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RESEARCH PAPER · Journal of the American Chemical Society · 2010

Yb3O(OH)6Cl·2H2O: An Anion-Exchangeable Hydroxide with a Cationic Inorganic Framework Structure

Helen V. Goulding, Sarah E. Hulse, W. Clegg, Ross W. Harrington, Helen Y. Playford, Richard I. Walton, Andrew M. Fogg

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Yb3O(OH)6Cl·2H2O: An Anion-Exchangeable Hydroxide with a Cationic Inorganic Framework StructureOriginalChemInform Abstract: Yb3O(OH)6Cl·2H2O: An Anion‐Exchangeable Hydroxide with a Cationic Inorganic Framework Structure.1New compounds and structures in the solid state0Recent progress in actinide borate chemistry94Reversible single crystal to single crystal transformation with anion exchange-induced weak Cu2+⋯I− interactions and modification of the structures and properties of MOFs84A New Paradigm for Anion Trapping in High Capacity and Selectivity: Crystal-to-Crystal Transformation of Cationic Materials279Copper Hydroxide Ethanedisulfonate: A Cationic Inorganic Layered Material for High‐Capacity Anion Exchange64Copper Hydroxide Ethanedisulfonate: A Cationic Inorganic Layered Material for High‐Capacity Anion Exchange15Synthesis and characterization of layered double hydroxides intercalated with sugar phosphates7Well-defined crystallites autoclaved from the nitrate/NH4OH reaction system as the precursor for (Y,Eu)2O3 red phosphor: Crystallization mechanism, phase and morphology control, and luminescent property42Temperature-Controlled Electrochemical Switch Based on Layered Double Hydroxide/Poly(N-Isopropylacrylamide) Ultrathin Films Fabricated via Layer-by-Layer Assembly68A Cationic Antimonite Chain Templated by Sulfate: [Sb6O74+][(SO42–)2]9Cerium(IV) Tellurite Halides [Ce2Te7O17]X2 (X = Cl– or Br–): The First Cerium-Containing Cationic Frameworks30Unusual Coordination for Plutonium(IV), Cerium(IV), and Zirconium(IV) in the Cationic Layered Materials [M2Te4O11]X2 (M = Pu, Ce, Zr; X = Cl, Br)29Lanthanide-Porphyrin Hybrids: from Layered Structures to Metal–Organic Frameworks with Photophysical Properties81Synthesis and characterisation of a new anion exchangeable layered hydroxyiodide4New layered double hydroxides by prepared by the intercalation of gibbsite13Synthesis, crystal structure, fluorescence and antimicrobial activity of a series of rare-earth complexes based on indolebutyric acid12Erbium Hydroxide Ethanedisulfonate: A Cationic Layered Material with Organic Anion Exchange Capability15Applications of Supramolecular Anion Recognition1249Boosting Proton Conductivity in Highly Robust 3D Inorganic Cationic Extended Frameworks through Ion Exchange with Dihydrogen Phosphate Anions19First Cationic Uranyl–Organic Framework with Anion-Exchange Capabilities101Two-Dimensional Inorganic Cationic Network of Thorium Iodate Chloride with Unique Halogen–Halogen Bonds8Exfoliation of a two-dimensional cationic inorganic network as a new paradigm for high-capacity Cr VI -anion capture42Two-step crystallization of a phase-pure Ln 2 (OH) 5 NO 3 ·nH 2 O layered compound for the smallest Ln ions of Tm, Yb and Lu, anion exchange, and exfoliation16Efficient and Selective Uptake of TcO 4 – by a Cationic Metal–Organic Framework Material with Open Ag + Sites415Exceptional Perrhenate/Pertechnetate Uptake and Subsequent Immobilization by a Low-Dimensional Cationic Coordination Polymer: Overcoming the Hofmeister Bias Selectivity217Selenium Sequestration in a Cationic Layered Rare Earth Hydroxide: A Combined Batch Experiments and EXAFS Investigation118Identifying the Recognition Site for Selective Trapping of 99TcO4– in a Hydrolytically Stable and Radiation Resistant Cationic Metal–Organic Framework500Ultrastable, cationic three-dimensional lead bromide frameworks that intrinsically emit broadband white-light73Design and synthesis of metal hydroxide three-dimensional inorganic cationic frameworks1Rapid and selective capture of perrhenate anion from simulated groundwater by a mesoporous silica-supported anion exchanger90Anion coordination chemistry using O–H groups60Mechanism unravelling for ultrafast and selective 99 TcO 4 − uptake by a radiation-resistant cationic covalent organic framework: a combined radiological experiment and molecular dynamics simulation study274Metal-organic frameworks for recognition and sequestration of toxic anionic pollutants9Y 8 O(OH) 15 (CO 3 ) 3 Cl: an excellent short-wave UV nonlinear optical material exhibiting an infrequent three-dimensional inorganic cationic framework61Successful Decontamination of 99 TcO 4 − in Groundwater at Legacy Nuclear Sites by a Cationic Metal‐Organic Framework with Hydrophobic Pockets48Successful Decontamination of 99TcO4− in Groundwater at Legacy Nuclear Sites by a Cationic Metal‐Organic Framework with Hydrophobic Pockets267Separation and Remediation of 99TcO4– from Aqueous Solutions165Microporous silica-supported cation exchanger with superior dimensional stability and outstanding exchange kinetics, and its application in element removal and enrichment13Hexadecylpyridinium (HDPy) modified bentonite for efficient and selective removal of 99Tc from wastewater47A Layered Cationic Aluminum Oxyhydroxide as a Highly Efficient and Selective Trap for Heavy Metal Oxyanions45A Layered Cationic Aluminum Oxyhydroxide as a Highly Efficient and Selective Trap for Heavy Metal Oxyanions6A Water-Stable Cationic Metal–Organic Framework with Hydrophobic Pore Surfaces as an Efficient Scavenger of Oxo-Anion Pollutants from Water8199TcO4− removal from legacy defense nuclear waste by an alkaline-stable 2D cationic metal organic framework223Highly efficient and selective capture of TcO4− or ReO4− by imidazolium-based ionic liquid polymers94Task-Specific Tailored Cationic Polymeric Network with High Base-Resistance for Unprecedented 99TcO4– Cleanup from Alkaline Nuclear Waste172Constructing Cationic Metal–Organic Framework Materials Based on Pyrimidyl as a Functional Group for Perrhenate/Pertechnetate Sorption44Water-stable metal–organic framework–based nanomaterials for removal of heavy metal ions and radionuclides4Enhancing the Stability of Poly(Ionic Liquids)@Mofs@Cofs Via Core-Shell Protection Strategy for 99tco4− Sequestration0Two-Fold Interlocking Cationic Metal–Organic Framework Material with Exchangeable Chloride for Perrhenate/Pertechnetate Sorption30Convenient preparation of activated carbon modified phosphoric acid-activated geopolymer microspheres (C@PAAGMs) for the efficient adsorption of ReO4−: Implications for TcO4− elimination31Separation and purification of elements from alkaline and carbonate nuclear waste solutions24Solvothermal and hydrothermal methods for preparative solid-state chemistry5Enhancing the stability of poly(ionic liquids)@MOFs@COFs via core–shell protection strategy for 99 TcO 4 − sequestration15Effective strategies toward imine-linked cationic covalent organic frameworks for rapid and selective removal of 99 TcO 4 − from water: insights from DFT and MD calculations14Radiation synthesis of binary poly(ionic liquid) functionalized silica-based materials for selective adsorption of ReO 4 − as analogue of TcO 4 − from simulated radioactive wastewater6Molecular engineering of cationic polymer networks for enhanced 99TcO4−/ReO4− removal efficiency in extreme environments20Luminescence of rare earth 3D hydroxide framework Eu3+-doped and its application in dye adsorption tests2Layered rare-earth hydroxides: crystal engineering toward functional nanosheets9Nanomaterial Based Remediation of Radioactive Waste0Synthesis and performance of guanidinium-based cationic organic polymer for the efficient removal of TcO4-/ReO4-29Creation of Cationic Polymeric Nanotrap Featuring High Anion Density and Exceptional Alkaline Stability for Highly Efficient Pertechnetate Removal from Nuclear Waste Streams58Cation Framework Nanowires Enabling Composite Solid‐State Electrolyte with Anion Exchange Platform for Rapid Li + Conduction30Gram-scale green synthesis of a highly stable cationic covalent organic framework for efficient and selective removal of ReO 4 − / 99 TcO 4 −13Chemically Robust Cationic Porous Organic Polymer (POP) for Selective Detection and Removal of ReO4− as a Surrogate of Radioactive 99TcO4−10Robust copper-based cationic metal–organic frameworks for efficient sequestration of perrhenate/pertechnetate4Steric hindrance-enhanced adsorption of imidazolium-based COFs/PES beads for perrhenate removal0Rare Earth Oxohydroxyglycinates: The Possible Missing Link Between Rare Earth Oxides and Hydroxides0

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  1. ChemInform Abstract: Yb3O(OH)6Cl·2H2O: An Anion‐Exchangeable Hydroxide with a Cationic Inorganic Framework Structure.

    ChemInform · 2010-12-23

    Helen V. Goulding, Sarah E. Hulse, W. Clegg, Ross W. Harrington, Helen Y. Playford, Richard I. Walton, Andrew M. Fogg

    Read original paper ↗ ·

  2. New compounds and structures in the solid state

    Annual Reports Section A (Inorganic Chemistry) · 2011-01-01

    Edmund J. Cussen

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  3. Recent progress in actinide borate chemistry

    Chemical Communications · 2011-01-01

    Shuao Wang, Evgeny V. Alekseev, Wulf Depmeier, Thomas E. Albrecht‐Schmitt

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  4. Reversible single crystal to single crystal transformation with anion exchange-induced weak Cu2+⋯I− interactions and modification of the structures and properties of MOFs

    Chemical Communications · 2011-01-01

    Junhong Fu, Huijun Li, Yajuan Mu, Hongwei Hou, Yaoting Fan

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  5. A New Paradigm for Anion Trapping in High Capacity and Selectivity: Crystal-to-Crystal Transformation of Cationic Materials

    Journal of the American Chemical Society · 2011-06-27

    Honghan Fei, Marc R. Bresler, Scott R. J. Oliver

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  6. Copper Hydroxide Ethanedisulfonate: A Cationic Inorganic Layered Material for High‐Capacity Anion Exchange

    Angewandte Chemie International Edition · 2011-08-24

    Honghan Fei, Scott R. J. Oliver

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  7. Copper Hydroxide Ethanedisulfonate: A Cationic Inorganic Layered Material for High‐Capacity Anion Exchange

    Angewandte Chemie · 2011-08-24

    Honghan Fei, Scott R. J. Oliver

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  8. Synthesis and characterization of layered double hydroxides intercalated with sugar phosphates

    Journal of Physics and Chemistry of Solids · 2011-10-16

    Tom C. Jellicoe, Andrew M. Fogg

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  9. Well-defined crystallites autoclaved from the nitrate/NH4OH reaction system as the precursor for (Y,Eu)2O3 red phosphor: Crystallization mechanism, phase and morphology control, and luminescent property

    Journal of Solid State Chemistry · 2012-04-21

    Qi Zhu, Ji‐Guang Li, Renzhi Ma, Takayoshi Sasaki, Xiaojing Yang, Xiaodong Li, Xudong Sun, Yoshio Sakka

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  10. Temperature-Controlled Electrochemical Switch Based on Layered Double Hydroxide/Poly(N-Isopropylacrylamide) Ultrathin Films Fabricated via Layer-by-Layer Assembly

    Langmuir · 2012-05-31

    Yibo Dou, Jingbin Han, Tengli Wang, Min Wei, David G. Evans, Xue Duan

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  11. A Cationic Antimonite Chain Templated by Sulfate: [Sb6O74+][(SO42–)2]

    Inorganic Chemistry · 2012-07-30

    Honghan Fei, Cari S. Han, Scott R. J. Oliver

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  12. Cerium(IV) Tellurite Halides [Ce2Te7O17]X2 (X = Cl– or Br–): The First Cerium-Containing Cationic Frameworks

    Inorganic Chemistry · 2012-09-19

    Jian Hung Lin, Juan Diwu, Justin N. Cross, Eric M. Villa, Thomas E. Albrecht‐Schmitt

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  13. Unusual Coordination for Plutonium(IV), Cerium(IV), and Zirconium(IV) in the Cationic Layered Materials [M2Te4O11]X2 (M = Pu, Ce, Zr; X = Cl, Br)

    Inorganic Chemistry · 2012-10-17

    Jian Hung Lin, Justin N. Cross, Juan Diwu, Matthew J. Polinski, Eric M. Villa, Thomas E. Albrecht‐Schmitt

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  14. Lanthanide-Porphyrin Hybrids: from Layered Structures to Metal–Organic Frameworks with Photophysical Properties

    Inorganic Chemistry · 2013-02-20

    Jan Demel, Pavel Kubát, Franck Millange, Jérôme Marrot, Ivana Cı́sařová, Kamil Lang

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  15. Synthesis and characterisation of a new anion exchangeable layered hydroxyiodide

    Dalton Transactions · 2014-01-01

    Faye Y. Southworth, Claire Wilson, Simon John Coles, Andrew M. Fogg

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  16. New layered double hydroxides by prepared by the intercalation of gibbsite

    Journal of Solid State Chemistry · 2014-03-21

    Jennifer R. Rees, Chloe S. Burden, Andrew M. Fogg

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  17. Synthesis, crystal structure, fluorescence and antimicrobial activity of a series of rare-earth complexes based on indolebutyric acid

    RSC Advances · 2015-01-01

    Zhi‐Nan Wang, Xueting Xu, Xiao Lv, Feng‐Ying Bai, Shuqing Liu, Yong‐Heng Xing

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  18. Erbium Hydroxide Ethanedisulfonate: A Cationic Layered Material with Organic Anion Exchange Capability

    Inorganic Chemistry · 2015-04-07

    Kevin M. Sergo, Cari S. Han, Marc R. Bresler, Susan C. Citrak, Yashar Abdollahian, Honghan Fei, Scott R. J. Oliver

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  19. Applications of Supramolecular Anion Recognition

    Chemical Reviews · 2015-05-21

    Nathalie Busschaert, Claudia Caltagirone, Wim Van Rossom, Philip Alan Gale

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  20. Boosting Proton Conductivity in Highly Robust 3D Inorganic Cationic Extended Frameworks through Ion Exchange with Dihydrogen Phosphate Anions

    Chemistry - A European Journal · 2015-10-22

    Chengliang Xiao, Yaxing Wang, Lanhua Chen, Xuemiao Yin, Jie Shu, Daopeng Sheng, Zhifang Chai, Thomas E. Albrecht‐Schmitt, Shuao Wang

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  21. First Cationic Uranyl–Organic Framework with Anion-Exchange Capabilities

    Inorganic Chemistry · 2016-06-16

    Zhuanling Bai, Yanlong Wang, Yuxiang Li, Wei Liu, Lanhua Chen, Daopeng Sheng, Juan Diwu, Zhifang Chai, Thomas E. Albrecht‐Schmitt, Shuao Wang

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  22. Two-Dimensional Inorganic Cationic Network of Thorium Iodate Chloride with Unique Halogen–Halogen Bonds

    Inorganic Chemistry · 2016-08-05

    Huangjie Lu, Yaxing Wang, Cui Wang, Lanhua Chen, Wei‐Qun Shi, Juan Diwu, Zhifang Chai, Thomas E. Albrecht‐Schmitt, Shuao Wang

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  23. Exfoliation of a two-dimensional cationic inorganic network as a new paradigm for high-capacity Cr VI -anion capture

    Chemical Communications · 2017-01-01

    Huimin Yang, Honghan Fei

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  24. Two-step crystallization of a phase-pure Ln 2 (OH) 5 NO 3 ·nH 2 O layered compound for the smallest Ln ions of Tm, Yb and Lu, anion exchange, and exfoliation

    Dalton Transactions · 2017-01-01

    Ji‐Guang Li, Ji‐Guang Li, Jing Li, Jing Li, Xuejiao Wang, Qi Zhu, Xiaodong Li, Byung‐Nam Kim, Xudong Sun

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  25. Efficient and Selective Uptake of TcO 4 – by a Cationic Metal–Organic Framework Material with Open Ag + Sites

    Environmental Science & Technology · 2017-02-17

    Daopeng Sheng, Lin Hong Zhu, Chao Xu, Chengliang Xiao, Yanlong Wang, Yaxing Wang, Lanhua Chen, Juan Diwu, Jing Chen, Zhifang Chai, Thomas E. Albrecht‐Schmitt, Shuao Wang

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  26. Exceptional Perrhenate/Pertechnetate Uptake and Subsequent Immobilization by a Low-Dimensional Cationic Coordination Polymer: Overcoming the Hofmeister Bias Selectivity

    Environmental Science & Technology Letters · 2017-05-31

    Lin Hong Zhu, Chengliang Xiao, Xing Dai, Jie Li, Daxiang Gui, Daopeng Sheng, Lanhua Chen, Ruhong Zhou, Zhifang Chai, Thomas E. Albrecht‐Schmitt, Shuao Wang

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  27. Selenium Sequestration in a Cationic Layered Rare Earth Hydroxide: A Combined Batch Experiments and EXAFS Investigation

    Environmental Science & Technology · 2017-06-26

    Lin Hong Zhu, Linjuan Zhang, Jie Li, Duo Zhang, Lanhua Chen, Daopeng Sheng, Shitong Yang, Chengliang Xiao, Jian‐Qiang Wang, Zhifang Chai, Thomas E. Albrecht‐Schmitt, Shuao Wang

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  28. Identifying the Recognition Site for Selective Trapping of 99TcO4– in a Hydrolytically Stable and Radiation Resistant Cationic Metal–Organic Framework

    Journal of the American Chemical Society · 2017-10-07

    Lin Hong Zhu, Daopeng Sheng, Chao Xu, Xing Dai, Mark A. Silver, Jie Li, Peng Li, Yaxing Wang, Yanlong Wang, Lanhua Chen, Chengliang Xiao, Jing Chen, Ruhong Zhou, Chao Zhang, Omar K. Farha, Zhifang Chai, Thomas E. Albrecht‐Schmitt, Shuao Wang

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  29. Ultrastable, cationic three-dimensional lead bromide frameworks that intrinsically emit broadband white-light

    Chemical Science · 2017-12-19

    Chengdong Peng, Zewen Zhuang, Huimin Yang, Guiyang Zhang, Honghan Fei

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  30. Design and synthesis of metal hydroxide three-dimensional inorganic cationic frameworks

    Dalton Transactions · 2018-01-01

    Long Yuan, Keke Huang, Wenchun Feng, Baiyan Li, Changmin Hou, Kaiqi Ye, Xiaofeng Wu, Zhan Shi, Shan Wang, Shouhua Feng

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  31. Rapid and selective capture of perrhenate anion from simulated groundwater by a mesoporous silica-supported anion exchanger

    Microporous and Mesoporous Materials · 2018-07-23

    Lifeng Chen, Xiangbiao Yin, Qing Bo Yu, Siming Lu, Fanyue Meng, Shunyan Ning, Xinpeng Wang, Yuezhou Wei

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  32. Anion coordination chemistry using O–H groups

    Chemical Society Reviews · 2019-01-01

    Stephanie A. Boer, Émer M. Foyle, Chriso M. Thomas, Nicholas G. White

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  33. Mechanism unravelling for ultrafast and selective 99 TcO 4 − uptake by a radiation-resistant cationic covalent organic framework: a combined radiological experiment and molecular dynamics simulation study

    Chemical Science · 2019-01-01

    Linwei He, Shengtang Liu, Long Chen, Xing Dai, Jie Li, Mingxing Zhang, Fuyin Ma, Chao Zhang, Zaixing Yang, Ruhong Zhou, Zhifang Chai, Shuao Wang

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  34. Metal-organic frameworks for recognition and sequestration of toxic anionic pollutants

    Elsevier eBooks · 2019-01-01

    Aamod V. Desai, Shivani Sharma, Sujit K. Ghosh

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  35. Y 8 O(OH) 15 (CO 3 ) 3 Cl: an excellent short-wave UV nonlinear optical material exhibiting an infrequent three-dimensional inorganic cationic framework

    Chemical Communications · 2019-01-01

    Yiting Zhang, Ying Long, Xuehua Dong, Lei Wang, Ling Huang, Hongmei Zeng, Zhien Lin, Xin Wang, Guohong Zou

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  36. Successful Decontamination of 99 TcO 4 − in Groundwater at Legacy Nuclear Sites by a Cationic Metal‐Organic Framework with Hydrophobic Pockets

    Angewandte Chemie · 2019-02-14

    Daopeng Sheng, Lin Hong Zhu, Xing Dai, Chao Xu, Peng Li, Carolyn Isobel Pearce, Chengliang Xiao, Jing Chen, Ruhong Zhou, Tao Duan, Omar K. Farha, Zhifang Chai, Shuao Wang

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  37. Successful Decontamination of 99TcO4− in Groundwater at Legacy Nuclear Sites by a Cationic Metal‐Organic Framework with Hydrophobic Pockets

    Angewandte Chemie International Edition · 2019-02-14

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  38. Separation and Remediation of 99TcO4– from Aqueous Solutions

    Chemistry of Materials · 2019-05-22

    Chengliang Xiao, Afshin Khayambashi, Shuao Wang

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  39. Microporous silica-supported cation exchanger with superior dimensional stability and outstanding exchange kinetics, and its application in element removal and enrichment

    Reactive and Functional Polymers · 2019-06-05

    Xinpeng Wang, Zhenxiong Ye, Lifeng Chen, Qi Feng Zheng, Caocong Liu, Shunyan Ning, Afshin Khayambashi, Yuezhou Wei

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  40. Hexadecylpyridinium (HDPy) modified bentonite for efficient and selective removal of 99Tc from wastewater

    Chemical Engineering Journal · 2019-09-19

    Junqiang Yang, Keliang Shi, Xiaoqing Gao, Xiaolin Hou, Wangsuo Wu, Wei‐Qun Shi

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  41. A Layered Cationic Aluminum Oxyhydroxide as a Highly Efficient and Selective Trap for Heavy Metal Oxyanions

    Angewandte Chemie International Edition · 2020-05-11

    Pu Bai, Zhuoya Dong, Shuang Wang, Xiangyu Wang, Yue Li, Yunzheng Wang, Yanhang Ma, Wenfu Yan, Xiaodong Zou, Jihong Yu

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  42. A Layered Cationic Aluminum Oxyhydroxide as a Highly Efficient and Selective Trap for Heavy Metal Oxyanions

    Angewandte Chemie · 2020-05-11

    Pu Bai, Zhuoya Dong, Shuang Wang, Xiangyu Wang, Yue Li, Yunzheng Wang, Yanhang Ma, Wenfu Yan, Xiaodong Zou, Jihong Yu

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  43. A Water-Stable Cationic Metal–Organic Framework with Hydrophobic Pore Surfaces as an Efficient Scavenger of Oxo-Anion Pollutants from Water

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  44. 99TcO4− removal from legacy defense nuclear waste by an alkaline-stable 2D cationic metal organic framework

    Nature Communications · 2020-11-04

    Nan‐Nan Shen, Zaixing Yang, Shengtang Liu, Xing Dai, Chengliang Xiao, Kathryn M. L. Taylor-Pashow, Dien Li, Chuang Yang, Jie Li, Yugang Zhang, Mingxing Zhang, Ruhong Zhou, Zhifang Chai, Shuao Wang

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  45. Highly efficient and selective capture of TcO4− or ReO4− by imidazolium-based ionic liquid polymers

    Chemical Engineering Journal · 2020-11-20

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  46. Task-Specific Tailored Cationic Polymeric Network with High Base-Resistance for Unprecedented 99TcO4– Cleanup from Alkaline Nuclear Waste

    ACS Central Science · 2021-08-13

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  47. Constructing Cationic Metal–Organic Framework Materials Based on Pyrimidyl as a Functional Group for Perrhenate/Pertechnetate Sorption

    Inorganic Chemistry · 2021-10-13

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  48. Water-stable metal–organic framework–based nanomaterials for removal of heavy metal ions and radionuclides

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  49. Enhancing the Stability of Poly(Ionic Liquids)@Mofs@Cofs Via Core-Shell Protection Strategy for 99tco4− Sequestration

    SSRN Electronic Journal · 2022-01-01

    Zhengyi Di, Zhao‐Fei Liu, Hai‐Ruo Li, Zhong Liu, Cheng‐Peng Li

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  50. Two-Fold Interlocking Cationic Metal–Organic Framework Material with Exchangeable Chloride for Perrhenate/Pertechnetate Sorption

    Inorganic Chemistry · 2022-07-14

    Kang Kang, Lei Li, Meiyu Zhang, Xiaohe Miao, Lecheng Lei, Chengliang Xiao

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