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RESEARCH PAPER · Journal of Alloys and Compounds · 2017

The design and synthesis of new double perovskite (Na,Li)YMg(W,Mo)O 6 :Eu 3+ red phosphors for white light-emitting diodes

Yanjie Liang, Hyeon Mi Noh, Weiguang Ran, Sung Heum Park, Byung Chun Choi, Jung Hyun Jeong, Kwang Ho Kim

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The design and synthesis of new double perovskite (Na,Li)YMg(W,Mo)O 6 :Eu 3+ red phosphors for white light-emitting diodesOriginalEu 3+ -activated Na 2 Gd(PO 4 )(MoO 4 ): A novel high-brightness red-emitting phosphor with high color purity and quantum efficiency for white light-emitting diodes273Red-emitting double perovskite phosphors Sr1−xCaxLaMgSbO6:Eu3+: Luminescence improvement based on composition modulation31Valence transfer of Eu3+ activated in Yb2Si2O7 phosphors: Luminescence and self reduction17Synthesis and luminescence properties of new red phosphor YBiW2O9:Eu3+6Thermally stable double perovskite CaLaMgSbO6:Eu3+ phosphors as a tunable LED-phosphor material88Synthesis and luminescence properties of double perovskite Gd2MgTiO6:Eu3+ red phosphors for white light-emitting diodes11A novel double perovskite tellurate Eu3+-doped Sr2MgTeO6 red-emitting phosphor with high thermal stability108Phase diagrams for the M2MoO4–Ln2(MoO4)3–Hf(MoO4)2 systems, where M = Li–Cs, Tl and Ln = La–Lu5Facile synthesis and color-tunable properties of monodisperse β-NaYF 4 :Ln 3+ (Ln = Eu, Tb, Tm, Sm, Ho) microtubes19Concentration and thermal quenching of SrGdLiTeO6: Eu3+ red-emitting phosphor for white light-emitting diode4Far-red-emitting double-perovskite CaLaMgSbO 6 :Mn 4+ phosphors with high photoluminescence efficiency and thermal stability for indoor plant cultivation LEDs76Lu 3+ doping induced photoluminescence enhancement in novel high-efficiency Ba 3 Eu(BO 3 ) 3 red phosphors for near-UV-excited warm-white LEDs21Tune color of single-phase LiGd(MoO 4 ) 2-X (WO 4 ) X : Sm 3+ , Tb 3+ via adjusting the proportion of matrix and energy transfer to create white-light phosphor18Crystal structure, electronic structure and photoluminescence properties of KLaMgWO6:Eu3+ phosphors44Novel high-brightness and thermal-stable Ca 3 Gd(AlO) 3 (BO 3 ) 4 :Eu 3+ red phosphors with high colour purity for NUV-pumped white LEDs68Simple coating synthesis and enhanced luminescence behaviour of LiLa(MoO4)2:Eu3+@NaF7Synthesis and photoluminescence properties of red-emitting NaLaMgWO6:Sm3+,Eu3+ phosphors for white LED applications80Spectroscopic behavior, thermal stability and temperature sensitivity of Ca 2 SiO 4 : Eu 3+ red emitting phosphor for solid state lighting application69Molybdenum substitution simultaneously induced band structure modulation and luminescence enhancement in LiLaMg(W, Mo)O6: Eu3+ red-emitting phosphor for near ultraviolet excited white light diodes38Effects of Sm3+ on Luminescent Properties of LiEu(0.55-x)Y0.45 (WO4)2Smx Red Phosphor2Synthesis and Luminescent Properties of LiEu(0.50-x)Gd0.50 (WO4)2Smx Red Phosphor1Luminescent properties, energy transfer, and thermal stability of double perovskites La2MgTiO6:Sm3+, Eu3+73Synthesis, energy transfer and photoluminescence properties of thermal-stable multicolour-emitting Ca3Gd(AlO)3(BO3)4:Tb3+,Eu3+ phosphors45Near-ultraviolet excited Eu3+ doped KSrY(BO3)2 phosphors for solid-state lighting: synthesis, structure and photoluminescent properties10High quantum efficiency red emitting α-phase La2W2O9:Eu3+ phosphor49Luminescence properties of Dy3+ or/and Sm3+ doped LiLa(WO4)2 phosphors and energy transfer from Dy3+ to Sm3+19Synthesis and photoluminescence properties of Ln3+ (Ln3+ = Sm3+/Eu3+) doped Na2NbAlO5 phosphors38Mn 4+ -activated Li 3 Mg 2 SbO 6 as an ultrabright fluoride-free red-emitting phosphor for warm white light-emitting diodes95Structure variation and luminescence enhancement of BaLaMg(Sb, Nb)O6:Eu3+ double perovskite red phosphors based on composition modulation29Ba3P4O13:Eu3+ phosphors with high thermal stability and high internal quantum efficiency for near-ultraviolet white light-emitting diodes13Eu3+ doped (Li, Na, K) LaMgWO6 red emission phosphors: An example to rational design with theoretical and experimental investigation43Novel high color-purity Eu3+-activated Ba3Lu4O9 red-emitting phosphors with high quantum efficiency and good thermal stability for warm white LEDs73Enhanced luminescence properties of Eu3+ activated CaGd2(WO4)4 red-emitting phosphors with Mo6+ doping9Investigation of photoluminescence properties, quenching mechanism and thermal stability of the red-emitting phosphor based on Eu ions doped apatite host NaLa9(SiO4)6O211Novel highly efficient and thermally stable Ca2GdTaO6:Eu3+ red-emitting phosphors with high color purity for UV/blue-excited WLEDs109Enhancement of zero phonon line for Na2TiF6:Mn4+, Li+ phosphors induced by Li+13High efficient Eu3+-activated Ca(La, Gd)MgSbO6 double perovskite phosphors: Thermal stability improvement by composition modulating13Synthesis and enhanced luminescence properties of double perovskite NaLa 0.95− x Y x Eu 0.05 MgWO 6 phosphors22Photoluminescence properties of a Dy3+, Na+-activated yafsoanite Ca3Zn3Te2O12 phosphor with excellent thermal stability6Luminescence properties of double perovskite Gd2MgTiO6:Tb3+ phosphors by solid-state reaction method7Novel luminescence enhancement and splitting of excitation and emission bands of Na2SiF6:Mn4+,Li+ phosphors induced by Li+ co-doping26Sol-gel synthesis, crystal structure and luminescence properties of Eu3+ doped double perovskite molybdates NaCaBi1−xEuxMoO6 (x = 0–0.27)4Expanding the Doubly Cation Ordered AA′BB′O6 Perovskite Family: Structural Complexity in NaLaInNbO6 and NaLaInTaO621Highly efficient and thermally stable CaMgLaSbO6:Mn4+ red phosphor for indoor plant growth17Luminescence properties, energy transfer and thermal stability of blue-green color tunable Sr3Y(BO3)3:Ce3+, Tb3+ phosphors281550 nm pumped upconversion chromaticity modulation in Er3+ doped double perovskite LiYMgWO6 for anti-counterfeiting107Combustion synthesis of Eu3+ doped Al4B2O9 phosphor for light emitting diode19Fast synthesis of Dy 3+ and Tm 3+ co-doped double perovskite NaLaMgWO 6 : a thermally stable single-phase white-emitting phosphor for WLEDs102Structure, energy transfer, and luminescence properties of NaLaMgWO6: Tb3+,Eu3+ phosphors for solid-state lighting16Synthesis and photoluminescence properties of the novel Eu3+-activated CaNa(PO3)3 phosphors13Controllable preparation and fluorescence property of spherical nano-phosphor YPO4:Eu3+21Improved temperature sensing performance based on Stark sublevels of Er3+/Yb3+ co-doped tungstate-molybdate up-conversion phosphors30Organic solvent-free lyophilization assisted recrystallization synthesis of high-purity green emissive Cs3MnX5 (X = I, Br)36Enhanced red emission of Eu3+-activated phosphors via the special design in A-sites of double perovskite structure19Synthesis and luminescent properties of novel thermal-stable orangish-red-emitting LnNbO4: Sm3+ (Ln=La, Y) phosphors13Eu3+-activated Ln2TeO6 (Ln = La, Y) as a novel red-emitting phosphor for warm white LEDs4Changing the Sensitivity and Operating Range of the Ba2MgWO6 : Eu3+ Optical Thermometer by Applying the Distinct Synthesis Routes1Synthesis and Photoluminescence Properties of Eu3+-Doped Na2YMg2V3O12: A Novel Red-Emitting Phosphor for White-Light-Emitting Diodes1Novel double perovskite Na1-Eu1+/3MgWO6 (0 ≤ x ≤ 0.4) phosphors for white LEDs: Sol-gel controlled synthesis, microstructure and luminescence properties21Efficient yellow phosphorescent [3+2+1] Ir (Ⅲ) complex for warm white lighting and visible light communication7On how the mechanochemical and co-precipitation synthesis method changes the sensitivity and operating range of the Ba2Mg1-xEuxWO6 optical thermometer22Enhanced luminescence performance in double perovskite Na4/5Gd16/15-MgWO6: xEu3+ red-emitting phosphors for white LEDs through cation modification11A Novel Red-Emitting Sr7sb2o12:Sm3+, Eu3+ Phosphor: Synthesis, Luminescent Properties, and Led Packaging0Excellent Red Phosphors of Eu3+ Activated Double Perovskite Structured Series NaSrBi1-xEuxMoO6 (x = 0.0-0.24) Prepared by Citrate-Gel Method0Luminescence studies of europium and terbium doped calcium orthosilicate phosphors4Tunable White Light Emission and Energy Transfer in Liymgwo6: Dy3+, Tm3+ Single-Phase Phosphor0Probing the multifunctionality of double layered perovskite NaGdMgTeO6:Eu3+ in ratiometric phosphor thermometry and solid-state lighting58Sol-gel synthesized double perovskite Na(1-)Gd(0.95+/3)MgWO6: 5% Eu3+ (0 ≤ x ≤ 0.5) phosphors with incommensurately modulated structure: Microstructures and luminescence properties15Eu3+ and Mn4+ co-doped BaLaMgNbO6 double perovskite phosphors for WLED application19Improvement in the luminescence and enhancement of the thermo-stability of SiO2 coating on LiAlSiO4:Eu3+ phosphor7A high quantum yield red phosphor NaGdSiO4: Eu3+ with intense emissions from the 5D0→7F1,2 transition44New red-emitting phosphor of Eu3+-doped Ba2Gd0.67W1−xMoxO6 for solid state lighting0Synthesis and photoluminescence properties of Eu3+-doped Na2YMg2V3O12: A novel red-emitting phosphor for WLEDs11Electrical Properties of Sr3Mo1–xWxO6‐Based Solid Solution0Novel double perovskite Ca2Gd0.5Nb1-W5/6O6:0.5 Eu3+ red phosphors with excellent thermal stability and high color purity for white LEDs92High Purity Red Emission from Amorphous Batio3:Eu3+ Ultra-Thin Film Phosphor0Novel Sm3+/Eu3+ co-doped Sr7Sb2O12 red-emitting phosphor for white LED46Comparative study of red-emitting pyrophosphate phosphors: Site-selective replacement of Eu3+ and luminescent properties12Luminescence studies of lanthanides (Europium and Terbium) doped Sr2SiO4 phosphor2Zero concentration quenching in europium doped complex perovskite Na1/2La1/2Mg1/3Nb2/3O3: A thermally stable phosphor for WLEDs13NaGd0.4Eu0.6Mg1–Zn WO6 solid solution red phosphors: Microstructure variation and luminescence enhancement induced by Zn2+-doping12Photoluminescence Color Prediction for Eu3+‐Doped Perovskite Red Phosphors Using Machine Learning3Eu 3+ Site Distribution and Local Distortion of Photoluminescent Ca 3 WO 6 :(Eu 3+ , K + ) Double Perovskites as High‐Color‐Purity Red Phosphors77Eu3+ activated non-crystalline BaTiO3 ultra-thin film phosphor with high purity, tailored red emission from n-UV excitation for WLEDs applications5A brief review of characteristic luminescence properties of Eu 3+ in mixed-anion compounds53Structural and luminescence properties of novel Eu 3+ -doped Na 3 Ba 2 LaNb 10 O 30 phosphors with high quantum efficiency and excellent color purity for w-LED applications22Tuning the luminescence color of Eu3+- and alkali-ion-codoped Sr2CaWO6 orange-red phosphors: Eu3+ site distribution and site-selective photoluminescence studies11Reduction mechanism and energy transfer between Eu 3+ and Eu 2+ in Eu-doped materials synthesized in air atmosphere23Photoluminescence and energy transfer studies in the Sm3+ and Eu3+ co-doped Sr2ZnSi2O7 red-emitting phosphors11Synthesis and optical properties of highly efficient Na7Mg13La(PO4)12:Eu3+ powders with excellent thermal stability3Thermally Stable Orange-Red BaLaLiWO6:Sm3+/Sr2+ Phosphors for Potential Application in Plant Growth5Color-tunable emission in Ca3Lu2Ge3O12: Bi3+, Eu3+ phosphor through energy transfer for WLEDs10Synthesis of an excellent red phosphor and photo luminescence studies of Eu 3+ activated double perovskite phosphors NaSrBi 1- x Eu x WO 6 ( x = 0.0–0.24)2Synthesis and multi-color emission properties of novel Na3KMg7(PO4)6: RE3+ (RE = Eu, Dy, Tb) phosphor for white LED and indoor plant growth7Ultra-broadband near infrared phosphor with wide spectral range and long peak wavelength achieved by double-site occupation1Up-conversion luminescence study of thermally stable Sr2ZnSi2O7: Er3+ phosphors6Luminescence properties of Eu3+-Doped double perovskite tungstate phosphors8Thermally stable K2ZnP2O7: Eu3+ red emitting phosphor for w-LEDs4Thermally boosted luminescent from a novel red phosphor with two-dimensional negative thermal expansion for high-quality WLEDs3Near-infrared mechanoluminescence in Fe3+-doped double perovskite oxides3Multicolor emission and luminescence behaviour of novel K2Pb8(PO4)6:RE3+(RE3+= Dy, Eu, Sm, Tb, Pr) phosphors for n-UV-excited solid-state lighting9Chemical unit substitution at B/B′ site enables efficient red emission and high thermal stability in NaGdMgWO6:Eu3+ for white light-emitting diodes application3Synthesis of Sr2Sb2O7: Eu3+ phosphors with excitation-dependent emission (normal 5D0→7F1/abnormally strong 5D0→7F2) for light-emitting diodes and optical fingerprint detection0Influence of the A site order–disorder transition on the photoluminescence properties of LiLa(Ca, Mg)(W, Mo)O6:Eu3+ red phosphor1Far-red emission garnet-type NaGd2Ga2InGe2O12:Eu3+ phosphors with 5D0→7F4 transition and thermal stability for plant-growth lighting and latent fingerprint visualization0Highly thermally stable Eu3 +-doped CaGd2Ge4O12 phosphor with intense 701 nm far-red emission for plant growth lighting and latent fingerprint identification0Thermally stable red phosphors based on (Na, Li)LuMgWO6:Eu3+0

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  1. Eu 3+ -activated Na 2 Gd(PO 4 )(MoO 4 ): A novel high-brightness red-emitting phosphor with high color purity and quantum efficiency for white light-emitting diodes

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  2. Red-emitting double perovskite phosphors Sr1−xCaxLaMgSbO6:Eu3+: Luminescence improvement based on composition modulation

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  3. Valence transfer of Eu3+ activated in Yb2Si2O7 phosphors: Luminescence and self reduction

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  4. Synthesis and luminescence properties of new red phosphor YBiW2O9:Eu3+

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  5. Thermally stable double perovskite CaLaMgSbO6:Eu3+ phosphors as a tunable LED-phosphor material

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  6. Synthesis and luminescence properties of double perovskite Gd2MgTiO6:Eu3+ red phosphors for white light-emitting diodes

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  7. A novel double perovskite tellurate Eu3+-doped Sr2MgTeO6 red-emitting phosphor with high thermal stability

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  8. Phase diagrams for the M2MoO4–Ln2(MoO4)3–Hf(MoO4)2 systems, where M = Li–Cs, Tl and Ln = La–Lu

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  9. Facile synthesis and color-tunable properties of monodisperse β-NaYF 4 :Ln 3+ (Ln = Eu, Tb, Tm, Sm, Ho) microtubes

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  10. Concentration and thermal quenching of SrGdLiTeO6: Eu3+ red-emitting phosphor for white light-emitting diode

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  11. Far-red-emitting double-perovskite CaLaMgSbO 6 :Mn 4+ phosphors with high photoluminescence efficiency and thermal stability for indoor plant cultivation LEDs

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  12. Lu 3+ doping induced photoluminescence enhancement in novel high-efficiency Ba 3 Eu(BO 3 ) 3 red phosphors for near-UV-excited warm-white LEDs

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  13. Tune color of single-phase LiGd(MoO 4 ) 2-X (WO 4 ) X : Sm 3+ , Tb 3+ via adjusting the proportion of matrix and energy transfer to create white-light phosphor

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  14. Crystal structure, electronic structure and photoluminescence properties of KLaMgWO6:Eu3+ phosphors

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  15. Novel high-brightness and thermal-stable Ca 3 Gd(AlO) 3 (BO 3 ) 4 :Eu 3+ red phosphors with high colour purity for NUV-pumped white LEDs

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  16. Simple coating synthesis and enhanced luminescence behaviour of LiLa(MoO4)2:Eu3+@NaF

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  17. Synthesis and photoluminescence properties of red-emitting NaLaMgWO6:Sm3+,Eu3+ phosphors for white LED applications

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  18. Spectroscopic behavior, thermal stability and temperature sensitivity of Ca 2 SiO 4 : Eu 3+ red emitting phosphor for solid state lighting application

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  19. Molybdenum substitution simultaneously induced band structure modulation and luminescence enhancement in LiLaMg(W, Mo)O6: Eu3+ red-emitting phosphor for near ultraviolet excited white light diodes

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  20. Effects of Sm3+ on Luminescent Properties of LiEu(0.55-x)Y0.45 (WO4)2Smx Red Phosphor

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  21. Synthesis and Luminescent Properties of LiEu(0.50-x)Gd0.50 (WO4)2Smx Red Phosphor

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  22. Luminescent properties, energy transfer, and thermal stability of double perovskites La2MgTiO6:Sm3+, Eu3+

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  24. Near-ultraviolet excited Eu3+ doped KSrY(BO3)2 phosphors for solid-state lighting: synthesis, structure and photoluminescent properties

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  25. High quantum efficiency red emitting α-phase La2W2O9:Eu3+ phosphor

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  26. Luminescence properties of Dy3+ or/and Sm3+ doped LiLa(WO4)2 phosphors and energy transfer from Dy3+ to Sm3+

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  27. Synthesis and photoluminescence properties of Ln3+ (Ln3+ = Sm3+/Eu3+) doped Na2NbAlO5 phosphors

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  28. Mn 4+ -activated Li 3 Mg 2 SbO 6 as an ultrabright fluoride-free red-emitting phosphor for warm white light-emitting diodes

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  29. Structure variation and luminescence enhancement of BaLaMg(Sb, Nb)O6:Eu3+ double perovskite red phosphors based on composition modulation

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  30. Ba3P4O13:Eu3+ phosphors with high thermal stability and high internal quantum efficiency for near-ultraviolet white light-emitting diodes

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  31. Eu3+ doped (Li, Na, K) LaMgWO6 red emission phosphors: An example to rational design with theoretical and experimental investigation

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  32. Novel high color-purity Eu3+-activated Ba3Lu4O9 red-emitting phosphors with high quantum efficiency and good thermal stability for warm white LEDs

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  33. Enhanced luminescence properties of Eu3+ activated CaGd2(WO4)4 red-emitting phosphors with Mo6+ doping

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  34. Investigation of photoluminescence properties, quenching mechanism and thermal stability of the red-emitting phosphor based on Eu ions doped apatite host NaLa9(SiO4)6O2

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  35. Novel highly efficient and thermally stable Ca2GdTaO6:Eu3+ red-emitting phosphors with high color purity for UV/blue-excited WLEDs

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  36. Enhancement of zero phonon line for Na2TiF6:Mn4+, Li+ phosphors induced by Li+

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  37. High efficient Eu3+-activated Ca(La, Gd)MgSbO6 double perovskite phosphors: Thermal stability improvement by composition modulating

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  38. Synthesis and enhanced luminescence properties of double perovskite NaLa 0.95− x Y x Eu 0.05 MgWO 6 phosphors

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  39. Photoluminescence properties of a Dy3+, Na+-activated yafsoanite Ca3Zn3Te2O12 phosphor with excellent thermal stability

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  40. Luminescence properties of double perovskite Gd2MgTiO6:Tb3+ phosphors by solid-state reaction method

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  41. Novel luminescence enhancement and splitting of excitation and emission bands of Na2SiF6:Mn4+,Li+ phosphors induced by Li+ co-doping

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  42. Sol-gel synthesis, crystal structure and luminescence properties of Eu3+ doped double perovskite molybdates NaCaBi1−xEuxMoO6 (x = 0–0.27)

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  43. Expanding the Doubly Cation Ordered AA′BB′O6 Perovskite Family: Structural Complexity in NaLaInNbO6 and NaLaInTaO6

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  44. Highly efficient and thermally stable CaMgLaSbO6:Mn4+ red phosphor for indoor plant growth

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  45. Luminescence properties, energy transfer and thermal stability of blue-green color tunable Sr3Y(BO3)3:Ce3+, Tb3+ phosphors

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  46. 1550 nm pumped upconversion chromaticity modulation in Er3+ doped double perovskite LiYMgWO6 for anti-counterfeiting

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  47. Combustion synthesis of Eu3+ doped Al4B2O9 phosphor for light emitting diode

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