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RESEARCH PAPER · Journal of Materials Chemistry C · 2018

Co-substitution in Ca 1−x Y x Al 12−x Mg x O 19 phosphors: local structure evolution, photoluminescence tuning and application for plant growth LEDs

Yinjian Zheng, Haiming Zhang, Haoran Zhang, Zhiguo Xia, Yingliang Liu, Мaxim S. Моlokeev, Bingfu Lei

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Co-substitution in Ca 1−x Y x Al 12−x Mg x O 19 phosphors: local structure evolution, photoluminescence tuning and application for plant growth LEDsOriginalFar-red-emitting double-perovskite CaLaMgSbO 6 :Mn 4+ phosphors with high photoluminescence efficiency and thermal stability for indoor plant cultivation LEDs76Novel SrMg 2 La 2 W 2 O 12 :Mn 4+ far-red phosphors with high quantum efficiency and thermal stability towards applications in indoor plant cultivation LEDs89Preparation, characterization, and luminescence properties of double perovskite SrLaMgSbO 6 :Mn 4+ far-red emitting phosphors for indoor plant growth lighting29Synthesis and photoluminescence properties of novel far-red-emitting BaLaMgNbO 6 :Mn 4+ phosphors for plant growth LEDs106Color tunable Ba3Lu(PO4)3:Tb3+,Mn2+ phosphor via Tb3+→Mn2+ energy transfer for white LEDs13pH dependent hydrothermal synthesis of Ca14Al10Zn6O35:0.15Mn4+ phosphor with enhanced photoluminescence performance and high thermal resistance for indoor plant growth lighting33Synthesis and photoluminescence properties of a novel red phosphor SrLaGaO 4 :Mn 4+61Enhancement of red emission and site analysis in Eu2+ doped new-type structure Ba3CaK(PO4)3 for plant growth white LEDs208Exploring the self-redox reaction mechanism of Mn-doped Mg2(Ti/Sn)O4 with its precise dopant position10A highly luminescent Mn 4+ activated LaAlO 3 far-red-emitting phosphor for plant growth LEDs: charge compensation induced Mn 4+ incorporation31A novel Na 3 La(PO 4 ) 2 /LaPO 4 :Eu blue-red dual-emitting phosphor with high thermal stability for plant growth lighting67Highly efficient and dual broad emitting light convertor: an option for next-generation plant growth LEDs45Highly luminescent and ultrastable cesium lead halide perovskite nanocrystal glass for plant-growth lighting engineering33Mn 4+ -activated BaLaMgSbO 6 double-perovskite phosphor: a novel high-efficiency far-red-emitting luminescent material for indoor plant growth lighting42Simultaneously enhanced far-red luminescence and thermal stability in Ca3Al4ZnO10:Mn4+ phosphor via Mg2+ doping for plant growth lighting69CaYAlO4:Mn4+,Mg2+: An efficient far-red-emitting phosphor for indoor plant growth LEDs58Enhance the luminescence properties of Ca14Al10Zn6O35:Ti4+ phosphor via cation vacancies engineering of Ca2+ and Zn2+26Prevailing Strategies to Tune Emission Color of Lanthanide‐Activated Phosphors for WLED Applications278Recent developments in luminescent nanoparticles for plant imaging and photosynthesis87A remarkably tunable emission from red to yellow to green in Mn4+-activated CaAl12O19 phosphor via co-doping Bi3+6Tunable white-light emission and energy transfer in single-phase Bi3+,Eu3+ co-doped Ba9Y2Si6O24 phosphors for UV w-LEDs54Enhancing quantum efficiency and tuning photoluminescence properties in far-red-emitting phosphor Ca14Ga10Zn6O35:Mn4+ based on chemical unit engineering142Novel Ca2GdTaO6:Mn4+,M (M = Li+, Na+, K+, and Mg2+) red phosphors for plant cultivation light-emitting diodes: Synthesis and luminescence properties47Novel high-efficiency violet-red dual-emitting Lu2GeO5: Bi3+, Eu3+ phosphors for indoor plant growth lighting41Deep-red-emitting Ca2LuSbO6:Mn4+ phosphors for plant growth LEDs: Synthesis, crystal structure, and photoluminescence properties69Double perovskite (Gd0.85-xYx)2MgTiO6:0.3Eu3+ red phosphors for white LEDs with excellent high temperature performance8Synthesis and photoluminescence properties of novel red-emitting phosphor SrAl3BO7:Mn4+ with enhanced emission by Mg2+/Zn2+/Ca2+ incorporation for plant growth LED lighting48The analyses of structure and luminescence in (MgyY3-y) (Al5-ySiy)O12 and Y3(MgxAl5-2xSix)O12 ceramic phosphors26Highly thermal-sensitive robust LaTiSbO6:Mn4+ with a single-band emission and its topological architecture for single/dual-mode optical thermometry93Bismuth activated full spectral double perovskite luminescence materials by excitation and valence control for future intelligent LED lighting28Enhanced red luminescence in CaAl 12 O 19 :Mn 4+ via doping Ga 3+ for plant growth lighting220Enhancing Luminescence and Controlling the Mn Valence State of Gd 3 Ga 5– x –δ Al x – y +δ O 12 : y Mn Phosphors by the Design of the Garnet Structure88Discovery of blue-emitting Eu2+-activated sodium aluminate phosphor with high thermal stability via phase segregation40Tuning the luminescence properties of Mn 4+ ‐activated CaYAlO 4 phosphor by co‐doping cations for indoor plant cultivation27Structure analysis, tuning photoluminescence and enhancing thermal stability on Mn4+-doped La2-xYxMgTiO6 red phosphor for agricultural lighting78F enhanced luminescence performance of SrLu2O4:Ce3+ glass ceramic for superior high-power artificial horticultural LEDs28A novel redshift mechanism of Ce3+ emission in ZrO2-Ce: YAG composite phosphor ceramics35Tunable luminescence and energy transfer in Y2BaAl4SiO12:Tb3+,Eu3+ phosphors for solid-state lighting63Luminescent properties of Cu+ doped aluminosilicate glasses: Effect of optical basicity and doping content19Synthesis and photoluminescence properties of near-UV-excitable cyan-emitting Ca2YHf2Ga3O12:Ce3+ garnet phosphors16Far-red-emitting Li6SrLa2Sb2O12: Mn4+ phosphor for plant growth LEDs application83Fabrication of ternary ZrO2-Al2O3-YAG:Ce ceramic phosphors for white light-emitting diodes12An insight into the luminescent properties and Judd–Ofelt analysis of Eu3+ doped CaZn2(PO4)2 phosphors32Eco‐friendly Mn‐doped CsPbCl 3 perovskite nanocrystal glass with blue‐red emission for indoor plant lighting18Development of a cyan blue-emitting Ba 3 La 2 (BO 3 ) 4 :Ce 3+ ,Tb 3+ phosphor for use in dental glazing materials: color tunable emission and energy transfer7Magical polyhedral twist via chemical unit co-substitution in LaAlO 3 :Mn 4+ to greatly enhance the zero phonon line for high-efficiency plant-growth LEDs49Thermal stability and luminescence of novel garnet-type yafsoanite Ca3Zn3(TeO6)2:Sm3+ phosphors for white LEDs37A novel far-red emitting phosphor activated Ba2LuTaO6:Mn4+: Crystal structure, optical properties and application in plant growth lighting37Deep-red-emitting Mg2InSbO6:Mn4+ phosphors with a double-perovskite structure for plant-cultivation LEDs: Synthesis and photoluminescence properties81Monodisperse micro-spherical Sr2–Mg1+Y Al22–O36:xMn4+ red phosphors11NaLaMgWO6:Mn4+/Pr3+/Bi3+ bifunctional phosphors for optical thermometer and plant growth illumination matching phytochrome P and P33Multifunctional Pr3+ single doped CaLaMgTaO6: Crystal structure, thermal behavior and applications25Equivalent cation substitution-triggered highly efficient Mn4+ red emission in double-perovskite type (Ba, Sr)2(Gd, La, Y, Lu)(Nb, Sb)O6:Mn4+ solid solution phosphors and photophysical studies62Sr3LiTaO6:xMn4+ red-emitting phosphors for indoor plant growth lighting: High thermal stability and quantum efficiency30Low-temperature microwave synthesis and luminescence properties of far-red emission ZnGa2O4:Cr3+ phosphor for plant cultivation20Artificial mimics of light-harvesting organic pigment via a double-perovskite structure (LiLa2SbO6:Bi3+, Mg2+, Mn4+) with single-composition and structure-activity relationship5Improved thermal stability of the near‐infrared Al‐modulated Zn 3 Ga 2 GeO 8 : Cr 3+ phosphors for plant growth applications36Enhanced luminescence properties of Li2MgTiO4: Mn4+, Ge4+ phosphor via single cation substitution for indoor plant cultivation31Optimization of the luminescence efficiency and moisture stability of a red phosphor KRb3Ge2F12:Mn4+ for indoor plant growth LED applications22Chemical unit co-substitution for a new far-red-emitting phosphor Ca3-6(NaLu)3LiSbO6:Mn4+ to achieve high quantum efficiency and superb thermal stability12Efficient and ultra-thermally stable Eu 3+ and Sm 3+ -activated narrow-band red/deep red-emitting phosphors and their versatile applications28Molten-salt synthesis and spectral characteristics of perovskite KCa2Nb3O10:Sm3+ phosphors31Achieving highly thermostable red emission in singly Mn 2+ -doped BaXP 2 O 7 (X = Mg/Zn) via self-reduction36Light keys open locks of plant photoresponses: A review of phosphors for plant cultivation LEDs75Novel Cr3+-activated far-red emitting phosphors with β-Ca3(PO4)2-type structure for indoor plant cultivation37Recent development of aluminate materials for solid state lighting37Site Preference-Driven Mn 4+ Stabilization in Double Perovskite Phosphor Regulating Quantum Efficiency from Zero to Champion53Excellent Quantum Efficiency and Superior Color Purity Red-Emitting CaAl12O19–CaAl4O7–MgAl2O4:Mn4+ Phosphors for Plant Growth and High Color Rendering Index White Light-Emitting Diode Applications37Monodisperse CaAl12O19:Mn4+ microspheres for full-spectrum white LEDs8Recent Advancements in Rare-earth Activated Phosphors in the Perspective of Phototherapy and Plant Lamp Applications: A Review1Double Perovskite Mn4+-Doped La2CaSnO6/La2MgSnO6 Phosphor for Near-Ultraviolet Light Excited W-LEDs and Plant Growth16Bi3+/Mn4+ co-activated phosphors for indoor plant growth and temperature sensing21Highly efficient Mn–Mn dimer activated phosphors for high-power near-infrared LED application27High quantum efficiency and excellent color purity of red-emitting Eu 3+ -heavily doped Gd(BO 2 ) 3 -Y 3 BO 6 -GdBO 3 phosphors for NUV-pumped WLED applications24Potential Use of Photo-Excited Phosphors in Energy-Efficient Plant Lighting1Ca2+ enhanced far-red emission performance and efficiency of SrGd2Al2O7:Mn4+ phosphor for the potential application in plant growth lighting6High-Efficiency Ce3+ Activated Orthorhombic Lanthanide Silicate Blue Phosphors for Plant Growth Lighting25Preparation and Optical Property of Far-Red LED Encapsulated with the Graded-Index Fluorescent Glass Film4Be 2+ ‐Induced Red Emission Enhancement in CaAl 12 O 19 :Mn 4+ for Wide Color Gamut Display: Suppressing Self‐Reduction of Mn 4+ to Mn 2+26Nano light conversion agents: recent advances, future prospects and challenges in enhancing plant green cultivation18Photoluminescence properties of Sb3+-activated Ca2YTaO6 dual color emitting phosphors for plant growth LEDs applications11Optimization of Al-excess nonstoichiometry on the densification and plasma resistance of YAG ceramics6Engineering efficient blue and far-red dual-emitting phosphor for plant growth25Colour tunable Ca3Y2Ge3O12: Tb3+, Eu3+ phosphors with high quantum yield for white LED applications35A green-light-driven Mn4+ doped aluminate for agricultural cultivation with high resemblance to the phytochrome spectrum9Optimized Mn4+ doped Sr9Y2W4O24 perovskite for enhanced far-red-emitting luminescent material30Red-emitting Mn4+-doped Li2MgSn2O6 phosphors for plant growth LED lighting34Promising deep‐red emitting Cr3+‐doped SrAl12O19 phosphors for plant growth LEDs9Influence of Mg doping on structure and optical properties of red-emitting phosphor Li2TiO3:Mn4+2Review on advancements in white light phosphor matrices for energy-efficient lighting36Toward Controllable Self‐Reduction of Mn4+ to Mn2+ by Lanthanide Ions for Luminescence Based Colorimetric Sensing of Temperature16Conversion into single-phase YAG ceramics at low temperature by stoichiometry adjustment3Recent progress of inorganic phosphors in artificial plant cultivation LEDs46Development of High‐Efficiency BaSrCaWO6:Mn4+ Red‐Emitting Phosphors via La3+ Addition Strategy2Dual deep red and far red emitting Cr-doped garnet-perovskite based phosphors with excellent responsiveness to P fr for plant growth LED lighting7Highly efficient red/orange-red emitting Eu 3+ and Sm 3+ /Eu 3+ co-doped phosphors with their versatile applications13Efficient Lead-Free Double Perovskite Phosphors Enabled by Sb3+ and Gd3+ Co-Doping toward Plant Lighting LEDs2Mn4+ co-doped double perovskite CaSrLaSbO6: Bi3+ phosphors with multiple luminescent centers for optical temperature sensing and indoor plant cultivation films9Bi 3+ /K + -Activated Calcium Lutetium Gallate and the Devices Under UV Chip for Warm WLED and Plant Lighting16Synthesis and luminescence of Mn4+-doped SrLa2Ga2O7 far-red phosphor with potential for plant growth applications0Cs2NaScCl6: Sb3+/Er3+ − a dual-emission double perovskite for high-sensitivity optical thermometry1Novel tungstate phosphors with high external quantum efficiency for plant supplement illumination3Dual green and red emission of novel Mn doped Mg 0.3 Zn 0.7 Al 2 O 4 phosphors synthesized by a solid-state method for high-sensitivity temperature sensor applications0Recent Advances in Nanomaterial‐Based Light Conversion for Agriculture0Synthesis and properties of Mn4+-doped CaAl4O7-based phosphors obtained from natural calcium-containing raw materials0

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  4. Synthesis and photoluminescence properties of novel far-red-emitting BaLaMgNbO 6 :Mn 4+ phosphors for plant growth LEDs

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  5. Color tunable Ba3Lu(PO4)3:Tb3+,Mn2+ phosphor via Tb3+→Mn2+ energy transfer for white LEDs

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  6. pH dependent hydrothermal synthesis of Ca14Al10Zn6O35:0.15Mn4+ phosphor with enhanced photoluminescence performance and high thermal resistance for indoor plant growth lighting

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  7. Synthesis and photoluminescence properties of a novel red phosphor SrLaGaO 4 :Mn 4+

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  9. Exploring the self-redox reaction mechanism of Mn-doped Mg2(Ti/Sn)O4 with its precise dopant position

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  13. Highly luminescent and ultrastable cesium lead halide perovskite nanocrystal glass for plant-growth lighting engineering

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  14. Mn 4+ -activated BaLaMgSbO 6 double-perovskite phosphor: a novel high-efficiency far-red-emitting luminescent material for indoor plant growth lighting

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  15. Simultaneously enhanced far-red luminescence and thermal stability in Ca3Al4ZnO10:Mn4+ phosphor via Mg2+ doping for plant growth lighting

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  16. CaYAlO4:Mn4+,Mg2+: An efficient far-red-emitting phosphor for indoor plant growth LEDs

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  17. Enhance the luminescence properties of Ca14Al10Zn6O35:Ti4+ phosphor via cation vacancies engineering of Ca2+ and Zn2+

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  18. Prevailing Strategies to Tune Emission Color of Lanthanide‐Activated Phosphors for WLED Applications

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  31. Enhanced red luminescence in CaAl 12 O 19 :Mn 4+ via doping Ga 3+ for plant growth lighting

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  32. Enhancing Luminescence and Controlling the Mn Valence State of Gd 3 Ga 5– x –δ Al x – y +δ O 12 : y Mn Phosphors by the Design of the Garnet Structure

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  33. Discovery of blue-emitting Eu2+-activated sodium aluminate phosphor with high thermal stability via phase segregation

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  34. Tuning the luminescence properties of Mn 4+ ‐activated CaYAlO 4 phosphor by co‐doping cations for indoor plant cultivation

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  41. Far-red-emitting Li6SrLa2Sb2O12: Mn4+ phosphor for plant growth LEDs application

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  42. Fabrication of ternary ZrO2-Al2O3-YAG:Ce ceramic phosphors for white light-emitting diodes

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  43. An insight into the luminescent properties and Judd–Ofelt analysis of Eu3+ doped CaZn2(PO4)2 phosphors

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  44. Eco‐friendly Mn‐doped CsPbCl 3 perovskite nanocrystal glass with blue‐red emission for indoor plant lighting

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  45. Development of a cyan blue-emitting Ba 3 La 2 (BO 3 ) 4 :Ce 3+ ,Tb 3+ phosphor for use in dental glazing materials: color tunable emission and energy transfer

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  46. Magical polyhedral twist via chemical unit co-substitution in LaAlO 3 :Mn 4+ to greatly enhance the zero phonon line for high-efficiency plant-growth LEDs

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  47. Thermal stability and luminescence of novel garnet-type yafsoanite Ca3Zn3(TeO6)2:Sm3+ phosphors for white LEDs

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  48. A novel far-red emitting phosphor activated Ba2LuTaO6:Mn4+: Crystal structure, optical properties and application in plant growth lighting

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  49. Deep-red-emitting Mg2InSbO6:Mn4+ phosphors with a double-perovskite structure for plant-cultivation LEDs: Synthesis and photoluminescence properties

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