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RESEARCH PAPER · The Journal of Physical Chemistry C · 2018

Red-Shifted Emission in Y3MgSiAl3O12:Ce3+ Garnet Phosphor for Blue Light-Pumped White Light-Emitting Diodes

Can He, Haipeng Ji, Zhaohui Huang, Tiesheng Wang, Xiaoguang Zhang, Yangai Liu, Minghao Fang, Xiaowen Wu, Jiaqi Zhang, Xin Min

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Red-Shifted Emission in Y3MgSiAl3O12:Ce3+ Garnet Phosphor for Blue Light-Pumped White Light-Emitting DiodesOriginalLuminescent-center tuning for Ba6Ca3YAlSi6O24:Ce3+, Na+ orthosilicate phosphors15Simple mass-preparation and enhanced thermal performance of Ce: YAG transparent ceramics for high power white LEDs33Luminescence quenching properties of Sr2Ga2GeO7: Pr3+ with and without traps participation18Highly efficient Ce 3+ → Tb 3+ energy transfer induced bright narrowband green emissions from garnet-type Ca 2 YZr 2 (AlO 4 ) 3 :Ce 3+ ,Tb 3+ phosphors for white LEDs with high color rendering index133Blue-emitting Bi-doped double perovskite Gd2ZnTiO6 phosphor with near-ultraviolet excitation for warm white light-emitting diodes48Sol-gel processing of Eu3+ doped Li6CaLa2Nb2O12 garnet for efficient and thermally stable red luminescence under near-ultraviolet/blue light excitation75Luminescent materials comprised of wood-based carbon quantum dots adsorbed on a Ce0.7Zr0.3O2 solid solution: synthesis, photoluminescence properties, and applications in light-emitting diode devices9Development of novel Na2Mg3Zn2Si12O30:Eu3+ red phosphor for white light emitting diodes38The analyses of structure and luminescence in (MgyY3-y) (Al5-ySiy)O12 and Y3(MgxAl5-2xSix)O12 ceramic phosphors26Study of composite Al2O3-Ce:Y3Mg18Al14Si18O12 ceramic phosphors12Ionic occupation sites, luminescent spectra, energy transfer behaviors in Y3MgAl3SiO12: Ce3+, Mn2+ phosphors for warm white LED50Novel multi-wavelength excitable single-component phosphor system for application in white-LEDs18Energy Transfer and Multicolor-Tunable Emissions of Sr3La6(SiO4)6:Ce3+, Tb3+, Eu3+27A broadband cyan-emitting Ca 2 LuZr 2 (AlO 4 ) 3 :Ce 3+ garnet phosphor for near-ultraviolet-pumped warm-white light-emitting diodes with an improved color rendering index244Thermally stable Na3.6Y1.8(PO4)3:Eu3+ phosphor, luminescent properties and application in WLEDs27Achieving ferromagnetic insulating properties in La 0.9 Ba 0.1 MnO 3 thin films through nanoengineering17Full-visible-spectrum lighting enabled by an excellent cyan-emitting garnet phosphor284High quantum efficiency Ce:(Lu,Y) 3 (Al,Sc) 2 Al 3 O 12 transparent ceramics with excellent thermal stability for high-power white LEDs/LDs40Massive red shift of Ce 3+ in Y 3 Al 5 O 12 incorporating super-high content of Ce48Selectivity of Mn 2+ ion occupancy and energy transfer of Ce 3+ → Mn 2+ ions in garnet solid solution40Study on Design, Synthesis and Controlled Color Emission of (Gd,Y)AG: Ce3+ Based Phosphors Through Replacing Al3+ Partly3Yellow Emission Obtained by Combination of Broadband Emission and Multi-Peak Emission in Garnet Structure Na2YMg2V3O12: Dy3+ Phosphor13Discovery of blue-emitting Eu2+-activated sodium aluminate phosphor with high thermal stability via phase segregation40Ca 8 Mg 7 Si 9 N 22 :Ce 3+ —A Yellow-Emitting Nitride Phosphor for White Light Emitting Diodes46Frequency conversion in lanthanide-doped sol-gel derived materials for energy applications12Filling the cyan gap toward full-visible-spectrum LED lighting with Ca2LaHf2Al3O12:Ce3+ broadband green phosphor78A comparison study on the substitution of Y 3+ −Al 3+ by M 2+ −Si 4+ (M = Ba, Sr, Ca, Mg) in Y 3 Al 5 O 12 : Ce 3+ phosphor21Crystal structure and admirable luminescence properties of novel red emitting BiOCl: Eu3+ phosphors for indoor illumination16Color Tuning from Greenish-Yellow to Orange-Red in Thermal-Stable KBaY(MoO4)3:Dy3+, Eu3+ Phosphors via Energy Transfer for UV W-LEDs61Achieving full-visible-spectrum LED lighting via employing an efficient Ce3+-activated cyan phosphor115Efficient radiation releasing in device-level glass ceramics driven by a blue laser2Synthesis and photoluminescence properties of near-UV-excitable cyan-emitting Ca2YHf2Ga3O12:Ce3+ garnet phosphors16Bright cyan-to-green color-tunable emissions from Ce3+/Tb3+ co-activated garnet phosphors for high-color-quality solid-state lighting31Optimization of Ce 3+ concentration and Y 4 MgSi 3 O 13 phase in Mg 2+ ‐Si 4+ Co‐doped Ce: YAG ceramic phosphors13Ce-doped YAG single-crystals prepared by continuous wave (CW)–CO2 laser combustion technique with attractive characteristics and moderate white LED performance12Rapid synthesis of Ce3+:YAG via CO2 laser irradiation combustion method: Influence of Ce doping and thickness of phosphor ceramic on the performance of a white LED device18Synthesis and properties of novel inorganic green chromophore based on Bi24Al2-Mn O397CaY 2 Al 4 SiO 12 :Ce 3+ ,Mn 2+ : a single component phosphor to produce high color rendering index WLEDs with a blue chip53Improvement of thermal stability and photoluminescence in Mg 2 Y 2 Al 2 Si 2 O 12 :Ce 3+ by the cation substitution of Ca 2+ , Sr 2+ and Ba 2+ ions14LaMoBO 6 :Tb 3+ ,Eu 3+ /Sm 3+ ,Bi 3+ yellow phosphors with exceptionally high quantum yields that can be excited by blue light24Improving the thermal stability and luminescent efficiency of (Ba,Sr)3SiO5:Eu2+ phosphors by structure, bandgap engineering and soft chemistry synthesis method98Daylight-White-Emitting and Abnormal Thermal Antiquenching Phosphors Based on a Layered Host SrIn 2 (P 2 O 7 ) 253A Study on the Anti-thermal Dy3+/Eu3+ Co-doped BaLa4Si3O13 Red Phosphors for White-Light-Emitting Diodes and Optical Thermometry Applications41Broadband emission Gd3Sc2Al3O12:Ce3+ transparent ceramics with a high color rendering index for high-power white LEDs/LDs38Preparation and characterization of Gd3(ScAl)2Al3O12:Ce3+ garnet phosphors towards high-color-rendering white-light illumination15Crystal Structure Induced Enhanced Afterglow Luminescence from Rare‐Earth Ion Doped Strontium Silicate Phosphors8Using an excellent near-UV-excited cyan-emitting phosphor for enhancing the color rendering index of warm-white LEDs by filling the cyan gap81Solid‐State Lighting5Distortion and energy transfer assisted tunability in garnet phosphors62Novel Ba3Lu4O9:Bi3+,Eu3+ phosphors for white LEDs: Efficient energy transfer, broad near-UV excitation band and green-yellow-orange-red color tunable emissions13Luminescence investigation of Lu2MgAl4SiO12:Ce3+ and Ca2+ substituted Lu2MgAl4SiO12:Ce3+ phosphors3Blue-light-excitable broadband yellow-emitting CaGd2HfSc(AlO4)3:Ce3+ garnet phosphors for white light-emitting diode devices with improved color rendering index68One-step synthesized single component white emitting carbon microspheres for lighting3Cesium Copper Iodide Perovskite Nanoscale-Thick Films with Tunable Photoluminescence for White Light-Emitting Diodes28Structure and photoluminescence properties of Ce3+ doped Ba7(BO3)3(SiO4)Br phosphors with complex anion groups8A mini review of machine learning in inorganic phosphors10Oxygen vacancy content drives self-reduction and anti-thermal quenching40Full-Spectrum White Light-Emitting Diodes Enabled by an Efficient Broadband Green-Emitting CaY 2 ZrScAl 3 O 12 :Ce 3+ Garnet Phosphor255Full-spectrum solid-state white lighting with high color rendering index exceeding 96 based on a bright broadband green-emitting phosphor45Multiobjective Machine Learning-Assisted Discovery of a Novel Cyan–Green Garnet: Ce Phosphors with Excellent Thermal Stability73Structural induced tunable NIR luminescence of (Y,Lu)3(Mg,Al)2(Al,Si)3O12: Cr3+ phosphors37Excellent enhancement of thermal stability and quantum efficiency for Na2BaCa(PO4)2:Eu2+ phosphor based on Sr doping into Ca30A garnet-structured (Y, Ca)3(Al, Mg)2(Al, Si)3O12:Ce3+ phosphor-in-glass engineering for use in high color rendering white LEDs2Elevating photoluminescence properties of Y3MgAl3SiO12:Ce3+ transparent ceramics for high-power white lighting34New aluminate-germanate hosts with garnet structure for solid state lighting applications3Li+ doping induced zero-thermal quenching in Cs3Zn6––B9O21:xEu3+,yLi+ (0 ≤ x ≤ 0.10, 0.06 ≤ y ≤ 0.16)10Band structure, photoluminescent properties, and energy transfer behavior of a multicolor tunable phosphor K3Lu(PO4)2: Tb3+, Eu3+ for warm white light-emitting diodes26Efficient dual mode emission in Ce3+/Yb3+/Er3+ doped yttrium aluminium gallium garnet for led device and optical thermometry29A novel Cr3+-doped stannate far red phosphor for plant lighting: structure evolution, broad-narrow spectrum tuning and application prospect39A novel extra-broadband visible-NIR phosphor doped with Ce3+ and Cr3+ towards multifunctional advanced applications20A novel red-emitting Na5W3O9F5:Eu3+ phosphor with high color purity for blue-based WLEDs61Powder synthesis and luminescence of a novel yellow-emitting Ba5Si11Al7N25: Eu2+ phosphor discovered by a single-particle-diagnosis approach for warm w-LEDs50Synthesis, crystal structure, and luminescence properties of RbCaF3:Eu3+ orange-red emitting phosphors for white light emitting diodes16Tunable Luminescence Properties of The Ca 3-X Lu X Sc 2-X Mg X Si 3 O 12:Ce 3+ Phosphor Based Ld Lighting1Tunable Luminescence Properties of The Ca3-Xluxsc2-Xmgxsi3o12:Ce3+ Phosphor Based Ld Lighting0Structure and Luminescence Studies of a Ce3+-Activated Ba5La3MgAl3O15 Green-Emitting Phosphor31Influence of lattice distortions on the emission wavelengths of Y3+– and Gd3+–substituted Lu3Al5O12:Ce3+ phosphors9Facile synthesis, novel structure, and tunable luminescence properties of K6Bi13(PO4)15:Dy3+,Eu3+ phosphors for ultraviolet converted white light-emitting diodes33Novel red-emitting Sr3LaTa3O12:Eu3+ phosphor with high color purity and stability for w-LEDs and visualization of latent fingerprint36Near-UV-excitable broadband green-emitting Ca2LaHf2GaAl2O12:Ce3+ garnet-type phosphors for high color rendering warm-white LEDs42Enhancement of green light emission from the LiSrVO4:Tb3+ doped vanadate phosphor by charge compensation via co-doping of the alkali metal ions (Li+/Na+/K+)32Realizing full-spectrum LED lighting with a bright broadband cyan-green-emitting CaY2ZrGaAl3O12:Ce3+ garnet phosphor25High-Efficiency Ce3+ Activated Orthorhombic Lanthanide Silicate Blue Phosphors for Plant Growth Lighting25Systematic synthesis of (Gd 1− x La x ) 2 O 2 SO 4 :Tb 3+ and (Gd 1− x La x ) 2 O 2 S:Tb 3+ nanophosphors for remarkably enhanced luminescence6High-color-quality blue-light-pumped full-spectrum white-light-emitting diodes realized by efficient green-emitting CaY2HfScAl3O12:Ce3+ phosphors24Highly efficient blue‐emitting phosphor via charge compensation strategy and its application for white LED lighting10Efficient broadband yellow-emitting Mg2.5Lu1.5Al1.5Si2.5O12:Ce3+ garnet phosphors for blue-light-pumped white light-emitting diodes21Charge compensators achieve controlled self-reduction of Europium in BaMgP2O730Tunable luminescence properties of the Ca3-xLuxSc2-xMgxSi3O12:Ce3+ phosphor based LD lighting4Tb3+ activated garnets for some novel applications1Luminescence and thermal stability of CaLu2-x-yMeyMg2Si3O12:xCe3+ (Me = Sr, Ba) fluorescent materials4New green garnet-type phosphor LuMgAl5SiO12:Ce3+ for filling cyan gap to achieve full-spectrum and high colour-rendering-index white light-emitting diodes19Achievement of high photoluminescence quantum yield orange-red phosphors by designing Eu2+ reduction environment for multi applications12The Composite Phosphor Sr2mgsi2o7:Eu2+,Dy3+/Y3mgal3sio12:Ce3+ with Stable White Afterglow0Photoluminescence Spectra Correlations with Structural Distortion in Eu3+- and Ce3+-Doped Y3Al5-2x(Mg,Ge)xO12 (x = 0, 1, 2) Garnet Phosphors3Yellow-emitting Ca2Gd(Sb,Nb)O6:Pr3+ double-perovskite phosphors excitable by blue-green light14Elastic, Magnetocaloric, and Magneto-Dielectric Properties of Dy3+ and La3+ Doped Co0.7Zn0.3Fe2O4 Ferrite Nanoparticles for Multifunctional Devices8Energy transfer and tunable photoluminescence of novel white-emitting Sr8MgY(PO4)7: Ce3+/Eu2+/Sm3+ phosphors7Prediction and exploration of emission wavelength (or energy) of luminescent materials based on machine learning6A novel red emitting phosphor CaSc2O4:Eu2+ for the warm white LEDs8Ultra broadband yellow emitting lead-free metal halide perovskite like compounds with near-unity emission quantum yields9Ceramic phosphors for laser-driven lighting1Development and luminescent properties of Ce3+-doped KNaMg3Zn2-xSi12O30 blue-emitting phosphor via solid-state reaction method for white light-emitting diodes (WLEDs)3Synthesis and luminescent properties of novel red-emitting K3GdSi2O7: Eu2+ phosphors for warm white leds0A Blue Light–Excited Broadband Chartreuse‐Emitting LuMg 2 Al 3 Si 2 O 12 :Ce 3+ Garnet Phosphor With High Thermal Stability for High‐Performance White LEDs0A novel narrow-band red-emitting phosphor for lighting and backlight display1Luminescence properties of Ce3+-activated BaLu2Al3ScSiO12 cyan-green emitting garnet phosphors for white LEDs4Broadband green-yellow emitting BaY2Al3ScSiO12:Ce3+ garnet phosphor for high-quality white LED applications5High-Output-Power Broadband Near-Infrared Phosphor Suitable for Various LED Applications5Surface-Engineered Carbon Dots for Bright, Tunable White Emission in Liquid and Solid State for Human-Centric Lighting0Near-zero thermal quenching and white-light regulation in Nb⁵⁺/Eu³⁺ Co-doped Gd1.88Ti₂O₇:0.12Dy³⁺ pyrochlore luminescent ceramics0INFLUENCE OF THE AL/GA RATIO ON THE OPTICAL PROPERTIES OF Y3ALXGA5-XO12:CE PHOSPHORS FOR LED APPLICATIONS0

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  47. Using an excellent near-UV-excited cyan-emitting phosphor for enhancing the color rendering index of warm-white LEDs by filling the cyan gap

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  48. Solid‐State Lighting

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