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RESEARCH PAPER · Dalton Transactions · 2013

New type of complex alkali and alkaline earth metal borates with isolated (B12O24)12− anionic group

Hongping Wu, Hongwei Yu, Shilie Pan, Anqing Jiao, Jian Wei Han, Kui Wu, Shujuan Han, Hongyi Li

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New type of complex alkali and alkaline earth metal borates with isolated (B12O24)12− anionic groupOriginalBa 2 B 10 O 17 : a new centrosymmetric alkaline-earth metal borate with a deep-UV cut-off edge50Ca3Na4LiBe4B10O24F: A New Beryllium Borate with a Unique Beryl Borate ∞2[Be8B16O40F2] Layer Intrabridged by [B12O24] Groups20Ba 7 (BO 3 ) 3 GeO 4 X (X = Cl, Br): borogermanate halides with rigid GeO 4 tetrahedra and flexible XBa 6 octahedra11Effect of cation substitution on structural transition: synthesis, characterization and theoretical studies of NaCa 4 B 3 O 9 , NaCaBO 3 , NaSrBO 3 and Li 4 CaB 2 O 618Synthesis, structures, and properties of two magnesium silicate fluorides Mg 5 (SiO 4 ) 2 F 2 and Mg 3 SiO 4 F 214Synthesis, Structures, and Luminescent Properties of Three Alkaline Earth Metal‐based MOFs Assembled from 3‐(3‐Carboxyphenoxy) Phthalic Acid Ligand8Na8MB21O36 (M = Rb and Cs): Noncentrosymmetric Borates with Unprecedented [B21O36]9– Fundamental Building Blocks36A novel mixed-metal borate with large [B12O18(OH)6]6- motif: Synthesis, structure and property5BaBOF 3 : a new aurivillius-like borate containing two types of F atoms32K 11 RbB 28 O 48 : a new triple-layered borate with an unprecedented [B 28 O 57 ] fundamental building block19The First Examples of Lithium‐Containing Mixed‐Alkali Strontium Borates with Different Dimensional Anionic Architectures and Short Cutoff Edges16Three Alumino/Galloborate Frameworks Templated by Organic Amines: Syntheses, Structures, and Nonlinear Optical Properties23The structure and classification of complex borates43Li 2 Na 2 [B 12 O 19 (OH) 2 ]: a new open framework borate with a pcu-type net constructed from large cyclic dodeca-oxoboron units8Sr[B(OH) 4 ](IO 3 ) and Li 4 Sr 5 [B 12 O 22 (OH) 4 ](IO 3 ) 2 : two unprecedented metal borate-iodates showing a subtle balance of enlarged band gap and birefringence34Four new deep ultraviolet borates with isolated B12O24 groups: Synthesis, structure, and optical properties9Synthesis, characterization, and theoretical analysis of three new nonlinear optical materials K7MRE2B15O30 (M= Ca and Ba, RE= La and Bi)28Second-order nonlinear optical-active selenide borate Zn8Se2(BO2)12: Experimental and theoretical analysis9Cs 2 AlB 5 O 10 : a short-wavelength nonlinear optical crystal with moderate second harmonic generation response12Five new rubidium borates with 0D clusters, 1D chains, 2D layers and 3D frameworks15M(B(SeO 3 ) 3 )H 2 O (M = Al, Ga): the first boroselenites with a unique sandwich like double-layer structure9Three mixed-alkaline-metal borates with {Li@B 12 O x (OH) 24− x } ( x = 18, 22) clusters: from isolated oxoboron cluster to unusual layer11Identical in Formula but Not Isotypic in Configuration: Discovery of a New Highly Polymerized [B12O24] Cluster in Cs3AlB6O1212Mechanochemical Synthesis of Zinc Borate for Use as a Dual-Release B Fertilizer11Sr 3 B 14 O 24 : a new borate with a [B 14 O 30 ] fundamental building block and an unwonted 2D double layer11Li 6.58 Na 7.43 Sr 4 (B 9 O 18 )(B 12 O 24 )Cl: unprecedented combination of the largest two highly polymerized isolated B–O clusters with novel isolated B 9 O 18 FBB18Design of New Borates with Deep Ultraviolet Transparency Inspired by the Flexibility of Unusual Triple-Layered Frameworks3Data Mining and Graph Network Deep Learning for Band Gap Prediction in Crystalline Borate Materials18Three Polyborates with High-Symmetry [B12O24] Units Featuring Different Dimensions of Anion Groups8Acid Post-Treatment Triggered High-Efficiency Blue-Emitting LiNa2Sr8B12O24F6Cl:Eu2+ Phosphors toward Multipurpose LED Applications0LiNa2Ca8B12O24F6Cl and Li1.2Na2.8B6O11: A Case of Cation-Induced Birefringence Enhancement via Dimensional Changes of Highly Polymerized [B12O24] Motifs10CO2-Promoted Assembly of Nonplanar B12O24-Ring as a Fundamental Building Block in Lithium–Sodium Alkali Borates during Carbon Capture0Achieving record-high birefringence in a 3D fluorozincoborate via coplanar alignment of π-conjugated [BO 3 ] units0BaScSi2O6F: A barium-containing rare-earth metal silicate fluoride with a short cutoff edge0FBB-directed open framework evolution in alkali metal borates: Synthesis and structure property relationships of NaRb2B9O150

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  1. Ba 2 B 10 O 17 : a new centrosymmetric alkaline-earth metal borate with a deep-UV cut-off edge

    Dalton Transactions · 2014-01-01

    Lili Liu, Xin Su, Yun Mo Yang, Shilie Pan, Xiaoyu Dong, Shujuan Han, Min Zhang, Jing Kang, Zhihua Yang

    Read original paper ↗ ·

  2. Ca3Na4LiBe4B10O24F: A New Beryllium Borate with a Unique Beryl Borate ∞2[Be8B16O40F2] Layer Intrabridged by [B12O24] Groups

    Inorganic Chemistry · 2014-08-01

    Siyang Luo, Wenjiao Yao, Pifu Gong, Jiyong Yao, Zheshuai Lin, Chuangtian Chen

    Read original paper ↗ ·

  3. Ba 7 (BO 3 ) 3 GeO 4 X (X = Cl, Br): borogermanate halides with rigid GeO 4 tetrahedra and flexible XBa 6 octahedra

    RSC Advances · 2015-01-01

    Ming Wen, Zhipeng Lian, Hongping Wu, Xin Su, Qingfeng Yan, Juanjuan Lu, Zhihua Yang, Shilie Pan

    Read original paper ↗ ·

  4. Effect of cation substitution on structural transition: synthesis, characterization and theoretical studies of NaCa 4 B 3 O 9 , NaCaBO 3 , NaSrBO 3 and Li 4 CaB 2 O 6

    Physical Chemistry Chemical Physics · 2015-01-01

    Yun Mo Yang, Xin Su, Shilie Pan, Zhihua Yang

    Read original paper ↗ ·

  5. Synthesis, structures, and properties of two magnesium silicate fluorides Mg 5 (SiO 4 ) 2 F 2 and Mg 3 SiO 4 F 2

    New Journal of Chemistry · 2015-01-01

    Ni Zhen, Kui Wu, Qiang Li, Shilie Pan, Wenhui Gao, Zhihua Yang

    Read original paper ↗ ·

  6. Synthesis, Structures, and Luminescent Properties of Three Alkaline Earth Metal‐based MOFs Assembled from 3‐(3‐Carboxyphenoxy) Phthalic Acid Ligand

    Zeitschrift für anorganische und allgemeine Chemie · 2015-11-18

    Runping Ye, Jin‐Xia Yang, Xin Zhang, Yuan‐Gen Yao

    Read original paper ↗ ·

  7. Na8MB21O36 (M = Rb and Cs): Noncentrosymmetric Borates with Unprecedented [B21O36]9– Fundamental Building Blocks

    Inorganic Chemistry · 2017-04-24

    Miriding Mutailipu, Min Zhang, Xin Su, Zhihua Yang, Shilie Pan

    Read original paper ↗ ·

  8. A novel mixed-metal borate with large [B12O18(OH)6]6- motif: Synthesis, structure and property

    Solid State Sciences · 2017-11-14

    Li Wei, Jie Pan, Zhen‐Zhen Xue, Guo‐Ming Wang, Yingxia Wang

    Read original paper ↗ ·

  9. BaBOF 3 : a new aurivillius-like borate containing two types of F atoms

    Dalton Transactions · 2018-01-01

    Dequan Jiang, Ying Wang, Hao Li, Zhihua Yang, Shilie Pan

    Read original paper ↗ ·

  10. K 11 RbB 28 O 48 : a new triple-layered borate with an unprecedented [B 28 O 57 ] fundamental building block

    Dalton Transactions · 2018-01-01

    Dequan Jiang, Ying Wang, Bingbing Zhang, Guopeng Han, Zhihua Yang, Shilie Pan

    Read original paper ↗ ·

  11. The First Examples of Lithium‐Containing Mixed‐Alkali Strontium Borates with Different Dimensional Anionic Architectures and Short Cutoff Edges

    Chemistry - A European Journal · 2018-08-07

    Ruru Ma, Yun Mo Yang, Cong Hu, Zhihua Yang, Shilie Pan

    Read original paper ↗ ·

  12. Three Alumino/Galloborate Frameworks Templated by Organic Amines: Syntheses, Structures, and Nonlinear Optical Properties

    Inorganic Chemistry · 2018-10-10

    Lin Cheng, Guo‐Yu Yang

    Read original paper ↗ ·

  13. The structure and classification of complex borates

    Russian Chemical Reviews · 2018-10-25

    Anastasiya P. Topnikova, Elena L. Belokoneva

    Read original paper ↗ ·

  14. Li 2 Na 2 [B 12 O 19 (OH) 2 ]: a new open framework borate with a pcu-type net constructed from large cyclic dodeca-oxoboron units

    CrystEngComm · 2019-01-01

    Bei-Bei Han, Jian‐Wen Cheng, Guo‐Yu Yang

    Read original paper ↗ ·

  15. Sr[B(OH) 4 ](IO 3 ) and Li 4 Sr 5 [B 12 O 22 (OH) 4 ](IO 3 ) 2 : two unprecedented metal borate-iodates showing a subtle balance of enlarged band gap and birefringence

    Chemical Communications · 2019-01-01

    Guang Peng, Chensheng Lin, Dan Zhao, Liling Cao, Huixin Fan, Kaichuang Chen, Ning Ye

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  16. Four new deep ultraviolet borates with isolated B12O24 groups: Synthesis, structure, and optical properties

    Journal of Solid State Chemistry · 2019-02-28

    Tuohetijiang Baiheti, Shujuan Han, B. Bashir, Zhihua Yang, Y. Wang, Hongwei Yu, Shilie Pan

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  17. Synthesis, characterization, and theoretical analysis of three new nonlinear optical materials K7MRE2B15O30 (M= Ca and Ba, RE= La and Bi)

    Science China Materials · 2019-03-22

    Zhiqing Xie, Ying Wang, Shichao Cheng, Guopeng Han, Zhihua Yang, Shilie Pan

    Read original paper ↗ ·

  18. Second-order nonlinear optical-active selenide borate Zn8Se2(BO2)12: Experimental and theoretical analysis

    Journal of Solid State Chemistry · 2020-07-18

    Wenfeng Zhou, Xiaohui Li, Wen‐Dong Yao, Huaiguo Xue, Sheng‐Ping Guo

    Read original paper ↗ ·

  19. Cs 2 AlB 5 O 10 : a short-wavelength nonlinear optical crystal with moderate second harmonic generation response

    Dalton Transactions · 2020-12-10

    Tuohetijiang Baiheti, Shujuan Han, Wenqi Jin, Zhihua Yang, Shilie Pan

    Read original paper ↗ ·

  20. Five new rubidium borates with 0D clusters, 1D chains, 2D layers and 3D frameworks

    CrystEngComm · 2021-01-01

    Qi–Ming Qiu, Kening Sun, Guo‐Yu Yang

    Read original paper ↗ ·

  21. M(B(SeO 3 ) 3 )H 2 O (M = Al, Ga): the first boroselenites with a unique sandwich like double-layer structure

    Dalton Transactions · 2021-01-01

    Ming‐Yang Cao, Chun‐Li Hu, Fang Kong, Zheyao Xiong, Jiang‐Gao Mao

    Read original paper ↗ ·

  22. Three mixed-alkaline-metal borates with {Li@B 12 O x (OH) 24− x } ( x = 18, 22) clusters: from isolated oxoboron cluster to unusual layer

    CrystEngComm · 2021-01-01

    Qi–Ming Qiu, Guo‐Yu Yang

    Read original paper ↗ ·

  23. Identical in Formula but Not Isotypic in Configuration: Discovery of a New Highly Polymerized [B12O24] Cluster in Cs3AlB6O12

    Inorganic Chemistry · 2021-09-30

    Jun Sun, Xiaoquan Lu, Miriding Mutailipu, Shilie Pan

    Read original paper ↗ ·

  24. Mechanochemical Synthesis of Zinc Borate for Use as a Dual-Release B Fertilizer

    ACS Sustainable Chemistry & Engineering · 2021-11-15

    Bo Zheng, Shervin Kabiri, Ivan Anđelković, Fien Degryse, Rodrigo Coqui da Silva, Roslyn Baird, Peter G. Self, Mike John McLaughlin

    Read original paper ↗ ·

  25. Sr 3 B 14 O 24 : a new borate with a [B 14 O 30 ] fundamental building block and an unwonted 2D double layer

    Dalton Transactions · 2021-12-01

    Chengfa Wu, Zilong Chen, Jianbang Chen, Zhihua Yang, Fangfang Zhang, Hongsheng Shi, Shilie Pan

    Read original paper ↗ ·

  26. Li 6.58 Na 7.43 Sr 4 (B 9 O 18 )(B 12 O 24 )Cl: unprecedented combination of the largest two highly polymerized isolated B–O clusters with novel isolated B 9 O 18 FBB

    Inorganic Chemistry Frontiers · 2022-01-01

    Feixiang Wang, Yun Mo Yang, Congcong Jin, Shilie Pan

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  27. Design of New Borates with Deep Ultraviolet Transparency Inspired by the Flexibility of Unusual Triple-Layered Frameworks

    Crystal Growth & Design · 2022-06-13

    Yidan Chen, Tinghao Tong, Da‐Wei Fu

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  28. Data Mining and Graph Network Deep Learning for Band Gap Prediction in Crystalline Borate Materials

    Inorganic Chemistry · 2023-03-08

    Ruihan Wang, Yeshuang Zhong, Xuehua Dong, Meng Du, Haolun Yuan, Yurong Zou, Xin Wang, Zhien Lin, Dingguo Xu

    Read original paper ↗ ·

  29. Three Polyborates with High-Symmetry [B12O24] Units Featuring Different Dimensions of Anion Groups

    ACS Omega · 2023-06-02

    Yu Dang, Jingdong Yan, Xueling Hou, Hongsheng Shi

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  30. Acid Post-Treatment Triggered High-Efficiency Blue-Emitting LiNa2Sr8B12O24F6Cl:Eu2+ Phosphors toward Multipurpose LED Applications

    Industrial & Engineering Chemistry Research · 2024-08-05

    Zhihua Leng, Hongbo He, Hanyue Zhang, Lei Chen, Fang Song, Zuobin Tang, Liping Li

    Read original paper ↗ ·

  31. LiNa2Ca8B12O24F6Cl and Li1.2Na2.8B6O11: A Case of Cation-Induced Birefringence Enhancement via Dimensional Changes of Highly Polymerized [B12O24] Motifs

    Inorganic Chemistry · 2024-08-21

    Ziting Yan, Jinbin Fan, Dongdong Chu, Zhihua Yang, Juanjuan Lu, Shilie Pan, Min Zhang

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  32. CO2-Promoted Assembly of Nonplanar B12O24-Ring as a Fundamental Building Block in Lithium–Sodium Alkali Borates during Carbon Capture

    Inorganic Chemistry · 2025-04-18

    David Unnervik, Takuya Harada

    Read original paper ↗ ·

  33. Achieving record-high birefringence in a 3D fluorozincoborate via coplanar alignment of π-conjugated [BO 3 ] units

    Inorganic Chemistry Frontiers · 2026-01-01

    Yucheng Hao, Qiuhui Zhang, Haoran Yu, Xikai Miu, Simin Cai, Xinnan Li, Fengshan Yu, Yuan Lin, Mingyang Cao

    Read original paper ↗ ·

  34. BaScSi2O6F: A barium-containing rare-earth metal silicate fluoride with a short cutoff edge

    Journal of Molecular Structure · 2026-01-15

    Xiya Wen, Tingwen Han, Yali Cao, Yun Yang

    Read original paper ↗ ·

  35. FBB-directed open framework evolution in alkali metal borates: Synthesis and structure property relationships of NaRb2B9O15

    Journal of Molecular Structure · 2026-10-03

    Mengyang Jiao, Jiaxing Wei, Jianji Yao, Xifa Long, Yun Yang

    Read original paper ↗ ·
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