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RESEARCH PAPER · Chemical Communications · 2017

Phosphorescent 2-, 3- and 4-coordinate cyclic (alkyl)(amino)carbene (CAAC) Cu( i ) complexes

Rasha Hamze, Rodolphe F. R. Jazzar, Michèle Soleilhavoup, Peter I. Djurovich, Guy Bertrand, Mark E. Thompson

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Phosphorescent 2-, 3- and 4-coordinate cyclic (alkyl)(amino)carbene (CAAC) Cu( i ) complexesOriginalSynthesis, Structures, and Photophysical Properties of a Series of Rare Near-IR Emitting Copper(I) Complexes77Synthesis and characterization of a gold( i ) bis(triazolylidene) complex featuring a large [(Tp Me2 ) 2 K] anion11Synthesis, structures and luminescence properties of amine-bis(N-heterocyclic carbene) copper( i ) and silver( i ) complexes29Spin-Vibronic Mechanism for Intersystem Crossing978Site-Selective Benzannulation of N-Heterocycles in Bidentate Ligands Leads to Blue-Shifted Emission from [(P^N)Cu]2(μ-X)2 Dimers50Highly Ambiphilic Room Temperature Stable Six-Membered Cyclic (Alkyl)(amino)carbenes147The chemistry of the carbon-transition metal double and triple bond: Annual survey covering the year 201725Photoactive Complexes with Earth-Abundant Metals597Mononuclear Silver Complexes for Efficient Solution and Vacuum‐Processed OLEDs108Synthesis of copper( i ) cyclic (alkyl)(amino)carbene complexes with potentially bidentate N^N, N^S and S^S ligands for efficient white photoluminescence34Eliminating nonradiative decay in Cu(I) emitters: >99% quantum efficiency and microsecond lifetime705Highly Efficient Photo- and Electroluminescence from Two-Coordinate Cu(I) Complexes Featuring Nonconventional N-Heterocyclic Carbenes336Tuning the Metal/Chalcogen Composition in Copper(I)–Chalcogenide Clusters with Cyclic (Alkyl)(amino)carbene Ligands25N-Heterocyclic Carbene Complexes of Copper, Nickel, and Cobalt468Atomically Defined Monocarborane Copper(I) Acetylides with Structural and Luminescence Properties Tuned by Ligand Sterics27Cu–F Interactions between Cationic Linear N-Heterocyclic Carbene Copper(I) Pyridine Complexes and Their Counterions Greatly Enhance Blue Luminescence Efficiency73Dendritic Carbene Metal Carbazole Complexes as Photoemitters for Fully Solution-Processed OLEDs102Triplet exciton diffusion in metalorganic phosphorescent host-guest systems from first principles23Synthesis, Structures, and Photophysical Properties of Novel Four-Coordinate Cu(I) Complexes Supported by Chelating N-Heterocyclic Carbene Ligands16Zwitterionic Mixed‐Carbene Coinage Metal Complexes: Synthesis, Structures, and Photophysical Studies21Yellow Circularly Polarized Luminescence from C1‐Symmetrical Copper(I) Complexes25Yellow Circularly Polarized Luminescence from C1‐Symmetrical Copper(I) Complexes102Synthèse et propriétés luminescentes de complexes de cuivre(I) stabilisés par des diphosphines ou des diimines macrocycliques0Design of Efficient Emissive Materials26Efficient methanol carbonylation to methyl acetate catalyzed by a cyclic(alkyl)(amino)carbene iridium complex9Modifying the luminescent properties of a Cu( i ) diphosphine complex using ligand-centered reactions in single crystals25Understanding the luminescence properties of Cu( i ) complexes: a quantum chemical perusal56Molecular dynamics of four-coordinate carbene-Cu(I) complexes employing tris(pyrazolyl)borate ligands6Two‐Coordinate Copper(I)/NHC Complexes: Dual Emission Properties and Ultralong Room‐Temperature Phosphorescence131Two‐Coordinate Copper(I)/NHC Complexes: Dual Emission Properties and Ultralong Room‐Temperature Phosphorescence20Revealing High-Lying Intersystem Crossing in Brightly Luminescent Cyclic Trinuclear CuI/AgI Complexes36Enhancement of the Luminescent Efficiency in Carbene-Au (I) -Aryl Complexes by the Restriction of Renner–Teller Distortion and Bond Rotation130Correction to “Cu–F Interactions between Cationic Linear N-Heterocyclic Carbene Copper(I) Pyridine Complexes and Their Counterions Greatly Enhance Blue Luminescence Efficiency”9Heteroleptic Cyclometalated NHC Iridium(III) complex with a bulky acetylacetonate: Photophysics of an unexplored class of compounds3Influence of Carbene and Phosphine Ligands on the Catalytic Activity of Gold Complexes in the Hydroamination and Hydrohydrazination of Alkynes58Cyclic (Alkyl)- and (Aryl)-(amino)carbene Coinage Metal Complexes and Their Applications320Understanding and Designing Thermally Activated Delayed Fluorescence Emitters: Beyond the Energy Gap Approximation94Cyclic (Amino)(aryl)carbenes Enter the Field of Chromophore Ligands: Expanded π System Leads to Unusually Deep Red Emitting CuI Compounds251RETRACTED ARTICLE: Mononuclear Cu Complexes Based on Nitrogen Heterocyclic Carbene: A Comprehensive Review2Highly Efficient Deep Blue Luminescence of 2-Coordinate Coinage Metal Complexes Bearing Bulky NHC Benzimidazolyl Carbene79Structural characterization, DFT studied, luminescent properties of cationic/neutral three‐coordinated copper (I) complexes and application in warm‐white light‐emitting diode10Mono- versus Bicyclic Carbene Metal Amide Photoemitters: Which Design Leads to the Best Performance?97Coinage-Metal-Based Cyclic Trinuclear Complexes with Metal–Metal Interactions: Theories to Experiments and Structures to Functions270Two‐Coordinate Cu(I) and Au(I) Complexes Supported by BICAAC and CAAC Ligands16Retraction Note to: Mononuclear Cu Complexes Based on Nitrogen Heterocyclic Carbene: A Comprehensive Review3Chiral complexes based on helicenic N-heterocyclic carbenes : synthesis, structure, photophysical and chiroptical properties0Phosphorescent monometallic and bimetallic two-coordinate Au(I) complexes with N-heterocyclic carbene and aryl ligands16Coordination modulated on-off switching of flexibility in a metal–organic framework21Synthesis and photophysical properties of linear gold( i ) complexes based on a CCC carbene9A Luminescent Two‐Coordinate AuI Bimetallic Complex with a Tandem‐Carbene Structure: A Molecular Design for the Enhancement of TADF Radiative Decay Rate36Luminescent coinage metal complexes of carbenes42Investigation on the photophysical properties of Cu(I) complexes supported by N‐heterocyclic carbene ligands with electron‐donating/withdrawing groups on imidazolylidene unit5Substituent Effect on the Circularly Polarized Luminescence of C1‐Symmetric Carbene‐Copper(I) Complexes18Imidazo[1,5-a]pyridinylidenes as π-Accepting NHC Ligands in Catalysis15Linear Carbene Pyridine Copper Complexes with Sterically Demanding N,N′-Bis(trityl)imidazolylidene: Syntheses, Molecular Structures, and Photophysical Properties37Cyclic (alkyl)(amino)carbene (CAAC) ligands: Electronic structure and application as chemically- and redox-non-innocent ligands and chromophores13Recent Advances in the Domain of Cyclic (Alkyl)(Amino) Carbenes106Nonclassical carbenes as noninnocent ligands1Luminescent copper(I) complexes bearing benzothiazole-imidazolylidene ligand with various substituents: Synthesis, photophysical properties and computational studies8Thiazoline Carbene–Cu(I)–Amide complexes: Efficient White Electroluminescence from Combined Monomer and Excimer Emission54Realizing 1,1‐Dehydration of Secondary Alcohols to Carbenes: Pyrrolidin‐2‐ols as a Source of Cyclic (Alkyl)(Amino)Carbenes6Realizing 1,1‐Dehydration of Secondary Alcohols to Carbenes: Pyrrolidin‐2‐ols as a Source of Cyclic (Alkyl)(Amino)Carbenes23Aggregation-Enhanced Emission in a Red Cu(I) Emitter with Quantum Yield >99%40Trigonal Copper(I) Complexes with Cyclic (Alkyl)(amino)carbene Ligands for Single-Photon Near-IR Triplet Emission23π-Extended Ligands in Two-Coordinate Coinage Metal Complexes95Synthesis and Photophysical Studies of Copper(I) CAAC Half-Sandwich Complexes as a Highly Modifiable Class of Emitters10Luminescent Complexes of Platinum, Iridium, and Coinage Metals Containing N -Heterocyclic Carbene Ligands: Design, Structural Diversity, and Photophysical Properties239Photoactive Copper Complexes: Properties and Applications376Light emission mechanism in dimers of carbene–metal–amide complexes10Highly phosphorescent carbene–metal–carboranyl complexes of copper( i ) and gold( i )6Towards Fast Circularly Polarized Luminescence in 2‐Coordinate Chiral Mechanochromic Copper(I) Carbene Complexes18A Rising Star: Luminescent Carbene‐Metal‐Amide Complexes51Two coordinate, monovalent copper complexes as chromophores and luminophores2Design and application of Earth abundant metal-based complexes for energy0Dft Investigation of Copper(I) in Linear Xcul' and (Lcul')+ (X = Cl, Ch3, Cn, Cf3, L = Co, Nh3, Ph3 and L' = C2h2, C2h4, C4h6, C6h6 and Nhc) Complexes: Electronic Structures and Nature Bonding from Energy Decomposition Analysis0How to tune luminescent Cu( i ) complexes with strong donor carbenes towards TADF?7Photophysical properties of copper(I), zinc(II) and nickel(II) complexes3Sulfonyl-functionalized benzo[ d ]imidazo[5,1- b ]thiazole-based carbenes as building blocks for two-coordinate Cu( i ) complexes exhibiting fast and efficient thermally activated delayed fluorescence15Two-coordinate, monovalent copper complexes as chromophores and luminophores0Two-Coordinate Thermally Activated Delayed Fluorescence Coinage Metal Complexes: Molecular Design, Photophysical Characters, and Device Application183Nature of the chemical bonding and electronic structure of dicoordinated copper(I) complexes of alkenes, alkynes, and NHC ligands: a DFT overview4A Strongly Ambiphilic Ferrocene‐Based Cyclic (Alkyl)(amino)carbene – Specific Decomposition to an Enamine by a 1,2‐Phenyl Shift4Study of the molecular design and synthesis status of metal complexes as unimolecular luminescent materials for white light emission9Redox Dependent Color Modulating Copper(I) Complex for Flexible Electrochromic Device3Photoactive Neutral Three-Coordinate Cu(I) Complexes of Anionic N-Heterocyclic Carbenes9Luminescent N-heterocyclic carbene Cu( i ) complexes with N^O chelating ligands exhibit microsecond lifetimes and photocatalytic activity2Carbene‐Induced Reversible and Complete Decoordination of Tridentate Trispyrazolylborate Ligands in Copper Complexes0D 2 -Symmetrical Cu 8 S 4 Clusters Supported by Chiral Carbenes Exhibiting Circularly Polarized Luminescence0High Radiative Rate and Brightness Electroluminescent Cu(I) Complexes via Carbene‐Induced Electronic Coupling Enhancement0

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  1. Synthesis, Structures, and Photophysical Properties of a Series of Rare Near-IR Emitting Copper(I) Complexes

    Inorganic Chemistry · 2017-07-25

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  2. Synthesis and characterization of a gold( i ) bis(triazolylidene) complex featuring a large [(Tp Me2 ) 2 K] anion

    New Journal of Chemistry · 2018-01-01

    Armando Priante-Flores, Verónica Salazar, Arnold L. Rheingold, Daniel Mendoza‐Espinosa

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  3. Synthesis, structures and luminescence properties of amine-bis(N-heterocyclic carbene) copper( i ) and silver( i ) complexes

    Dalton Transactions · 2018-01-01

    Taotao Lu, Jin-Yun Wang, Lin‐Xi Shi, Zhong‐Ning Chen, Xue‐Tai Chen, Zi‐Ling Xue

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  4. Spin-Vibronic Mechanism for Intersystem Crossing

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  5. Site-Selective Benzannulation of N-Heterocycles in Bidentate Ligands Leads to Blue-Shifted Emission from [(P^N)Cu]2(μ-X)2 Dimers

    Inorganic Chemistry · 2018-04-12

    Rajarshi Mondal, Issiah B. Lozada, Rebecca L. Davis, J. A. Gareth Williams, David E. Herbert

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  6. Highly Ambiphilic Room Temperature Stable Six-Membered Cyclic (Alkyl)(amino)carbenes

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    Cory M. Weinstein, Glen P. Junor, Daniel R. Tolentino, Rodolphe F. R. Jazzar, Mohand Melaïmi, Guy Bertrand

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  7. The chemistry of the carbon-transition metal double and triple bond: Annual survey covering the year 2017

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  8. Photoactive Complexes with Earth-Abundant Metals

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  9. Mononuclear Silver Complexes for Efficient Solution and Vacuum‐Processed OLEDs

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  10. Synthesis of copper( i ) cyclic (alkyl)(amino)carbene complexes with potentially bidentate N^N, N^S and S^S ligands for efficient white photoluminescence

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  11. Eliminating nonradiative decay in Cu(I) emitters: >99% quantum efficiency and microsecond lifetime

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  12. Highly Efficient Photo- and Electroluminescence from Two-Coordinate Cu(I) Complexes Featuring Nonconventional N-Heterocyclic Carbenes

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  13. Tuning the Metal/Chalcogen Composition in Copper(I)–Chalcogenide Clusters with Cyclic (Alkyl)(amino)carbene Ligands

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  14. N-Heterocyclic Carbene Complexes of Copper, Nickel, and Cobalt

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  15. Atomically Defined Monocarborane Copper(I) Acetylides with Structural and Luminescence Properties Tuned by Ligand Sterics

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  16. Cu–F Interactions between Cationic Linear N-Heterocyclic Carbene Copper(I) Pyridine Complexes and Their Counterions Greatly Enhance Blue Luminescence Efficiency

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  17. Dendritic Carbene Metal Carbazole Complexes as Photoemitters for Fully Solution-Processed OLEDs

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  18. Triplet exciton diffusion in metalorganic phosphorescent host-guest systems from first principles

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  19. Synthesis, Structures, and Photophysical Properties of Novel Four-Coordinate Cu(I) Complexes Supported by Chelating N-Heterocyclic Carbene Ligands

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  20. Zwitterionic Mixed‐Carbene Coinage Metal Complexes: Synthesis, Structures, and Photophysical Studies

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  21. Yellow Circularly Polarized Luminescence from C1‐Symmetrical Copper(I) Complexes

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  22. Yellow Circularly Polarized Luminescence from C1‐Symmetrical Copper(I) Complexes

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  23. Synthèse et propriétés luminescentes de complexes de cuivre(I) stabilisés par des diphosphines ou des diimines macrocycliques

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  24. Design of Efficient Emissive Materials

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  25. Efficient methanol carbonylation to methyl acetate catalyzed by a cyclic(alkyl)(amino)carbene iridium complex

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  26. Modifying the luminescent properties of a Cu( i ) diphosphine complex using ligand-centered reactions in single crystals

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  27. Understanding the luminescence properties of Cu( i ) complexes: a quantum chemical perusal

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  28. Molecular dynamics of four-coordinate carbene-Cu(I) complexes employing tris(pyrazolyl)borate ligands

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  29. Two‐Coordinate Copper(I)/NHC Complexes: Dual Emission Properties and Ultralong Room‐Temperature Phosphorescence

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  30. Two‐Coordinate Copper(I)/NHC Complexes: Dual Emission Properties and Ultralong Room‐Temperature Phosphorescence

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  31. Revealing High-Lying Intersystem Crossing in Brightly Luminescent Cyclic Trinuclear CuI/AgI Complexes

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  32. Enhancement of the Luminescent Efficiency in Carbene-Au (I) -Aryl Complexes by the Restriction of Renner–Teller Distortion and Bond Rotation

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  33. Correction to “Cu–F Interactions between Cationic Linear N-Heterocyclic Carbene Copper(I) Pyridine Complexes and Their Counterions Greatly Enhance Blue Luminescence Efficiency”

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  34. Heteroleptic Cyclometalated NHC Iridium(III) complex with a bulky acetylacetonate: Photophysics of an unexplored class of compounds

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  35. Influence of Carbene and Phosphine Ligands on the Catalytic Activity of Gold Complexes in the Hydroamination and Hydrohydrazination of Alkynes

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  36. Cyclic (Alkyl)- and (Aryl)-(amino)carbene Coinage Metal Complexes and Their Applications

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  37. Understanding and Designing Thermally Activated Delayed Fluorescence Emitters: Beyond the Energy Gap Approximation

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  38. Cyclic (Amino)(aryl)carbenes Enter the Field of Chromophore Ligands: Expanded π System Leads to Unusually Deep Red Emitting CuI Compounds

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  39. RETRACTED ARTICLE: Mononuclear Cu Complexes Based on Nitrogen Heterocyclic Carbene: A Comprehensive Review

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  40. Highly Efficient Deep Blue Luminescence of 2-Coordinate Coinage Metal Complexes Bearing Bulky NHC Benzimidazolyl Carbene

    Frontiers in Chemistry · 2020-05-08

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  41. Structural characterization, DFT studied, luminescent properties of cationic/neutral three‐coordinated copper (I) complexes and application in warm‐white light‐emitting diode

    Applied Organometallic Chemistry · 2020-05-15

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  42. Mono- versus Bicyclic Carbene Metal Amide Photoemitters: Which Design Leads to the Best Performance?

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  43. Coinage-Metal-Based Cyclic Trinuclear Complexes with Metal–Metal Interactions: Theories to Experiments and Structures to Functions

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  44. Two‐Coordinate Cu(I) and Au(I) Complexes Supported by BICAAC and CAAC Ligands

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  45. Retraction Note to: Mononuclear Cu Complexes Based on Nitrogen Heterocyclic Carbene: A Comprehensive Review

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  46. Chiral complexes based on helicenic N-heterocyclic carbenes : synthesis, structure, photophysical and chiroptical properties

    Unknown journal · 2020-11-26

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  47. Phosphorescent monometallic and bimetallic two-coordinate Au(I) complexes with N-heterocyclic carbene and aryl ligands

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  48. Coordination modulated on-off switching of flexibility in a metal–organic framework

    Chemical Science · 2021-01-01

    Jorge Albalad, Ricardo A. Peralta, Michael Thomas Huxley, Steven Tsoukatos, Zhaolin Shi, Yue‐Biao Zhang, Jack D. Evans, Christopher J. Sumby, Christian J. Doonan

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  49. Synthesis and photophysical properties of linear gold( i ) complexes based on a CCC carbene

    Dalton Transactions · 2021-01-01

    Alexander S. Romanov, Mikko Linnolahti, Manfred Bochmann

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  50. A Luminescent Two‐Coordinate AuI Bimetallic Complex with a Tandem‐Carbene Structure: A Molecular Design for the Enhancement of TADF Radiative Decay Rate

    Chemistry - A European Journal · 2021-02-10

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