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RESEARCH PAPER · Dalton Transactions · 2014

Exploration of new second-order nonlinear optical materials of the Cs–Hg–Br–I system

Qi Wu, Yin Huang, Xiang‐Gao Meng, Cheng Zhong, Xingguo Chen, Jingui Qin

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Exploration of new second-order nonlinear optical materials of the Cs–Hg–Br–I systemOriginalDevelopment of nonlinear optical materials promoted by density functional theory simulations32Na 2 ZnGe 2 S 6 : A New Infrared Nonlinear Optical Material with Good Balance between Large Second-Harmonic Generation Response and High Laser Damage Threshold302Crystalline Mixed Halide Halobismuthates and Their Induced Second Harmonic Generation63Recent achievements on middle and far-infrared second-order nonlinear optical materials433Selective enhancement of optical nonlinearity in two-dimensional organic-inorganic lead iodide perovskites193Absorption and Mid-IR SHG in Two-Dimensional Halogen and Hydrogen Saturated Silicene Series12Synthesis, crystal and electronic structures and optical properties of (HIm)2Hg3Cl8 and (HIm)HgI3 (HIm = imidazolium)13Structural insights into T 2 -cluster-containing chalcogenides with vertex-, edge- and face-sharing connection modes of NaQ 6 ligands: Na 3 ZnM III Q 4 (M III = In, Ga; Q = S, Se)13Second-order nonlinear optical crystals with mixed anions250Synthesis, crystal structures and nonlinear optical properties of polymorphism: α- and β-RbHgI3·H2O18Recent advances and future perspectives on infrared nonlinear optical metal halides223Synthesis, crystal structures and nonlinear optical properties of β-RbCdI 3 ·H 2 O and CsCdI 3 ·H 2 O8Two-dimensional nonlinear optical materials predicted by network visualization14[Ge2S5(S2)]4−, A NLO‐Active Unit Leading to an Asymmetric Structure Discovered in Li2Cs4Ge2S5(S2)Cl2: An Experimental and Theoretical study18Mixed-Anion Inorganic Compounds: A Favorable Candidate for Infrared Nonlinear Optical Materials140From BiF 3 to BiF 3 ·H 2 O: diverse Bi( iii ) coordination for structural transformation and birefringence regulation14A Series of Organic–Inorganic Hybrid Compounds [(C2H5)4N]InCl4–xBrx (x = 0, 2, 4): Synthesis, Crystal Structure, and Nonlinear Optical Properties37Dimensionality–Band Gap–Third-Harmonic Generation Property Relationship in Novel Main-Group Metal Iodates37Structure-property survey and computer-assisted screening of mid-infrared nonlinear optical chalcohalides114SrZnSnSe4: Synthesis, crystal structure and nonlinear optical properties14Acentric Organic–Inorganic Hybrid Halide [N(CH3)4]2HgBr2I2 Featuring an Isolated [HgBr2I2]2– Tetrahedron and Second-Order Nonlinearity18Frequency Down-Conversion of Optical Pulse to the Far Infrared and THz Frequency Ranges Due to the Cascading Process in a Medium with a Quadratic Nonlinear Response2Mid-Infrared Nonlinear Optical Halides with Diamond-like Structures: A Theoretical and Experimental Study44γ-P 4 S 3 I 2 : a new metal-free infrared second-order nonlinear optical crystal designed by polymorphism strategy17Inherent law of SHG and phase-matching in 0D NLO materials: Permutation tetra-coordinated groups2β -CsHg 2 I 5 , a compound with rare [Hg 2 I 5 ] dimers and large optical anisotropy2Designing Zero-Dimensional Cadmium-Based Organic–Inorganic Hybrids: The Role of Halogen Doping in Modulating Multifunctional Properties9Novel antimony-based mixed halides exhibiting an excellent SHG response and a broad transmission range20(NH 4 ) 2 Cd 2 Cl 3 F 3 and (NH 4 ) 2 Cd 2 Br 3 F 3 : The First Fluoride‐Containing d 10 Metal Mixed Halides Exhibiting Superior Ultraviolet Nonlinear Optical Properties29Halogen-Driven Structural Engineering in Tellurium Oxyhalides: Enhanced SHG Response and Broad Optical Transparency6Planar [HgCl 3 ] and V‑Shaped [HgCl 2 ] Units Synergistically Creating a Prominent Halide Birefringent Crystal β ‐CsHg 2 Cl 5 with Wide‐Spectrum7Water Molecule-Driven Structural Evolution from Na2ZnCl4 to Na2ZnCl4·3H2O: A Route to Promising Deep-UV Nonlinear Optical Crystals0Strategic Integration Between Trigonal Architecture Construction and Molecular Polarization Enhancement for Record SHG Effect in Selenates4Strategic Integration Between Trigonal Architecture Construction and Molecular Polarization Enhancement for Record SHG Effect in Selenates0Molecular Dipole Engineering in Layered Perovskite Ferroelectrics Enables Large Rashba-Dresselhaus Spin Splitting and Persistent Spin Texture for UV Circularly Polarized Light Detection6

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  1. Development of nonlinear optical materials promoted by density functional theory simulations

    International Journal of Modern Physics B · 2014-10-30

    Xingxing Jiang, Lei Kang, Siyang Luo, Pifu Gong, Ming‐Hsien Lee, Zheshuai Lin

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  2. Na 2 ZnGe 2 S 6 : A New Infrared Nonlinear Optical Material with Good Balance between Large Second-Harmonic Generation Response and High Laser Damage Threshold

    Journal of the American Chemical Society · 2016-05-19

    Guangmao Li, Kui Wu, Qiong Liu, Zhihua Yang, Shilie Pan

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  3. Crystalline Mixed Halide Halobismuthates and Their Induced Second Harmonic Generation

    Chemistry of Materials · 2016-05-20

    Xiaoxin Zheng, Yang Liu, Guangfeng Liu, Jie Liu, Xin Ye, Quanxiang Han, Chao Ge, Xutang Tao

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  4. Recent achievements on middle and far-infrared second-order nonlinear optical materials

    Coordination Chemistry Reviews · 2016-12-27

    Sheng‐Ping Guo, Yang Chi, Guo‐Cong Guo

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  5. Selective enhancement of optical nonlinearity in two-dimensional organic-inorganic lead iodide perovskites

    Nature Communications · 2017-09-25

    Felix O. Saouma, Constantinos C. Stoumpos, J. Wong, Mercouri G. Kanatzidis, Joon Ik Jang

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  6. Absorption and Mid-IR SHG in Two-Dimensional Halogen and Hydrogen Saturated Silicene Series

    The Journal of Physical Chemistry C · 2017-11-14

    Guoyu Yang, Kechen Wu

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  7. Synthesis, crystal and electronic structures and optical properties of (HIm)2Hg3Cl8 and (HIm)HgI3 (HIm = imidazolium)

    Journal of Solid State Chemistry · 2017-11-23

    Hariharan Nhalil, Vincent R. Whiteside, Ian Roberts Sellers, Wenmei Ming, Mao‐Hua Du, Bayrammurad Saparov

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  8. Structural insights into T 2 -cluster-containing chalcogenides with vertex-, edge- and face-sharing connection modes of NaQ 6 ligands: Na 3 ZnM III Q 4 (M III = In, Ga; Q = S, Se)

    Dalton Transactions · 2018-01-01

    Ruijiao Chen, Xiaowen Wu, Zhi Su

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  9. Second-order nonlinear optical crystals with mixed anions

    Coordination Chemistry Reviews · 2018-08-06

    Yu Pan, Sheng‐Ping Guo, Bin‐Wen Liu, Huaiguo Xue, Guo‐Cong Guo

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  10. Synthesis, crystal structures and nonlinear optical properties of polymorphism: α- and β-RbHgI3·H2O

    Journal of Alloys and Compounds · 2018-09-04

    Ling Huang, Qian Wang, Fangfang He, Xiaoyan Liu, Ziwei Chen, Wen Jun He, Xueying Luo, Daojiang Gao, Jian Bi, Guohong Zou

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  11. Recent advances and future perspectives on infrared nonlinear optical metal halides

    Coordination Chemistry Reviews · 2018-10-23

    Pifu Gong, Fei Liang, Lei Kang, Xingguo Chen, Jingui Qin, Yicheng Wu, Zheshuai Lin

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  12. Synthesis, crystal structures and nonlinear optical properties of β-RbCdI 3 ·H 2 O and CsCdI 3 ·H 2 O

    Dalton Transactions · 2019-01-01

    Qi Wu, Xian Liu, Siran Xu, Hongbing Pi, Xue Han, Yang Liu, Yanjun Li

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  13. Two-dimensional nonlinear optical materials predicted by network visualization

    Molecular Systems Design & Engineering · 2019-01-01

    Guoyu Yang, Kechen Wu

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  14. [Ge2S5(S2)]4−, A NLO‐Active Unit Leading to an Asymmetric Structure Discovered in Li2Cs4Ge2S5(S2)Cl2: An Experimental and Theoretical study

    Chemistry - A European Journal · 2019-03-06

    Guangmao Li, Kui Wu, Yi Huang, Zhihua Yang, Shilie Pan

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  15. Mixed-Anion Inorganic Compounds: A Favorable Candidate for Infrared Nonlinear Optical Materials

    Crystal Growth & Design · 2019-06-07

    Yanyan Li, Wenjing Wang, Hui Wang, Hua Lin, Li‐Ming Wu

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  16. From BiF 3 to BiF 3 ·H 2 O: diverse Bi( iii ) coordination for structural transformation and birefringence regulation

    CrystEngComm · 2020-01-01

    Xian Liu, Can Yang, Qi Wu, Juan Sun, Fei Liang

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  17. A Series of Organic–Inorganic Hybrid Compounds [(C2H5)4N]InCl4–xBrx (x = 0, 2, 4): Synthesis, Crystal Structure, and Nonlinear Optical Properties

    Inorganic Chemistry · 2020-04-01

    Xian Liu, Wenli Xu, Siran Xu, Xin‐Yao Yu, Yuqing Deng, Xiaohui Wu, Fei Liang, Qi Wu

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  18. Dimensionality–Band Gap–Third-Harmonic Generation Property Relationship in Novel Main-Group Metal Iodates

    Chemistry of Materials · 2020-04-07

    Geonju Park, Hye Ryung Byun, Joon Ik Jang, Kang Min Ok

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  19. Structure-property survey and computer-assisted screening of mid-infrared nonlinear optical chalcohalides

    Coordination Chemistry Reviews · 2020-07-13

    Le Gao, Junben Huang, Siru Guo, Zhihua Yang, Shilie Pan

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  20. SrZnSnSe4: Synthesis, crystal structure and nonlinear optical properties

    Journal of Solid State Chemistry · 2021-02-26

    Xin Pang, Ruiqi Wang, Xiangli Che, Fuqiang Huang

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  21. Acentric Organic–Inorganic Hybrid Halide [N(CH3)4]2HgBr2I2 Featuring an Isolated [HgBr2I2]2– Tetrahedron and Second-Order Nonlinearity

    Inorganic Chemistry · 2021-04-22

    Can Yang, Xian Liu, Chunlin Teng, Qi Wu, Fei Liang

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  22. Frequency Down-Conversion of Optical Pulse to the Far Infrared and THz Frequency Ranges Due to the Cascading Process in a Medium with a Quadratic Nonlinear Response

    Applied Sciences · 2022-04-12

    Vyacheslav A. Trofimov, Dmitry M. Kharitonov, Mikhail V. Fedotov, Yongqiang Yang

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  23. Mid-Infrared Nonlinear Optical Halides with Diamond-like Structures: A Theoretical and Experimental Study

    Chemistry of Materials · 2022-05-16

    Pifu Gong, Fei Liang, Lei Kang, Zheshuai Lin

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  24. γ-P 4 S 3 I 2 : a new metal-free infrared second-order nonlinear optical crystal designed by polymorphism strategy

    Inorganic Chemistry Frontiers · 2022-12-19

    Xin Lei Zhao, Chensheng Lin, Shunda Yang, Haotian Tian, Chao Wang, Tao Yan, Jian Zhang, Bingxuan Li, Ning Ye, Min Luo

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  25. Inherent law of SHG and phase-matching in 0D NLO materials: Permutation tetra-coordinated groups

    Journal of Solid State Chemistry · 2023-05-19

    Chaoyi Zhu, Dajiang Mei, Yuandong Wu

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  26. β -CsHg 2 I 5 , a compound with rare [Hg 2 I 5 ] dimers and large optical anisotropy

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  27. Designing Zero-Dimensional Cadmium-Based Organic–Inorganic Hybrids: The Role of Halogen Doping in Modulating Multifunctional Properties

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  28. Novel antimony-based mixed halides exhibiting an excellent SHG response and a broad transmission range

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  29. (NH 4 ) 2 Cd 2 Cl 3 F 3 and (NH 4 ) 2 Cd 2 Br 3 F 3 : The First Fluoride‐Containing d 10 Metal Mixed Halides Exhibiting Superior Ultraviolet Nonlinear Optical Properties

    Advanced Science · 2025-01-28

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  30. Halogen-Driven Structural Engineering in Tellurium Oxyhalides: Enhanced SHG Response and Broad Optical Transparency

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  31. Planar [HgCl 3 ] and V‑Shaped [HgCl 2 ] Units Synergistically Creating a Prominent Halide Birefringent Crystal β ‐CsHg 2 Cl 5 with Wide‐Spectrum

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  32. Water Molecule-Driven Structural Evolution from Na2ZnCl4 to Na2ZnCl4·3H2O: A Route to Promising Deep-UV Nonlinear Optical Crystals

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  33. Strategic Integration Between Trigonal Architecture Construction and Molecular Polarization Enhancement for Record SHG Effect in Selenates

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  34. Strategic Integration Between Trigonal Architecture Construction and Molecular Polarization Enhancement for Record SHG Effect in Selenates

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  35. Molecular Dipole Engineering in Layered Perovskite Ferroelectrics Enables Large Rashba-Dresselhaus Spin Splitting and Persistent Spin Texture for UV Circularly Polarized Light Detection

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