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RESEARCH PAPER · Chemistry of Materials · 2022

Ligand Control of Structural Diversity in Luminescent Hybrid Copper(I) Iodides

Shuxin Wang, Emily E. Morgan, Shobhana Panuganti, Lingling Mao, Pratap Vishnoi, Guang Xin Wu, Quanlin Liu, Mercouri G. Kanatzidis, Richard D. Schaller, Ram Seshadri

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Ligand Control of Structural Diversity in Luminescent Hybrid Copper(I) IodidesOriginalA Red-Emitting Cu(I)–Halide Cluster Phosphor with Near-Unity Photoluminescence Efficiency for High-Power wLED Applications11Chiral 2D Cu(I) Halide Frameworks53Emission and Luminescent Vapochromism Control of Octahedral Cu4I4 Complexes by Conformationally Restricted P,N Ligands27Chemical etching strategy to prepare microtubes of a hybrid organic cuprous halide5Green Emissive Copper(I) Coordination Polymer Supported by the Diethylpyridylphosphine Ligand as a Luminescent Sensor for Overheating Processes14A Rare Structural Motif for a Luminescent Cu(I) Coordination Polymer with 3-(Pyridin-2-yl)triimidazotriazine10The fluorescent detection of biothiols and antimicrobial study based on copper(I) iodide coordination polymer14One‐Dimensional Chiral Copper Iodide Chain‐Like Structure Cu 4 I 4 ( R / S ‐3‐quinuclidinol) 3 with Near‐Unity Photoluminescence Quantum Yield and Efficient Circularly Polarized Luminescence47Mono‐ and Bi‐Dentate Chiral Ligands Lead to Efficient Circularly Polarized Luminescence in 0D and 3D Semiconducting Copper(I) Iodides37A copper(II) chloride coordination compound with an adamantane-like core3Efficient blue-light-excitable copper(I) coordination network phosphors for high-performance white LEDs18One-Dimensional Organic–Inorganic Lead Bromide Hybrids with Excitation-Dependent White-Light Emission Templated by Pyridinium Derivatives12Highly sensitive and selective colorimetric and fluorescent dual-readout assay for the analysis of spermine, spermidine and cysteine14Self-Assembly of an Anionic [Cu5I8]3– Supramolecular Cluster Driven by Ion-Pair Interaction and Catalytic Properties7Self-Assemblies of Isomeric Copper Iodide Trimers with Geometry-Dependent Photophysical Properties25Cubane Dimerization: Cu4 vs Cu8 Copper Iodide Clusters12Matériaux photoluminescents à base de complexes de cuivre(I)0Design of luminescent complexes with different Cu 4 I 4 cores based on pyridyl phenoxarsines13A copper( i ) thiocyanate-based photoresponsive semiconducting 2D coordination polymer4Pyridine-amide-based hetero-copper iodide for the photocatalytic degradation of dyes and aerosol discolouration of VOC gases11Stabilization of copper iodide hybrids with increased strength of ionic bonding for lighting and X-ray imaging6Crystal structures of five gold(I) complexes with methylpiperidine ligands3Isomeric Zero-Dimensional Hybrid Copper(I) Iodides as Highly Efficient Multicolor Phosphors31Coordination complexes of isoquinoline with cobalt and nickel halides1Structure directing factors and photophysical properties of five Cu(I)-iodide materials with N-donor heteroaromatic ligands70D and 1D-dimensional Cu(I)-based halides pyridyltriazoles basis: Synthesis, Structures, and photophysical properties5Ultrastable Copper Iodide Hybrid with Intrinsic Greenish White-Light Emission by Incorporating an Anionic Inorganic Functional Unit into an Extended Structure8Activation of TADF in Photon Upconverting Crystals of Dinuclear Cu(I)-Iodide Complexes by Ligand Engineering22Copper Iodide Hybrid with Unique Cu3I3 Trimeric Inorganic Functional Unit and Far‐red/Near‐infrared Emission1Semiconducting Copper(I) Iodide 2D-Coordination Polymers for Efficient Sunlight-Driven Photocatalysis in Dye Degradation13Semiconducting 2D Copper(I) Framework for Sub-ppb-Level Ammonia Sensing12Photoactive Cluster-Organic frameworks with 1D Cu-I chain0Anomalous Pressure‐Induced Blue‐Shifted Emission of Ionic Copper‐Iodine Clusters: The Competitive Effect between Cuprophilic Interactions and Through‐Space Interactions19Anomalous Pressure‐Induced Blue‐Shifted Emission of Ionic Copper‐Iodine Clusters: The Competitive Effect between Cuprophilic Interactions and Through‐Space Interactions4Rational Design of Single‐Component White‐Light Emissive Molecular Copper Clusters8Ionothermal synthesis of a stable three-dimensional [Cu 4 I 4 ] cluster scintillator with near-unity quantum efficiency and weak thermal quenching19Application of Voronoi Polyhedra for Analysis of Electronic Dimensionality in Emissive Halide Materials17Ionothermal synthesis of a hybrid cuprous(I) iodide scintillator with efficient cyan emission and high antiwater stability23Multifunctional light-emitting materials based on hybrid copper iodide compounds2Near-unity room-temperature phosphorescence quantum yield induced by halogen–halogen interaction in chiral hybrid copper( i ) iodide clusters19New highly efficient phosphorescent manganese halides as green and blue emitters8Recent advances in mono- and multi-nuclear photoluminescent Cu( i ) complexes with nitrogen containing ligands and their stimuli responsiveness27Regulating charge transfer of copper( i ) coordination compounds via conformation engineering for highly efficient radioluminescence and 3D X-ray imaging10Trinuclear copper( i ) furanyl ortho -diphosphine halide clusters: structure, photophysical and photocatalytic hydrogen production properties5Controlling Triplet-Harvesting Pathways and Nonlinear Optical Properties in Cu(I) Iodide-Based Polymers through Ligand Engineering14Copper‐Iodide Cluster Ink for Fast and Robust Anti‐Counterfeiting and Erasable Encryption3Rigidity‐Regulated Copper(I) Halide Clusters Toward Highly Efficient Photoluminescence and Radioluminescence2Adjusting Cu⋯Cu distances by modification on ligands of four binuclear cuprous clusters to realize near-white-light emission0Amplified excited-state diverse effects arising from ligand regioisomerism in Cu( i ) complexes for advanced applications0Diverse structures and emission properties of copper( i ) iodide complexes based on an oxadiazole-type ligand6Manipulating the d-band center of Cu( i )-MOFs for the catalytic ignition of [BMIM]N(CN) 2 IL-H 2 O 2 propellants1Modulation of the structure and ionizing radiation detection performance of solution self-assembled cuprous iodide clusters0Molecular design of a polynuclear Cu 5 I 5 –bisquinoline complex as a new type of cysteine-selective chemodosimeter with turn-on color luminescence in aqueous media: crystal structures and spectroscopic studies0Synthesis and characterization of a heteroleptic Cu( i ) complex with diphosphine and nitrogen-containing ligands featuring thermally activated delayed fluorescence0Ligand Confinement for Fast‐Decay Cu─I Chain Scintillators Enabling High‐Resolution X‐ray Imaging and 3D Tomography12Ligand Confinement for Fast‐Decay Cu─I Chain Scintillators Enabling High‐Resolution X‐ray Imaging and 3D Tomography1Water‐Stable 3D Cu 4 I 4 Framework With Near‐Unity Photoluminescence From Cluster‐Centered Self‐Trapped Excitons1Crystallization-Induced Coordination Diversity of Cu(I)-Pyridine Halide Complexes Resulting in Optical Tunability4Supramolecular‐Assembled Chiral Cu(I) Halide Scintillators With Near‐Unity Cyan Photoluminescence for High‐Resolution X‐Ray Imaging5NaI‐Mediated Dispersion of Cuprous Halide Clusters via Ball‐Milling for Efficient White Light‐Emitting Diodes0Color‐Tunable Broadband Chiral Copper(I) Halides Scintillators for High‐Resolution X‐Ray Polarization Imaging1Aliphatic Ligand‐Mediated Cu–Cu Distance Tuning Enables Near‐Unity Efficient and Color‐Tunable Circularly Polarized Luminescent Copper(I) Iodide Clusters0Hybrid Copper(I) Iodide Scintillators: From Molecular Architecture to X‐Ray Imaging Applications0Confining copper (I) iodide (CuI) modules in metal organic frameworks (MOFs): Structures and applications of CuI-MOFs1Engineering Morphology and Dimensionality in 1D and 2D Cu(I)-I Coordination Polymers for Enhanced Photocatalysis, Luminescence, and Selective Antibiotic Sensing0Vapochromic Photoluminescence in Structurally Diverse Hydrogen‐Bonded Copper(I) Cluster Networks0

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  1. A Red-Emitting Cu(I)–Halide Cluster Phosphor with Near-Unity Photoluminescence Efficiency for High-Power wLED Applications

    Molecules · 2022-07-11

    Wenjiang Zhaxi, Miao Li, Jing Wu, Luying Liu, Zetao Huang, Huixian Miao, Xiao Ma, Shenlong Jiang, Qun Zhang, Wei Qiu Huang, Dayu Wu

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  2. Chiral 2D Cu(I) Halide Frameworks

    Chemistry of Materials · 2022-09-02

    Xiaoqin Ji, Shining Geng, Shuai Zhang, Ya-Ping Gong, Xuanyu Zhang, Ruiqian Li, Yang Liu, Jian Chen, Rui Chen, Zewen Xiao, Lingling Mao

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  3. Emission and Luminescent Vapochromism Control of Octahedral Cu4I4 Complexes by Conformationally Restricted P,N Ligands

    Chemistry - A European Journal · 2022-11-24

    Igor D. Strelnik, Aliia V. Shamsieva, Kamil D. Akhmadgaleev, Tatiana P. Gerasimova, Irina R. Dayanova, Ilya E. Kolesnikov, Robert R. Fayzullin, Daut R. Islamov, Elvira I. Musina, Andrey A. Karasik, Oleg Gerol'dovich Sinyashin

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  4. Chemical etching strategy to prepare microtubes of a hybrid organic cuprous halide

    CrystEngComm · 2023-01-01

    Siyu Xu, Jieru Yang, Yanan Wu, Hang-qing Lin, Yun Chai, Jia-Wei Lin, Ke‐Zhao Du

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  5. Green Emissive Copper(I) Coordination Polymer Supported by the Diethylpyridylphosphine Ligand as a Luminescent Sensor for Overheating Processes

    Molecules · 2023-01-10

    Kamila R. Enikeeva, Aliia V. Shamsieva, Anna G. Strelnik, Robert R. Fayzullin, Dmitry V. Zakharychev, Ilya E. Kolesnikov, Irina R. Dayanova, Tatiana P. Gerasimova, Igor D. Strelnik, Elvira I. Musina, Andrey A. Karasik, Oleg Gerol'dovich Sinyashin

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  6. A Rare Structural Motif for a Luminescent Cu(I) Coordination Polymer with 3-(Pyridin-2-yl)triimidazotriazine

    Crystals · 2023-01-14

    Daniele Malpicci, Delia Blasi, Daniele Marinotto, Alessandra Forni, Elena Cariati, Elena Lucenti, Lucia Carlucci

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  7. The fluorescent detection of biothiols and antimicrobial study based on copper(I) iodide coordination polymer

    Dyes and Pigments · 2023-03-09

    Lin Si, Quanbin Fu, Zekun Shi, Tingting Zhang, Qin Hou, Zhixiang Xu, Shiyun Ai

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  8. One‐Dimensional Chiral Copper Iodide Chain‐Like Structure Cu 4 I 4 ( R / S ‐3‐quinuclidinol) 3 with Near‐Unity Photoluminescence Quantum Yield and Efficient Circularly Polarized Luminescence

    Small · 2023-03-18

    Jian Chen, Xin Pan, Xuanyu Zhang, Chen Sun, Congcong Chen, Xiaoqin Ji, Rui Chen, Lingling Mao

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  9. Mono‐ and Bi‐Dentate Chiral Ligands Lead to Efficient Circularly Polarized Luminescence in 0D and 3D Semiconducting Copper(I) Iodides

    Advanced Optical Materials · 2023-05-13

    Xiaoqin Ji, Yang Liu, Ruiqian Li, Zixuan Zhang, Xuanyu Zhang, Congcong Chen, Jian Chen, Haipeng Lu, Rui Chen, Lingling Mao

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  10. A copper(II) chloride coordination compound with an adamantane-like core

    Journal of Coordination Chemistry · 2023-05-19

    Benjamin Mukda, C.P. Landee, M. Rademeyer, Mark M. Turnbull, Brian Wells

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  11. Efficient blue-light-excitable copper(I) coordination network phosphors for high-performance white LEDs

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  12. One-Dimensional Organic–Inorganic Lead Bromide Hybrids with Excitation-Dependent White-Light Emission Templated by Pyridinium Derivatives

    Inorganic Chemistry · 2023-06-07

    Runan Chen, Chen Sun, Xiaohua Cheng, Yufan Lin, Jiaqian Zhou, Jun Li Yin, Bin‐Bin Cui, Lingling Mao

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  13. Highly sensitive and selective colorimetric and fluorescent dual-readout assay for the analysis of spermine, spermidine and cysteine

    Dyes and Pigments · 2023-08-30

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  14. Self-Assembly of an Anionic [Cu5I8]3– Supramolecular Cluster Driven by Ion-Pair Interaction and Catalytic Properties

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  15. Self-Assemblies of Isomeric Copper Iodide Trimers with Geometry-Dependent Photophysical Properties

    Chemistry of Materials · 2023-10-18

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  16. Cubane Dimerization: Cu4 vs Cu8 Copper Iodide Clusters

    Inorganic Chemistry · 2023-10-23

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  17. Matériaux photoluminescents à base de complexes de cuivre(I)

    Unknown journal · 2023-12-12

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  18. Design of luminescent complexes with different Cu 4 I 4 cores based on pyridyl phenoxarsines

    Dalton Transactions · 2023-12-15

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  19. A copper( i ) thiocyanate-based photoresponsive semiconducting 2D coordination polymer

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  20. Pyridine-amide-based hetero-copper iodide for the photocatalytic degradation of dyes and aerosol discolouration of VOC gases

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  21. Stabilization of copper iodide hybrids with increased strength of ionic bonding for lighting and X-ray imaging

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  22. Crystal structures of five gold(I) complexes with methylpiperidine ligands

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  23. Isomeric Zero-Dimensional Hybrid Copper(I) Iodides as Highly Efficient Multicolor Phosphors

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  24. Coordination complexes of isoquinoline with cobalt and nickel halides

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  25. Structure directing factors and photophysical properties of five Cu(I)-iodide materials with N-donor heteroaromatic ligands

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  26. 0D and 1D-dimensional Cu(I)-based halides pyridyltriazoles basis: Synthesis, Structures, and photophysical properties

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  27. Ultrastable Copper Iodide Hybrid with Intrinsic Greenish White-Light Emission by Incorporating an Anionic Inorganic Functional Unit into an Extended Structure

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  28. Activation of TADF in Photon Upconverting Crystals of Dinuclear Cu(I)-Iodide Complexes by Ligand Engineering

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  29. Copper Iodide Hybrid with Unique Cu3I3 Trimeric Inorganic Functional Unit and Far‐red/Near‐infrared Emission

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  30. Semiconducting Copper(I) Iodide 2D-Coordination Polymers for Efficient Sunlight-Driven Photocatalysis in Dye Degradation

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  31. Semiconducting 2D Copper(I) Framework for Sub-ppb-Level Ammonia Sensing

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  32. Photoactive Cluster-Organic frameworks with 1D Cu-I chain

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  33. Anomalous Pressure‐Induced Blue‐Shifted Emission of Ionic Copper‐Iodine Clusters: The Competitive Effect between Cuprophilic Interactions and Through‐Space Interactions

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  34. Anomalous Pressure‐Induced Blue‐Shifted Emission of Ionic Copper‐Iodine Clusters: The Competitive Effect between Cuprophilic Interactions and Through‐Space Interactions

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  35. Rational Design of Single‐Component White‐Light Emissive Molecular Copper Clusters

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  36. Ionothermal synthesis of a stable three-dimensional [Cu 4 I 4 ] cluster scintillator with near-unity quantum efficiency and weak thermal quenching

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  37. Application of Voronoi Polyhedra for Analysis of Electronic Dimensionality in Emissive Halide Materials

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  38. Ionothermal synthesis of a hybrid cuprous(I) iodide scintillator with efficient cyan emission and high antiwater stability

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  39. Multifunctional light-emitting materials based on hybrid copper iodide compounds

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  40. Near-unity room-temperature phosphorescence quantum yield induced by halogen–halogen interaction in chiral hybrid copper( i ) iodide clusters

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  41. New highly efficient phosphorescent manganese halides as green and blue emitters

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  42. Recent advances in mono- and multi-nuclear photoluminescent Cu( i ) complexes with nitrogen containing ligands and their stimuli responsiveness

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  43. Regulating charge transfer of copper( i ) coordination compounds via conformation engineering for highly efficient radioluminescence and 3D X-ray imaging

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  44. Trinuclear copper( i ) furanyl ortho -diphosphine halide clusters: structure, photophysical and photocatalytic hydrogen production properties

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  45. Controlling Triplet-Harvesting Pathways and Nonlinear Optical Properties in Cu(I) Iodide-Based Polymers through Ligand Engineering

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  46. Copper‐Iodide Cluster Ink for Fast and Robust Anti‐Counterfeiting and Erasable Encryption

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  47. Rigidity‐Regulated Copper(I) Halide Clusters Toward Highly Efficient Photoluminescence and Radioluminescence

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  48. Adjusting Cu⋯Cu distances by modification on ligands of four binuclear cuprous clusters to realize near-white-light emission

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  49. Amplified excited-state diverse effects arising from ligand regioisomerism in Cu( i ) complexes for advanced applications

    Journal of Materials Chemistry A · 2026-01-01

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  50. Diverse structures and emission properties of copper( i ) iodide complexes based on an oxadiazole-type ligand

    Dalton Transactions · 2026-01-01

    Alexey N. Gusev, Mikhail A. Kiskin, Elena Braga, Ekaterina Zamnius, Konstantin Zakharov, Andrey Sergeevich Tyutyunik, В. Г. Власенко, Ekaterina М. Zueva, Maria M. Petrova, Wolfgang Linert

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