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RESEARCH PAPER · Journal of the American Chemical Society · 2024

Double-Layered Perovskite Oxyfluoride Cathodes with High Capacity Involving O–O Bond Formation for Fluoride-Ion Batteries

Hidenori Miki, Kentaro Yamamoto, Hiroyuki Nakaki, Takahiro Yoshinari, Koji Nakanishi, Shinji Nakanishi, Hideki Iba, Jun Miyawaki, Yoshihisa Harada, Akihide Kuwabara, Yanchang Wang, Toshiki Watanabe, Toshiyuki Matsunaga, Kazuhiko Maeda, Hiroshi Kageyama, Yoshiharu Uchimoto

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Double-Layered Perovskite Oxyfluoride Cathodes with High Capacity Involving O–O Bond Formation for Fluoride-Ion BatteriesOriginalInternal strain-driven bond manipulation and band engineering in Bi 2− x Sb x YO 4 Cl photocatalysts with triple fluorite layers7Transient phase change of Ruddlesden-Popper type perovskite on fluoride-ion intercalation reaction1Revealing the Unusual Mechanism of Mixed Cationic and Anionic Redox in Oxyfluorosulfide Cathode for All-Solid-State Fluoride-Ion Batteries15Improved electrical transport properties of La0.7Ca0.3−xKxMnO3 (0.0 ≤ x ≤ 0.3) films grown on La0.3Sr0.7Al0.65Ta0.35O3 (00l) substrates by sol–gel spin coating method4Machine learning potentials for the simulation of fluoride ion batteries electrolytes0Reversible Fluoride-Ion (De)Intercalation of CuLaO2 Cathodes with Crystalline/Amorphous Phase Transition Involving Multi-Electron Reaction5Mechanistic Insights on the Formation of a Carbodiimide Ion from Urea in La2O2NCN Synthesis Based on the “Proanion” Strategy4Toward Practical Fluoride-Ion Batteries: A Review and Perspective on Liquid Electrolyte Development9Fluoride Ion Storage and Conduction Mechanism in Fluoride Ion Battery Positive Electrode, Ruddlesden–Popper-Type Layered Perovskite La1.2Sr1.8Mn2O7 Crystal6Summary, Future, and Challenges of Fluoride‐Ion Batteries11Supra-ceramics: a molecule-driven frontier of inorganic materials45Nanoarchitectonics for Biomedical Research: Post‐Nanotechnology Materials Approach for Bio‐Active Application6Iron-Based Layered Perovskite Oxyfluoride Electrocatalyst for Oxygen Evolution: Insights from Crystal Facets with Heteroanionic Coordination15Commonalities and Characteristics Analysis of Fluorine and Iodine used in Lithium‐Based Batteries4Shielding Fluoride Ion Basicity through Diurea Coordination for Nonaqueous Fluoride Shuttle Batteries2Shielding Fluoride Ion Basicity through Diurea Coordination for Nonaqueous Fluoride Shuttle Batteries7Manganese electrode for all-solid-state fluoride batteries2Capacity enhancement of LaAl 2 Ag ternary alloy anode for fluoride-ion batteries2Design and synthesis of a weakly solvated electrolyte for high-performance fluoride-ion batteries5Design and synthesis of asymmetric anhydrous quaternary ammonium fluoride electrolytes for fluoride ion batteries5Highly efficient atomic-scale design of CaF 2 for ultrafast fluoride-ion conduction5How Amino Acids Intercalate in CaFe Layered Double Hydroxides: A Combined RIXS and NEXAFS Study1Cathode Design Based on Nitrogen Redox and Linear Coordination of Cu Center for All-Solid-State Fluoride-Ion Batteries19Localized assembly in biological activity: Origin of life and future of nanoarchitectonics120Construction of Acceptor‐Multi‐F State Electrolyte to Enable Unprecedented Long‐Life and High‐Capacity Fluoride‐Ion Batteries16Fluorine as a Key Element in Solid-State Chemistry of Mixed Anions 3d Transition Metal-Based Materials for Electronic Properties and Energy24Oxyfluorides for electrochemical and photoelectrochemical water oxidation: a review and basic tutorial0Tailored 3‐Alkoxy‐ N , N , N ,2,2‐Pentamethylpropan‐1‐Ammonium Bis (trifluoromethylsulfonyl)Imide Ionic Liquids for Room‐Temperature Fluoride‐Ion Batteries5Tailored 3‐Alkoxy‐N,N,N,2,2‐Pentamethylpropan‐1‐Ammonium Bis(trifluoromethylsulfonyl)Imide Ionic Liquids for Room‐Temperature Fluoride‐Ion Batteries1Anion-Controlled Inorganic Materials as Catalysts for Small-Molecule Conversion Reactions8Reversible Phase Transition in Ruddlesden-Popper-type Oxysulfide Y2Ti2O5S2 for Lithium-Ion Battery Anodes2Evidence of High Fluorine Ion Conductivity in SrF2-Rich SrF2–TiO2-Based Compounds0Toward Carbon‐Free Cathodes for Fluoride Ion Batteries: Deconvoluting Effects of Active Material and Conductive Additive on Charging and Cyclic Stability2Rapid fluorination using polyvinylidene-difluoride (PVDF) for the synthesis of oxyfluoride Bi2VO5F1−x0Tuning the Electronic Structure of BaAl2O4–xAy with Anion Substitution for Cobalt-Loaded Ammonia Synthesis Catalysts4Three-dimensional flame-retardant quasi-solid composite electrolyte with a fiber structure formed using the coaxial electrospinning to suppress lithium dendrite growth14Ultra‐High‐Capacity of Earth‐Abundant Cathodes Enabled by Excess Fluoride‐Ion Insertion/Extraction6Structural and electrochemical behaviour of bilayer manganite LaSr2Mn2O6.96 cathode for all-solid-state fluoride ion batteries0LaCu5 intermetallic alloy cathode for fluoride-ion batteries1High-Capacity Intercalation-Based Anodes for Solid-State Fluoride-Ion Batteries Enabled by the Substitution of Conductive Carbon by Metallic Copper2Gas evolution in Ruddlesden–Popper-type intercalation cathodes in all-solid-state fluoride-ion-batteries: implications on battery performance and synthesis of highly oxidized oxyfluorides5Clarifying fluoride-ion conduction of La0.9Ba0.1F2.9 solid electrolyte0Fluoride-Ion Batteries: A Review of Recent Advances and Future Opportunities5Engineering sintering-induced secondary phases in La 0.9 Ba 0.1 F 2.9 -based composite electrolytes for fluoride-ion conduction0Reversible fluoride-ion (de)intercalation of a melilite-type Sr 2 Fe 2 GeO 7 cathode with small volume change0The role of oxygen excess on fluoride intercalation in Ruddlesden–Popper electrodes for fluoride ion batteries: the case of LaSrMnO 40Sodium halide solid electrolytes for all-solid-state sodium batteries: advances, challenges, strategies, and prospects3Mechanistic Insights into Oxygen Release from Layered Oxide Cathodes for Reliable Sodium‐Ion Batteries0Study on Microstructure Characterization and Correlation Mechanism of Transport Properties in the BaSnF 4 Solid Electrolyte0Fluoride ions as charge carriers in electrochemical energy storage0Propylene Carbonate-Based Liquid Electrolyte with Enhanced Chemical Stability for Fluoride Ion Batteries0Fluoride‐Ion Batteries: Unraveling the Fundamental Science for Next‐Generation Energy Storage0

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  1. Internal strain-driven bond manipulation and band engineering in Bi 2− x Sb x YO 4 Cl photocatalysts with triple fluorite layers

    Chemical Science · 2024-01-01

    Artem Gabov, Daichi Kato, Hiroki Ubukata, Ryotaro Aso, Naoji Kakudou, Koji Fujita, Hajime Suzuki, Osamu Tomita, Akinori Saeki, Ryu Abe, Smagul Zh. Karazhanov, Hiroshi Kageyama

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  2. Transient phase change of Ruddlesden-Popper type perovskite on fluoride-ion intercalation reaction

    Solid State Ionics · 2024-02-07

    Hidenori Miki, Kentaro Yamamoto, Toshiyuki Matsunaga, Toshiki Watanabe, Mukesh Kumar, Neha Thakur, Hideki Iba, Hiroshi Kageyama, Yoshiharu Uchimoto

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  3. Revealing the Unusual Mechanism of Mixed Cationic and Anionic Redox in Oxyfluorosulfide Cathode for All-Solid-State Fluoride-Ion Batteries

    Chemistry of Materials · 2024-02-14

    Zulai Cao, Kentaro Yamamoto, Toshiyuki Matsunaga, Toshiki Watanabe, Mukesh Kumar, Neha Thakur, Ryogo Ohashi, Shintaro Tachibana, Hidenori Miki, Kazuto Ide, Hideki Iba, Hisao Kiuchi, Yoshihisa Harada, Yuki Orikasa, Yoshiharu Uchimoto

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  4. Improved electrical transport properties of La0.7Ca0.3−xKxMnO3 (0.0 ≤ x ≤ 0.3) films grown on La0.3Sr0.7Al0.65Ta0.35O3 (00l) substrates by sol–gel spin coating method

    Ceramics International · 2024-05-01

    Zimeng Pan, Zihao Chen, Zhenyu Wang, Xiaokun Zhu, Jiamei Han, Jiabin Jiang, Yao Wang, Xiaolu Liang, Haitao Wang, Yiliang Liu, Yufei Du, Jiachen Wang, Xiang Liu, Xin Gu

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  5. Machine learning potentials for the simulation of fluoride ion batteries electrolytes

    Unknown journal · 2024-07-15

    Xiliang Lian

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  6. Reversible Fluoride-Ion (De)Intercalation of CuLaO2 Cathodes with Crystalline/Amorphous Phase Transition Involving Multi-Electron Reaction

    ACS Applied Energy Materials · 2024-07-30

    Zulai Cao, Kentaro Yamamoto, Toshiyuki Matsunaga, Mukesh Kumar, Neha Thakur, Toshiki Watanabe, Koji Nakanishi, Hidenori Miki, Hideki Iba, Koji Amezawa, Hiroshi Kageyama, Yoshiharu Uchimoto

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  7. Mechanistic Insights on the Formation of a Carbodiimide Ion from Urea in La2O2NCN Synthesis Based on the “Proanion” Strategy

    Inorganic Chemistry · 2024-08-05

    Oomi Sumioka, Naoki Tarutani, Kiyofumi Katagiri, Kei Inumaru, Zi Lang Goo, Kunihisa Sugimoto, Yusuke Asai, Miwa Saito, Teruki Motohashi

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  8. Toward Practical Fluoride-Ion Batteries: A Review and Perspective on Liquid Electrolyte Development

    ACS Materials Letters · 2024-08-30

    Peichao Zou, Kai Yu, Ruoqian Lin

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  9. Fluoride Ion Storage and Conduction Mechanism in Fluoride Ion Battery Positive Electrode, Ruddlesden–Popper-Type Layered Perovskite La1.2Sr1.8Mn2O7 Crystal

    Inorganic Chemistry · 2024-10-07

    Hidenori Miki, Toshiyuki Matsunaga, Zhuoran Li, Zulai Cao, Kentaro Yamamoto, Mukesh Kumar, Neha Thakur, Toshiki Watanabe, Hideki Iba, Shintaro Kobayashi, Shogo Kawaguchi, Kazutaka Ikeda, Masato Hagihala, Takashi Kamiyama, Akihide Kuwabara, Hiroshi Kageyama, Kazuhiko Maeda, Yoshiharu Uchimoto

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  10. Summary, Future, and Challenges of Fluoride‐Ion Batteries

    Energy Technology · 2024-10-16

    Jingwen Li, Mingqiang Li, Haochen Weng, Shuailiang Xu

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  11. Supra-ceramics: a molecule-driven frontier of inorganic materials

    Science and Technology of Advanced Materials · 2024-10-16

    Kazuhiko Maeda, Teruki Motohashi, Ryo Ohtani, Kunihisa Sugimoto, Yuta Tsuji, Akihide Kuwabara, Satoshi Horike

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  12. Nanoarchitectonics for Biomedical Research: Post‐Nanotechnology Materials Approach for Bio‐Active Application

    Advanced NanoBiomed Research · 2024-11-01

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  13. Iron-Based Layered Perovskite Oxyfluoride Electrocatalyst for Oxygen Evolution: Insights from Crystal Facets with Heteroanionic Coordination

    Journal of the American Chemical Society · 2024-11-13

    Ryusuke Mizuochi, Yuuki Sugawara, Kengo Oka, Yoshiyuki Inaguma, Shunsuke Nozawa, Toshiyuki Yokoi, Takeo Yamaguchi, Kazuhiko Maeda

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  14. Commonalities and Characteristics Analysis of Fluorine and Iodine used in Lithium‐Based Batteries

    Advanced Functional Materials · 2024-11-20

    Lu Gao, Xia Liu, Lei Li, Nanping Deng, Weimin Kang, Bowen Cheng

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  15. Shielding Fluoride Ion Basicity through Diurea Coordination for Nonaqueous Fluoride Shuttle Batteries

    Angewandte Chemie · 2024-11-22

    Huijian Wang, Chengjun Lei, Tingting Liu, Ruijin Meng, Xiao Liang

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  16. Shielding Fluoride Ion Basicity through Diurea Coordination for Nonaqueous Fluoride Shuttle Batteries

    Angewandte Chemie International Edition · 2024-11-22

    Huijian Wang, Chengjun Lei, Tingting Liu, Ruijin Meng, Xiao Liang

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  17. Manganese electrode for all-solid-state fluoride batteries

    Chemical Communications · 2024-12-24

    Atsushi Inoishi, Naoko Setoguchi, Megumi Motoyama, Shigeto Okada, Hikarí Sakaebe

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  18. Capacity enhancement of LaAl 2 Ag ternary alloy anode for fluoride-ion batteries

    Journal of Materials Chemistry A · 2025-01-01

    Shun Sasano, Ryo Ishikawa, Kazuaki Kawahara, Naoya Shibata, Yuichi Ikuhara

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  19. Design and synthesis of a weakly solvated electrolyte for high-performance fluoride-ion batteries

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    jia xiang, Wei Hua Zou, Ying Lei, Hua‐Jun Fan, Rongwen Lu, Shufen Zhang

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  20. Design and synthesis of asymmetric anhydrous quaternary ammonium fluoride electrolytes for fluoride ion batteries

    Sustainable Energy & Fuels · 2025-01-01

    Tiancheng Tan, Richard J. Murdey, Shunsuke Sumitomo, Atsushi Wakamiya

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  21. Highly efficient atomic-scale design of CaF 2 for ultrafast fluoride-ion conduction

    Journal of Materials Chemistry A · 2025-01-01

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  22. How Amino Acids Intercalate in CaFe Layered Double Hydroxides: A Combined RIXS and NEXAFS Study

    ChemPhysChem · 2025-01-10

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  23. Cathode Design Based on Nitrogen Redox and Linear Coordination of Cu Center for All-Solid-State Fluoride-Ion Batteries

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  24. Localized assembly in biological activity: Origin of life and future of nanoarchitectonics

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  25. Construction of Acceptor‐Multi‐F State Electrolyte to Enable Unprecedented Long‐Life and High‐Capacity Fluoride‐Ion Batteries

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  26. Fluorine as a Key Element in Solid-State Chemistry of Mixed Anions 3d Transition Metal-Based Materials for Electronic Properties and Energy

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  27. Oxyfluorides for electrochemical and photoelectrochemical water oxidation: a review and basic tutorial

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  28. Tailored 3‐Alkoxy‐ N , N , N ,2,2‐Pentamethylpropan‐1‐Ammonium Bis (trifluoromethylsulfonyl)Imide Ionic Liquids for Room‐Temperature Fluoride‐Ion Batteries

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  29. Tailored 3‐Alkoxy‐N,N,N,2,2‐Pentamethylpropan‐1‐Ammonium Bis(trifluoromethylsulfonyl)Imide Ionic Liquids for Room‐Temperature Fluoride‐Ion Batteries

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  30. Anion-Controlled Inorganic Materials as Catalysts for Small-Molecule Conversion Reactions

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  31. Reversible Phase Transition in Ruddlesden-Popper-type Oxysulfide Y2Ti2O5S2 for Lithium-Ion Battery Anodes

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  32. Evidence of High Fluorine Ion Conductivity in SrF2-Rich SrF2–TiO2-Based Compounds

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  33. Toward Carbon‐Free Cathodes for Fluoride Ion Batteries: Deconvoluting Effects of Active Material and Conductive Additive on Charging and Cyclic Stability

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  34. Rapid fluorination using polyvinylidene-difluoride (PVDF) for the synthesis of oxyfluoride Bi2VO5F1−x

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  35. Tuning the Electronic Structure of BaAl2O4–xAy with Anion Substitution for Cobalt-Loaded Ammonia Synthesis Catalysts

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  36. Three-dimensional flame-retardant quasi-solid composite electrolyte with a fiber structure formed using the coaxial electrospinning to suppress lithium dendrite growth

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  37. Ultra‐High‐Capacity of Earth‐Abundant Cathodes Enabled by Excess Fluoride‐Ion Insertion/Extraction

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  38. Structural and electrochemical behaviour of bilayer manganite LaSr2Mn2O6.96 cathode for all-solid-state fluoride ion batteries

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  39. LaCu5 intermetallic alloy cathode for fluoride-ion batteries

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  40. High-Capacity Intercalation-Based Anodes for Solid-State Fluoride-Ion Batteries Enabled by the Substitution of Conductive Carbon by Metallic Copper

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  41. Gas evolution in Ruddlesden–Popper-type intercalation cathodes in all-solid-state fluoride-ion-batteries: implications on battery performance and synthesis of highly oxidized oxyfluorides

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  42. Clarifying fluoride-ion conduction of La0.9Ba0.1F2.9 solid electrolyte

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  43. Fluoride-Ion Batteries: A Review of Recent Advances and Future Opportunities

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  44. Engineering sintering-induced secondary phases in La 0.9 Ba 0.1 F 2.9 -based composite electrolytes for fluoride-ion conduction

    Journal of Materials Chemistry A · 2026-01-01

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  45. Reversible fluoride-ion (de)intercalation of a melilite-type Sr 2 Fe 2 GeO 7 cathode with small volume change

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  46. The role of oxygen excess on fluoride intercalation in Ruddlesden–Popper electrodes for fluoride ion batteries: the case of LaSrMnO 4

    Journal of Materials Chemistry A · 2026-01-01

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  47. Sodium halide solid electrolytes for all-solid-state sodium batteries: advances, challenges, strategies, and prospects

    Energy storage materials · 2026-03-15

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  48. Mechanistic Insights into Oxygen Release from Layered Oxide Cathodes for Reliable Sodium‐Ion Batteries

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  49. Study on Microstructure Characterization and Correlation Mechanism of Transport Properties in the BaSnF 4 Solid Electrolyte

    ACS Applied Energy Materials · 2026-06-09

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  50. Fluoride ions as charge carriers in electrochemical energy storage

    Nature Materials · 2026-07-10

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