halide perovskite nanocrystals: From a single particle to nanocomposites17Machine Learning-Directed Predictive Models: Deciphering Complex Energy Transfer in Mn-Doped CsPb(Cl 1– y Br y ) 3 Perovskite Nanocrystals21HPMC-Mediated ZnCl2 Doping Possible Substitution of Pb2+ for Environment-Friendly Halide Perovskite Solar Cell Fabrication2Color adjustable CsPbX3 (X=Cl, Br, I) perovskite quantum dots germanate glass15K, Rb-hydroxyborates series with deep-ultraviolet KRbB 5 O 8 (OH) possessing moderate second harmonic generation response0Manganese-enriched CsPbCl 3 perovskite nanocrystals for self-assembled supercrystals4Novel One-Dimensional Organic–Inorganic Hybrid Halide Perovskite Material with Coexistence of High Phase Transition Temperature and Corresponding Dielectric Response17Direct Evidence of the Effect of Water Molecules Position in the Spectroscopy, Dynamics, and Lighting Performance of an Eco‐Friendly Mn‐Based Organic–Inorganic Metal Halide Material for High‐Performance LEDs and Solvent Vapor Sensing16Tackling toxicity and stability using eco-friendly metal-halide ion substituted perovskite nanocrystals for advanced display color conversion11Multicolor luminescence of Eu3+/Tm3+ co-doped CsPbBr3 quantum dots phosphate glass by mechanical crystallization5Surface Defect Recovery in Perovskite Nanocrystals with Excess Halide for Core–Shell Structure26Environmentally-Friendly Europium-Based Yellow Perovskite Nanocrystals with Near-Unit Efficiency for White LED3Cation doping engineering of metal halide perovskites for high-energy X-ray exploration14Preparation and properties of highly stabilized CsPbX3 (X = Cl, Br, I) by liquid phase molten salt method1

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