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RESEARCH PAPER · Chemistry of Materials · 2017

Semiconducting Pavonites CdMBi4Se8 (M = Sn and Pb) and Their Thermoelectric Properties

Jing Zhao, Saiful M. Islam, Shiqiang Hao, Gangjian Tan, Xianli Su, Haijie Chen, Wenwen Lin, Rukang K. Li, Chris M. Wolverton, Mercouri G. Kanatzidis

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Semiconducting Pavonites CdMBi4Se8 (M = Sn and Pb) and Their Thermoelectric PropertiesOriginalNa 3 Ca 4 (TeO 3 )(PO 4 ) 3 : a new noncentrosymmetric tellurite phosphate with fascinating multimember-ring architectures and intriguing nonlinear optical performance30Quaternary Chalcogenide Semiconductors with 2D Structures: Rb2ZnBi2Se5 and Cs6Cd2Bi8Te1712Thermoelectric Material SnPb2Bi2S6: The 4,4L Member of Lillianite Homologous Series with Low Lattice Thermal Conductivity12Syntheses, structures, optical properties, and electronic structures of Ba6Cu2GSn4S16 (G = Fe, Ni) and Sr6D2FeSn4S16 (D = Cu, Ag)9Six Quaternary Chalcogenides of the Pavonite Homologous Series with Ultralow Lattice Thermal Conductivity42Computational strategies for design and discovery of nanostructured thermoelectrics68Pavonite homologues as potential n-type thermoelectric materials: crystal structure and performance16Ultralow thermal conductivity through the interplay of composition and disorder between thick and thin layers of makovickyite structure9Slowing down the heat in thermoelectrics128Quasi-layered Crystal Structure Coupled with Point Defects Leading to Ultralow Lattice Thermal Conductivity in n-Type Cu2.83Bi10Se167Key properties of inorganic thermoelectric materials—tables (version 1)127A promising thermoelectrics In4SnSe4 with a wide bandgap and cubic structure composited by layered SnSe and In4Se324Synthesis and Characterization of New Multinary Selenides A10B18Se37 (A=Sn/Pb; B=In/Sb/Bi)3Incompletely Decomposed In4SnSe4 Leads to High‐Ranged Thermoelectric Performance in n‐Type PbTe27Synthesis and characterization of new homologue multinary selenides, M2Sb5Bi5Se17 (M = Sn, Pb)2Conductivity, thermoelectric, and magnetic properties of pavonite homologue In0.45Mn2.17Bi3.38Se8 with N = 34New thermoelectric semiconductors Pb5Sb12+Bi6−Se32 with ultralow thermal conductivity6Ultralow Thermal Conductivity of a Chalcogenide System Pt3Bi4Q9 (Q = S, Se) Driven by the Hierarchy of Rigid [Pt6Q12]12– Clusters Embedded in Soft Bi-Q Sublattice11Crystal Structure and Thermoelectric Properties of Pavonite Homologous Pb4Sb12–xBi8+xSe3494P-Pavonite-type Cu1.8Sb5.4Se9: A potential one-dimensional copper ion conductor0Pavonite Homologous CdAg2.5Sb6.5Se12 as a Promising Thermoelectric Compound2Self-assembled bulk nanostructured Bi2Se3/CdSe heterojunction synthesized by a single step spinodal decomposition of Bi2.4Cd0.8Se4.40Lead-free SnTe thermoelectrics: Materials design, device engineering, and sustainable energy perspectives1Exceptional Thermoelectric Performance of Naturally High‐Entropy Pavonite Ag 3 Pb 4 Bi 11 Se 22 with Unique Quasi‐Superlattice Structure and Sextuple Conduction Valleys5Rational Design of Multi-Polyhedral Units-Induced Hybrid Bonding and Quadruple-Valley Band Structure in Ag 0.5 CdBi 4.5 Se 8 for Enhanced Thermoelectric Performance4

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  1. Na 3 Ca 4 (TeO 3 )(PO 4 ) 3 : a new noncentrosymmetric tellurite phosphate with fascinating multimember-ring architectures and intriguing nonlinear optical performance

    Dalton Transactions · 2018-01-01

    Zhuang Li, Shengzi Zhang, Wenlong Yin, Zheshuai Lin, Jiyong Yao, Yicheng Wu

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  2. Quaternary Chalcogenide Semiconductors with 2D Structures: Rb2ZnBi2Se5 and Cs6Cd2Bi8Te17

    Inorganic Chemistry · 2018-07-16

    Jing Zhao, Shiqiang Hao, Saiful M. Islam, Haijie Chen, Shulan Ma, Chris M. Wolverton, Mercouri G. Kanatzidis

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  3. Thermoelectric Material SnPb2Bi2S6: The 4,4L Member of Lillianite Homologous Series with Low Lattice Thermal Conductivity

    Inorganic Chemistry · 2018-12-31

    Jingpeng Li, Yiming Zhou, Shiqiang Hao, Tianyan Zhang, Chris M. Wolverton, Jing Zhao, Li‐Dong Zhao

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  4. Syntheses, structures, optical properties, and electronic structures of Ba6Cu2GSn4S16 (G = Fe, Ni) and Sr6D2FeSn4S16 (D = Cu, Ag)

    Journal of Solid State Chemistry · 2019-01-29

    Ling‐Yun Zhang, Dajiang Mei, Yuanwang Wu, Chenfei Shen, Wenxin Hu, Lujia Zhang, Jinjin Li, Yuandong Wu, Xiao Dong He

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  5. Six Quaternary Chalcogenides of the Pavonite Homologous Series with Ultralow Lattice Thermal Conductivity

    Chemistry of Materials · 2019-04-09

    Jing Zhao, Shiqiang Hao, Saiful M. Islam, Haijie Chen, Gangjian Tan, Shulan Ma, Christopher Wolverton, Mercouri G. Kanatzidis

    Read original paper ↗ ·

  6. Computational strategies for design and discovery of nanostructured thermoelectrics

    npj Computational Materials · 2019-05-14

    Shiqiang Hao, Vinayak P. Dravid, Mercouri G. Kanatzidis, Christopher Wolverton

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  7. Pavonite homologues as potential n-type thermoelectric materials: crystal structure and performance

    Materials Chemistry Frontiers · 2020-11-16

    Shangqing Qu, Jing Wei Zhao, Zimin Jiang, Dequan Jiang, Yonggang Wang

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  8. Ultralow thermal conductivity through the interplay of composition and disorder between thick and thin layers of makovickyite structure

    Journal of Materials Chemistry C · 2021-01-01

    Srikanth Balijapelly, Ashlee K. Hauble, Mathew Pollard, Morgane Poupon, Václav Petříček, Jeremy Watts, Y. S. Hor, Susan M. Kauzlarich, Amitava Choudhury

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  9. Slowing down the heat in thermoelectrics

    InfoMat · 2021-06-15

    Bingchao Qin, Dongyang Wang, Li‐Dong Zhao

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  10. Quasi-layered Crystal Structure Coupled with Point Defects Leading to Ultralow Lattice Thermal Conductivity in n-Type Cu2.83Bi10Se16

    ACS Applied Energy Materials · 2021-10-13

    Zhengyang Ye, Wanyue Peng, Fei Wang, Ashiwini Balodhi, Rabindra Basnet, Jin Hu, Alexandra Zevalkink, Jian Wang

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  11. Key properties of inorganic thermoelectric materials—tables (version 1)

    Journal of Physics Energy · 2022-01-10

    Robert Freer, Dursun Ekren, Tanmoy Ghosh, Kanishka Biswas, Pengfei Qiu, Shun Wan, Lidong Chen, Shen Han, Chenguang Fu, Tiejun Zhu, A. K. M. Ashiquzzaman Shawon, Alexandra Zevalkink, Kazuki Imasato, Gerald Jeffrey Snyder, Melis Özen, Kıvanç Sağlık, Umut Aydemir, Raúl Cardoso‐Gil, Eteri Svanidze, Ryoji Funahashi, Anthony V. Powell, Shriparna Mukherjee, Sahil Tippireddy, Paz Vaqueiro, Franck Gascoin, Theodora Kyratsi, Philipp Sauerschnig, Takao Mori

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  12. A promising thermoelectrics In4SnSe4 with a wide bandgap and cubic structure composited by layered SnSe and In4Se3

    Journal of Materiomics · 2022-03-23

    Haonan Shi, Changrong Guo, Bingchao Qin, Guangtao Wang, Dongyang Wang, Li‐Dong Zhao

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  13. Synthesis and Characterization of New Multinary Selenides A10B18Se37 (A=Sn/Pb; B=In/Sb/Bi)

    European Journal of Inorganic Chemistry · 2022-09-08

    Guan‐Ruei Chen, Gang Lin, Kuei‐Bo Chen, Ming‐Fang Wang, Chi‐Shen Lee

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  14. Incompletely Decomposed In4SnSe4 Leads to High‐Ranged Thermoelectric Performance in n‐Type PbTe

    Advanced Energy Materials · 2022-09-11

    Haonan Shi, Yongxin Qin, Bingchao Qin, Lizhong Su, Yuping Wang, Yongjin Chen, Xiang Gao, Hao Liang, Zhen‐Hua Ge, Tao Hong, Li‐Dong Zhao

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  15. Synthesis and characterization of new homologue multinary selenides, M2Sb5Bi5Se17 (M = Sn, Pb)

    Journal of the Chinese Chemical Society · 2023-04-15

    Wan‐Zhen Xiao, Chia‐Wei Yang, Chi‐Shen Lee

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  16. Conductivity, thermoelectric, and magnetic properties of pavonite homologue In0.45Mn2.17Bi3.38Se8 with N = 3

    Journal of Alloys and Compounds · 2023-06-15

    Shangqing Qu, Jinhao Chen, Jikun Chen, Guohong Cai, Yonggang Wang, Zhongnan Guo, Jing Wei Zhao, Quanlin Liu

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  17. New thermoelectric semiconductors Pb5Sb12+Bi6−Se32 with ultralow thermal conductivity

    Chinese Journal of Structural Chemistry · 2024-03-01

    Ruizhi Yang, Xia Li, Weiping Guo, Zixuan Chen, Hongwei Ming, Zhong‐Zhen Luo, Zhigang Zou

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  18. Ultralow Thermal Conductivity of a Chalcogenide System Pt3Bi4Q9 (Q = S, Se) Driven by the Hierarchy of Rigid [Pt6Q12]12– Clusters Embedded in Soft Bi-Q Sublattice

    Journal of the American Chemical Society · 2024-03-06

    Ruiqi Wang, Fei Liang, Xian Zhang, Chendong Zhao, Yuqiang Fang, Chong Zheng, Fuqiang Huang

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  19. Crystal Structure and Thermoelectric Properties of Pavonite Homologous Pb4Sb12–xBi8+xSe34

    ACS Applied Energy Materials · 2024-05-28

    Ruizhi Yang, Xia Li, Hongwei Ming, Weiping Guo, Zixuan Chen, Hong‐Hua Cui, Zhong‐Zhen Luo, Zhigang Zou

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  20. 4P-Pavonite-type Cu1.8Sb5.4Se9: A potential one-dimensional copper ion conductor

    Journal of Alloys and Compounds · 2025-01-07

    Stefan Schwarzmüller, Maximilian Amsler, Stefan Goedecker, Hubert Huppertz

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  21. Pavonite Homologous CdAg2.5Sb6.5Se12 as a Promising Thermoelectric Compound

    ACS Applied Energy Materials · 2025-02-26

    Bowen Jin, Chenghao Xie, Yicheng Wang, Rongcheng Li, Chengyun Liao, Zhengjie Liu, Xinfeng Tang, Gangjian Tan

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  22. Self-assembled bulk nanostructured Bi2Se3/CdSe heterojunction synthesized by a single step spinodal decomposition of Bi2.4Cd0.8Se4.4

    SSRN Electronic Journal · 2026-01-01

    Zipporah Rini Benher, Sandra Gardonio, Mattia Fanetti, Thanveer Thajudheen, Blaž Belec, Saúl Estandía, V. Tileli, Polina Makarovna Sheverdyaeva, Paolo Moras, Marco Bianchi, Matjaž Valant

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  23. Lead-free SnTe thermoelectrics: Materials design, device engineering, and sustainable energy perspectives

    Sustainable materials and technologies · 2026-01-09

    U. Rehman, Kashaf Ul Sahar, Chun‐Ming Wang

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  24. Exceptional Thermoelectric Performance of Naturally High‐Entropy Pavonite Ag 3 Pb 4 Bi 11 Se 22 with Unique Quasi‐Superlattice Structure and Sextuple Conduction Valleys

    Advanced Energy Materials · 2026-02-10

    Zhengjie Liu, Pengcheng Luo, Chengyun Liao, Chenghao Xie, Minghao Ye, Weibin Xu, Zhiying Liu, Junxi Mei, Guoqing Ding, Qingjie Zhang, Xinfeng Tang, Gangjian Tan

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  25. Rational Design of Multi-Polyhedral Units-Induced Hybrid Bonding and Quadruple-Valley Band Structure in Ag 0.5 CdBi 4.5 Se 8 for Enhanced Thermoelectric Performance

    Journal of the American Chemical Society · 2026-04-27

    Chengyun Liao, Weiping Guo, Zhengjie Liu, Qicai Mei, Chenghao Xie, Dengkai Huang, Zhongzhen Luo, Qi Zhang, Xinfeng Tang, Gangjian Tan

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