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RESEARCH PAPER · Chemistry of Materials · 2016

Exploring the Origin of High Dechlorination Activity in Polar Materials M 2 B 5 O 9 Cl (M = Ca, Sr, Ba, Pb) with Built-In Electric Field

Xiaoyun Fan, Zhi‐Peng Wu, Lichang Wang, Chuanyi Wang

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Exploring the Origin of High Dechlorination Activity in Polar Materials M 2 B 5 O 9 Cl (M = Ca, Sr, Ba, Pb) with Built-In Electric FieldOriginalRapid fabrication of SnO 2 nanoparticle photocatalyst: computational understanding and photocatalytic degradation of organic dye109Polar Fluorooxoborate, NaB4O6F: A Promising Material for Ionic Conduction and Nonlinear Optics495Polar Fluorooxoborate, NaB4O6F: A Promising Material for Ionic Conduction and Nonlinear Optics67In Situ Raman Probing of Chlorphenol Degradation on Different Facets of K3B6O10Br Single Crystal8Facet, Junction and Electric Field Engineering of Bismuth‐Based Materials for Photocatalysis111Band structure engineering of boron–oxygen-based materials for efficient charge separation12Improved photo-dechlorination at polar photocatalysts K 3 B 6 O 10 X (X = Cl, Br) by halogen atoms-modulated polarization9Multifunctional property exploration: Bi 4 O 5 I 2 with high visible light photocatalytic performance and a large nonlinear optical effect32Enhanced photocatalytic hydrogen evolution of CdWO4 through polar organic molecule modification19The Role of Polarization in Photocatalysis930The Role of Polarization in Photocatalysis60Polar Molecular Modification onto BiOBr to Regulate Molecular Oxygen Activation26High-Efficiency Visible Light Responsive Sulfide KSb5S8 Photocatalyst with a Layered Crystal Structure6The halogen atoms induced different oxygen vacancies in RbNa2B6O10X (X = Cl, Br) for the enhanced photo-dechlorination properties8Ferroelectric polarization and thin-layered structure synergistically promoting CO 2 photoreduction of Bi 2 MoO 6164Ca 2 B 5 O 9 Cl and Sr 2 B 5 O 9 Cl: Nonlinear Optical Crystals with Deep-Ultraviolet Transparency Windows46Designing Sulfide Borate as a Novel Type of Second-Order Nonlinear-Optical Material91Resource‐Efficient Low‐Temperature Synthesis of Microcrystalline Pb2B5O9X (X = Cl, Br) for Surfaces Studies by Optical Second Harmonic Generation10Nanostructured Borate Halides for Optical Second Harmonic Generation at Surfaces7Zn4B6O13: Efficient Borate Photocatalyst with Fast Carrier Separation for Photodegradation of Tetracycline44Photocatalysis Within Intrinsic Spontaneous Polarization Electric Field47Local-interaction-field-coupled semiconductor photocatalysis: recent progress and future challenges74Atomic‐Level Charge Separation Strategies in Semiconductor‐Based Photocatalysts505Newly emerging borate-based nonlinear optical materials for organic pollutant degradation: A review33Strain‐Engineered Nano‐Ferroelectrics for High‐Efficiency Piezocatalytic Overall Water Splitting234Strain‐Engineered Nano‐Ferroelectrics for High‐Efficiency Piezocatalytic Overall Water Splitting20Synergistic Polarization Engineering on Bulk and Surface for Boosting CO 2 Photoreduction306Synergistic Polarization Engineering on Bulk and Surface for Boosting CO2 Photoreduction21Polarization-enhanced photocatalytic activity in non-centrosymmetric materials based photocatalysis: A review132Ethanol-assisted molten salt synthesis of Bi4Ti3O12/Bi2Ti2O7 with enhanced visible light photocatalytic performance15Internal electric field driving separation and migration of charge carriers via Z-scheme path in AgIn5S8/ZnO heterojunction for efficient decontamination of pharmaceutical pollutants100Recent advances in structural tailoring of BiOX-based 2D composites for solar energy harvesting50Adjusting the match-degree between electron library and surface-active sites and forming surface polarization in MOF-based photo-cocatalysts for accelerating electron transfer3High-Efficient Removal of 2,4 Dichlorophenol by Co-Degradation and Adsorption with Embedded Sr/Fe/Fexoy/Srfe12o19 Heterojunctions Loading on Biochar0Solar-Driven Upgrading of 5-Hydroxymethylfurfural on Bivo4 Photoanodes: Effect of Tempo Mediator and Cocatalyst on Reaction Kinetics50Coherently degenerate state engineering of organic small molecule materials to generate Wannier excitons6Cd4InO(BO3)3: A New Nonlinear Optical Crystal Exhibiting Strong Second Harmonic Generation Effect and Moderate Birefringence2Microelectronic structure changes electron utilization: Core-shell structure catalysts with electron library and quantum dots for photocatalytic hydrogen production13Borate particulate photocatalysts for photocatalytic applications: A review127The strong alternating built-in electric field sourced by ball milling on Pb2BO3X (X Cl, Br, I) piezoelectric materials contributes to high catalytic activity50DFT studies of aggregation induced energy splitting and excitonic diversification in benzene and anthracene multimers8La3+’s Effect on the Surface (101) of Anatase for Methylene Blue Dye Removal, a DFT Study14J-Aggregated Dyes for Dye-Sensitized Solar Cells: Suppressing Aggregation-Induced Excited-State Quenching by Intramolecular Charge Separation25High‐Performance Photocatalytic Reduction of Nitrogen to Ammonia Driven by Oxygen Vacancy and Ferroelectric Polarization Field of SrBi 4 Ti 4 O 15 Nanosheets61Polar semiconductor photocatalysts with intrinsic electric fields for selective organic transformation8Development and Implementation of a Two-Level Inquiry- and Project-Based Modular Approach to Teaching a Second-Semester Physical Chemistry Laboratory Course1Vibration‐driven Reduction of CO 2 to Acetate with 100 % Selectivity by SnS Nanobelt Piezocatalysts83Vibration‐driven Reduction of CO 2 to Acetate with 100 % Selectivity by SnS Nanobelt Piezocatalysts16High-performance piezoelectric nanogenerators based on Cs2Ag0.3Na0.7InCl6 double perovskites with high polarity induced by Zr/Te codoping17Engineering a Z-Scheme Heterostructure on ZnIn 2 S 4 @NH 2 -MIL-125 Composites for Boosting the Photocatalytic Performance49A Full-Spectrum ZnS Photocatalyst with Gradient Distribution of Atomic Copper Dopants and Concomitant Sulfur Vacancies for Highly Efficient Hydrogen Evolution64Polar peripheral substituent-regulated organic/inorganic hybrid photocatalysts promoting the degradation of phenolic pollutants8Synergistic polarization engineering of dielectric towards low-voltage high-mobility solution-processed ultraflexible organic transistors14Bulk internal electric field in Photocatalyst:From recognition, understanding to construction strategy25Reversible heterostructure CuI/CuII@BaTiO3 constructed to enhance piezocatalytic activity27Local Polarization Piezoelectric Electric Field Promoted Water Dissociation for Hydroxyl Radical Generation under Ambient Humidity Condition11In Situ Grown Cs 2 Ag 0.3 Na 0.7 InCl 6 Double Perovskites within a PVDF Matrix for High-Performance Flexible Piezoelectric Nanogenerators7Plasmon‐Ferroelectric Induced Multifield Coupling Effect Accelerates Charge Spatial Separation for Boosting Tandem Photoredox Catalysis3Plasmon‐Ferroelectric Induced Multifield Coupling Effect Accelerates Charge Spatial Separation for Boosting Tandem Photoredox Catalysis13Hydrogen bond formation-modulated H2O2 generation under periodic local polarization piezoelectric electric field4Dual‐Mode Thermal Response of Visible/NIR Emission in Er 3+ ‐Doped Layered Perovskite via Modulating Thermally Induced Oxygen Vacancies and Cross Relaxation4Dual‐Mode Thermal Response of Visible/NIR Emission in Er 3+ ‐Doped Layered Perovskite via Modulating Thermally Induced Oxygen Vacancies and Cross Relaxation11Ti–Cl bond induced fast electron transfer in OH− regulated SrBi4Ti4O15/BiOCl for enhanced piezo-photocatalytic antibiotic degradation27π–Conjugated B3O6 units drive directional O2 adsorption and charges separation for efficient piezoelectric H2O2 production1First principles study of quaternary SiXSSe (X = Ge, Sn) monolayers with lone-pair electrons: Promising photocatalysts with strong piezoelectric response for overall water splitting1Local polarization-piezoelectric field promotes water dissociation for efficient fluorinated pollutants defluorination0Intensifying Localized Polarization Piezoelectric Field via Tip Effect on Carbon Quantum Dots Modified Ca 2 B 3 O 6 Cl for H 2 O 2 Production in Pure Water0The First Silver Lead Borate, AgPb[B5O9]0Dissolution of Liquid B2O3 in Molten CaCl2−CaO0

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  1. Rapid fabrication of SnO 2 nanoparticle photocatalyst: computational understanding and photocatalytic degradation of organic dye

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  2. Polar Fluorooxoborate, NaB4O6F: A Promising Material for Ionic Conduction and Nonlinear Optics

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  3. Polar Fluorooxoborate, NaB4O6F: A Promising Material for Ionic Conduction and Nonlinear Optics

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  4. In Situ Raman Probing of Chlorphenol Degradation on Different Facets of K3B6O10Br Single Crystal

    The Journal of Physical Chemistry C · 2018-06-05

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  5. Facet, Junction and Electric Field Engineering of Bismuth‐Based Materials for Photocatalysis

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  6. Band structure engineering of boron–oxygen-based materials for efficient charge separation

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  7. Improved photo-dechlorination at polar photocatalysts K 3 B 6 O 10 X (X = Cl, Br) by halogen atoms-modulated polarization

    Catalysis Science & Technology · 2019-01-01

    Yang Zhang, Yufei Zhai, Yang Yu, Zhi Su, Jiao Yin, Chuanyi Wang, Xiaoyun Fan

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  8. Multifunctional property exploration: Bi 4 O 5 I 2 with high visible light photocatalytic performance and a large nonlinear optical effect

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  9. Enhanced photocatalytic hydrogen evolution of CdWO4 through polar organic molecule modification

    International Journal of Hydrogen Energy · 2019-01-30

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  10. The Role of Polarization in Photocatalysis

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  11. The Role of Polarization in Photocatalysis

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  12. Polar Molecular Modification onto BiOBr to Regulate Molecular Oxygen Activation

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  13. High-Efficiency Visible Light Responsive Sulfide KSb5S8 Photocatalyst with a Layered Crystal Structure

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  14. The halogen atoms induced different oxygen vacancies in RbNa2B6O10X (X = Cl, Br) for the enhanced photo-dechlorination properties

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  15. Ferroelectric polarization and thin-layered structure synergistically promoting CO 2 photoreduction of Bi 2 MoO 6

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  16. Ca 2 B 5 O 9 Cl and Sr 2 B 5 O 9 Cl: Nonlinear Optical Crystals with Deep-Ultraviolet Transparency Windows

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  17. Designing Sulfide Borate as a Novel Type of Second-Order Nonlinear-Optical Material

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  18. Resource‐Efficient Low‐Temperature Synthesis of Microcrystalline Pb2B5O9X (X = Cl, Br) for Surfaces Studies by Optical Second Harmonic Generation

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  19. Nanostructured Borate Halides for Optical Second Harmonic Generation at Surfaces

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  20. Zn4B6O13: Efficient Borate Photocatalyst with Fast Carrier Separation for Photodegradation of Tetracycline

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  21. Photocatalysis Within Intrinsic Spontaneous Polarization Electric Field

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  22. Local-interaction-field-coupled semiconductor photocatalysis: recent progress and future challenges

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  23. Atomic‐Level Charge Separation Strategies in Semiconductor‐Based Photocatalysts

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  24. Newly emerging borate-based nonlinear optical materials for organic pollutant degradation: A review

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  30. Ethanol-assisted molten salt synthesis of Bi4Ti3O12/Bi2Ti2O7 with enhanced visible light photocatalytic performance

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  31. Internal electric field driving separation and migration of charge carriers via Z-scheme path in AgIn5S8/ZnO heterojunction for efficient decontamination of pharmaceutical pollutants

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  34. High-Efficient Removal of 2,4 Dichlorophenol by Co-Degradation and Adsorption with Embedded Sr/Fe/Fexoy/Srfe12o19 Heterojunctions Loading on Biochar

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  35. Solar-Driven Upgrading of 5-Hydroxymethylfurfural on Bivo4 Photoanodes: Effect of Tempo Mediator and Cocatalyst on Reaction Kinetics

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  36. Coherently degenerate state engineering of organic small molecule materials to generate Wannier excitons

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  44. High‐Performance Photocatalytic Reduction of Nitrogen to Ammonia Driven by Oxygen Vacancy and Ferroelectric Polarization Field of SrBi 4 Ti 4 O 15 Nanosheets

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  45. Polar semiconductor photocatalysts with intrinsic electric fields for selective organic transformation

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  47. Vibration‐driven Reduction of CO 2 to Acetate with 100 % Selectivity by SnS Nanobelt Piezocatalysts

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  48. Vibration‐driven Reduction of CO 2 to Acetate with 100 % Selectivity by SnS Nanobelt Piezocatalysts

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  49. High-performance piezoelectric nanogenerators based on Cs2Ag0.3Na0.7InCl6 double perovskites with high polarity induced by Zr/Te codoping

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  50. Engineering a Z-Scheme Heterostructure on ZnIn 2 S 4 @NH 2 -MIL-125 Composites for Boosting the Photocatalytic Performance

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