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RESEARCH PAPER · Inorganic Chemistry · 2020

Dicopper(I) Paddle-Wheel Complexes with Thermally Activated Delayed Fluorescence Adjusted by Ancillary Ligands

Alexander V. Artem’ev, Maria P. Davydova, Alexey S. Berezin, Maxim R. Ryzhikov, Denis G. Samsonenko⧫

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Dicopper(I) Paddle-Wheel Complexes with Thermally Activated Delayed Fluorescence Adjusted by Ancillary LigandsOriginalCoordination‐Driven Supramolecular Synthesis Based on Bimetallic Cu(I) Precursors: Adaptive Behavior and Luminescence32A series of luminescent Cu( i ) complexes based on the diphosphine ligand and diimine ligand: weak intermolecular interactions, terahertz spectroscopy and photoproperties5Coordination-driven supramolecular syntheses of new homo- and hetero-polymetallic Cu( i ) assemblies: solid-state and solution characterization11Coordination-induced emission enhancement in copper( i ) iodide coordination polymers supported by 2-(alkylsulfanyl)pyrimidines40Efficiently luminescent mononuclear copper iodide complexes with sterically hindered iminephosphine chelating ligands17Self-assembled luminescent Cu( i ) tetranuclear metallacycles based on 3,3′-bipyridine ligands20Investigation of Structural Changes of Cu(I) and Ag(I) Complexes Utilizing a Flexible, Yet Sterically Demanding Multidentate Phosphine Oxide Ligand15Heteroleptic Cu(I) halide complexes with perchlorinated 1,10-phenanthroline14Syntheses, Crystal Structures and Photophysical Properties of Dinuclear Copper(I) Complexes Bearing Diphenylphosphino‐Substituted Benzimidazole Ligands7Cu(I) complexes designed on 2-pyrimidylphosphine and 1,4-dicyanobenzene: Synthesis and thermally activated delayed fluorescence16Crystalline Metal‐Organic Materials with Thermally Activated Delayed Fluorescence59P∩N Bridged Cu(I) Dimers Featuring Both TADF and Phosphorescence. From Overview towards Detailed Case Study of the Excited Singlet and Triplet States30A Halomanganates(II) with P,P’-Diprotonated Bis(2-Diphenylphosphinophenyl)ether: Wavelength-Excitation Dependence of the Quantum Yield and Role of the Non-Covalent Interactions19Luminescent cationic/neutral Cu(I) complexes for use in light-emitting diodes: Synthesis, structural characterization, DFT studies and properties11A brightly emissive halomanganates(II) with triphenylphosphonium cation: Synthesis, luminescence, and up-conversion phenomena25TADF: Enabling luminescent copper( i ) coordination compounds for light-emitting electrochemical cells162Highly phosphorescent dinuclear Cu(I) complexes with iminephosphine tetradentate chelating ligand (PNNP): Structures and luminescence properties7Access to Perfluorometallacyclopentane Complexes of Cobalt through the [(MeCN)4Co(C4F8)][PF6] Precursor4Excellent Blue Emissive Neutral Cu(I) Complexes: Structural Analysis, Thermochromic Luminescent Properties, and Terahertz Spectrum Research17Luminescent Cu(I) and Au(I) complexes based on diphenyl(5-pyrimidyl)phosphine13Fabrication of a Solution-Processed White Light Emitting Diode Containing a Single Dimeric Copper(I) Emitter Featuring Combined TADF and Phosphorescence21QM/MM Studies on Thermally Activated Delayed Fluorescence of a Dicopper Complex in the Solid State26A COPPER(I) COORDINATION COMPOUND WITH RED PHOTOLUMINESCENCE3Thermally activated delayed fluorescence in luminescent cationic copper( i ) complexes51Coinage Metal Complexes of Bis(quinoline‐2‐ylmethyl)phenylphosphine‐Simple Reactions Can Lead to Unprecedented Results11Asymmetric Coordination Mode of Phenanthroline-like Ligands in Gold(I) Complexes: A Case of the Antichelate Effect21Regulated Adaptive Self-Assembly of Cu3I3 Supramolecular Clusters and their Photocatalytic Properties8Thermo-, Mechano-, and Vapochromic Dinuclear Cuprous-Emissive Complexes with a Switchable CH3CN–Cu Bond19Deep-Blue Emissive Copper(I) Complexes Based on P-Thiophenylethyl-Substituted Cyclic Bisphosphines Displaying Photoinduced Structural Transformations of the Excited States19Interaction of N -nitrosamines with binuclear copper complexes for luminescent detection4Recent advances in the design of afterglow materials: mechanisms, structural regulation strategies and applications475Rotational isomerization: spontaneous structural transformation of a thermally activated delayed fluorescence binuclear copper( i ) complex6A Novel Photoluminescent Ag/Cu Cluster Exhibits a Chromic Photoluminescence Response towards Volatile Organic Vapors3From K6[Re6−xMoxS8(CN)5] Solid Solution to Individual Cluster Complexes: Separation and Investigation of [Re4Mo2S8(CN)6]n− and [Re3Mo3S8(CN)6]n− Heterometallic Clusters9AgNO3 COMPLEXES WITH DIPHENYL(2-PYRIMIDYL) PHOSPHINE: SYNTHESIS, STRUCTURE, LUMINESCENT PROPERTIES3A super-stable Cu( i )-based polymer exhibiting thermally activated delayed fluorescence and water/acid-resistant properties6From Mono- to Polynuclear 2-(Diphenylphosphino)pyridine-Based Cu(I) and Ag(I) Complexes: Synthesis, Structural Characterization, and DFT Calculations111D, 2D and 3D networks based on group 11 metal ions and (pyrazin-2-ylmethyl)phosphines: synthesis, metallophilic interactions and emission properties6Two-Coordinate Thermally Activated Delayed Fluorescence Coinage Metal Complexes: Molecular Design, Photophysical Characters, and Device Application183Ultraviolet up-conversion luminescent tetrahalozincates(II) with triphenylphosphonium cation: Synthesis, optical properties, and DFT calculations4Thermally Activated Delayed Fluorescence (TADF) Materials Based on Earth‐Abundant Transition Metal Complexes: Synthesis, Design and Applications78Thermally Activated Delayed Fluorescence and Beyond. Photophysics and Material Design Strategies.24Metal complex-based TADF: design, characterization, and lighting devices78Blue to yellow-emitting neutral Cu( i ) complexes with μ-bridging 1,2,4-triazole: synthesis, photophysical characterization and DFT calculations4Tunable dual-emission in a hybrid [Ph3PH]2[ZnI4] system: The role of {ZnI…HP} interactions and proton transfer in 3ILCT/3L(X + M)CT phosphorescence1Lantern-type complexes of the first row transition metals: Experimental and computational insights into ground state metal-metal bond lengths and bond orders0Tris(2-pyrimidyl)- and tris(5-pyrimidyl)phosphines: new multidentate ligands with diverse coordination chemistry0Crystallization-Induced Coordination Diversity of Cu(I)-Pyridine Halide Complexes Resulting in Optical Tunability4Switching Colors: Multiple Emission in a Manganese(II) Bromide Compound0Chiral Ligand Engineering Enables High-Contrast Stimuli-Responsive Luminescence and Circularly Polarized Luminescence in Enantiomeric Dinuclear Cu(I) Complexes0Long-lived room temperature phosphorescence and short-lived ultraviolet fluorescence: Dual-emission in a hybrid [Ph3PH][BF4] salt - for multiplexed anti-counterfeiting0

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  5. Efficiently luminescent mononuclear copper iodide complexes with sterically hindered iminephosphine chelating ligands

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  7. Investigation of Structural Changes of Cu(I) and Ag(I) Complexes Utilizing a Flexible, Yet Sterically Demanding Multidentate Phosphine Oxide Ligand

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  8. Heteroleptic Cu(I) halide complexes with perchlorinated 1,10-phenanthroline

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  9. Syntheses, Crystal Structures and Photophysical Properties of Dinuclear Copper(I) Complexes Bearing Diphenylphosphino‐Substituted Benzimidazole Ligands

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  10. Cu(I) complexes designed on 2-pyrimidylphosphine and 1,4-dicyanobenzene: Synthesis and thermally activated delayed fluorescence

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  11. Crystalline Metal‐Organic Materials with Thermally Activated Delayed Fluorescence

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  12. P∩N Bridged Cu(I) Dimers Featuring Both TADF and Phosphorescence. From Overview towards Detailed Case Study of the Excited Singlet and Triplet States

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  18. Access to Perfluorometallacyclopentane Complexes of Cobalt through the [(MeCN)4Co(C4F8)][PF6] Precursor

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  30. Interaction of N -nitrosamines with binuclear copper complexes for luminescent detection

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