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RESEARCH PAPER · Journal of the American Chemical Society · 2018

A Stable, Narrow-Gap Oxyfluoride Photocatalyst for Visible-Light Hydrogen Evolution and Carbon Dioxide Reduction

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A Stable, Narrow-Gap Oxyfluoride Photocatalyst for Visible-Light Hydrogen Evolution and Carbon Dioxide ReductionOriginalFacile Synthesis of Ag/AgCl Grafted AgBi(MoO4)2 with Enhanced Photocatalytic Performance Under Visible Light2Perovskite Oxide LaNiO3 Nanoparticles for Boosting H2 Evolution over Commercial CdS with Visible Light82Kazuhiko Maeda0Kazuhiko Maeda0One-pot synthesis of BaMg1/3Ta2/3O3-xNy/Ta3N5 heterostructures as H2-evolving photocatalysts for construction of visible-light-driven Z-scheme overall water splitting64Development of Mixed‐Anion Photocatalysts with Wide Visible‐Light Absorption Bands for Solar Water Splitting60Hetero-metallic active sites coupled with strongly reductive polyoxometalate for selective photocatalytic CO 2 -to-CH 4 conversion in water145Two-Dimensional Metal Oxide Nanosheets as Building Blocks for Artificial Photosynthetic Assemblies192Copolymerization Approach to Improving Ru(II)-Complex/C3N4 Hybrid Photocatalysts for Visible-Light CO2 Reduction44A Visible-Light-Driven Z-Scheme CO2 Reduction System Using Ta3N5 and a Ru(II) Binuclear Complex30Light Absorption Properties and Electronic Band Structures of Lead Titanium Oxyfluoride Photocatalysts Pb 2 Ti 4 O 9 F 2 and Pb 2 Ti 2 O 5.4 F 1.238Photocatalytic Reduction on Bismuth-Based p-Block Semiconductors87Formation of Hierarchical Co 9 S 8 @ZnIn 2 S 4 Heterostructured Cages as an Efficient Photocatalyst for Hydrogen Evolution852A BiOCl-CuO photocatalyst based on p-n heterojunction and its photocatalytic performance under visible-light77Photoelectrocatalytic Reduction of Carbon Dioxide to Methanol Using CuFe2O4 Modified with Graphene Oxide under Visible Light Irradiation82Control of Spatially Homogeneous Distribution of Heteroatoms to Produce Red TiO2 Photocatalyst for Visible‐Light Photocatalytic Water Splitting36Mixed-Anion Compounds: A New Trend in Solid State Chemistry3Argonne Leadership Computing Facility (2018 Annual Report)2A symbiotic hetero-nanocomposite that stabilizes unprecedented CaCl 2 -type TiO 2 for enhanced solar-driven hydrogen evolution reaction26A zinc-based oxysulfide photocatalyst SrZn 2 S 2 O capable of reducing and oxidizing water26Band gap engineering and transport properties of Ba 2 In 2 O 5 : effect of fluorine doping and hydration9Enhanced charge separation and transport efficiency induced by vertical slices on the surface of carbon nitride for visible-light-driven hydrogen evolution5Molybdenum Sulfide within a Metal–Organic Framework for Photocatalytic Hydrogen Evolution from Water23Preparation of a magnetic mesoporous Fe 3 O 4 –Pd@TiO 2 photocatalyst for the efficient selective reduction of aromatic cyanides16Reactive solid phase epitaxy of layered aurivillius-type oxyfluorides Bi 2 TiO 4 F 2 using polyvinylidene fluoride9Visible-Light Bismuth Iron Molybdate Photocatalyst for Artificial Nitrogen Fixation32Structure and Photocatalytic Activity of PdCrOx Cocatalyst on SrTiO3 for Overall Water Splitting29Monometallic Catalytic Models Hosted in Stable Metal–Organic Frameworks for Tunable CO2 Photoreduction3841.金属錯体光触媒を用いた二酸化炭素還元と複合系への展開0A BiOCl/β-FeOOH heterojunction for HER photocatalytic performance under visible-light illumination18Optoelectronic Structure and Photocatalytic Applications of Na(Bi,La)S2 Solid Solutions with Tunable Band Gaps18Oxygen-vacancies-engaged efficient carrier utilization for the photocatalytic coupling reaction55Metal‐Complex/Semiconductor Hybrid Photocatalysts and Photoelectrodes for CO2 Reduction Driven by Visible Light280Encapsulating a Ni(II) molecular catalyst in photoactive metal–organic framework for highly efficient photoreduction of CO268Oxygen‐Doped Ta3N5 Nanoparticles for Enhanced Z‐Scheme Carbon Dioxide Reduction with a Binuclear Ruthenium(II) Complex under Visible Light13Recent advances in copper ferrite nanoparticles and nanocomposites synthesis, magnetic properties and application in water treatment: Review284Highly Selective Photoreduction of CO2 with Suppressing H2 Evolution over Monolayer Layered Double Hydroxide under Irradiation above 600 nm286Highly Selective Photoreduction of CO2 with Suppressing H2 Evolution over Monolayer Layered Double Hydroxide under Irradiation above 600 nm72Low-temperature formation of Pb2OF2 with O/F anion ordering by solid state reaction9Supporting Ultrathin ZnIn 2 S 4 Nanosheets on Co/N‐Doped Graphitic Carbon Nanocages for Efficient Photocatalytic H 2 Generation438Particulate Photocatalysts for Light-Driven Water Splitting: Mechanisms, Challenges, and Design Strategies2808Spinel‐Type Mixed Metal Sulfide NiCo2S4 for Efficient Photocatalytic Reduction of CO2 with Visible Light43Solar-Driven Photoelectrochemical Water Oxidation over an n-Type Lead–Titanium Oxyfluoride Anode51Unravelling the Promotional Effect of La2O3 in Pt/La‐TiO2 Catalysts for CO2 Hydrogenation23Amine functionalized homoleptic ruthenium(II) sensitizer for dye‐sensitized solar cells: A combined effect of ancillary ligands and co‐sensitization14Oxyfluoride Pb2Ti4O9F2 as a Stable Anode Material for Photoelectrochemical Water Oxidation20Activation of a Pt-loaded Pb 2 Ti 2 O 5.4 F 1.2 photocatalyst by alkaline chloride treatment for improved H 2 evolution under visible light14Fabrication of hierarchical Co 3 O 4 @CdIn 2 S 4 p–n heterojunction photocatalysts for improved CO 2 reduction with visible light254Formation of breathing pyrochlore lattices: structural, thermodynamic and crystal chemical aspects33Structure of the water-splitting photocatalyst oxysulfide α-LaOInS 2 and ab initio prediction of new polymorphs28The InSe/SiH type-II van der Waals heterostructure as a promising water splitting photocatalyst: a first-principles study46Light Absorption Properties and Electronic Band Structures of Lead‐Vanadium Oxyhalide Apatites Pb5(VO4)3X (X=F, Cl, Br, I)12600 nm Irradiation-Induced Efficient Photocatalytic CO2 Reduction by Ultrathin Layered Double Hydroxide Nanosheets79600 nm-driven photoreduction of CO2 through the topological transformation of layered double hydroxides nanosheets66Oxysulfide Ba5(VO2S2)2(S2)2 Combining Disulfide Channels and Mixed-Anion Tetrahedra and Its Third-Harmonic-Generation Properties15Constructing Fe-MOF-Derived Z-Scheme Photocatalysts with Enhanced Charge Transport: Nanointerface and Carbon Sheath Synergistic Effect298Triple-layered Sillén–Aurivillius Perovskite Oxychloride Bi5PbTi3O14Cl as a Visible-light-responsive Photocatalyst for Water Splitting15Photocatalytic CO2 Reduction Using a Robust Multifunctional Iridium Complex toward the Selective Formation of Formic Acid163Photoinduced Defect and Surface Chemistry of Niobium Tellurium Oxides ANbTeO6 (A = K, Rb, Cs) with Defect-Pyrochlore Structure24Sr5Ga8O3S14: A Nonlinear Optical Oxysulfide with Melilite-Derived Structure and Wide Band Gap48Selective CO2 reduction into formate using Ln–Ta oxynitrides combined with a binuclear Ru(II) complex under visible light18Synthesis of NaMoO3F and Na5W3O9F5 with Morphological Controllability in Non-Aqueous Solvents15Development of Catalytic Reduction of Renewable Carbon Resources Using Well-Elaborated Organometallic Complexes with PNNP Tetradentate Ligands42D β-NiS as electron harvester anchors on 2D ZnIn2S4 for boosting photocatalytic hydrogen production91Recent Progress in Mixed‐Anion Materials for Solar Fuel Production58A bifunctional lead–iron oxyfluoride, PbFeO 2 F, that functions as a visible-light-responsive photoanode and an electrocatalyst for water oxidation5Photochemical reduction of carbon dioxide to formic acid115Pyrochlore oxides as visible light-responsive photocatalysts39Synthesis, band structure and photocatalytic properties of Sillén–Aurivillius oxychlorides BaBi 5 Ti 3 O 14 Cl, Ba 2 Bi 5 Ti 4 O 17 Cl and Ba 3 Bi 5 Ti 5 O 20 Cl with triple-, quadruple- and quintuple-perovskite layers43600 nm induced nearly 99% selectivity of CH4 from CO2 photoreduction using defect-rich monolayer structures55Lattice Disorder and Oxygen Migration Pathways in Pyrochlore and Defect-Fluorite Oxides44Enhanced cocatalyst-support interaction and promoted electron transfer of 3D porous g-C3N4/GO-M (Au, Pd, Pt) composite catalysts for hydrogen evolution226New Visible‐Light‐Responsive Photocatalysts for Water Splitting Based on Mixed Anions1Rational design of stratified material with spatially separated catalytic sites as an efficient overall water-splitting photocatalyst26Visible-Light-Driven Water Splitting over Particulate LaNbON2 Prepared from La-Rich Lanthanum Niobium Oxides20An Investigation of Photocatalytic Activity of Coatings Based on Strontium Bismuthate Deposited on a Ceramic Carrier1Water Splitting with a Single-Atom Cu/TiO 2 Photocatalyst: Atomistic Origin of High Efficiency and Proposed Enhancement by Spin Selection134S = 1/2 Chain in BiVO3F: Spin Dimers versus Photoanodic Properties19MOF–derived hollow porous ZnFe2O4/AgCl/Ag/C nanotubes with magnetic–dielectric synergy as high–performance photocatalysts for hydrogen evolution reaction39Sn-Based Perovskite with a Wide Visible-Light Absorption Band Assisted by Hydride Doping16Molecule/Semiconductor Hybrid Materials for Visible-Light CO 2 Reduction: Design Principles and Interfacial Engineering99Ni-doped MoS2 modified graphitic carbon nitride layered hetero-nanostructures as highly efficient photocatalysts for environmental remediation53Quinoline‐Coupled Coumarin‐Based Ruthenium(II) Dye Sensitizer for Photoelectrochemical Cells and Solar Cells: A Mimic for an Artificial‐Light‐Harvesting System5Durable Metal Heteroanionic Photocatalysts24Development of Sn2+-based oxyfluoride photocatalyst with visible light response of ca. 650 nm via strengthened hybridization of Sn 5s and O 2p orbitals20Lattice disorder and oxygen migration pathways in pyrochlore and defect-fluorite oxides2Electrochemical Crystal Growth of Titanium Oxyfluorides—A Strategy for Development of Electron-Doped Materials2Exploring novel functional properties arose from anion order in mixed anion compounds1Controllable Syntheses, Crystal Structure Evolution, and Photoluminescence of Polymorphic Zirconium Oxyfluorides6Effect of Micropores of a Porous Coordination Polymer on the Product Selectivity in RuII Complex‐catalyzed CO2 Reduction6Bi4AO6Cl2 (A = Ba, Sr, Ca) with Double and Triple Fluorite Layers for Visible-Light Water Splitting17High thermal stability of doped oxide semiconductor for monolithic 3D integration11Recent Progress on Mixed-Anion Materials for Energy Applications110Enhancement of photocatalytic properties of nanosized La2Ti2O7 synthesized by glycine-assisted sol-gel route10Synthesis of Fluoride-Substituted Layered Perovskites ZnMoO4 with an Enhanced Photocatalytic Activity9A two-dimensional perovskite oxyfluoride Pb 3 Fe 2 O 5 F 2 as a catalyst for electrochemical oxidation of water to oxygen9An unusual O 2− /F − distribution in the new pyrochlore oxyfluorides: Na 2 B 2 O 5 F 2 (B = Nb, Ta)6Anionic ordering in Pb 2 Ti 4 O 9 F 2 revisited by nuclear magnetic resonance and density functional theory3CO2 Reduction Using Molecular Photocatalysts2Importance of steric bulkiness of iridium photocatalysts with PNNP tetradentate ligands for CO 2 reduction16Low Temperature Synthesis of Oxyfluoride Csti2o2.85f3.15 from a Layered Oxide Cs0.68ti1.83o41Manipulation of charge carrier flow in Bi 4 NbO 8 Cl nanoplate photocatalyst with metal loading40Pyrochlore-structural Nd 2 Ta 2 O 5 N 2 photocatalyst with an absorption edge of over 600 nm for Z-scheme overall water splitting11Pyrochlores: Prospects as a photocatalyst for environmental and energy applications3Structural dimension modulation in a new oxysulfide system of Ae 2 Sb 2 O 2 S 3 (Ae = Ca and Ba)4Multi anion-based materials: Synthesis and catalytic applications30Synthesis of Hydride-Doped Perovskite Stannate with Visible Light Absorption Capability6Improvement of Visible‐Light H2 Evolution Activity of Pb2Ti2O5.4F1.2 Photocatalyst by Coloading of Rh and Pd Cocatalysts5Low temperature synthesis of oxyfluoride CsTi2O2.85F3.15 from a layered oxide Cs0.68Ti1.83O43First Investigation of Nonlinear Optical Oxychalcogenide with Three‐Dimensional Anionic Framework and Special Windmill‐Like Functional Motifs †28Bi12O17Cl2 with a Sextuple BiO Layer Composed of Rock‐Salt and Fluorite Units and its Structural Conversion through Fluorination to Enhance Photocatalytic Activity31A core-satellite structured type II heterojunction photocatalyst with enhanced CO2 reduction under visible light48Two-dimensional SiC/AlN based type-II van der Waals heterobilayer as a promising photocatalyst for overall water disassociation22A band-to-band transition visible-light-responsive anatase titania photocatalyst by N,F-codoping for water splitting and CO 2 reduction17Layered β‐ZrNBr Nitro‐Halide as Multifunctional Photocatalyst for Water Splitting and CO2 Reduction7Layered β‐ZrNBr Nitro‐Halide as Multifunctional Photocatalyst for Water Splitting and CO2 Reduction32Promoting Photocatalytic Carbon Dioxide Reduction by Tuning the Properties of Cocatalysts20New Pyrochlore-like Oxyfluorides Na2–2xSnxM2O5F2 (M = Nb5+ or Ta5+ and 1 ≤ x ≤ 0) as Potential Candidates for Overall Water Splitting Photocatalysis8A Review on Heteroanionic-Based Materials for Photocatalysis Applications37Visible‐light‐responsive Photocatalyst Based on Nitrogen‐doped Bulk Oxide YTaO4−xNy for Z‐scheme Overall Water Splitting7Highly efficient visible-light photocatalytic hydrogen production using ZIF-derived Co9S8/N, S-CNTs-ZnIn2S4 composite16Tremella-like Boron-doped hierarchical CN and dispersion Co phthalocyanine assembling heterojunction for photocatalytic hydrogen evolution21Molten Salts‐Driven Discovery of a Polar Mixed‐Anion 3D Framework at the Nanoscale: Zn4Si2O7Cl2, Charge Transport and Photoelectrocatalytic Water Splitting1Molten Salts‐Driven Discovery of a Polar Mixed‐Anion 3D Framework at the Nanoscale: Zn4Si2O7Cl2, Charge Transport and Photoelectrocatalytic Water Splitting0Reduction of a Band Gap and Visible-Light Photocatalytic Activity Induced by the Interaction between 6s and 2p Orbitals known as Revised Lone Pair Model0Fluorosulfide La 2+ x Sr 1– x F 4+ x S 2 with a Triple-Fluorite Layer Enabling Interstitial Fluoride-Ion Conduction20Sn2+-based pyrochlore oxysulfides with narrow band gaps for photocatalytic water splitting11Bismuth-based nanomaterials-assisted photocatalytic water splitting for sustainable hydrogen production70Impact of Anionic Ordering on the Iron Site Distribution and Valence States in Oxyfluoride Sr2FeO3+xF1–x (x = 0.08, 0.2) with a Layered Perovskite Network8Orbital Engineering in Sillén–Aurivillius Phase Bismuth Oxyiodide Photocatalysts through Interlayer Interactions37Low-Temperature Microwave-Assisted Hydrothermal Synthesis of Pb2Ti2O5.4F1.2 Photocatalyst for Improved H2 Evolution under Visible Light16Topochemical Fluorination of LaBaInO 4 to LaBaInO 3 F 2 , Their Optical Characterization, and Photocatalytic Activities for Hydrogen Evolution10Photoelectrochemical Water Oxidation over Pb2Ti2O5.4F1.2 Photoanodes Prepared by the Particle Transfer Method5Structural modeling of oxygen-fluorine ordering in transition metal inorganic oxyfluorides0Tetrazine‐Linked Covalent Organic Frameworks With Acid Sensing and Photocatalytic Activity88Facile synthesis of Zn 0.5 Cd 0.5 S nanosheets with tunable S vacancies for highly efficient photocatalytic hydrogen evolution19Internal strain-driven bond manipulation and band engineering in Bi 2− x Sb x YO 4 Cl photocatalysts with triple fluorite layers7Photocatalytic activity of Ag doped CuFe2O4 nanoparticles supported on reduced graphene oxide for the degradation of organic dyes under visible light irradiation10Interfacial Electronic States of GeC/g‐C3N4 van der Waal Heterostructure with Promising Photocatalytic Activity via Hydrogenation9Band Gap Narrowing by Suppressed Lone-Pair Activity of Bi 3+85Functions and Applications of Mixed-anion Compounds0Functions and Applications of Mixed-anion Compounds1Efficient Visible-Light-Driven Water Oxidation by a Carbon Nitride Modified with Cobalt Polyoxometalate Molecular Catalyst15Origin of extended visible light absorption in nitrogen-doped CuTa2O6 perovskites: the role of copper defects1Modification of Visible‐Light‐Responsive Pb2Ti2O5.4F1.2 with Metal Oxide Cocatalysts to Improve Photocatalytic O2 Evolution toward Z‐Scheme Overall Water Splitting7Tunable optoelectronic, thermoelectric, and photocatalytic properties of β-SiTe and SiH monolayers as a photocatalytic water-splitting65Simple and Scalable Synthetic Route for Tunable Compositions of Multimetallic Oxyfluorides as Oxygen Evolution Reaction Catalysts8Ferrite-based photocatalysts: Synthesis, modifications, and key parameters in photocatalytic-related applications22Molecular Terpyridine–Lanthanide Complexes Modified Carbon Nitride for Enhanced Photocatalytic CO2 Reduction6Rational Design of Conjugated Polymers for Photocatalytic CO2 Reduction: Towards Localized CO Production and Macrophage Polarization26

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  1. Facile Synthesis of Ag/AgCl Grafted AgBi(MoO4)2 with Enhanced Photocatalytic Performance Under Visible Light

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  2. Perovskite Oxide LaNiO3 Nanoparticles for Boosting H2 Evolution over Commercial CdS with Visible Light

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  5. One-pot synthesis of BaMg1/3Ta2/3O3-xNy/Ta3N5 heterostructures as H2-evolving photocatalysts for construction of visible-light-driven Z-scheme overall water splitting

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  6. Development of Mixed‐Anion Photocatalysts with Wide Visible‐Light Absorption Bands for Solar Water Splitting

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  7. Hetero-metallic active sites coupled with strongly reductive polyoxometalate for selective photocatalytic CO 2 -to-CH 4 conversion in water

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  11. Light Absorption Properties and Electronic Band Structures of Lead Titanium Oxyfluoride Photocatalysts Pb 2 Ti 4 O 9 F 2 and Pb 2 Ti 2 O 5.4 F 1.2

    The Journal of Physical Chemistry C · 2018-10-29

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  12. Photocatalytic Reduction on Bismuth-Based p-Block Semiconductors

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  33. Metal‐Complex/Semiconductor Hybrid Photocatalysts and Photoelectrodes for CO2 Reduction Driven by Visible Light

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  34. Encapsulating a Ni(II) molecular catalyst in photoactive metal–organic framework for highly efficient photoreduction of CO2

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  35. Oxygen‐Doped Ta3N5 Nanoparticles for Enhanced Z‐Scheme Carbon Dioxide Reduction with a Binuclear Ruthenium(II) Complex under Visible Light

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  36. Recent advances in copper ferrite nanoparticles and nanocomposites synthesis, magnetic properties and application in water treatment: Review

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  37. Highly Selective Photoreduction of CO2 with Suppressing H2 Evolution over Monolayer Layered Double Hydroxide under Irradiation above 600 nm

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