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RESEARCH PAPER · Dalton Transactions · 2016

Recent developments in the new inorganic solid-state LED phosphors

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Recent developments in the new inorganic solid-state LED phosphorsOriginalAdvanced red phosphors for white light-emitting diodes455Full color control and white emission from CaZnOS:Ce 3+ ,Na + ,Mn 2+ phosphors via energy transfer68Narrow-band red emitting phosphor BaTiF 6 :Mn 4+ : preparation, characterization and application for warm white LED devices64Structure and luminescence of a novel orange-yellow-emitting Ca 1.62 Eu 0.38 Si 5 O 3 N 6 phosphor for warm white LEDs, discovered by a single-particle-diagnosis approach44A chromaticity-tunable white LED by screen-printing red phosphor coating on PiG plates43Progress in discovery and structural design of color conversion phosphors for LEDs1095Green Light-Excitable Ce-Doped Nitridomagnesoaluminate Sr[Mg2Al2N4] Phosphor for White Light-Emitting Diodes162Energy transfer and thermal stability in Bi^3+/Eu^3+ co-doped germanium-borate glasses for organic-resin-free UV LEDs48Red-emitting CaLa4(SiO4)3O:Eu3+ phosphor with superior thermal stability and high quantum efficiency for warm w-LEDs171Synthesis and spectroscopic investigation of Ba3La6(SiO4)6:Eu2+ green phosphors for white light-emitting diodes105Ce 3+ -Doped garnet phosphors: composition modification, luminescence properties and applications1149Double perovskite LiLaMgWO6:Eu3+ novel red-emitting phosphors for solid sate lighting: Synthesis, structure and photoluminescent properties185Color tunable dual-phase transparent glass ceramics for warm white light-emitting diodes83Tunable white light of multi-cation-site Na 2 BaCa(PO 4 ) 2 :Eu,Mn phosphor: synthesis, structure and PL/CL properties68Broad near-ultraviolet and blue excitation band induced dazzling red emissions in Eu 3+ -activated Gd 2 MoO 6 phosphors for white light-emitting diodes124Facile synthesis, morphology and photoluminescence of a novel red fluoride nanophosphor K 2 NaAlF 6 :Mn 4+115Mn 4+ ,Li + co-doped SrMgAl 10 O 17 phosphor-in-glass: application in high-power warm w-LEDs52Structure and luminescence behavior of a single-ion activated single-phased Ba 2 Y 3 (SiO 4 ) 3 F:Eu white-light phosphor90Synthesis, optical properties and applications of light-emitting copper nanoclusters237The design and preparation of the thermally stable, Mn 4+ ion activated, narrow band, red emitting fluoride Na 3 GaF 6 :Mn 4+ for warm WLED applications161Eu 3+ ‐Doped Phosphor‐in‐Glass: A Route toward Tunable Multicolor Materials for Near‐UV High‐Power Warm‐White LEDs109Optimized photoluminescence of red phosphor Na 2 SnF 6 :Mn 4+ as red phosphor in the application in “warm” white LED s54Tuning excitation and emission of Mn4+ emitting center in Y3Al5O12 by cation substitution91Lanthanide-Activated Phosphors Based on 4f-5d Optical Transitions: Theoretical and Experimental Aspects1025Charge compensated derived enhanced red emission from Sr 3 (VO 4 ) 2 :Eu 3+ nanophosphors for white light emitting diodes and flat panel displays46Chemistry-Inspired Adaptable Framework Structures368The design and synthesis of new double perovskite (Na,Li)YMg(W,Mo)O 6 :Eu 3+ red phosphors for white light-emitting diodes108Luminescence Properties of Ca19Ce(PO4)14:A (A = Eu3+/Tb3+/Mn2+) Phosphors with Abundant Colors: Abnormal Coexistence of Ce4+/3+–Eu3+ and Energy Transfer of Ce3+ → Tb3+/Mn2+ and Tb3+–Mn2+68Eu 3+ -activated Na 2 Gd(PO 4 )(MoO 4 ): A novel high-brightness red-emitting phosphor with high color purity and quantum efficiency for white light-emitting diodes273A novel Eu3+-doped garnet-type tellurate red-emitting phosphor with high thermal stability and color purity101Temperature dependent photoluminescence of Dy3+ doped LiCaBO3 phosphor52CsPbX3 nanocrystals films coated on YAG:Ce3+ PiG for warm white lighting source43Photoluminescence Properties of Double Perovskite Tantalates Activated with Mn4+, AE2LaTaO6:Mn4+ (AE = Ca, Sr, and Ba)42Composition Screening in Blue-Emitting Li4Sr1+xCa0.97–x(SiO4)2:Ce3+ Phosphors for High Quantum Efficiency and Thermally Stable Photoluminescence133Eu3+-activated La2MoO6-La2WO6 red-emitting phosphors with ultrabroad excitation band for white light-emitting diodes88Highly Efficient and Stable Narrow-Band Red Phosphor Cs2SiF6:Mn4+ for High-Power Warm White LED Applications215Luminescent characteristics of Tm3+/Tb3+/Eu3+ tri-doped phosphate transparent glass ceramics for white LEDs43Single-Phase White Light-Emitting Ca x Ba(9– x )Lu2Si6O24:Eu2+/Mn2+ Phosphors40Critical Review—Narrow-Band Emission of Nitride Phosphors for Light-Emitting Diodes: Perspectives and Opportunities72Ca 2- x Y 1+ x Zr 2- x Al 3+ x O 12 :Ce 3+ : Solid Solution Design toward the Green Emission Garnet Structure Phosphor for Near-UV LEDs and Their Luminescence Properties64Energy transfer and tunable emission of Ca14Al10Zn6O35:Bi3+,Sm3+ phosphor41Waterproof Narrow-Band Fluoride Red Phosphor K2TiF6:Mn4+ via Facile Superhydrophobic Surface Modification185Novel highly efficient single-component multi-peak emitting aluminosilicate phosphors co-activated with Ce 3+ , Tb 3+ and Eu 2+ : luminescence properties, tunable color, and thermal properties50Achieving High Quantum Efficiency Narrow-Band β-Sialon:Eu 2+ Phosphors for High-Brightness LCD Backlights by Reducing the Eu 3+ Luminescence Killer356Near-ultraviolet and blue light excited Sm3+ doped Lu2MoO6 phosphor for potential solid state lighting and temperature sensing133Red-emitting enhancement by inducing lower crystal field symmetry of Eu3+ site in CaWO4:Eu3+ phosphor for n-UV w-LEDs63A green synthetic route to the highly efficient K 2 SiF 6 :Mn 4+ narrow-band red phosphor for warm white light-emitting diodes129An efficient green phosphor of Ce 3+ and Tb 3+ -codoped Ba 2 Lu 5 B 5 O 17 and a model for elucidating the high thermal stability of the green emission53Cation vacancy repair for the enhancement of orange-yellow luminescence in Sr 9 Mg 1.5−x K x (PO 4 ) 7 :Eu 2+ phosphors46Efficient rare-earth free red-emitting Ca 2 YSbO 6 :Mn 4+ ,M(M = Li + , Na + , K + , Mg 2+ ) phosphors for white light-emitting diodes117Enhanced luminescence of a Ba 2 GdSbO 6 :Mn 4+ red phosphor via cation doping for warm white light-emitting diodes146High efficiency red emission carbon dots based on phenylene diisocyanate for trichromatic white and red LEDs65Mn 2+ and Mn 4+ red phosphors: synthesis, luminescence and applications in WLEDs. A review706Narrow-band red-emitting KZnF 3 :Mn 4+ fluoroperovskites: insights into electronic/vibronic transition and thermal quenching behavior51Photoluminescence properties of a Ce 3+ doped Sr 3 MgSi 2 O 8 phosphor with good thermal stability40Red-emission over a wide range of wavelengths at various temperatures from tetragonal BaCN 2 :Eu 2+41Structural construction and photoluminescence tuning via energy transfer in apatite-type solid-state phosphors81Crystal structure, electronic structure and photoluminescence properties of KLaMgWO6:Eu3+ phosphors44Blue photons excited highly chromatic red light emitting K3La(PO4)2:Pr3+ phosphors for white light emitting diodes40On the origin of temperature dependence of the emission maxima of Eu2+and Ce3+- activated phosphors40Luminescence of an Oxonitridoberyllate: A Study of Narrow-Band Cyan-Emitting Sr[Be 6 ON 4 ]:Eu 2+96Narrow-Band Yellow-Orange Emitting La3–xCa1.5xSi6N11:Eu2+ (x ≈ 0.77): A Promising Phosphor for Next-Generation Amber pcLEDs46Glass Ceramic Phosphors: Towards Long‐Lifetime High‐Power White Light‐Emitting‐Diode Applications–A Review356Significant improved quantum yields of CaAl12O19:Mn4+ red phosphor by co-doping Bi3+ and B3+ ions and dual applications for plant cultivations60New Eu3+-activated bismuthate tellurate LiSrBiTeO6 red-emitting phosphor for InGaN-based w-LEDs52Highly Stable K2SiF6:Mn4+@K2SiF6 Composite Phosphor with Narrow Red Emission for White LEDs248A Review on Halide Perovskites as Color Conversion Layers in White Light Emitting Diode Applications92New design of highly sensitive and selective MoO3:Eu3+ micro-rods: Probing of latent fingerprints visualization and anti-counterfeiting applications83Preparation, band-structure and luminescence of double perovskite Ba2MgMoO6:Eu3+ orange-red phosphor for white LEDs56Eu 2+ Site Preferences in the Mixed Cation K 2 BaCa(PO 4 ) 2 and Thermally Stable Luminescence577Improving Quantum Efficiency and Thermal Stability in Blue-Emitting Ba 2– x Sr x SiO 4 :Ce 3+ Phosphor via Solid Solution244Learning from a Mineral Structure toward an Ultra‐Narrow‐Band Blue‐Emitting Silicate Phosphor RbNa3(Li3SiO4)4:Eu2+226Learning from a Mineral Structure toward an Ultra‐Narrow‐Band Blue‐Emitting Silicate Phosphor RbNa3(Li3SiO4)4:Eu2+129Next‐Generation Narrow‐Band Green‐Emitting RbLi(Li 3 SiO 4 ) 2 :Eu 2+ Phosphor for Backlight Display Application532Design and Development of a Bluish-Green Luminescent Material (K2HfSi3O9:Eu2+) with Robust Thermal Stability for White Light-Emitting Diodes106Structural Confinement toward Giant Enhancement of Red Emission in Mn2+‐Based Phosphors165Preparation and investigation of Dy3+-doped Ca9LiGd2/3(PO4)7 single-phase full-color phosphor43Synthesis and photoluminescence properties of novel thermally robust Na3GdP2O8: Re3+ (Re = Sm, Dy) phosphors46Control of Narrow-Band Emission in Phosphor Materials for Application in Light-Emitting Diodes160Eu3+-doped highly thermal-stable barium yttrium aluminate as a red-emitting phosphor for UV based white LED45Importance of Evaluating the Intensity Dependency of the Quantum Efficiency: Impact on LEDs and Persistent Phosphors66Highly Efficient and Thermally Stable Blue-Green (Ba0.8Eu0.2O)(Al2O3)4.575×(1+x) Phosphor through Structural Modification55Blue-yellow multicolor phosphor, Eu2+-activated Li3NaSiO4: Excellent thermal stability and quenching mechanism47Synthesis and photoluminescence properties of Sm3+ and Dy3+ ions activated double perovskite Sr2MgTeO6 phosphors107Highly efficient and thermally stable single-activator white-emitting phosphor K 2 Ca(PO 4 )F:Eu 2+ for white light-emitting diodes71Structural design of new Ce 3+ /Eu 2+ -doped or co-doped phosphors with excellent thermal stabilities for WLEDs133Discovery of New Narrow‐Band Phosphors with the UCr 4 C 4 ‐Related Type Structure by Alkali Cation Effect137Synthesis and photoluminescence properties of BaGeTeO6:Eu3+ red-emitting phosphor for n-UV Light Emitting Diodes42Eu3+ doped (Li, Na, K) LaMgWO6 red emission phosphors: An example to rational design with theoretical and experimental investigation43Synthesis and photoluminescence properties of novel Sr3LiSbO6:Mn4+ red phosphor for indoor plant growth51Thermally stable double-perovskite Ca3TeO6:Eu3+ red-emitting phosphors with high color purity113Y3Al5O12:Ce3+ single crystal and red-emitting Y3Al5O12:Cr3+ single crystal for high power W-LEDs57Surface Passivation toward Highly Stable Mn4+‐Activated Red‐Emitting Fluoride Phosphors and Enhanced Photostability for White LEDs97Structural Evolution and Effect of the Neighboring Cation on the Photoluminescence of Sr(LiAl 3 ) 1− x (SiMg 3 ) x N 4 :Eu 2+ Phosphors70Sr[Li2Al2O2N2]:Eu2+—A high performance red phosphor to brighten the future340Polyhedron Transformation toward Stable Narrow‐Band Green Phosphors for Wide‐Color‐Gamut Liquid Crystal Display201New red phosphors enable white LEDs to show both high luminous efficacy and color rendering index80Novel cyan‐emitting KBaScSi 2 O 7 :Eu 2+ phosphors with ultrahigh quantum efficiency and excellent thermal stability for WLEDs57Near UV-pumped yellow-emitting Ca3TeO6:Dy3+ phosphor for white light-emitting diodes74Effects of cationic substitution on the luminescence behavior of Dy3+ doped orthophosphate phosphor87Promotion of efficiency and thermal stability by restraining dynamic energy migration based on the highly symmetric rigid structure in the n-UV excitation green emission garnet phosphors62Lead-Free Halide Perovskites and Perovskite Variants as Phosphors toward Light-Emitting Applications159Hybrid Metal Halides with Multiple Photoluminescence Centers233New physical insight into crystal structure, luminescence and optical properties of YPO4:Dy3+∖Eu3+∖Tb3+ single-phase white-light-emitting phosphors87Tunable lanthanide/transition metal ion‐doped novel phosphors for possible application in w‐LEDs: a review77A study of optical properties and site preference of Bi3+/Eu3+ co-doped CaLa4Si3O13 red-emitting phosphors for w-LED applications47Thermal stability and photoluminescence of Mn2+ activated green-emitting feldspar phosphor SrAl2Si2O8: Mn2+ for wide gamut w-LED backlight45Designing High‐Performance LED Phosphors by Controlling the Phase Stability via a Heterovalent Substitution Strategy76A novel multi-center activated single-component white light-emitting phosphor for deep UV chip-based high color-rendering WLEDs190Ca(Mg0.8Al0.2)(Si1.8Al0.2)O6:Ce3+,Tb3+ Phosphors: Structure Control, Density-Functional Theory Calculation, and Luminescence Property for pc-wLED Application41Broad-band emission in metal halide perovskites: Mechanism, materials, and applications288Dual‐Shelled RbLi(Li 3 SiO 4 ) 2 :Eu 2+ @Al 2 O 3 @ODTMS Phosphor as a Stable Green Emitter for High‐Power LED Backlights90Probing structural and photophysical features of Eu3+ activated NaCdPO4 orthophosphate phosphor51Data-Driven Photoluminescence Tuning in Eu2+-Doped Phosphors76Pressure‐Driven Eu 2+ ‐Doped BaLi 2 Al 2 Si 2 N 6 : A New Color Tunable Narrow‐Band Emission Phosphor for Spectroscopy and Pressure Sensor Applications105Narrow-band emitters in LED backlights for liquid-crystal displays217Thermoluminescence study and evaluation of trapping parameters CaTiO3: RE (RE=Eu3+, Dy3+) phosphor for TLD applications65Structural Engineering of Eu2+-Doped Silicates Phosphors for LED Applications242Achieving the potential multifunctional near-infrared materials Ca 3 In 2−x Ga x Ge 3 O 12 :Cr 3+ using a solid state method59Recent progress of zero-dimensional luminescent metal halides873Room-temperature synthesis of blue-emissive zero-dimensional cesium indium halide quantum dots for temperature-stable down-conversion white light-emitting diodes with a half-lifetime of 186 h45Structure and photoluminescence of Eu 3+ doped Sr 2 InTaO 6 red phosphor with high color purity90Luminescent properties of Na2GdMg2(VO4)3:Eu3+ red phosphors for NUV excited pc-WLEDs59Insights into the crystal structure and multifunctional optical properties of A2CdTeO6 (A=Ba, Sr, Ca) double perovskites52Learning from Mineral Structures toward New Luminescence Materials for Light-Emitting Diode Applications146A Study on the Anti-thermal Dy3+/Eu3+ Co-doped BaLa4Si3O13 Red Phosphors for White-Light-Emitting Diodes and Optical Thermometry Applications41High Quantum Yield Gd4.67Si3O13:Eu3+ Red-Emitting Phosphor for Tunable White Light-Emitting Devices Driven by UV or Blue LED87Rare earth (RE) doped phosphors and their emerging applications: A review632Design principles for achieving red emission in Eu2+/Eu3+ doped inorganic solids83Research trends in combinatorial optimization42Defect Engineering in a Eu2+-Doped β-Al2O3 Structure Blue Phosphor and Its Controllable Zero-Thermal Quenching Luminescence97Finding an efficient far-red-emitting CaMg2La2W2O12:Mn4+ phosphor toward indoor plant cultivation LED lighting91Bi-Color Phosphor-in-Glass Films Achieve Superior Color Quality Laser-Driven Stage Spotlights84Synthesis optimisation and efficiency enhancement in Eu3+ doped barium molybdenum titanate phosphors for w-LED applications83Tuning of emission by effect of local symmetry in BaLaLiWO6:Dy3+/Eu3+ for WLEDs41A novel Bi3+-Activated garnet phosphor with site-selected excitations and high temperature sensitivity42Er3+ activated LaAlO3 perovskite phosphor: Crystal structure and down conversion photoluminescent behaviour for optoelectronic devices69Preparation and luminescence behaviour of perovskite LaAlO3:Tb3+ nanophosphors for innovative displays71Optical thermometry based on fluorescence intensity ratio of Dy3+-Doped oxysilicate apatite warm white phosphor67Recent progress in trivalent europium (Eu 3+ )-based inorganic phosphors for solid-state lighting: an overview72Blue light emitting Sr2MgSi2O7:Eu2+ nanophosphor for latent fingerprint, anti-counterfeiting and near UV-LED applications45Structural and photoluminescence properties of Sm3+ ions doped strontium yttrium tungstate phosphors for reddish-orange photonic device applications45Multi‐Mode Optical Manometry Based on Li 4 SrCa(SiO 4 ) 2 :Eu 2+ Phosphors61Luminescence studies of high color purity red-emitting CaAl4O7:Eu3+ phosphor prepared by microwave-assisted synthesis technique45A novel thermally-stable single-phase phosphor Ca2InTaO6:Dy3+ for NUV-excited white LEDs60Highly Efficient Narrow-Band Green-Emitting Na 3 K 5 (Li 3 SiO 4 ) 8 :Eu 2+ Phosphor with Low Thermal Quenching49Recent progress on modulating luminescence thermal quenching properties of Bi 3+ -activated phosphors77Doping Up the Light: A Review of A/B-Site Doping in Metal Halide Perovskite Nanocrystals for Next-Generation LEDs64Exploring inorganic phosphors: basics, types, fabrications and their luminescence properties for LED/WLED/displays60Synthesis Strategies for Rare Earth Activated Inorganic Phosphors: A Mini Review43

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