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RESEARCH PAPER · Inorganic Chemistry Frontiers · 2024

From BaAlBO 3 F 2 to BaAlB 3 O 6 F 2 and BaAl 2 (B 3 O 6 ) 2 F 2 : the enhancement of birefringence and band gap by extending the π-conjugated system combined with [Al–O/F] functional groups

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From BaAlBO 3 F 2 to BaAlB 3 O 6 F 2 and BaAl 2 (B 3 O 6 ) 2 F 2 : the enhancement of birefringence and band gap by extending the π-conjugated system combined with [Al–O/F] functional groupsOriginalCoordinated assembly of alkali and alkaline earth metals with the perfluorinated [AlF 6 ] group to design deep-ultraviolet zero-order waveplate materials2Synthesising a series of promising ultraviolet nonlinear optical materials with the aid of the flexibility of isolated [B 5 O 10 ] groups3Designed Metal‐Free Quasi‐1D Crystals with Giant Birefringence8[C( NH2 )3] 2SiF6 : Design of Deep Ultraviolet Crystals with Large Birefringence Based on a Fluorination‐Oriented Strategy13Design, Synthesis, and Improvement of Nonlinear Optical Properties from Aluminophosphite to Aluminophosphate1Modulation of Crystal Structure and Birefringence: Cation Size Effect in Alkali Metal Fluoroaluminoborates4Rational Design of a Deep-Ultraviolet Nonlinear Optical Crystal25Achieving record-high birefringence in a 3D fluorozincoborate via coplanar alignment of π-conjugated [BO 3 ] units0Constructing Deep‐Ultraviolet Nonlinear Optical Crystals via Synergistic Combination of Fluorinated Polyhedra and Polymerized BO 3 Units15Peroxide‐Assisted Solvate Engineering Enables Record‐High Birefringence in a Solar‐Blind Transparent Crystal0Peroxide‐Assisted Solvate Engineering Enables Record‐High Birefringence in a Solar‐Blind Transparent Crystal0Decoupling Contributions of Distinct Strategies for Enhancing Polarizability Anisotropy in Crystals Containing π-Conjugated Groups0MAlB3O6F2 (M = Ca and Pb): Two New Fluoroaluminoborates Featuring π-Conjugated [BO3] and [AlO4F2] Units with Large Birefringence0

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  1. Coordinated assembly of alkali and alkaline earth metals with the perfluorinated [AlF 6 ] group to design deep-ultraviolet zero-order waveplate materials

    Dalton Transactions · 2025-01-01

    Shaohua Liu, Lili Zhang, Ke Li, Xiaotian Ma, Xifa Long, Yun Mo Yang

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  2. Synthesising a series of promising ultraviolet nonlinear optical materials with the aid of the flexibility of isolated [B 5 O 10 ] groups

    Dalton Transactions · 2025-01-01

    Yixin Song, Hongwei Yu, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  3. Designed Metal‐Free Quasi‐1D Crystals with Giant Birefringence

    Chemistry - A European Journal · 2025-04-07

    Yang Li, Jihyun Lee, Kang Min Ok

    Read original paper ↗ ·
  4. [C( NH2 )3] 2SiF6 : Design of Deep Ultraviolet Crystals with Large Birefringence Based on a Fluorination‐Oriented Strategy

    Chinese Journal of Chemistry · 2025-06-24

    Shaohua Liu, Xiaoqin Ma, Xifa Long, Yun Mo Yang

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  5. Design, Synthesis, and Improvement of Nonlinear Optical Properties from Aluminophosphite to Aluminophosphate

    Inorganic Chemistry · 2025-06-27

    Yucheng Hao, Changlin Chen, Cheng Hou, Xi Zhao, Yuan Hua Lin, Rongfang Zhang, Hongdian Lu, Kunhong Hu, Wei Cheng, Mingli Liang

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  6. Modulation of Crystal Structure and Birefringence: Cation Size Effect in Alkali Metal Fluoroaluminoborates

    Inorganic Chemistry · 2025-08-02

    Chao Wei, Danyang Dou, Bingbing Zhang, Ying Wang

    Read original paper ↗ ·
  7. Rational Design of a Deep-Ultraviolet Nonlinear Optical Crystal

    Journal of the American Chemical Society · 2025-08-26

    Haonan Liu, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

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  8. Achieving record-high birefringence in a 3D fluorozincoborate via coplanar alignment of π-conjugated [BO 3 ] units

    Inorganic Chemistry Frontiers · 2026-01-01

    Yucheng Hao, Qiuhui Zhang, Haoran Yu, Xikai Miu, Simin Cai, Xinnan Li, Fengshan Yu, Yuan Lin, Mingyang Cao

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  9. Constructing Deep‐Ultraviolet Nonlinear Optical Crystals via Synergistic Combination of Fluorinated Polyhedra and Polymerized BO 3 Units

    Advanced Functional Materials · 2026-01-10

    Hongkang Su, chenxu li, Jiahao Jiao, Zhihua Yang, Shilie Pan, Min Zhang

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  10. Peroxide‐Assisted Solvate Engineering Enables Record‐High Birefringence in a Solar‐Blind Transparent Crystal

    Angewandte Chemie International Edition · 2026-06-22

    Yang Li, Congcong Jin, Kang Min Ok

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  11. Peroxide‐Assisted Solvate Engineering Enables Record‐High Birefringence in a Solar‐Blind Transparent Crystal

    Angewandte Chemie · 2026-06-22

    Yang Li, Congcong Jin, Kang Min Ok

    Read original paper ↗ ·
  12. Decoupling Contributions of Distinct Strategies for Enhancing Polarizability Anisotropy in Crystals Containing π-Conjugated Groups

    Inorganic Chemistry · 2026-08-23

    Haoran Liu, Chenhui Hu, Xueli Du, Qingyu Liu, Xiaona Li, Zhihua Yang, Min Zhang

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  13. MAlB3O6F2 (M = Ca and Pb): Two New Fluoroaluminoborates Featuring π-Conjugated [BO3] and [AlO4F2] Units with Large Birefringence

    Crystal Growth & Design · 2026-10-02

    Yaozu Li, Chao Wei, Wenjing Zhang, Huiyi Zhang, Bo Zhao, Bingbing Zhang, Ying Wang

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