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RESEARCH PAPER · Inorganic Chemistry · 2016

Luminescence and Nonlinear Optical Properties in Copper(I) Halide Extended Networks

Natasha M. Khatri, Michele H. Pablico-Lansigan, William L. Boncher, Julie E. Mertzman, Aura C. Labatete, L.M. Grande, Donald Wunder, Michael J. Prushan, Weiguo Zhang, P. Shiv Halasyamani, Jorge H. S. K. Monteiro, Ana de Bettencourt‐Dias, Sarah L. Stoll

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Luminescence and Nonlinear Optical Properties in Copper(I) Halide Extended NetworksOriginalAnion-dependent self-assembly of copper coordination polymers based on pyrazole-3,5-dicarboxylate and 1,2-di(4-pyridyl)ethylene24Phosphorescent 2-, 3- and 4-coordinate cyclic (alkyl)(amino)carbene (CAAC) Cu( i ) complexes89CdX2 Coordination Polymers with 2‐Chloropyrazine and 2‐Methylpyrazine: Similar Ligands – Similar Structures – Different Reactivity17Structure and photoluminescence of cubane-like [Cu4I4] cluster-based 1D coordination polymer assembled with bis(triazole)pyridine ligand12Thermochromic Luminescent Materials and Multi-Emission Bands in d10 Clusters26Partial in Situ Reduction of Copper(II) Resulting in One-Pot Formation of 2D Neutral and 3D Cationic Copper(I) Iodide–Pyrazine Coordination Polymers: Structure and Emissive Properties24Thermal and Mechanochemical Syntheses of Luminescent Mononuclear Copper(I) Complexes24Synthesis, Crystal Structures, and Properties of M(NCS)2‐3‐aminomethylpyridine Coordination Compounds (M = Cd, Zn)16A new semiconducting coordination polymer consisting of copper(I)-iodide and 3-pyridinecarboxaldehyde7Smart composite films of nanometric thickness based on copper–iodine coordination polymers. Toward sensors54CuI-based coordination polymers with 2-thiazolyl sulfide ligands: First examples10Supramolecular Interactions Modulating Electrical Conductivity and Nanoprocessing of Copper–Iodine Double-Chain Coordination Polymers24Recent progress in coordination chemistry, photo-physical properties, and applications of pyridine-based Cu(I) complexes41New iodometallates(I) with in situ generated organic base derivatives as countercations (M+ = Ag+, Cu+)8Copper(I)–polymers and their photoluminescence thermochromism properties15Equation of state and structural characterization of Cu4I4{PPh2(CH2CH = CH2)}4under pressure5CuI-Based Coordination Polymer Assembled from a 2-Pyridyl Sulfide Ligand: Synthesis and Luminescent Properties5Organic ligand capping of CuI for enhanced electrical and ionic conductivity5Stretchable and luminescent networks from copper(I)-coordinated main-chain thioether polymers7Copper(I)-Based Highly Emissive All-Inorganic Rare-Earth Halide Clusters51Mechanochemistry, an Easy Technique to Boost the Synthesis of CuI Pyrazine Coordination Polymers20Copper(I) iodide complexes with cyanopyridine and 3-nitropyridine ligands11Synthesis, Structures, Thermal and Luminescence Properties of Zn and Cd Halide Coordination Polymers with 2‐Cyanopyrazine1Dicopper(I) Paddle-Wheel Complexes with Thermally Activated Delayed Fluorescence Adjusted by Ancillary Ligands51Tunable Luminescence in Hybrid Cu(I) and Ag(I) Iodides14Cu(I)–I-2,4-diaminopyrimidine Coordination Polymers with Optoelectronic Properties as a Proof of Concept for Solar Cells16Tuning the architectures and luminescence properties of Cu( i ) compounds of phenyl and carboranyl pyrazoles: the impact of 2D versus 3D aromatic moieties in the ligand backbone22Assembly of Heterometallic AuICu2I2 Cores on the Scaffold of NPPN-Bridging Cyclic Bisphosphine23Multi-stimulus semiconductor Cu( i )–I-pyrimidine coordination polymer with thermo- and mechanochromic sensing14Modulated luminescence of zero-dimensional bimetallic all-inorganic halide clusters3Optical and charge transfer properties of a new cadmium based metal-organic-framework material6Electrochemical Thin Film Deposition of Copper(I) Halides in Aqueous Solution: Substrate Extension and Structure Transformation9Ligand Control of Structural Diversity in Luminescent Hybrid Copper(I) Iodides66Organic–Inorganic Hybrid Noncentrosymmetric (Morpholinium) 2 Cd 2 Cl 6 Single Crystals: Synthesis, Nonlinear Optical Properties, and Stability43Zero-Dimensional (Piperidinium)2MnBr4: Ring Puckering-Induced Isostructural Transition and Strong Electron–Phonon Coupling-Mediated Self-Trapped Exciton Emission24Electron–Phonon Coupling Mediated Self-Trapped-Exciton Emission and Internal Quantum Confinement in Highly Luminescent Zero-Dimensional (Guanidinium)6Mn3X12 (X = Cl and Br)29Optical Properties of Novel Materials for Optoelectronic Applications7Structural and Luminescence Properties of Cu(I)X-Quinoxaline under High Pressure (X = Br, I)32D Cu(I)-I Coordination Polymer with Smart Optoelectronic Properties and Photocatalytic Activity as a Versatile Multifunctional Material20Liquid reagents are not enough for liquid assisted grinding in the synthesis of [(AgBr)( n -pica)] n2A new multifunctional copper iodide–pyrazine hybrid for sensitive creatinine detection in biological samples: synthesis, structural features, characterization, and electrochemical evaluation5Investigation of structural variation on the luminescence of Cu(I) complexes with benzotriazole-based imine and phosphorus donor ligands – experimental and theoretical studies1Improving the Singlet Oxygen Photosensitization Activity of Fluorenone-Based Materials2The dual-emissive Cu4X4 complex with transitive octahedral to stair-step structure3Solvent- and Stoichiometry-Controlled Assembly and Mechanoresponsive Behavior of Carbazole–Pyrimidine-Derived Cu(I) Coordination Polymers0Structural studies, thermochromic luminescent properties and crystal-to-crystal transformation of a double-stranded Cu I –I-bisquinoline coordination polymer3Hydrogen Bonding-Induced Synergistic Effect on Second-Harmonic Generation and High Photoluminescence of Morpholinium Cuprous Bromide Dihydrate Single Crystals1Crystallization-Induced Coordination Diversity of Cu(I)-Pyridine Halide Complexes Resulting in Optical Tunability4Electrochemiluminescence-enhanced mesoporous composite enabling sensitive deoxynivalenol detection and nano-delivery of a ROCK inhibitor for spinal cord injury0

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  2. Phosphorescent 2-, 3- and 4-coordinate cyclic (alkyl)(amino)carbene (CAAC) Cu( i ) complexes

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  3. CdX2 Coordination Polymers with 2‐Chloropyrazine and 2‐Methylpyrazine: Similar Ligands – Similar Structures – Different Reactivity

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    Christian Näther, Inke Jeß, Luzia S. Germann, Robert E. Dinnebier, Michael Braun, Huayna Terraschke

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  4. Structure and photoluminescence of cubane-like [Cu4I4] cluster-based 1D coordination polymer assembled with bis(triazole)pyridine ligand

    Journal of Organometallic Chemistry · 2017-03-23

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  5. Thermochromic Luminescent Materials and Multi-Emission Bands in d10 Clusters

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  6. Partial in Situ Reduction of Copper(II) Resulting in One-Pot Formation of 2D Neutral and 3D Cationic Copper(I) Iodide–Pyrazine Coordination Polymers: Structure and Emissive Properties

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    Iurie L. Malaestean, Victor Kravtsov, Janusz S. Lipkowski, Elena Cariati, Stefania Righetto, Daniele Marinotto, Alessandra Forni, Marina S. Fonarı

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  7. Thermal and Mechanochemical Syntheses of Luminescent Mononuclear Copper(I) Complexes

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  8. Synthesis, Crystal Structures, and Properties of M(NCS)2‐3‐aminomethylpyridine Coordination Compounds (M = Cd, Zn)

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  9. A new semiconducting coordination polymer consisting of copper(I)-iodide and 3-pyridinecarboxaldehyde

    Inorganic Chemistry Communications · 2017-12-20

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  10. Smart composite films of nanometric thickness based on copper–iodine coordination polymers. Toward sensors

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  11. CuI-based coordination polymers with 2-thiazolyl sulfide ligands: First examples

    Polyhedron · 2018-05-26

    Alexander V. Artem’ev, Denis G. Samsonenko⧫, Olga V. Antonova

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  12. Supramolecular Interactions Modulating Electrical Conductivity and Nanoprocessing of Copper–Iodine Double-Chain Coordination Polymers

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  13. Recent progress in coordination chemistry, photo-physical properties, and applications of pyridine-based Cu(I) complexes

    Journal of Coordination Chemistry · 2018-08-14

    Rashid Ilmi, Idris Juma Al-Busaidi, Ashanul Haque, Muhammad S. Khan

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  14. New iodometallates(I) with in situ generated organic base derivatives as countercations (M+ = Ag+, Cu+)

    Journal of Solid State Chemistry · 2018-09-27

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  15. Copper(I)–polymers and their photoluminescence thermochromism properties

    Photochemical & Photobiological Sciences · 2018-11-21

    Rongyan Wang, Xiao Zhang, Jie‐Hui Yu, Ji‐Qing Xu

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  16. Equation of state and structural characterization of Cu4I4{PPh2(CH2CH = CH2)}4under pressure

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  17. CuI-Based Coordination Polymer Assembled from a 2-Pyridyl Sulfide Ligand: Synthesis and Luminescent Properties

    Journal of Structural Chemistry · 2019-04-01

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  18. Organic ligand capping of CuI for enhanced electrical and ionic conductivity

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  19. Stretchable and luminescent networks from copper(I)-coordinated main-chain thioether polymers

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  20. Copper(I)-Based Highly Emissive All-Inorganic Rare-Earth Halide Clusters

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  21. Mechanochemistry, an Easy Technique to Boost the Synthesis of CuI Pyrazine Coordination Polymers

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  22. Copper(I) iodide complexes with cyanopyridine and 3-nitropyridine ligands

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  23. Synthesis, Structures, Thermal and Luminescence Properties of Zn and Cd Halide Coordination Polymers with 2‐Cyanopyrazine

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  24. Dicopper(I) Paddle-Wheel Complexes with Thermally Activated Delayed Fluorescence Adjusted by Ancillary Ligands

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  25. Tunable Luminescence in Hybrid Cu(I) and Ag(I) Iodides

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  26. Cu(I)–I-2,4-diaminopyrimidine Coordination Polymers with Optoelectronic Properties as a Proof of Concept for Solar Cells

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  27. Tuning the architectures and luminescence properties of Cu( i ) compounds of phenyl and carboranyl pyrazoles: the impact of 2D versus 3D aromatic moieties in the ligand backbone

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  28. Assembly of Heterometallic AuICu2I2 Cores on the Scaffold of NPPN-Bridging Cyclic Bisphosphine

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  29. Multi-stimulus semiconductor Cu( i )–I-pyrimidine coordination polymer with thermo- and mechanochromic sensing

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  30. Modulated luminescence of zero-dimensional bimetallic all-inorganic halide clusters

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  33. Ligand Control of Structural Diversity in Luminescent Hybrid Copper(I) Iodides

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