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RESEARCH PAPER · Chemistry of Materials · 2017

Influence of Anion/Cation Substitution (Sr2+ → Ba2+, Al3+ → Si4+, N3– → O2–) on Phase Transformation and Luminescence Properties of Ba3Si6O15:Eu2+ Phosphors

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Influence of Anion/Cation Substitution (Sr2+ → Ba2+, Al3+ → Si4+, N3– → O2–) on Phase Transformation and Luminescence Properties of Ba3Si6O15:Eu2+ PhosphorsOriginalA broad-band orange-yellow-emitting Lu 2 Mg 2 Al 2 Si 2 O 12 : Ce 3+ phosphor for application in warm white light-emitting diodes56Improvement of thermal stability and photoluminescence in Sr 0.8 Ca 0.2 Al 2 Si 2 O 8 :Eu 2+ by the substitution of Si–Na # Al–Sr and Ca # Sr for structural modifications16The design and synthesis of new double perovskite (Na,Li)YMg(W,Mo)O 6 :Eu 3+ red phosphors for white light-emitting diodes108The Inductive Effect of Neighboring Cations in Tuning Luminescence Properties of the Solid Solution Phosphors33Valence transfer of Eu3+ activated in Yb2Si2O7 phosphors: Luminescence and self reduction17Fabrication of Bi3+/Ln3+:LuVO4 (Ln = Eu, Sm, Dy, Ho) nanophosphors and its color-tunable optical performance17Photoluminescence of Eu2+, Ce3+ and Tb3+ in a new potassium barium phosphate K2Ba3(P2O7)2 host lattice23Orange emission of Sm 3+ in a double phosphate KMgLa(PO 4 ) 2 under near-ultraviolet excitation15Photoluminescence properties of a double perovskite tungstate based red-emitting phosphor NaLaMgWO6:Sm3+70Novel highly efficient single-component multi-peak emitting aluminosilicate phosphors co-activated with Ce 3+ , Tb 3+ and Eu 2+ : luminescence properties, tunable color, and thermal properties50NaLaMgWO6:Pr3+: A novel blue-light excitable red-emitting phosphor for white light-emitting diodes51Broad color tuning of Bi 3+ /Eu 3+ -doped (Ba,Sr) 3 Sc 4 O 9 solid solution compounds via crystal field modulation and energy transfer107Cation vacancy repair for the enhancement of orange-yellow luminescence in Sr 9 Mg 1.5−x K x (PO 4 ) 7 :Eu 2+ phosphors46Controllable optical tuning and improvement in Li + ,Eu 3+ -codoped BaSc 2 O 4 :Bi 3+ based on energy transfer and charge compensation96Controllable two-dimensional luminescence tuning in Eu 2+ ,Mn 2+ doped (Ca,Sr) 9 Sc(PO 4 ) 7 based on crystal field regulation and energy transfer61Efficient green phosphor realized by Ce 3+ →Tb 3+ energy transfer in Li 3 Sc 2 (PO 4 ) 3 for ultraviolet white light-emitting diodes45Electronic structure and photoluminescence properties of single component white emitting Sr 3 LuNa(PO 4 ) 3 F:Eu 2+ ,Mn 2+ phosphor for WLEDs53Exploring the optical properties of La 2 Hf 2 O 7 :Pr 3+ nanoparticles under UV and X-ray excitation for potential lighting and scintillating applications63Highly Efficient Blue Emission and Superior Thermal Stability of BaAl 12 O 19 :Eu 2+ Phosphors Based on Highly Symmetric Crystal Structure388On the origin of temperature dependence of the emission maxima of Eu2+and Ce3+- activated phosphors40Synthesis and luminescence properties of Sr2−xY x Si5−xAl x N8:Eu2+ red phosphor for white light-emitting diodes5White Light Emission and Enhanced Color Stability in a Single-Component Host161New design of highly sensitive and selective MoO3:Eu3+ micro-rods: Probing of latent fingerprints visualization and anti-counterfeiting applications83Color tunable Ba3Lu(PO4)3:Tb3+,Mn2+ phosphor via Tb3+→Mn2+ energy transfer for white LEDs13The Vis-NIR multicolor emitting phosphor Ba4Gd3Na3(PO4)6F2: Eu2+, Pr3+ for LED towards plant growth44Full Color Luminescence Tuning in Bi 3+ /Eu 3+ -Doped LiCa 3 MgV 3 O 12 Garnet Phosphors Based on Local Lattice Distortion and Multiple Energy Transfers112Luminescence Tuning of Sr8MgCe(PO4)7:Eu2+,Mn2+ Phosphors: Structure Refinement, Site Occupancy, and Energy Transfer8Al-doping effects on mechanical, optical and scintillation properties of Ce:(La,Gd)2Si2O7 single crystals4Preferential Neighboring Substitution-Triggered Full Visible Spectrum Emission in Single-Phased Ca10.5–xMgx(PO4)7:Eu2+ Phosphors for High Color-Rendering White LEDs122Layered Structure Produced Nonconcentration Quenching in a Novel Eu3+-Doped Phosphor185Enhancement of the up-conversion luminescence in LaVO4 nanomaterials by doping with M2+, M4+ (M2+ = Sr2+, Ba2+, Mg2+; M4+ = Sn4+) ions27Synthesis and red emitting properties of NaAlP2O7:Pr3+ polycrystal for blue chip-excited WLEDS15Electronic structure and luminescent properties of Ce3+-doped Ba3Lu2B6O15, a high-efficient blue-emitting phosphor33A novel blue-emitting Eu 2+ -doped chlorine silicate phosphor with a narrow band for illumination and displays: structure and luminescence properties23An ultra-high yield of spherical K 2 NaScF 6 :Mn 4+ red phosphor and its application in ultra-wide color gamut liquid crystal displays95Luminescence color tuning and energy transfer properties in (Sr,Ba) 2 LaGaO 5 :Bi 3+ ,Eu 3+ solid solution phosphors: realization of single-phased white emission for WLEDs107Nitride-Doped Sr4Al14O25:Eu2+ Phosphor with Improved Photoluminescence and Long Afterglow9Structural design of new Ce 3+ /Eu 2+ -doped or co-doped phosphors with excellent thermal stabilities for WLEDs133Synthesis, luminescence and application of novel europium, cerium and terbium-doped apatite phosphors32Discovery of New Narrow‐Band Phosphors with the UCr 4 C 4 ‐Related Type Structure by Alkali Cation Effect137First-principles calculation of influence of nitrogen substituting for oxygen on the crystal structures and electronic band structures of Sr3MgSi2O8-σNσ5Unraveling the Mechanisms of Thermal Quenching of Luminescence in Ce3+-Doped Garnet Phosphors238NaKLaNbO5:Eu3+: A highly efficient and thermally stable orange-red emitting phosphor for white light-emitting diodes24Prevailing Strategies to Tune Emission Color of Lanthanide‐Activated Phosphors for WLED Applications278Facile fabrication of thermal stable Eu(HCOO)3 red-emitting crystals with high color purity for near-ultraviolet chip triggered white light-emitting diodes17Realization of color-tunable emission via energy transfer in novel single-phase K3YB6O12:Bi3+, Eu3+ phosphors2Site occupancy and tunable photoluminescence properties of Eu2+-Activated Ba3Sc(BO3)3 phosphors for white light emitting diodes33A narrow-band ultra-bright green phosphor for LED-based applications30Combining experiment and computation to elucidate the optical properties of Ce 3+ in Ba 5 Si 8 O 2113Luminescence properties and energy transfer of novel Bi 3+ and Mn 2+ -co-activated Y 3 Ga 5 O 12 single-component white light-emitting phosphor54Multiple Substitution Strategies toward Tunable Luminescence in Lu2MgAl4SiO12:Eu2+ Phosphors90Multisite-Occupancy-Driven Intense Narrow-Band Blue Emission from Sr 5 SiO 4 Cl 6 :Eu 2+ Phosphor with Excellent Stability and Color Performance69Tuning the luminescence properties of Mn 4+ ‐activated CaYAlO 4 phosphor by co‐doping cations for indoor plant cultivation27Synthesis and photoluminescence tuning of (Sr,Ln)9Mg1.5(PO4)7 phosphors by Ln (Ln = Y, La, Gd, Lu) substitution11Eu3+, Sm3+ Deep‐Red Phosphors as Novel Materials for White Light‐Emitting Diodes and Simultaneous Performance Enhancement of Organic–Inorganic Perovskite Solar Cells84Photoluminescence properties and energy transfer of high thermal stable Na2GdPO4F2:RE (RE = Sm3+, Ce3+, Tb3+) phosphor for solid-state lighting21Recent Advances in Bismuth Ion‐Doped Phosphor Materials: Structure Design, Tunable Photoluminescence Properties, and Application in White LEDs363Lanthanide spectroscopy in probing structure-property correlation in multi-site photoluminescent phosphors161A novel thermally stable eulytite-type NaBaBi2(PO4)3:Eu3+ red-emitting phosphor for pc-WLEDs104Manipulating the redistribution of single dopant via crystal-site engineering approach in Ba4Gd3(K1-xNax)3(PO4)6F2:Eu2+ phosphors for warm white light emitting diodes45Luminescence property improvement and controllable color regulation of a novel Bi 3+ doped Ca 2 Ta 2 O 7 green phosphor through charge compensation engineering and energy transfer19Structure, luminescence of Eu 2+ and Eu 3+ in CaMgSi 2 O 6 and their co-existence for the excitation-wavelength/temperature driven colour evolution32Local structure modification for identifying the site preference and characteristic luminescence property of Eu2+ ions in full-color emission phosphors Sr18Mg3(PO4)14:Eu2+23Single phase white LED phosphor Ca3YAl3B4O15:Ce3+,Tb3+,Sm3+ with superior performance: Color-tunable and energy transfer study183The composition engineering of red‐emitting Eu 3+ ‐doped Ca 10.5 (PO 4 ) 7 ‐type solid solution phosphors and application in LED11Effect of Al3+ on the spectroscopic properties of Eu2+- and Tb3+-Doped high silica glass11Double-site Eu3+ occupation in the langbeinite-type phosphate phosphor toward adjustable emission for pc-WLEDs28First principles calculation of enhanced absorptions of Sr3MgSi2O8-δSδ in UV region induced by sulfide ions substituting for oxygen ions6A promising novel red-emitting Eu3+-activated neodymium calcium phosphate phosphor with good thermal stability and excellent color purity for WLEDs37Robust thermal performance of red-emitting phosphor composites for white light-emitting diodes: Energy transfer and oxygen-vacancy induced electronic localization43Rapid Synthesis of Red‐Emitting Sr2Sc0.5Ga1.5O5:Eu2+ Phosphors and the Tunable Photoluminescence Via Sr/Ba Substitution90Equivalent cation substitution-triggered highly efficient Mn4+ red emission in double-perovskite type (Ba, Sr)2(Gd, La, Y, Lu)(Nb, Sb)O6:Mn4+ solid solution phosphors and photophysical studies62A novel Eu-dependent G-La2Si2O7 single matrix phosphor for white light-emitting diodes2Advances in Near-Infrared Luminescent Materials without Cr3+: Crystal Structure Design, Luminescence Properties, and Applications171Ultra-wideband phosphor Mg2Gd8(SiO4)6O2:Ce3+,Mn2+: Energy transfer and pressure-driven color tuning for potential applications in LEDs and pressure sensors79Tunable photoluminescence and temperature sensing properties of Ce3+, Eu2+ co-doped Ca2-Sr MgSi2O7 phosphors11Giant Red‐Shifted Emission in (Sr,Ba)Y 2 O 4 :Eu 2+ Phosphor Toward Broadband Near‐Infrared Luminescence230Extension of Spectral Shift Controls from Equivalent Substitution to an Energy Migration Model Based on Eu2+/Tb3+-Activated Ba4–xSrxGd3–xLuxNa3(PO4)6F2 Phosphors11Enhancement of Eu2+ photoluminescence behavior in NaBaB9O15 based on the K+ doping13A novel single-phased white light emitting phosphor with single Eu2+ doped whitlockite structure24Charge compensation engineering for high-performance dolomite-type BaTi(BO 3 ) 2 :Eu 3+ red-emitting phosphor for backlight display applications with a wide color gamut15Tuning of the thermal quenching performance of Bi 3+ -doped scheelite Ca(Mo/W)O 4 solid solution phosphors13Sn4+ induced Bi3+ multi-lattice selective occupation and its color-tunable emission of La2MgZrO6: Bi3+, Sn4+ double perovskite phosphors24Green-emitting Bi3+-doped La2SrSc2O7 phosphor for pc-WLED lighting: Luminescent properties and energy transfer strategy50Effect of Al3+ on the photoluminescence and radioluminescence properties of Mn2+-Doped high silica glass11Luminescent ionic lattice occupation and wide tunable emission spectra of La2MgZrO6:Bi3+,Eu3+ double perovskite phosphors for white light LED41Highly Efficient Broad-Band Green-Emitting Cerium(III)-Activated Garnet Phosphor Allows the Fabrication of Blue-Chip-Based Warm-White LED Device with a Superior Color Rendering Index69A high quantum yield red phosphor NaGdSiO4: Eu3+ with intense emissions from the 5D0→7F1,2 transition44Local structure distortion enhanced the emission intensity of KBaYSi2O7:Eu2+ phosphor for full-visible-spectrum LED lighting4Band structure, photoluminescent properties, and energy transfer behavior of a multicolor tunable phosphor K3Lu(PO4)2: Tb3+, Eu3+ for warm white light-emitting diodes26Sr-substitution-guided Eu2+ site engineering of Ca9Nd(PO4)7:Eu2+ for high-efficiency white light-emitting diodes9A Zero-Thermal-Quenching Blue Phosphor for Sustainable and Human-Centric WLED Lighting130Ultra‐Broadband Green‐Emitting Phosphors without Cyan Gap Based on Double‐Heterovalent Substitution Strategy for Full‐Spectrum WLED Lighting89Environment-Dependent Eu2+-Activated Ba3CaK(PO4)3 toward White-Light Emission by Chemical Cosubstitution of the (BO3)3– Anion Group19Investigation into the photoluminescence and energy levels in bismuth-doped Sr3MgSi2O8 through first principles calculations1Ionic selective occupation, lattice modulation and photoluminescence properties of garnet typed orange-yellow phosphors for white-light-emitting diodes7A novel efficient red-emitting K7SrY2B15O30: Eu3+ phosphor with non-concentration quenching and robust thermal stability for white LEDs26A novel extra-broadband visible-NIR phosphor doped with Ce3+ and Cr3+ towards multifunctional advanced applications20Recent development in color tunable phosphors: A review205A novel narrow-band blue-emitting phosphor with high efficiency and thermal stability for WLEDs and FEDs31Ceramics phosphor powders4Non-concentration quenching and energy transfer enhanced green emission in Ca 8 SrGd(PO 4 ) 7 :Eu 2+ ,Tb 3+ for near-UV white LEDs with a high color rendering index20Eu3+‐activated red phosphor Ca3YAl3B4O15 with low thermal quenching behaviour8Simultaneous realization of tunable luminescence and enhanced thermal stability in Eu2+-based blue-green phosphors for multifunctional applications16Enhancement of Scintillation Properties of LYSO:Ce Crystals by Al Codoping31Cation substitution induced highly symmetric crystal structure in cyan-green-emitting Ca2La1-xLuxHf2Al3O12:Ce3+ solid-solution phosphors with enhanced photoluminescence emission and thermal stability: Toward full-visible-spectrum white LEDs41Site regulation and luminescence properties of Eu3+, Eu2+ in (La, Mg):SrAl12O19 matrix6Calibration of local chemical pressure by optical probe12Regulation of Bi3+ emission in Ca3Ga4O9 phosphors through doping concentration and solid-solution component design15Visual Representation of the Stress Distribution with a Color‐Manipulated Mechanoluminescence of Fluoride for Structural Mechanics45Centimeter‐Sized Single Crystals of Tetrahedral Manganese (II) Halide Hybrids for Wide‐Color Gamut Backlighting Displays33Highly Efficient Narrow-Band Green-Emitting Na 3 K 5 (Li 3 SiO 4 ) 8 :Eu 2+ Phosphor with Low Thermal Quenching49Achieving a Eu 2+ -doped NIR phosphor via ionic modulation and its multifunctional applications4Development of a novel Eu 2+ activated oxonitridosilicate cyan phosphor for enhancing the color quality of a violet-chip-based white LED9Multifunctional self-refrigerated multivariate {GdLn} (Ln = Dy, Tb, Tb/Eu) metal–organic frameworks16Bioimaging and prospects of night pearls‐based persistence phosphors in cancer diagnostics36Multicolor regulation of trivalent lanthanide ions-codoped boggildite-type phosphor toward superb warm white luminescence for white light-emitting diodes13Defect regulation of a distinctive synthetic Eu2+-doped SiAlON S-phase towards controllable spectra and thermal quenching for white-light-emitting diode17Study on a Highly Thermostable Dy 3+ -Activated Borophosphate Phosphor71One stone, two birds: Luminescence properties of Ca8ZnY(PO4)7:Eu2+, Mn2+ and multifunctional applications in WLEDs & optical anti-counterfeiting26Crystal Field Engineering Inducing Transformation from Narrow Band of Eu3+ to Broadband of Eu2+2Acid Post-Treatment Triggered High-Efficiency Blue-Emitting LiNa2Sr8B12O24F6Cl:Eu2+ Phosphors toward Multipurpose LED Applications0Review on advancements in white light phosphor matrices for energy-efficient lighting36Tuning the Luminescence Properties of Mn-Cr Codoped Sr2mgal22o36 Phosphors Via Ultrahigh Energy Transfer between Mn2+ and Cr3+ for Wled Applications0Site occupation engineering induced red-shifted luminescence in (Ca, Sr)Sc2O4:Eu2+ phosphor20Luminescence and structural insights of β-Ca2SiO4:Pr3+ Phosphor: Applications towards TL dosimetry and solid state lighting13Synthesis and multi-color emission properties of novel Na3KMg7(PO4)6: RE3+ (RE = Eu, Dy, Tb) phosphor for white LED and indoor plant growth7Stability enhancement and photoluminescence modulation in Ca3Al2O6:Ce3+ phosphor via ionic pair substitution strategy0Highly efficient Eu3+→Tb3+ energy transfer and colour tunable Y4Al2O9: Eu3+, Tb3+ nanophosphors: A promising material for concealed fingerprint analysis and solid-state lighting15Charge-space dual effects inducing Eu2 +-Ce3 + ions occupancy luminescence in NaSiAlO4 constructed by waste glass coupled aluminum air batteries byproduct Al(OH)32Synthesis, spectral, and thermal properties of K2CaP2O7:Sm3+ phosphors to fill the amber gap in LED applications10RETRACTED: DFT-supported design and multifunctional evaluation of Sm3+ doped Ca3WO6 nanophosphors for photoluminescence, forensics, and photocatalysis1Thermal‐Robust and Glass‐Compatible K 1.3 Al 9 Ga 2 O 17.15 :Eu for Laser‐Driven Lighting and Underwater Optical Communication3A novel Eu3+-Doped LiYMgWO6 red phosphor with high quantum efficiency for white LEDs and wide-gamut displays7Nitrogen-rich dicyandiamide-grafted graphene oxide catalyst for the synthesis of 1,2,5,6-tetrahydropyridine-3-carboxylates0Zn3-Mg (VO4)2 solid solution phosphor: Structural variation, photoluminescence performance regulation and WLEDs application1Towards a universal ansatz for heat-induced emission peak shifts: insights from M 2 SiO 4 :Eu 2+ (M = Sr, Ba, Ca) phosphors2A broadband cyan-emitting NaBa2Al(P2O7)2: Eu2+ phosphor for white light-emitting diodes0Tuning the luminescence properties of Mn-Cr codoped Sr2MgAl22O36 phosphors via ultrahigh energy transfer between Mn2+ and Cr3+ for WLED applications0Synthesis and luminescent properties of Eu2+-doped sodalite- and bystrite-type aluminosilicates: Implications for europium incorporation in feldspathoids0

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