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RESEARCH PAPER · Journal of Materials Chemistry C · 2016

New garnet structure phosphors, Lu 3−x Y x MgAl 3 SiO 12 :Ce 3+ (x = 0–3), developed by solid solution design

Haipeng Ji, Le Wang, Мaxim S. Моlokeev, Naoto Hirosaki, Zhaohui Huang, Zhiguo Xia, Otmar M. ten Kate, Lihong Liu, Rong‐Jun Xie

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New garnet structure phosphors, Lu 3−x Y x MgAl 3 SiO 12 :Ce 3+ (x = 0–3), developed by solid solution designOriginalNew Y 2 BaAl 4 SiO 12 :Ce 3+ yellow microcrystal-glass powder phosphor with high thermal emission stability74Recent developments in the new inorganic solid-state LED phosphors565Structure evolution and photoluminescence of Lu 3 (Al,Mg) 2 (Al,Si) 3 O 12 :Ce 3+ phosphors: new yellow-color converters for blue LED-driven solid state lighting317Synthesis, structure and photoluminescence properties of Ca 2 LuHf 2 (AlO 4 ) 3 :Ce 3+ , a novel garnet-based cyan light-emitting phosphor78Optical spectroscopy of the Ce-doped multicomponent garnets6Nonequivalent Substitution and Charge-Induced Emitter-Migration Design of Tuning Spectral and Duration Properties of NaCa2GeO4F:Mn2+ Persistent Luminescent Phosphor26Relationship between thermal quenching of Eu2+ luminescence and cation ordering in (Ba1−Sr )2SiO4:Eu phosphors50Photoluminescence and charge compensation effects in Lu3MgyAl5−−Si O12:Ce3+ phosphors for white LEDs8Ce 3+ -Doped garnet phosphors: composition modification, luminescence properties and applications1149A bright and moisture-resistant red-emitting Lu 3 Al 5 O 12 :Mn 4+ ,Mg 2+ garnet phosphor for high-quality phosphor-converted white LEDs93A broad-band orange-yellow-emitting Lu 2 Mg 2 Al 2 Si 2 O 12 : Ce 3+ phosphor for application in warm white light-emitting diodes56Cooperative Upconversion Luminescence Properties of Yb3+and Tb3+Heavily Codoped Silicate Garnet Obtained by Multiple Chemical Unit Cosubstitution23Phase formation of (Y,Ce)2BaAl4SiO12 yellow microcrystal-glass phosphor for blue LED pumped white lighting12Structure and luminescence properties of Ce 3+ doped KBa 1 − x (Mg/Zn) x Y(BO 3 ) 2 and K 1 − y Na y BaY(BO 3 ) 2 phosphors evolved from cation substitution5Tunable Luminescence in Sr2MgSi2O7:Tb3+, Eu3+Phosphors Based on Energy Transfer34Perovskite CsPbBr1.2I1.8 quantum dot alloying for application in white light-emitting diodes with excellent color rendering index43Structure, energy level analysis and luminescent properties of a novel broadband blue-emitting phosphor KBaYSi 2 O 7 : Ce 3+30Improved photoluminescence, thermal stability and temperature sensing performances of K+ incorporated perovskite BaTiO3:Eu3+ red emitting phosphors91A novel Eu3+-doped garnet-type tellurate red-emitting phosphor with high thermal stability and color purity101Synthesis and photoluminescence investigation of (Ba0.97-M )Y2Si3O10:0.03Eu2+ and Ba0.97(Y2-RE )Si3O10:0.03Eu2+ (M = Ca, Sr; RE = La, Yb) by cation substitution2Selective coordination of N3− and tuning of luminescence in garnet (Y1−x,Lax)3(Al,Si)5(O,N)12: Ce3+ phosphors21SrBi2TeO7:Eu3+: A novel blue-light excitable red-emitting phosphor for solid-state lighting23Ionic occupation, structures, and microwave dielectric properties of Y 3 MgAl 3 SiO 12 garnet‐type ceramics84Origin of Spectral Blue Shift of Lu3+-Codoped YAG:Ce3+ Phosphor: First-Principles Study27(Ba,Sr)TiO 3 :RE perovskite phosphors (RE = Dy, Eu): nitrate pyrolysis synthesis, enhanced photoluminescence, and reversible emission against heating20Co-substitution in Ca 1−x Y x Al 12−x Mg x O 19 phosphors: local structure evolution, photoluminescence tuning and application for plant growth LEDs105Massive red-shifting of Ce 3+ emission by Mg 2+ and Si 4+ doping of YAG:Ce transparent ceramic phosphors105Phosphors for white LEDs6Significantly enhanced photoluminescence and thermal stability of La 3 Si 8 N 11 O 4 :Ce 3+ ,Tb 3+ via the Ce 3+ → Tb 3+ energy transfer: a blue-green phosphor for ultraviolet LEDs12Tunable dual emission of Ca 3 Al 4 ZnO 10 :Bi 3+ ,Mn 4+ via energy transfer for indoor plant growth lighting154Structure, bandgap, photoluminescence evolution and thermal stability improved of Sr replacement apatite phosphors Ca10-xSrx(PO4)6F2:Eu2+ (x = 4, 6, 8)40Energy transfer between terbium and europium ions in barium orthosilicate phosphors obtained from sol-gel route33A zero-thermal-quenching and color-tunable phosphor LuVO4: Bi3+, Eu3+ for NUV LEDs79On the origin of temperature dependence of the emission maxima of Eu2+and Ce3+- activated phosphors40Red-Shifted Emission in Y3MgSiAl3O12:Ce3+ Garnet Phosphor for Blue Light-Pumped White Light-Emitting Diodes112Optical properties of a novel Ce3+-activated antimony garnet-like Y3Sb5O12 phosphor1Local coordination, electronic structure, and thermal quenching of Ce 3+ in isostructural Sr 2 GdAlO 5 and Sr 3 AlO 4 F phosphors15Polyhedral distortion control of unusual photoluminescence color tuning in garnet phosphors via cation substitution16Spectral broadening of a single Ce3+-doped garnet by chemical unit cosubstitution for near ultraviolet LED14Crystal structure analysis and evidence of mixed anion coordination at the Ce 3+ site in Y 3 Al 2 (Al,Si) 3 (O,N) 12 oxynitride garnet phosphor22Full spectrum core–shell phosphors under ultraviolet excitation7Insights into a novel garnet-based yellowish-green phosphor: structure, luminescence properties and application for warm white light-emitting diodes24Dehydrogenation-driven to synthesize high-performance Lu2Si4N6C:Ce3+- a broad green-emitting phosphor for full-spectrum lighting18Crystal structure and photo-luminescence of Gd3Ga2(Al3-Si )(O12-N ):Ce3+ phosphors for AC-warm LEDS25Sol-gel processing of Eu3+ doped Li6CaLa2Nb2O12 garnet for efficient and thermally stable red luminescence under near-ultraviolet/blue light excitation75Fabrication of (Tb,Gd)3Al5O12:Ce3+ phosphor ceramics for warm white light-emitting diodes application50“Frozen” pressure effect in GGAG:Ce3+ white light emitting nanoceramics9Tunable emission and energy-transfer mechanism of single-phase Na3Y(PO4)2:Ce3+, Mn2+phosphors for white LEDs14A broadband cyan-emitting Ca 2 LuZr 2 (AlO 4 ) 3 :Ce 3+ garnet phosphor for near-ultraviolet-pumped warm-white light-emitting diodes with an improved color rendering index244A review on the advancements in phosphor-converted light emitting diodes (pc-LEDs): Phosphor synthesis, device fabrication and characterization731Ultra-broadband cyan-to-orange emitting Ba 1+x Sr 1−x Ga 4 O 8 :Bi 3+ phosphors: luminescence control and optical temperature sensing95Designing a super broadband near infrared material Mg 3 Y 2 Ge 3 O 12 :Cr 3+ using cation inversion for future light sources21Efficient and stable Sr 3 Eu 2 B 4 O 12 red phosphor benefiting from low symmetry and distorted local environment48High quantum efficiency Ce:(Lu,Y) 3 (Al,Sc) 2 Al 3 O 12 transparent ceramics with excellent thermal stability for high-power white LEDs/LDs40High recorded color rendering index in single Ce,(Pr,Mn):YAG transparent ceramics for high-power white LEDs/LDs71Selectivity of Mn 2+ ion occupancy and energy transfer of Ce 3+ → Mn 2+ ions in garnet solid solution40Ultrabroadband red luminescence of Mn 4+ in MgAl 2 O 4 peaking at 651 nm45Synthesis and characterization of Dy-doped $\hbox {Lu}_{{1}}\hbox {Gd}_{{2}}\hbox {Ga}_{{2}}\hbox {Al}_{{3}}\hbox {O}_{{12}}$ phosphor for LEDs10A novel Al3+ modified Li6CaLa2Sb2O12:Mn4+ far-red-emitting phosphor with garnet structure for plant cultivation36Weak thermal quenching and tunable luminescence in Ce:Y3(Al,Sc)5O12 transparent ceramics for high power white LEDs/LDs83Phosphor-converted LEDs15Vacancies Substitution Tuning Photoluminescence and Distortion Triggered Eu Migration in NASICON-Type Phosphors11Photoluminescence and afterglow tuning in ultra-broadband near-infrared Mg3Y2Ge3O12:Cr3+ phosphor via cation substitution27Learning from Mineral Structures toward New Luminescence Materials for Light-Emitting Diode Applications146Broadband emission Gd3Sc2Al3O12:Ce3+ transparent ceramics with a high color rendering index for high-power white LEDs/LDs38Distortion and energy transfer assisted tunability in garnet phosphors62Novel Cyan-Green-Emitting Bi3+-Doped BaScO2F, R+ (R = Na, K, Rb) Perovskite Used for Achieving Full-Visible-Spectrum LED Lighting51Structure and photoluminescence properties of Ce3+ doped Ba7(BO3)3(SiO4)Br phosphors with complex anion groups8A green emitting (Ba,Ca)ScO 2 F:Bi 3+ ,K + perovskite phosphor with high efficiency and good thermal stability for LED backlight displays6Remarkable structure and luminescence regulation of a Gd 2 LuAl 5 O 12 :Ce garnet phosphor with a Ca 2+ /Si 4+ pair for high-quality w-WLED lighting8White light emitting diodes based on green graphene quantum dots and red graphene quantum dots9Relationship of the different Ca sites in the matrix with luminescence properties of orange‒red emitting Li0.04Ca0.96-xSiO3:Smx phosphors27Tailoring the Luminescent Properties of SrS:Ce3+ by Sr-Deficiency and Na+ Doping15Design and technological aspects of novel CdS quantum dots doped glass–ceramics16Highly efficient Ce: Lu(Mg,Al)2(Si,Al)3O12 phosphor ceramics for high-power white LEDs/LDs15Biphasic Lu3MgAl3SiO12-based transparent ceramics for uniform laser-diode-driven white lighting20Recent progress in Ce 3+ /Eu 2+ -activated LEDs and persistent phosphors: focusing on the local structure and the electronic structure137Novel double perovskite Ca2Gd0.5Nb1-W5/6O6:0.5 Eu3+ red phosphors with excellent thermal stability and high color purity for white LEDs92A mini review on phosphor converted white light emitting diodes material2Designing and controlling the Ni 2+ -activated (Zn, Mg)Al 2 O 4 spinel solid-solution for phosphor-converted broadband near-infrared illumination81Bi3+ ions doped double perovskite Ca2MgWO6 phosphor for yellow light emission33Simultaneous realization of tunable luminescence and enhanced thermal stability in Eu2+-based blue-green phosphors for multifunctional applications16Modification of the green CSS:Ce3+ phosphor by ion substitution for obtaining an orange phosphor for white LEDs4Amber Light Emitting Samarium Incorporated Barium Cerate Perovskite with 100% Color Purity for Pharmaceutical Industry10Structures and luminescence properties of some new rare-earth aluminates and gallates obtained by non-equilibrium synthesis0High efficient and ultrahigh thermal stability in a rigid rare-earth hybrid molecular crystal: [(CH3CH2)4N]Tb[CH2(SO3)2]2Filling the Cyan Gap in wLEDs with Ba2MgWO6:Bi3+ Solid Solution for Full-Spectrum LED Illumination4Broadband emitting Mg3Lu2Ge3O12:Cr3+ phosphors with garnet structure for high-performance NIR LEDs applications25Enhancement of optical performance and thermal stability of LuAG: Ce phosphor-in-glass via a new TS+SPS method for laser lighting6Development of a double-sided heat-conducting BN@PiGF@Al 2 O 3 color converter for high-brightness laser lighting3A novel white powder light tunable luminescence in dibarium magnesium disilicate phosphor with Tb3+Eu3+ based on energy transfer0A review of recent advances in Ce3+-activated garnet phosphors for blue-chip-pumped pc-WLEDs81Improvement the near-infrared long afterglow luminescence of Ca3MgSnGe3O12:Cr3+ by introducing Li+ and its application to biological tissue penetration, tracking and localization4A Blue Light–Excited Broadband Chartreuse‐Emitting LuMg 2 Al 3 Si 2 O 12 :Ce 3+ Garnet Phosphor With High Thermal Stability for High‐Performance White LEDs0Anomalous concentration anti-quenching of Eu3+ red luminescence based on novel rare-earth borate K7SrLu2B15O302Structural analysis and JO theory calculations on color-tunable phosphor LiCaSiO3:Sm3+,Eu3+2

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  1. New Y 2 BaAl 4 SiO 12 :Ce 3+ yellow microcrystal-glass powder phosphor with high thermal emission stability

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  2. Recent developments in the new inorganic solid-state LED phosphors

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  3. Structure evolution and photoluminescence of Lu 3 (Al,Mg) 2 (Al,Si) 3 O 12 :Ce 3+ phosphors: new yellow-color converters for blue LED-driven solid state lighting

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  4. Synthesis, structure and photoluminescence properties of Ca 2 LuHf 2 (AlO 4 ) 3 :Ce 3+ , a novel garnet-based cyan light-emitting phosphor

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  5. Optical spectroscopy of the Ce-doped multicomponent garnets

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  6. Nonequivalent Substitution and Charge-Induced Emitter-Migration Design of Tuning Spectral and Duration Properties of NaCa2GeO4F:Mn2+ Persistent Luminescent Phosphor

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  7. Relationship between thermal quenching of Eu2+ luminescence and cation ordering in (Ba1−Sr )2SiO4:Eu phosphors

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  8. Photoluminescence and charge compensation effects in Lu3MgyAl5−−Si O12:Ce3+ phosphors for white LEDs

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  9. Ce 3+ -Doped garnet phosphors: composition modification, luminescence properties and applications

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  10. A bright and moisture-resistant red-emitting Lu 3 Al 5 O 12 :Mn 4+ ,Mg 2+ garnet phosphor for high-quality phosphor-converted white LEDs

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  11. A broad-band orange-yellow-emitting Lu 2 Mg 2 Al 2 Si 2 O 12 : Ce 3+ phosphor for application in warm white light-emitting diodes

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  12. Cooperative Upconversion Luminescence Properties of Yb3+and Tb3+Heavily Codoped Silicate Garnet Obtained by Multiple Chemical Unit Cosubstitution

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  13. Phase formation of (Y,Ce)2BaAl4SiO12 yellow microcrystal-glass phosphor for blue LED pumped white lighting

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  14. Structure and luminescence properties of Ce 3+ doped KBa 1 − x (Mg/Zn) x Y(BO 3 ) 2 and K 1 − y Na y BaY(BO 3 ) 2 phosphors evolved from cation substitution

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  15. Tunable Luminescence in Sr2MgSi2O7:Tb3+, Eu3+Phosphors Based on Energy Transfer

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  16. Perovskite CsPbBr1.2I1.8 quantum dot alloying for application in white light-emitting diodes with excellent color rendering index

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  17. Structure, energy level analysis and luminescent properties of a novel broadband blue-emitting phosphor KBaYSi 2 O 7 : Ce 3+

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  18. Improved photoluminescence, thermal stability and temperature sensing performances of K+ incorporated perovskite BaTiO3:Eu3+ red emitting phosphors

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  19. A novel Eu3+-doped garnet-type tellurate red-emitting phosphor with high thermal stability and color purity

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  20. Synthesis and photoluminescence investigation of (Ba0.97-M )Y2Si3O10:0.03Eu2+ and Ba0.97(Y2-RE )Si3O10:0.03Eu2+ (M = Ca, Sr; RE = La, Yb) by cation substitution

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  21. Selective coordination of N3− and tuning of luminescence in garnet (Y1−x,Lax)3(Al,Si)5(O,N)12: Ce3+ phosphors

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  22. SrBi2TeO7:Eu3+: A novel blue-light excitable red-emitting phosphor for solid-state lighting

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  23. Ionic occupation, structures, and microwave dielectric properties of Y 3 MgAl 3 SiO 12 garnet‐type ceramics

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  24. Origin of Spectral Blue Shift of Lu3+-Codoped YAG:Ce3+ Phosphor: First-Principles Study

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  25. (Ba,Sr)TiO 3 :RE perovskite phosphors (RE = Dy, Eu): nitrate pyrolysis synthesis, enhanced photoluminescence, and reversible emission against heating

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  26. Co-substitution in Ca 1−x Y x Al 12−x Mg x O 19 phosphors: local structure evolution, photoluminescence tuning and application for plant growth LEDs

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  27. Massive red-shifting of Ce 3+ emission by Mg 2+ and Si 4+ doping of YAG:Ce transparent ceramic phosphors

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  28. Phosphors for white LEDs

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  29. Significantly enhanced photoluminescence and thermal stability of La 3 Si 8 N 11 O 4 :Ce 3+ ,Tb 3+ via the Ce 3+ → Tb 3+ energy transfer: a blue-green phosphor for ultraviolet LEDs

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  30. Tunable dual emission of Ca 3 Al 4 ZnO 10 :Bi 3+ ,Mn 4+ via energy transfer for indoor plant growth lighting

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  31. Structure, bandgap, photoluminescence evolution and thermal stability improved of Sr replacement apatite phosphors Ca10-xSrx(PO4)6F2:Eu2+ (x = 4, 6, 8)

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  32. Energy transfer between terbium and europium ions in barium orthosilicate phosphors obtained from sol-gel route

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  33. A zero-thermal-quenching and color-tunable phosphor LuVO4: Bi3+, Eu3+ for NUV LEDs

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  34. On the origin of temperature dependence of the emission maxima of Eu2+and Ce3+- activated phosphors

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  35. Red-Shifted Emission in Y3MgSiAl3O12:Ce3+ Garnet Phosphor for Blue Light-Pumped White Light-Emitting Diodes

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  36. Optical properties of a novel Ce3+-activated antimony garnet-like Y3Sb5O12 phosphor

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  37. Local coordination, electronic structure, and thermal quenching of Ce 3+ in isostructural Sr 2 GdAlO 5 and Sr 3 AlO 4 F phosphors

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  38. Polyhedral distortion control of unusual photoluminescence color tuning in garnet phosphors via cation substitution

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  39. Spectral broadening of a single Ce3+-doped garnet by chemical unit cosubstitution for near ultraviolet LED

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  40. Crystal structure analysis and evidence of mixed anion coordination at the Ce 3+ site in Y 3 Al 2 (Al,Si) 3 (O,N) 12 oxynitride garnet phosphor

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  41. Full spectrum core–shell phosphors under ultraviolet excitation

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  42. Insights into a novel garnet-based yellowish-green phosphor: structure, luminescence properties and application for warm white light-emitting diodes

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  43. Dehydrogenation-driven to synthesize high-performance Lu2Si4N6C:Ce3+- a broad green-emitting phosphor for full-spectrum lighting

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  44. Crystal structure and photo-luminescence of Gd3Ga2(Al3-Si )(O12-N ):Ce3+ phosphors for AC-warm LEDS

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  45. Sol-gel processing of Eu3+ doped Li6CaLa2Nb2O12 garnet for efficient and thermally stable red luminescence under near-ultraviolet/blue light excitation

    Chemical Engineering Journal · 2019-06-10

    Panpan Du, Qinghong Meng, Xuejiao Wang, Qi Zhu, Xiaodong Li, Xudong Sun, Ji‐Guang Li

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  46. Fabrication of (Tb,Gd)3Al5O12:Ce3+ phosphor ceramics for warm white light-emitting diodes application

    Optical Materials Express · 2019-07-12

    Jie Chen, Yanru Tang, Xuezhuan Yi, Yanna Tian, Gang Ao, Deming Hao, Yandan Lin, Shengming Zhou

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  47. “Frozen” pressure effect in GGAG:Ce3+ white light emitting nanoceramics

    Ceramics International · 2019-07-17

    Paweł Głuchowski, Robert Andrzej Tomala, Robert M. Kowalski, Oleg V. Ignatenko, Marcin E. Witkowski, Winicjusz Drozdowski, W. Stręk, Witold Ryba‐Romanowski, Piotr Solarz

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  48. Tunable emission and energy-transfer mechanism of single-phase Na3Y(PO4)2:Ce3+, Mn2+phosphors for white LEDs

    Journal of Luminescence · 2019-07-26

    R. Vishwanath, Keelapattu Munirathnam, R. Vijaya, Patnamsetty Chidanandha Nagajyothi

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  49. A broadband cyan-emitting Ca 2 LuZr 2 (AlO 4 ) 3 :Ce 3+ garnet phosphor for near-ultraviolet-pumped warm-white light-emitting diodes with an improved color rendering index

    Journal of Materials Chemistry C · 2019-11-29

    Liangling Sun, Balaji Devakumar, Jia Liang, Shaoying Wang, Qi Sun, Xiaoyong Huang

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  50. A review on the advancements in phosphor-converted light emitting diodes (pc-LEDs): Phosphor synthesis, device fabrication and characterization

    Progress in Materials Science · 2019-11-29

    Govind B. Nair, Hendrik Christoffel Swart, S.J. Dhoble

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